Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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607 views

Why do we ignore rotational energy in monatomic gases? [duplicate]

I understand that the average energy of each degree of freedom in a thermodynamic system is $\frac12kT$. And so, for an ideal monatomic gas, there are three degrees of freedom associated with the ...
3
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1answer
1k views

Equation of state of a rubber band

I have the following question that I attached in png format. I have done part (a), but I am having difficulties in part (b) when I proceed according to the book. I have non zero tension at ...
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2answers
1k views

Energy of unmixing

Mixing of two different fluids is associated with an increase of entropy. Conversely, separation of two gases must be associated with a decrease of the entropy of the two fluids. Is there a minimum ...
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1answer
78 views

What is the physical implication of Clausius inequality?

Clausius inequality is given as: $$\oint \frac{\delta Q_\text{res}}{T_\text{res}} \le 0\;.$$ From Carnot cycle, we get the equality relation as the entropy lost by the hot reservoir is the same as ...
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0answers
106 views

Le Sage's Theory of Gravitation, is “drag” the only reason why this theory fails? [closed]

Le Sage's Theory of Gravitation was originally proposed allready 1690 by Nicolas Fatio, and has ever since been studied by remarkable scientists; Leonhard Eluer once remarked that it was "infinitely ...
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2answers
2k views

Is there an equation to calculate the average speed of liquid molecules?

I seem to remember from first year physics that we can calculate the RMS speed of a stationary, ideal gas with $v=\sqrt{\frac{3RT}{M}}$. Does a similar equation exist for liquids?
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1answer
4k views

Definition of “intensive” and “extensive” properties

Today I was asked what does it mean for a physical property of a system to be intensive. My first answer, loosely speaking, was: "It is a property that is local." I was specifically thinking ...
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3answers
640 views

Mathematical proof of non-negative change of entropy $\Delta S\geq0$

I understand that we can prove that for any process that occurs in an isolated and closed system it must hold that $$\Delta S\geq0$$ via Clausius' theorem. My question is, how can I prove this in a ...
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2answers
174 views

How can Maxwell's Demon erase information while a black hole can not?

It is stated, that information can't disappear even in black holes. On the other hand, it is stated, that mystic beings, like Maxwell demons, can easily erase any information if they just pay with ...
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1answer
130 views

Isothermal compressibility

How does one get from the thermodynamics definition : $$ \chi_T = -\frac{1}{V} \left(\frac{\partial V}{\partial p}\right)_T$$ to the fluid dynamics definition : $$ \chi_T = \frac{1}{\rho} ...
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3answers
7k views

Why can the entropy of an isolated system increase?

From the second law of thermodynamics: The second law of thermodynamics states that the entropy of an isolated system never decreases, because isolated systems always evolve toward ...
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3answers
1k views

Best way to chill a cup of coffee with cold water and 5 minutes [duplicate]

Initial data 1 x 3/4 full cup of hot coffee / tea / your favorite morning beverage cold water 5 minutes Considering that it's starting to get hot outside, and we all want to drink reasonably cold ...
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5answers
1k views

Is speed an intensive property?

I remember being taught in elementary physics that while it makes sense to add volumes, masses, or heat, it makes no sense to add temperatures. As I wanted to use that to illustate some other issue, ...
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3answers
801 views

Why must the particles of an ideal gas be point-like?

Why is a gas of elastically colliding hard balls of finite size not ideal? Respectively: Why is it essential that the particles of an ideal gas are point-like? Especially: Which ...
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3answers
5k views

Why does deodorant always feel cold?

We all use deodorant and they always feel cold, why is that? Is it because it is liquid inside the bottle and a gas when it is released?
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1answer
241 views

Thermodynamics: heat transfer

I hope this question isn't too simplistic but I've been in a discussion with someone who claims that no energy is transferred between a cool object and a warm one (either by radiation or conduction) ...
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2answers
625 views

Solidification by the application of heat

When you add heat to a liquid (or a fluid), can it be solidified? If not, why in the world does an egg's stuffs become solid (or at least no more a liquid) when you 'boil' it in water?
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1answer
477 views

Maxwell demon : how can the demon move the door without doing any work ?

