Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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Kinetic energy of different phases of water [closed]

In a closed flask at zero degrees Celsius, all three forms of water exist. Which form of water will have the maximum average kinetic energy? The answer is that all forms of water will have same ...
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48 views

What is the best thermal heatsink compound?

Re-worded This is about the Experimental Physics not PC building or how to grease a car's radiator. I have to insert a stainless steel enclosed PT100 into a block of metal to monitor its temperature ...
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15 views

How much temperature reduction can we expect when pouring water into the cup from an elevated kettle?

Turns out some people who are into green tea use the following technique to cool the water from the kettle down. They lift the kettle and pour a rather thin stream of water in the cup. Because of high ...
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14 views

Internal energy given surface tension

Could anyone offer some insight for the following problem: The internal energy and the entropy are proportional to the area. Show that the internal energy per area is given by $$u(T) = \frac{U}{A} = ...
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39 views

Work needed to pump the balloons

Let's suppose that we want to pump the balloons underwater from the initial volume $V_0$ to the volume $V_1$. The pressure there equals $p_1$ and the atmospheric pressure is $p_0$. It is claimed ...
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getting frm micro to macro entropy problem

For an ideal gas entropy forvolume change from micro to macro can be rewritten as: $S=k\ln W$ $\Delta S= S_2-S_1=k\ln W_2-k\ln W_1=k \ln\frac{W_2}{W_1} $ since we are constrained from derivation ...
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91 views

Limitations of Redlich-Kwong equation of state

I have been using the Redlich-Kwong EOS to calculate the compressibility factor for nitrogen. I am currently running an Excel VBA that performs the calculation. I have noticed that the process of ...
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11 views

Does a sonic pulse in a gas enhance thermal mixing?

I have a sonic pulse consisting of around 10 cycles that is propagated longitudinally through a gas in a tube. If there are thermal differentials in the gas (say between case and central portion of ...
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Thermal de Broglie wave length

If we refer to this wiki page thermal de Broglie wave length, we can see there are two expressions. One is derived using equipartition theorem, which makes perfect sense. The other one used $\pi kT$ ...
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220 views

Heat Transfer through a wall

If a volume of air enclosed by a physical box is kept at a constant temperature that's different from the temperature outside, will the temperature of the inner wall of the box be the same as the ...
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24 views

Will heating water vapor induce equilibrium?

What happens to the vapor content if a mixture of gases saturated with water vapor is heated isobarically? Will the amount of liquid water present decrease, yielding up more vapor so as to ...
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58 views

Heat loss from water surface heated in a room

I have one question regarding total heat losses from water surface. Water is heated with immersion heater in open condition in a room. Heat losses from the top of the pan to air is to be calculated. ...
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38 views

What is the gas entropy as a functional of a one-particle distribution function?

There are some discrepancies on how to introduce entropy in classical kinetic theory. In what follows $f(r,p,t)$ is the usual one-particle distribution function of a monatomic gas, normalised to the ...
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26 views

Effective Area of Isotropic Antenna: Explanation?

I'm reading some introduction to antenna theory and I've often puzzled on the equation: $$ A_{eff} = \frac{\lambda^2}{4\pi} $$ which relates the effective area by which an antenna captures radiation ...
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4answers
414 views

I don't understand why a cavity with a hole is a black body [duplicate]

It makes no sense to me that a cavity with a hole is identical to a black body. Sure, the cavity will probably be a near perfect absorber, but I don’t see how it will be a perfect emitter as well. ...
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34 views

Number of particles in a box at thermal equalibrium

Consider a cube box of volume $V$ in thermal equilibrium at temperature $T$. We have 3 pieces of information: The probability of finding a particle of mass $m$ in the box having momentum in ...
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29 views

High pitched noise as hot object hits water?

https://www.youtube.com/watch?v=9qSEfcIfYbw Just wondering what this phenomenon was called, and its cause? Would have googled, but I don't even know what it's called.
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rocket propulsion [closed]

As I understand it, in rocket propulsion a converging/diverging nozzle is used to convert the random velocity vectors of the combustion chamber gases into a mostly unidirectional velocity field at the ...
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4answers
105 views

Why doesn't fire flow back INTO the cylinder?

