Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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Is this Process Possible?

An inventor has devised a complicated non-flow process in which 1 mol of air is the working fluid. The net effects of the process are claimed to be: A change in state of air from 250$^{\circ}$C and ...
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17 views

Pressure components in a film

I am performing molecular-dynamics simulations of a polymer near a crystalline substrate (polymer film). I am comparing the mechanical properties in the film with the properties in the bulk polymer. ...
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31 views

Calculating The Change in Thermodynamic Potentials for Reversible Adiabatic Expansion of Real Gas

The question asks to find which quantities have a change of zero for the reversible adiabatic expansion of a real gas: Entropy, Enthalpy, Internal Energy, Helmholtz Energy, and Gibbs Energy. Change ...
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9 views

Calculating vapor quality in a two-phase region

I'm currently trying to find the vapour quality of a refrigerant in a two-phase region of cycle. I know $v_l$ and $v_g$, the specific volumes of the liquid and gas. I also know the temperature and ...
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22 views

Solution to a kinetic temperature problem

I have a particular equation that needs to be solved for the kinetic temperature of a stream of gas particles. If we let the kinetic temperature be designated by the letter x, the equation becomes, ...
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15 views

Callen's Second Postulate - Composite or Closed+Composite systems?

In section 1.9 of Callen's Thermodynamics he says: The single, all-encompassing problem of thermodynamics is the determination of the equilibrium state that eventually results after the removal of ...
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31 views

Robin boundary conditions for the heat equation

Consider a 3D channel with fluid or gas with walls $\Gamma_1$, inflow part $\Gamma_2$ and outflow part $\Gamma_3$. The temperature is described by the heat equation: $$ \frac{\partial T}{\partial t} ...
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23 views

maximun work in a reversible process

I often read maximum work done is by a reversible process. Shouldnt the more appropriate sensence should be maximum work done per unit of heat is maximum in a reversible process. ?
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40 views

Why can thermal shocks damage/break materials?

When an object is heated a lot and then brutally cooled down or vice-versa, it can crack or even break spectacularly. What happens inside that makes it do that? Is it only because the hot core swells ...
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14 views

final state when Saturated liquid-vapour mixture contained in a rigid tank is heated

I have this question: Determine the final state when a 2 kg of Saturated liquid-vapour mixture at 50 °C contained in a rigid tank is heated so that the it reaches a single phase for each of the case ...
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27 views

How does Brake specific fuel consumption vary with Brake mean effective pressure?

I'm aware that there is a certain relationship between brake specific fuel consumption (BSFC) and brake mean effective pressure (BMEP), but I am wondering if someone could explain how each varies with ...
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22 views

Trying to calculate the length of a tube to heat Ar gas

If one were trying to heat Argon gas from ambient (~20C) through a mild steel tube of some diameter 'd' how long would it need to be? Additional unknown includes flow rate of Ar gas so some general ...
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19 views

How do we compute the volumetric efficiency of an engine which is based on forced induction?

The volumetric efficiency of a naturally aspirated engine is computed by: $$n= \frac{V_1}{V_2}$$ With n: volumetric efficiency $V_1$: actual volume of air drawn $V_2$: volume swept by piston ...
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30 views

Two Limits in Thermodynamics - Reducing Driving Force and Increasing Resistance

I just wanted to clarify what is probably a very obvious idea. Suppose I'm holding a a piston separating two containers at different pressures. If I release the piston, it will naturally move, ...
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24 views

joule-thomson effect and linde process

According to the j-t effect the decrease in the temperature is a result of the work done by molecule to expand thus increasing their PE and decreasing their KE, but in the linde process the next step ...
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16 views

Can the effectiveness of a heat sink be increased with surface texturing?

Some supercapacitors use chemical etching to increase their surface area by several orders of magnitude. Could a similar process be used on a heat sink to increase its surface area and thus its ...
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18 views

Thermal resistance of an aluminium plate to ambient?