Here is something that I never understood about Maxwell's demon paradox : in order to contradict the second law of thermodynamics, the demon must open and close the door without doing any work... But ...
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1answer
173 views

Dropping condition

Imagine opening a water tap in order to have a smooth and cylindrical outflow and then slowly decrease the flow by adjusting the knob. At a certain moment, the side profile of the flow will become ...
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3answers
372 views

Why does the air pressure at the surface of the earth exactly equal the weight of the entire air column above it

Why does the air pressure at the surface of the earth (resulting from collisions of molecules on the surface of the earth which has to do with the velocity of the particles) exactly equal the weight ...
4
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1answer
227 views

What happens at the interface between two universes with opposite thermodynamic arrows of time? [closed]

I was trying to think but cannot figure it out. For instance, if the interaction is small, for instance limited to a windows, the observers in each universe will see that the other goes in reverse. ...
3
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1answer
191 views

Thermal emission cathode electron velocity distribution

I can't find any experimental data (or theoretical expression) on what is the velocity (or energy) distribution of thermal emission cathode electrons emmited from the cathode at approximately 2000 K ...
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2answers
3k views

Why does blowing on hot coffee cool it down?

And will it cool off faster if you blow across the top of the cup or directly into the coffee? Does it have to do with the fact that when you blow across the top of the cup the velocity of the air ...
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3answers
784 views

Is there an upper limit to temperature in thermodynamics or statistical mechanics

In many presentations of statistical mechanics where we have a system of particles having mass, such as the molecules of an ideal gas, the temperature is often equated to the average relative velocity ...
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2answers
591 views

How to reconcile the two definitions of work? (mechanical and thermodynamical)

When studying classical mechanics, work is defined as: $W_M=\int F_{tot} \hspace{2 mm} dx$. However, for thermodynamics, work is defined as: $W_T=\int -F_{ext} \hspace{2 mm} dx$. I'm having trouble ...
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3answers
234 views

Colder surface radiates to warmer surface

When radiation from a colder source arrives at a warmer surface there is some debate about what happens next. To make the question more concrete lets say that the colder source is at temperature 288K. ...
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1answer
208 views

How is pressure an intensive coordinate?

Most textbooks explain intensive coordinates by asking us to consider a system and divide it into two parts. The properties which remain the same will be called intensive and the properties that ...
2
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1answer
152 views

Why do windows fog quickly?

I'm from Bogotá, Colombia. In my city the temperature is all the year between 12ºC and 25ºC (bus mostly under 19ºC) and when I drive and it's raining, there is accumulation of fog on the windows, but ...
2
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2answers
590 views

Why does a substance expands upon freezing? What conditions necessitate this?

Why does a substance expands upon freezing? What conditions necessitate this? For example, how does the slope of sublimation or fusion curve in a P-T diagram affect this?
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3answers
322 views

How to combat the black-body temperature of an object?

I'm trying to model the temperature of a large spacecraft for a space colony simulation game I'm working on. In another question, I checked my calculations for the steady-state black-body temperature ...
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2answers
56 views

Gas Circulation Using Pressure Difference

Dear all, see attached picture Please, is it possible to have the gas recirculated from the gas phase to the liquid as described in the diagram assuming the gas is not soluble in the water. These ...
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1answer
2k views

When a color LCD/LED display is off it is black, when on it is colored. What color to light is an LCD/LED display

When a modern display using pixels is turned on its colors are different than the black that the screen is actually made up of. When put in light, such as sunlight, does the screen react to the color ...
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3answers
205 views

Speed of heat / quantification of heat and other magnitudes

Is the speed of heat infinite? When solving the heat equation in a semi-infinite bar, we can see that a pulse in the finite end draws an immediate change in every point of the bar. So, at any given ...
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2answers
77 views

Is there a portable method of preventing all IR radiation from being emitted?