Let us take into a consideration a (pressurized) kerosene stove. The pressure drives fuel out of the nozzle, like or in a much simpler arrangement as in Question- Why doesn't fire flow back ...
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40 views

Gibbs free energy for an ideal gas (problem)

so I'm trying to find the gibbs free energy for an ideal gas $$g = u -Ts + pv $$ Hence, $$dg = du -Tds -sdT +pdv +vdp = -sdt + vdp$$ The entropy is $$s = c_{p} \ln T -R \ln P + s_{o}$$ Which ...
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Landau's derivation of the law of entropy increase - clarification

In Landau&Lifshitz V: Statistical Physics the following derivation of the law of increase of entropy is given. I need help understanding several crucial steps; I'll briefly summarize the notations ...
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2answers
41 views

What is the theoretical instantaneous temperature of a gas?

When we measure the temperature of a gas we typically integrate the molecular collisions and wind up with an 'average' temperature due to the sensor comprising a relatively large thermal mass. And ...
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27 views

There is some attempt to build a magnetic flywheel (reservoir of motion)

We know how flywheel works! There is some attempt to substitute the flywheel-friction mechanism for some magnetic torque ? Exist some mechanism that uses thermal cycle of gases for generate magnetic ...
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1answer
70 views

Partition function: Number of states? Doesn't add up for ising

While trying to really understanding the partition function in statistical mechanics, I tried looking at it for a 2D ising model, as that's been helpful for me for all kinds of thermodynamic values. ...
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3answers
102 views

Why is the change in entropy for a given energy input dependent on the temperature?

In my thermodinamics class, we saw that $$dS=\frac{dQ}{T}$$ and $$\Delta S=\int_{a}^{b}\frac{dQ}{T}$$ My question is: why for the same energy input $dQ$ the entropy increases more in lower ...
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42 views

How quickly does a gas reach a uniform temperature in an enclosure?

I'm just looking for ballpark figures and reasoning. Suppose a gas (air) at STP was introduced into a 10cm diameter sphere of infinite heat capacity and conductivity at one degree above the gas. How ...
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34 views

Chemical reaction A+B$\leftrightarrow$C. Equilibrium VS Non Equilibrium

Could you please confirm or say why I am wrong? Let us consider the steady state of the chemical reaction $A+B \leftrightarrow^{k_+}_{k_-} C$, with $k_+$ and $k_-$ the forward and backward rates. ...
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61 views

Find Solution to the Heat Equation with Bessel Functions and Initial Values

I'm trying to find the time dependent solution to the heat equation in a very long cylinder (the problem only depends on radius, r, and time, t) with the initial value $T(r,0)=T_1$ and the Dirichlet ...
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2answers
41 views

If I accelerate a mass quickly enough through a short distance (i.e. unit step function), would I create wind, sound, and heat?

As far as I know, the movement of air molecules can result in what we call wind, sound, or heat (and maybe some other things I'm not thinking of), depending on the assumptions about its motion. Wind ...
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3answers
211 views

100°C = 100 K =?

I'm in first year. Our class is in lesson " Heat and Thermodynamics". While solving a numerical problem of a reversible engine he told us that 100 degree Celsius is equal to 100 kelvin. I inquired but ...
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55 views

Thermodynamics of expanding nitrogen bubble as it rises in water

Problem An air bubble is released from a nitrogen tank 20 meters under water. The bubble has a radius of 1 mm. What will be the radius of the bubble when it reaches the surface? My Questions Is it ...
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Given the Pair Correlation Functions for a Multi-component Fluid, is There a Simple Way to Obtain the Helmholtz Free Energy?

I think it may not be possible. Given all the pair correlation functions (e.g. calculated from Ornstein Zernike theory), it seems possible to obtain the internal energy (assuming different species ...
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1answer
64 views

What is a “fundamental thermodynamic relation”?

