Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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246 views

Computing the efficiency of a heat engine

With the heat engine we have an ideal gas working the substance. I want to show that the efficiency of this heat engine is $$\eta = 1 - \frac{1}{\gamma}\frac{\bigg(\frac{V_3}{V_1}\bigg)^\gamma - ...
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1answer
366 views

How to determine the amount of light energy (photons) being released from an incandescent light bulb?

I have got this all down pat: 1.Collision with a moving particle excites an atom. 2.This causes an electron to jump to a higher energy level. 3.The electron falls back to its original energy level, ...
5
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1answer
297 views

A thermodynamic transformation that can be represented by a continuous quasistatic path in its state space may still be irreversible. Why?

A thermodynamic transformation that has a path (in its state space) that lies on the surface of its equation of state (e.g., $PV=NkT$) is always reversible (right?). However, if the path is a ...
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2answers
749 views

Adiabatic filling of a container

Suppose a thermally insulated container is filled with atmospheric air until the pressure reaches 5000 psi. This could represent the filling of a diving cylinder, before thermal dissipation becomes ...
2
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1answer
295 views

Is there an easy way to get water at roughly 70°C in our kitchen?

Some green tea requires to pour water at 70°C. I have no thermal sensor or kettle with adjustable temperature with me. Do you know a way to get water at roughly 70°C like “boil water and wait for x ...
3
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1answer
588 views

Should entropy have units and temperature in terms of energy? [duplicate]

I've been thinking about entropy for a while and why it is a confusing concept and many references are filled with varying descriptions of something that is a statistical probability (arrows of time, ...
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2answers
147 views

Waterflow of coolant in nuclear reactor [closed]

The generator in a nuclear reactor delivers 580 MW electric power. a) How much TWh electrical energy is delivered yearly if the reactor runs only 70 % of the time? b) What flow of coolant ...
2
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1answer
101 views

Textbook Problem: Free energy expression

In Klotz, Introduction to Chemical Thermodynamics, Ex. 8.2 requires me to derive $$ dG = V \left( \frac{\partial p}{\partial V} \right)_V dV + \left[ V \left( \frac{\partial p}{\partial T} ...
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1answer
70 views

Bug in linear thermal expansion, $L_0$ must be $0$

Assume we change the temperature of an object with negligible size in $2^{nd}$ and $3^{rd}$ dimensions from $T_0$ to $T_1$ to $T_2$, with all of them pairwise different. We choose a substance with ...
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3answers
320 views

Why does Joule heating not occur when no current flows through a conductor?

Joule heating happens every time when the conduction electrons transfer kinetic energy to the conductor's atoms through collisions, causing these conductor's atoms to increase their kinetic and ...
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2answers
1k views

Must a reversible engine be a carnot engine?

I have this homework question: "Show that any reversible engine operating between T1 and T2 is a carnot engine." I think I have a solution, but it feels very hand-wavy. We know that any process that ...
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1answer
207 views

Does the big bang violate the conservation of energy? [duplicate]

It is a fact that a thing is existing now because it had already been created. So why don't we take this to account to redefine law of conservation of energy.
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3answers
247 views

What limits the mass transfer from a boiler to a condenser in a sealed vessel?

If we set up an evacuated vessel where we keep one end at a higher temperature than the other, and then introduce a liquid at the warm end, it will evaporate and condense at the cooler end. If we trap ...
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2answers
398 views

How does one calculate where the “surface” of a gas-giant would be?

Okay, so Jupiter, Saturn, et. al are gas giants. I understand that they have large gassy atmospheres, which, due to the pressure would eventually become more and more dense as one approaches the ...
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1answer
158 views

What's the relationship between the energy density of a black-body and its radiant exitance?

