Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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liquid polymers of high molecular weight

We often see a limit of melting point as a function of polymer chain length. Polyethlyene tops at about 190C, and polyethlyene glycol saturates at only 67C no matter how long the chain is: ...
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140 views

How does enthalpy help us to find the state of equilibrium?

For an adiabatic system with constant external (generalized) forces, in a state out of equilibrium we have: $$\delta H\leq 0 $$ If I understand correctly, derivation of this inequality does not rely ...
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94 views

How long will it take to cool? [closed]

Is it possible to cool down a system in milliseconds? And if so how can I? If I have a red hot metal at 773.15K can I dope it to 673.15K super fast?
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169 views

Calculating phase diagrams (Calphad)

I am calculating the phase diagrams for Li-Mg binary alloy with reference to the following text: http://ieeexplore.ieee.org/xpl/articleDetails.jsp?arnumber=5600701 In the equation used in the above ...
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265 views

Thermodynamic quantities of thin soap film on wire frame

Here is a question I am trying to solve. Sorry for the highlighting, it is not relevant. Here are my answers. For a), I would write $dE = dQ + dW$, following the first principle of thermodynamics. ...
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1k views

Definitions in thermodynamics: temperature, thermal equilibrium, heat

I'm currently reading Fermi's "Thermodynamics" and I'm trying to grasp the (possibly different) right definitions for temperature, thermal equilibrium, heat. To clarify, I'm looking for definitions ...
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81 views

How can we calculate heat transfer through hot gas to moving thermic fluid? [closed]

Heat is to be transfer from $CO_2$ gas to fluid. $CO_2$ is being heated by solar energy. How can we calculate heat transfer from the hot $CO_2$ gas to the moving fluid?
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424 views

Making an equal amount of positive and negative energy?

I was wondering if it would be possible to create an amount of positive energy out of a vacuum, in addition to an equal amount of negative energy, thus not violating the first law of thermodynamics, ...
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75 views

Where does the relation $u=h_f-RT+(c_p-R)(T-T_0)$ come from?

I'm working on a college project for a subject called Motorcycle Engineering, and in this project I'm supposed to do some reverse engineering on a MATLAB program to model the engine of the motorcycle. ...
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86 views

Compressibility and specific heat: interconnectedness and independence?

Consider a Mott insulator (insulator arising from strong correlations). This is an incompressible phase i.e. it costs energy to add a single particle to it; the ease of compression (compressibility) ...
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86 views

Biological Themodynamics - What does an endpoint saturated signal mean. How does it relate to equillibrium constant

I have had a question that has been bugging me for a couple of years in my graduate school career, and I was wondering if perhaps some physicist could help explain it to me. Given an endpoint assay ...
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59 views

Can I run a pulse tube cooler in reverse to generate pressure oscillations?

Since a pulse tube cooler is basically a Stirling engine without moving parts running "in reverse", does that imply that when I keep the cold end at ambient temperature and apply heat to the hot end, ...
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58 views

commutators in an uncertainty relationship derived from a partition function?

The maximum information principle for the discrete case gives rise to a partition function (>>> see details here) $$Z(\lambda_1,\ldots, \lambda_m) = \sum_{i=1}^n \exp\left[\lambda_1 f_1(x_i) + \cdots ...
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115 views

Traditional Transfer Matrix on the Potts model — how it grows for strip lattices?

What is the transfer matrix size for a strip lattice of width $n$ vertices, with arbitrary $q$?? I am not sure if it is $q^n$ x $q^n$ or something else. Any reference is also welcome.
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62 views

Does time stand still at a phase transition?

For second order phase transition thermodynamic properties can be described in very general terms by their critical exponents. So at every transition the correlation length $\xi$ should diverge as ...
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265 views

ideal gas law modelization in a vacuum chamber

I am trying to model a pressure sensor in COMSOL. The basic work is that there is current flowing inside it, if the pressure of the gas around it drops down, the temperature goes down as well (ideal ...
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185 views

Optimal way to heat liquid from the sun?