I have heaters mounted on an aluminium plate inside an enclosure, and I would like to know what the temperature of the plate will be at thermal equilibrium for a given heating power. For this I need ...
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46 views

Euler Equation Arbitrary Quantities

I have a question about the Euler equation. For some state I can write down: $$ U = TS - pV + \mu N$$ In this equation $T$, $p$, $V$, and $N$ are directly measurable so they have fixed values. ...
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14 views

dynamic structure factor for nucleation

I know that using the peak position/moment of structure factor or may be by first zero or minimum of pair correlation function we can estimate the characteristic length scale in a phase separating ...
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49 views

Chemical potentials at triple point

How to prove that chemical potential of each phase at triple point are equal? My attempt: At phase transition, $P$ and $T$ are constant and using $dG=0$(Gibbs free energy at minimum) at equilibrium ...
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27 views

What makes fluorescent lamps lower in heat than high pressure lamps coated with phosphorus?

Why does a fluorescent lamp give off more pure visible light (without heat) than a high-pressure lamp? Is the heat given off by high-pressure lamps caused by the intensity of light being emitted from ...
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51 views

I have got some weird data after a homemade battery experiment

Okay, so i've been searching for some time, for perpetual motion machines of the second kind. So things got into my mind, such as this homemade solar cell. And i thought in my mind:" It's not the ...
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38 views

gibbs free energy and maximum work

I'm getting confused between two important results.... Gibbs free energy G = H-TS where h is the enthalpy and S is the entropy. This relation indicates only when the temperature and pressure are ...
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183 views

What is the minimum volume in which, for a given temperature difference $\Delta T$, natural convection would occur?

I'm trying to figure out if convection will occur in a plastic bottle slice and what length of slice would be optimal to achieve high R value transparent insulation on the cheap. The bottle slice is ...
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42 views

Temperature dependence for specific thermal diffusivity in the diffusion formula

I recently found this answer about the diffusion equation (nice one actually), but have one doubt about the temperature dependence of this formula. If the "packet" of energy (terminology suggested ...
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15 views

Creating correlated Szilard engines

A demon has a large number of boxes with a single particle in. He / she adiabatically introduces a wall in the box, dividing it in two with a particle in one of the two halves (L, R). The demon does ...
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31 views

How much energy does a powerlifter need to perform a session of squats?

So I started the math myself and I'm hoping someone can look this over and improve on my idea. Let's say that a powerlifter performs the following sets of squats: % 1RM = lifted weight in percent ...
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27 views

Is the rapid compression of a non-insulated/insulated cylinder “practically” the same process?

I recently had an exercise which had us examine the following 4 situations: A quasi-static isothermic compression of a mono-atomic ideal gas. A rapid compression of a mono-atomic ideal gas, where ...
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12 views

Which constant is required to calculate the energy in a thermal analysis?

I want to calculate the energy in a thermal analysis. I want to do it in analogy to the electrostatic field, because I'm interested calculating the $H_1$ error in a Finite Element analysis. For ...
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92 views

Quadratic versus other types of degrees of freedom

In my text book I have the following question and after thinking about this one for hours, I can't figure out what they're getting at: In Section 2.5* I quoted a theorem on the multiplicity of any ...
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43 views

Simple Conduction Simulation

What is the simplest way to simulate heat conduction on a 2D plane? What I want to do is have 1024x1024 2D plane of uniform temperature 0°C and specify the temperature of a cartesian coordinate. ...
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65 views

Steam Turbine Inlet Velocity

Consider an ideal steam turbine. The power generated by a steam turbine comes down to the torque and the angular velocity, which is ultimately dependent on the velocity at which the flow enters the ...
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117 views

Derivation of Van der Waal's Equation from Helmholtz Free Energy

From the following equation $$ f(T,v) = f_{id}(T,v) - RT \ln\bigg(1-\frac{b}{v}\bigg)-\frac{a}{v}$$ how do I derive Van der Waal's equation. In the equation above, $f$ and $f_{id}$ are the Helmholtz ...
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77 views