Through a bit calculation we can derive that in a cavity, the energy density $$u(f,T)=\overline{E(f)}\times G(f)=\frac{8\pi h}{c^3}\frac{f^3}{e^{h\nu /kT}-1}$$ If we take the integral over all ...
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2answers
285 views

Thermalisation - Open quantum systems

I would like to understand better a phenomenon of a quantum heat bath. Below I present one example, which seems quite clear to me. It would be great to see some less-discrete models, and more ...
5
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1answer
207 views

Is there valid physics behind the bodybugg?

The bodybugg is a faddish gadget whose marketers claim it can measure your body's daily energy expenditure. Their sales literature says: As reported in the British Journal of Sports Medicine, 2008 ...
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2answers
577 views

Why does Platinum evaporate if left long enough?

I have been reading into research relating to the redefining the 1 kg weight as the current Platinum-Iridium is becoming smaller. In this article, here, it mentions that the original metal weight ...
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1answer
228 views

What is the net radiative balance between two blackbodies with different temperature?

Context In trying to understand a crop productivity model, I want to figure out how to derive the equation for the net exchange of longwave radiation between two adjacent blackbodies (soil and ...
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0answers
82 views

How can we calculate heat transfer through hot gas to moving thermic fluid? [closed]

Heat is to be transfer from $CO_2$ gas to fluid. $CO_2$ is being heated by solar energy. How can we calculate heat transfer from the hot $CO_2$ gas to the moving fluid?
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1answer
211 views

Do ice crystals grow only as heat is being removed or also when an item is at a set temperature?

Chicken develops ice crystals between -2C to -4C. Now as chicken's temperature moves slowly from -2C to -4C ice crystals will grow. However, let's say that in a freezer, we set the final temp to -3C. ...
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2answers
793 views

How does a gas of particles with uniform speed reach the Maxwell-Boltzmann distribution?

Take an empty container and fill it with $N$ gas particles (ideally a monoatomic gas), each having the same kinetic energy $E$, then isolate the container. Since initially the speeds don't follow the ...
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2answers
488 views

The statistical nature of the 2nd Law of Thermodynamics

Ok, so entropy increases... This is supposed to be an absolute statement about entropy. But then someone imagines a box with a 10 particle gas, and finds that every now and then all particles are in ...
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0answers
62 views

Which pressure to use in the $T~ds$ equation?

Let's say I have an adiabatic, rigid, open container that has an amount of air at some pressure, $P_\text{cv}$, and some temperature, $T_\text{cv}$. I have heated pressurized air coming into the ...
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3answers
380 views

Shouldn't the sign of generated entropy always be positive?

I have a process where 10 g of liquid lead at 400 C is dropped into a water bath that is at 25 C. The lead solidifies over time and comes to thermal equilibrium with the water bath. The bath is so ...
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1answer
240 views

How does heating cause motion?

W.R.T. Newton's laws a force is required to change the state of rest of a body. Then how does heating cause a particular object's atoms and molecules to wiggle ? What is the force being applied when ...
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3answers
5k views

What is the Units for Thermal conductivity?

What are the units for thermal conductivity and why?
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1answer
136 views

Water coolso object by heat absorption [duplicate]

Why do water of water based liquids like sweat cool objects? The most clear example I have is the sweat on the skin. I learned that it absorbed heat because it evaporates, but this is something ...
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0answers
140 views

Which cosmological models support the Boltzmann Brain Paradox?

In this article, they mention that the Boltzmann Brain paradox is supported by 'the best cosmological models.' However, it gives no references, and I haven't found any by a Google search. I was ...
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0answers
426 views

Making an equal amount of positive and negative energy?

I was wondering if it would be possible to create an amount of positive energy out of a vacuum, in addition to an equal amount of negative energy, thus not violating the first law of thermodynamics, ...
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1answer
345 views

Why do humans like to break the second law of thermodynamics? [closed]

Roughly speaking, Entropy is a measure of the disorder of a system. However as humans, we tend to do the complete opposite. For instance, in a home if a painting that is hanging on the wall is ...
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0answers
89 views

Best material for heat transfer between ice and water

What is the best container material for heat transfer between ice and water? this is a difficult question to ask without displaying a picture of what I'm meaning.
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1answer
667 views

What sense can be made of the natural logarithm in physics? [closed]

What sense can be made of the natural logarithm, When appearing in a physical process? For example, This integral in the thermodynamic $\int_i^f \frac {dV}{V}=Ln\frac {V_f}{V_i}$ when $V$ denotes ...
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5answers
2k views

Perpetual motion machine of the second kind possible in nano technology?

