Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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41 views

Rijke tube: Why Sound is maximum when heated 1/4th length from bottom of tube

Why is it that the maximum sound coming from a Rijke tube happens only when heated wire gauze is placed at 1/4th the length of the tube from the bottom. According to Rayleigh: If heat be ...
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16 views

What coefficients may be used for evaluation the heat keeping?

The final goal is to compare two objects (similar to boxes) from the standpoint of keeping the heat inside? May be there is numerical coefficient or any approaches?
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33 views

Expression of $\kappa_S$ in photon gas

I'm calculating some properties of the photon gas. That gas is defined by $$U=aVT^4$$ $$P=\dfrac{1}{3}aT^4$$ I calculated photon gas entropy: $$S = \dfrac{4}{3}aT^3V $$ I could calculate $c_V$. ...
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335 views

What is the difference between heat and work

If 700 J of work is applied onto a gas, and therefore the gas contracted 0.005 m^3 (from 0.01m^3), and the temperature stayed at a constant rate of 300 kelvin, then how come when pressure is added to ...
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121 views

Does coffee with cream cool slower than black coffee?

At Modernist Cuisine, Nathan Myhrvold states that "Coffee with cream cools about 20% slower than black coffee". He then gives three reasons, two of them related to radiation and the third one to the ...
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50 views

Legendre transformation of Entropy as a natural function of T, V, n

I have come across a question asking to get a Legendre transformation of entropy which is a natural function of 1/T, V, n starting from entropy being a natural function of T, V and n. However, I have ...
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62 views

Calculate thermal conductance of thick walls of a cuboid, given material conductivity and cube size

Note 1: This is probably as much a maths question as physics. Note 2: I am not sure if my use of the the term conductance is correct. I want to make a kiln. The walls will be thick. I can come to ...
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37 views

Linearity of the critical isochore?

When looking at the pressure-temperature diagram along the critical isochore (up to quite high reduced temperatures) a very linear trend can be observed. From a theoretical point of view, is the ...
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80 views

Characteristic length of differential element of cylinder surface?

I am trying to find the Nusselt number for a small element of the outside of a cylinder that has a height of $Delta z$. I found the average Grashof number of a surface as $$Gr_{L}=\frac{\beta \rho ...
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62 views

How to relate compression ratio to work input for a compressor in a heat pump

So I need to calculate the COP (Coefficient of Performance) for a 6-ton air conditioner system in terms of the compression ratio. I understand that: $$COP=\frac{Q_L}{W_{net,in}}$$ I cannot find out ...
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38 views

What's the typical material used as a low-k ILD in semiconductors?

Semiconductor companies (namely IBM, Intel, TSMC and etc.) may use different low-k materials as inter-layer dielectric (ILD) in their fabrication process. I'm wondering what is the most typical one. ...
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96 views

Definition and Measurment of Energy and Heat in Thermodynamics

The concept of work is clear from mechanics, where $dW=F\cdot dx$, leading to $dW=PdV$. Also different forms of energy are defined in mechanics, e.g., $E=\frac{1}{2}m v^2$, etc. How are the energy and ...
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25 views

Properties of material affecting magnetic refrigeration

I am reading about magnetic refrigeration at the moment - I see that two factors affecting the applicability of the material for use in magnetic refrigeration is that they must react strongly (i.e the ...
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44 views

Experimental heat equation for a bottle of water

I'm not sure if this question belongs here, because I'm asking a question about experimental data rather than theoretic formula. Anyway, I'm trying to figure out the time-temperature relation of the ...
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80 views

diesel steam engine

Let's imagine a diesel engine's cylinder head would be heated by external means, to some hundred degree celsius, and the fuel would be replaced by water. We've made modifications so that water ...
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100 views

Food kept in a container in my pressure cooker cooks slower

The pressure cooker is heated at the base to cook the food. The pressure cooker releases steam when the force exerted by pressure exceeds the counterweight, at which point the weight rises up allowing ...
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56 views

How does enthalpy help us to find the state of equilibrium?

For an adiabatic system with constant external (generalized) forces, in a state out of equilibrium we have: $$\delta H\leq 0 $$ If I understand correctly, derivation of this inequality does not rely ...
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215 views

Thermodynamics shell-and-tube heat exchanger

A shell-and-tube heat exchanger is used to cool a flow of steam using a stream of cooling water cooling water. The steam enters the heat exchanger at $0.1 ~bar$ and a quality of $91$% , and exits as ...
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55 views

Is it correct to assume that a stretched rubber-band has negative entropy change?

If so, how could we express it in equations connecting S,T,Q? I was wondering if the net change is heat transfer was positive; Since we could feel the heat when it is stretched.
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91 views

Super cooled steam and entropy change

I was thinking about a situation where I have some super cooled steam which suddenly freezes to water.What are the entropy changes(positive or negative) for the system and the universe? My ...
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69 views

thermoelectric effect

The Absolute Seebeck effect states that an electric potential (voltage) is produced to any isolated conducting when subject to a temperature gradient.But why? My view of this is that when you apply ...
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58 views

Which pressure to use in the $T~ds$ equation?

Let's say I have an adiabatic, rigid, open container that has an amount of air at some pressure, $P_\text{cv}$, and some temperature, $T_\text{cv}$. I have heated pressurized air coming into the ...
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287 views

Making an equal amount of positive and negative energy?

I was wondering if it would be possible to create an amount of positive energy out of a vacuum, in addition to an equal amount of negative energy, thus not violating the first law of thermodynamics, ...
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78 views

Best material for heat transfer between ice and water

What is the best container material for heat transfer between ice and water? this is a difficult question to ask without displaying a picture of what I'm meaning.
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14 views

Calimetric Perfect Ideal Gas

What is the energy equation when you have a ridgid adiabatic open system where you have a mass flow rate in and a mass static inside the system?
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31 views

Is there a thermodynamic law or theorem that expresses how systems “break” or “change” when enough energy is added?