Heat engine efficiency, compression ratio vs temperatures

I want to understand the role or even existence of a cold reservoir in the Otto cycle gasoline engine. The efficiency of the Otto engine is given as a function of compression ratio $$ ...
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39 views

Modeling an Adiabatic Expansion (EES)

How would one model an isentropic (reversible) adiabatic expansion using thermodynamic software in order to determine isentropic work? What I am looking for is an actual pressure-volume curve for the ...
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103 views

Difference between Residual Function and Excess Property

Sengers describes the deviation function as the difference of the actual mixture property and as determined from a model. If this model happens to be the ideal gas model, then it is also called ...
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20 views

Distribution of temperature in a plume of a jet

The exaust gases of a plume of a missile have a distribution in temperature and in density vs. distance from the nozzle. Using a CFD software it is quite simple to get such distribution. Is there some ...
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19 views

I need to calculate the temperature of some flat copper wire as it loses contact with a chilled capstan roller

I need some help in designing a system for cooling wire as it comes off a resistance annealer. I need to calculate the temperature of that flat copper wire as it comes off a chilled roller (call it a ...
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40 views

Thermal Conduction through sphere

In general, a sphere with conductivity $\kappa$, heat capacity per unit volume $C$ and radius $R$ obeys the differential equation at time t: $$C\frac{\partial T}{\partial t} = \kappa \frac{\partial^2 ...
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58 views

How to calculate net power output of heated, expanding air?

I'm interested in designing and building a Stirling engine which uses air that has been heated, which expands and then acts upon a piston producing power. There is a fixed amount of air inside the ...
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36 views

Hamiltonian (temperature?) and frame of reference

So we can define a particle by defining its kinetic and potential energy, knowing that we can get a wavefunction describing a particle. But the kinetic energy involves motion, and motion can be ...
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29 views

If maximal work is extracted, in what manner does the heat flow between bodies?

There are two bodies starting with different temperatures and specific heat capacities (for simplicity assume that the bodies are solid to the volumes are constant). Let the rate of heat flow from ...
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38 views

Which metal will be on the surface after solidification?

I know that there are some metals that just "like" to be on a surface, so if I make an alloy of such metal and some other metal, the first one will be on the surface after solidification of initially ...
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42 views

How to calculate the amount of energy in joules/s that gas oven uses?

I know there may be missing information, but my question is really simple and yet I haven't found an answer to it. To make things easy, let's assume we have a $40×40×40$ cm oven that we want to keep ...
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18 views

Understanding how clouds form: warm air near the earth's surface?

I'm trying to understand how clouds are formed. I've read that it begins with air near the earth's surface heating up. But I'm hearing two different reasons for how this happens: Air pressure near ...
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12 views

Does transverse flow always assist in mixed convection?

I am dealing with both natural convection and transverse forced convection over a flat plate. There are 4 different situations: Upward-facing cold plate Downward facing cold plate Upward facing hot ...
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46 views

Landau free energy

I am reading the statistical mechanics by Pathria in Chap 12. I have a question about the Landau free energy. What is the physical reasoning for that the free energy could be a functional of the order ...
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65 views

Cooling power for cloud chamber

I'd like to build a small Peltier cell cooled cloud chamber. The cold surface would be a copper sheet with a surface of 200x200 millimeters. Is there a way to even guess the cooling power needed to ...
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17 views

Is there a way to tell the rate of temperature change due to provided energy?

Let's say we have an isolated system containing two bodies with different temperatures. The bodies are touching each other. Is there a way to tell how long will it take them to reach thermodynamic ...
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50 views

Proving $RTln(a_i)$ equal to non PV work done by system,where $a_i$ is activity

First of all many here will might say that it is Chemistry question.If you think so then read this article and then answer question. Question is --- We know chemical potential is defined as $\mu_i ...