I understand that one way to tell how much a liquid will be heated up by a remote heat source is by looking at its color. I assume clear and colorless heats up least, then white, other colors and last ...
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86 views

Calculate heat loss of aquifer with unknown shape

I am trying to calculate the heat loss of an aquifer. An aquifer is basically a hot-cold storage $80\: \mathrm{meters}$ under the ground. It is an open system and utilizes groundwater. By pumping for ...
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368 views

Explain to me how this water cooler works?

Goodday all, I was recently reading up on a few projects that might be of interest to me when I found "CPU Bong water coolers", there isn't much online on them so I figure I would ask y'all. If you ...
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54 views

Negative temperature [duplicate]

How can we prove that if a negative-temperature system is in contact with a positive-temperature system, then the heat flow from the first to the second (and finally, the temperature of the second ...
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639 views

what's the difference between linear n-atom molecule and nonlinear n-atom molecule?

I am reading a material about the degree of freedom for linear n-atom molecule and nonlinear n-atom molecule. Here is my analysis for a diatomic molecule, if there are two atoms, we have to use 3 ...
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37 views

Henry's Law in metals

For fixed temperature the concentration of a gas dissolved in a solution is directly proportional to the gas pressure $p$, i.e. $c_s (T,p) = f(T)p$. Since $H_2$ only dissolves in metals as single ...
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126 views

What temperatures can be reached in an air-to-air thermocompressor nozzle and why?

People are generally of the opinion that the boiler injector cannot be redesigned to run on air. In other words, an air-to-air thermocompressor that puts fresh air into a tank without a mechanical ...
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176 views

Maximizing Multiplicity of Einstein Solid == (Temperature = $\infty$)?

If I have a system consisting of 2 Einstein solids (A and B) is it equivalent to say that maximizing the multiplicity of the ...
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2k views

Joule-Thomson effect of Van der Waals gas

I'm supposed to calculate the inversion pressure $p_i$ of a Van der Waals gas. The state equation of the Van der Waals gas is: $$(p + \frac{a}{V^2})(V-b) = RT.$$ To get a hold of the inversion ...
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262 views

Behaviour of individual terms in Einstein-Smoluchowski fluctuation-dissipation relation

Consider a bath of Brownian particles at temperature $T$. If we sprinkle some larger particles in this (eg: pollen grains in water or dust motes in air), they'll diffuse with diffusion constant $D$ ...
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439 views

Rotational Constant and Moment of Inertia of Fluorine gas

I have come across some homework question on thermodynamics which needs me to calculate $B$ of $F_2$ My attempt: $B= \frac{h}{8\pi^2cI}$ where $I=\mu r^2=\frac{m_1m_2}{m_1+m_2} r^2$ Atomic mass of ...
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133 views

How to solve state parameters using these givens for an ideal gas?

In a thermodynamic turbine using air as an ideal gas, given that you have a known inlet temperature value $T_i$, a known exit pressure value $P_e$, a known inlet and exit velocity $V_i$ and $V_e$, a ...
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185 views

How much money does an unused but plugged-in cellphone-charger waste in a year, if its not getting warm?

Is it right as xkcd states: You can use heat flow to come up with simple rule of thumb: If an unused charger isn’t warm to the touch, it’s using less than a penny of electricity a day. Or, more ...
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52 views

Height of a piston in a heated cylinder containing H2O

I'm a first time user and I hope I won't be too enigmatic asking the following question: I have a cylinder (radius= $6$ $\text{cm}$) with a frictionless piston on top of it and inside $30$ $g$ of ...
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92 views

Several questions about spring chiller and LMTD

I'm designing a simple copper coil wort chiller. Digging formulas I'm having hard time to figure some things out, perhaps some simple guides may help me to go the right direction: LMTD need inlet ...
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52 views

Heat contained in compressed gas [closed]

I am trying to compute the amount of energy released in the form of heat if I compress 1 cubic meter of Hydrogen to 0.1 cubic meter while submerged in a large body of water of a given temperature - ...
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31 views

Does a flame produce free electrons? [duplicate]

Possible Duplicate: Does Fire Conduct Electricity? Why? Is fire plasma? Does a flame produce free electrons ? Or is the answer sometimes depending on the chemicals ? Does the answer depend ...
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3answers
371 views

Is enthalpy defined under non-isobaric conditions?