Me and some friends were recently disuccing "How cool it would be to be invisible", from a military viewpoint, I said that Camouflage, when done correctly, works surprisingly well, so invisibility was ...
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1answer
185 views

What's the relationship between the energy density of a black-body and its radiant exitance?

Through a bit calculation we can derive that in a cavity, the energy density $$u(f,T)=\overline{E(f)}\times G(f)=\frac{8\pi h}{c^3}\frac{f^3}{e^{h\nu /kT}-1}$$ If we take the integral over all ...
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1answer
16k views

How much work is needed to compress a certain volume of gas?

I want to know the formula (and what does the symbols stand for) for how much work is needed to compress a certain volume of gas?
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2answers
2k views

What is the physical or mathematical meaning of the Gibbs-Duhem equation?

The Gibbs-Duhem equation states $$0~=~SdT-VdP+\sum(N_i d\mu_i),$$ where $\mu$ is the chemical potential. Does it have any mathematical (about intensive parameters) or physical meaning?
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2answers
78 views

Heat rejected by a refrigerator?

What is the amount of heat rejected by the condenser of a vapour compression refrigeration system, typically those found in households? Something in the nature of a 25W compressor, for example
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2answers
1k views

Why specific heat at constant pressure is greater than specific heat at constant volume?

I know the relation between specific heat at constant volume and pressure and I also know how to calculate it. Thing is, I don't understand its concept I want to know why at constant pressure, ...
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0answers
109 views

Entropy: Disorder or energy dispersal?

The first definition of entropy given by Clausius is I believe this $$S=Q/T$$ It is as I understand a common fact to understand entropy and maybe often teach it as a measure of disorder through the ...
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2answers
98 views

The 1st law of thermodynamics

If a gas expands adiabatically will the work done be positive or negative? I think it will be positive as $\delta W=p dV$ and we have a positive sign due to the work done by the gas is positive as it ...
0
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1answer
600 views

What does 1/k represent regarding Newtons Law of Cooling?

What does 1/k represent regarding Newtons Law of Cooling? I know k represents the cooling constant. I think the inverse of k is the time taken for the liquid to cool from its maximum temperture to ...
0
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2answers
1k views

Why is the direction of a flame is always upward? [duplicate]

why a candle's flame direction is always upward? What is the coposition of fire? Don't say it's energy. There is something else.
0
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1answer
11k views

Enthalpy Change in Reversible, Isothermal Expansion of Ideal Gas

For the reversible isothermal expansion of an ideal gas: $${∆H}={∆U}=0 \tag1$$ This is obvious for the case of internal energy because $${∆U} = \frac {3}{2} n R {∆T} = 0 \tag2$$ and $${∆U} = -C_P n ...
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1answer
558 views

Do ideal gases at zero Kelvin have potential energy?

Do ideal gases at zero Kelvin have potential energy?
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1answer
73 views

Problem Boltzmann distribution [closed]

I am trying to solve a problem about boltzmann distribution. If(A)=0.74 Uf(V)=0.037 Ia(A)=0.130 I have to find ...
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1answer
60 views

Alka Seltzer Model: formulas/models requested [closed]

This evening I became fascinated with how my Alka Seltzer tablet disintegrates over time within a small portion of Diet Lipton Citrus Ice Tea. I used a nearly frozen cup; tall, as one might request in ...
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5answers
16k views

Why does a candle blow out when we blow on it? Our breath is 16% oxygen and only 4% CO2

Don't say that a layer of carbon dioxide covers the flame, because our breath has more oxygen than carbon dioxide. Also, our breath does not cool the flame as it is itself warm. So what is happening ...
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5answers
427 views

Is the Boltzmann constant really that important?

I read a book in which one chapter gave a speech about the fundamental constants of the Universe, and I remember it stated this: If the mass of an electron, the Planck constant, the speed of ...
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8answers
4k views

Entropy is…disorder?

As I read somewhere, it said that the universe is heading toward disorder a.k.a entropy increasing. Now as far as I know from the second law of thermodynamics it states that entropy is indeed ...