I have a simple question about thermodynamic laws, and I am hoping you can help me. Let's say that I have a sphere container with some pressurized gas in it. I can slowly increase the pressure over ...
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240 views

What is an accurate equation for joule heating?

I know two different equations that provides the joule heating effect. The first one only depends on the potential ($\varphi$) and the electrical conductivity ($\gamma$) and can de modeled based on ...
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85 views

Rotary Steam Engine

Leon Crux invented the concept of interlocking archimedes spirals that eventually led to the scroll compressor but intended it to be used as a rotary steam engine. However technological limitations of ...
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44 views

What is the relationship between strain and electric current?

Strain or stress can be caused by different sources. I categorized theses sources as mechanical, thermal and electrical loads and formulated the total stress as follows: $$ \epsilon_{total} = ...
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40 views

Estimating magnitude of error in the simplified Debye heat capacity

If you recall, there are two separate Debye cut-off frequencies that correspond to the longitudinal and transverse modes of vibration. Taking this into account, one can generalize the Debye heat ...
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28 views

Decompression cooler

How would I figure the needed pressure differential to freeze water inside a cooler using ambient air? I am assuming that the combined gas law would apply here and that the formula P1•V1/T1=P2•V2/T2 ...
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67 views

When to dump water from a water cooler

If space in your cooler is not an issue and you're not concerned about other issues associated with water collecting in your cooler, under what conditions should you dump water from your cooler if ...
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64 views

Calculating the osmotic pressure in counterion (Manning) condensation

I'm going through Manning article about counterion condensation and I've reached equation 27 $ kT \left ( \phi - 1 \right ) \left (n_1 + n_2\right) = \pi = - \left ( \frac{\partial F^{ex}}{\partial ...
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97 views

Please correct my understanding of Clausius-Clapeyron and latent heat

As I work a problem set, I'm being asked to calculate the latent heat associated with a particular phase transition of $NH_3$ (solid -> liquid, liquid -> gas, solid -> gas). I'm being told to perform ...
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32 views

How to compute the change in entropy of s system when the temperature is decreasing?

How to compute the change in entropy of s system when the temperature is decreasing? Such a question may be too general,then we may ask a special case:How to compute the change in entropy of Annealing ...
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165 views

Constant Pressure lines in evaporation diagram

Assume that there is the following $T-H$ phase diagram with the constant pressure lines. Which is greater preasure? The preasure drops as we move to lower temperatures (i.e. from top to bottom)? ...
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230 views

Triple point temperature and freezing point

Why does the triple point temperature have very similar values to the freezing point, in most substances?
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61 views

Temperature, internal or thermal energy?

Suppose we have all the data we want on weather conditions $W$ around some building $B$. And we have various measurements $I$ on temperature, cooling, ventilation etc. of the interior of the building. ...
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214 views

How does the volume change affect an adiabatic process?

A gas consisting of rigid diatomic molecules was initially under standard conditions. Then the gas was compressed adiabatically, 5 times the original volume. Find the mean KE of rotating molecules ...
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98 views

Total massflow through heat exchanger

I am working on a project and I stumbled on a problem. The project is to design a heat pump to replace the old system (actual problem, not some homework problem). There are 100 or so induction units ...
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39 views

How connected thermodynamical stability and dynamical stability for black holes?

Criteria for thermodynamical stability is the convex of entropy. But for black hole entropy is non-additive.
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45 views

Heat transfer in fluid between two horizontal plates vs unconfined case

I often see the correlation for turbulent heat transfer between liquid cells published by Globe and Dropkin (1959). In the original paper the fluid was confined between two horizontal plates and ...
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54 views

Lambda transition data points of $\require{mhchem}\ce{^4He}$

I'm looking to get some data on the lambda transition of $\require{mhchem}\ce{^4He}$. I need the data points of the specific heat vs. temperature graph, if that makes sense.
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44 views

Heat of adsorption from fugacity data

I have a set of data relating the fugacity ($\approx$ pressure) to the loading for a given set of temperatures. There are three temperature sets each having five fugacity vs. loading points. The ...
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57 views

Increase in number of micro states explanation or restatement of second law?

Is the boltzmann's expression of entropy as log of micro states leading to the formulation that system is more likely to be in a macrostate with more no. Of micro states really is an explanation or ...
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79 views

Landauer's principle vs Rayleigh–Jeans law

Can we argue based on Landauer's principle that if one bit information is changed inside a blackbody, the total radiated energy should be at least or in order of $kTln2$? If it is so, can we also ...
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389 views

Entalpy and entropy role in freezing-point depression phenomena

There's this "atomic" explanation of the freezing-point phenomena on Wikipedia that leaves me really intrigued. Consider the problem in which the solvent freezes to a very nearly pure crystal, ...
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84 views

Using thermodynamics and Kinematics together to solve a parachuter problem?

I need to find a parachutist's displacement after a given height (nearly 37000m) and at a given latitude. I have his mass, area, parachute area, drop height, parachute deployment height, data about ...
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185 views

Constant volume specific heat

A monatomic ideal gas is confined to move in two dimensions. What is the constant volume specific heat for this gas? Consider a system of N independent harmonic oscillators moving in two dimensions. ...
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328 views

Carnot Engine for Finite Reservoirs

Two solid, finite thermal reservoirs have temperatures of $T_1$ and $T_2$ respectively and an engine operates between the two. Assume $T_1 > T_2$ and that each reservoir has constant heat capacity ...