My professor handed me a quiz in which he said something like (I don't remember exactly) "write down the four fundamental thermodynamic relations for $A,G,H,U$". I showed the differential elements of ...
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62 views

Molecular structure correction factor in Mass Flow Controller

This question concerns device called Mass Flow Controller (or Mass Flow Meter). For a video explaining the principle: see https://www.youtube.com/watch?v=G62ma2IFh9o These devices are factory ...
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6answers
2k views

Does placing a lid on a pot affect the rate of boiling?

On the subject of cooking, someone once told me "If you have too much water in your pot after cooking a dish, just turn up the heat and let it boil without a lid for a few minutes". Now I've thought ...
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58 views

why doesn't liquid metal vaporize in a vacuum?

I am wondering why molten metal in a vacuum of electron beam and machines never turns to gas like liquid water does when exposed to a vacuum.
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Is Boltzmann constant $k_B$ constant?

I heard in a lecture that Boltzmann constant $k_B$ is not constant in some special cases. Do you know the title of the article which contains this one? Do you think this idea is true?
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Does ambient day/night temperature change have significant energy generation potential

Is there significant energy to capture in daily day/night temperature change? For instance, I see from posts such as the following that there are materials with varying coefficients of linear thermal ...
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1answer
43 views

Why does the rate of melting of an ice block vary in different methods?

I saw that an ice block melts faster when it is placed in a microwave rather than when it is exposed to flame. Could it be because the flame creates a layer of water vapor between the flame and ice? ...
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303 views

Why isn't in counting the no. of degrees of freedom, rotation about the axis running down the length of the molecule counted?

I was reading about the Equipartition Theorem. Then I got the following quotations from my books: A diatomic molecule like oxygen can rotate about two different axes. But rotation about the axis ...
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1answer
53 views

Carnot vs. Otto

Otto cycle is reversible and according to Carnot theorem should have the same efficiency as Carnot $\eta_{Carnot}=1-T_C/T_H$. The efficiency of Otto is $\eta_{Otto}=1-\frac{T_4-T_1}{T_3-T_2}$ (see ...
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46 views

Corrections to the Equipartitio theorem

Does anyone know why sometimes $E = \frac{3}{2}k_{b}T $ is written as $E = \pi k_{b}T$. Where does this come from?
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112 views

Are we feeling the sun's heat?

If I may summarize something I told a friend in a pub... "We don't get heat from the sun at all. Heat requires matter to move through and there's too much vacuum between the sun and us for any heat ...
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101 views

Does a vacuum, suddenly opened, become hotter than its surroundings?

Suppose you have an insulated container that is equipped with a valve to let air in. Initially the container is evacuated. You then quickly open the valve, allowing air to rush in. What is the ...
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1answer
70 views

Third law of thermodynamics

Does Third Law of thermodynamics violates Quantum Mechanics, I mean Why third law of Thermodynamics holds if we think about it in terms of Quantum Mechanics ?
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4answers
199 views

Mass, energy, and entropy.

I have a seemingly simple question about the relation between these three that for some reason doesn't make sense to me. If entropy is the disorder of a system, then a low entropy state is one of ...
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2answers
83 views

Thermodynamics : Work done on gas inside container by the force due to pressure exerted by external atmosphere

Suppose a container is fitted with a massless and frictionless piston lying on a table such that pressure due to gas is greater than pressure due to external atmosphere. Hence piston will move. Now ...
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2answers
105 views

Average surface temperature of Earth [duplicate]

I had a question in my school exam. Will the average surface temperature of the Earth be lower or higher, if there was no atmosphere? Now, the answer expected is "The avg temp will be lower, because ...
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1answer
31 views

What does this extraneous solution to an elementary thermodynamics problem represent?

I recently had the following homework problem (Knight 3e, exercise 16.72, page 467): The cylinder in Figure CP16.72 has a moveable piston attached to a spring. The cylinder's cross-section area ...
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55 views

(No need of 2nd law) Adiabatic and isothermal compressibility relation with specific heat

One classical example of thermodynamics is the relation between the Adiabatic and Isothermal Compressibility Relation with the Specific Heats: Compressibilities: ...