My question is this, Does Enthalpy have a meaning under non-isobaric conditions? Is its existence as a property of a system independent of whether the system is under isobaric condition or not? ...
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47 views

Any new texts directly on second law of thermodynamics? [duplicate]

Possible Duplicate: Recommendations for Statistical Mechanics book Is anyone aware of any recent text that summarises the research and arguments on second law of thermodynamics and also on ...
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380 views

Does a Peltier Thermoelectric layer make a good regulator for LN2 heat-sink interfacing

I understand that when cooling water with LN2 directly (through pipes for example), that it can be too effective, freezing the water (and blocking the pipe). From what I read, regulation of the heat ...
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318 views

Simple heat transfer question [closed]

You add an unknown volume of milk of $5.2 ^\circ C$ to a cup of coffee ($40 mL$ of water, temperature: $80.3 ^\circ C$). After a while of stirring the temperature reaches $73.2 ^\circ C$. The ...
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47 views

Free Energy and quantum measurement

Free Energy must be expended to reset the state of an measurement apparatus. Is this statement valid in all situations? Is there a Definitive mathematical exposition?
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137 views

“This is not a perpetual motion machine, because reservoir temperatures are changing.” Is it a valid argument?

I've already faced this situation several times: given a statement (in area of thermodynamics) I used it to provide an example of some perpetual motion machine (of first or second kind). Therefore, I ...
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128 views

Physics of homebrewing heat exchangers

In homebrewing on of the key steps when brewing with extract is to rapidly chill the wort from boiling temperatures to about 80F in 30 min. This is needed to reduce risk of environmental ...
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59 views

Temperature measurement, precision

I am having problems with one of the problems I have done (a) which is basically $\theta = 273.16K (19/15) = 346.00K$ For (b) I am given that the length is 15.00cm when the thermometer is incontact ...
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1k views

Carnot efficiency, coefficient of performance for a refrigerator

I was reading that a new type of refrigerator might reach a coefficient of performance (COP) of 10. This seems quite the achievement and the authors state that their approach might achieve a Carnot ...
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57 views

upper bound for the Kelvin scale [duplicate]

Possible Duplicate: Why is there no absolute maximum temperature? On the Kelvin scale, absolute zero represents the temperature at which there is no thermal motion. Consequently, speaking ...
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47 views

What is the fluid approximation for BCS action?

For a system with free fermion gas at finite density (i.e. free Dirac action), we have an ideal fluid description with rho, p, n. What is the fluid description for BCS action? Suppose we have a box ...
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193 views

What kind of phases nanoparticles have (gas-solid-liquid)?

If a phase transition requires a number of particles that is in the TD-limit, can nanoparticles (~10 atoms) have phase transitions? What kind of phases and transitions nanoparticles have?
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438 views

Is the $mL_c$ value for triangular and rectangular fins the same value?

I am looking at the solutions that my professor put up and I feel that he did something wrong. Here is the question and I will give my stab at the solution so you can see why I think that it is wrong. ...
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464 views

How equivalent are heat energy and work energy in connection with a spinning flywheel?

Let's say we have two identical spinning flywheels, that have arbitrary geometry, and are made of copper. Now we apply some heat energy at the center point of flywheel A, causing it to slow down a ...
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379 views

Exam review question on thermodynamics [closed]

A cube has a side length of $20\text{ cm}$. An atom in the gas moves around the cube as shown. It continually bounces off the four lateral walls of the cube. The atom has a mass of $6.6\times ...
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64 views

How many times brighter could the stars shine without raising the temperature of space?

If my understanding is correct, the temperature of space (as defined by the temperature that a black-body will reach) has been decreasing since the big bang. It has never increased. Additionally, ...
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732 views

Do the properties of two streams flowing into an engine add together when they mix?

Let's say I have two stream supplys that have separate mass flow rates, enthalpies, and velocities that flow into an engine. Upstream of the engine's inlet, the two streams mix to form one stream that ...