First of all sorry for my English - it is not my native language. During my engineering studies at the university the thermodynamics professor told us that the "second law of thermodynamics is not ...
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1answer
282 views

What is the physical basis behind thermal diffusion in a Clusius-Dickel column?

A Clusius-Dickel column allows separation of two species by the application of a thermal gradient. In its simplest form, two bulbs are maintained at two different temperatures $T_1$ and $T_2$ and ...
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2answers
260 views

Second law of thermodynamics implies a linear cosmology?

If one applies the second law of thermodynamics to the Universe[1] as a whole then one might expect that the entropy of the Universe always increases as time goes forward (or more accurately that the ...
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1answer
114 views

Evidence of atoms from Dulong–Petit law?

All materials have same molar specific heat, cf. the Dulong–Petit law. Is it an evidence of atoms? What other examples are there for atomic theory?
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4answers
7k views

Why does boiling water in the microwave make a cup of tea go weird?

When I boil water in the kettle, it makes a nice cup of tea. Sometimes I need to use a microwave because a kettle isn't available. I boil the water in the mug and it looks pretty normal, but when I ...
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1answer
275 views

Do bifacial solar panels operate at lower temperature than normal solar panels?

Bifacial solar panels have a glass backplane instead of the usual aluminum and are designed to absorb and convert to electricity light incident on either face. Many manufacturers claim that their ...
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1answer
806 views

Stress due to the mismatch of thermal expansion coefficients of two different attached materials

I'm simulating the thermo-electro-mechanical behavior of a copper wire which is surrounded by silicon dioxide. In other words, the wire segments is under mechanical and thermal loads and at the same ...
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2answers
370 views

Does heat radiation come from the nucleus or the electrons?

Is more of the thermal radiation due to acceleration of electrons or acceleration of the nuclei? Do electrons and nuclei carry the same fractions of thermal energy in a hot body?
9
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2answers
299 views

Would this pump water up? and if so, how far?

I had this idea of an osmotic pump way back in high school and I never got a satisfactory answer if it would work. If I had this configuration: Would it continually pump water up given ambient ...
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2answers
593 views

Boundary between supercritical fluid and gaseous phase

As far as I understand, going around the critical point, it is possible to transform a liquid into a gas without seeing a phase transition. Does this also mean that there is no clear separation ...
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0answers
31 views

Is there a thermodynamic law or theorem that expresses how systems “break” or “change” when enough energy is added?

I have a simple question about thermodynamic laws, and I am hoping you can help me. Let's say that I have a sphere container with some pressurized gas in it. I can slowly increase the pressure over ...
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3answers
11k views

Thermodynamics: Are pressure and temperature enough to calculate enthalpy?

From the chart above, it looks like it is possible to calculate enthalpy from just pressure and temperature. After a few hours of Googling my question, I'm not able to find anything helpful. My ...
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2answers
1k views

When is temperature not a measure of the average kinetic energy of the particles in a substance?

I had always thought that temperature of a substance was a measure of the average kinetic energy of the particles in that substance: $E_k = (3/2) k_bT $ where $E_k$ is the average kinetic energy of ...
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1answer
61 views

Fourier rate equation valid in which frame of reference?

I wonder about the following; the Fourier rate equation of heat conduction states: $$\vec q = -k\nabla T$$ But I'm wondering if this is valid in every frame of reference, because the heat flux $\vec ...
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1answer
110 views

Explanation Needed: Thermodynamics of a hot/cold water jet machine

I didn't know where to begin with this problem. I eventually found a solution online, which is why I'm reposting this question with an answer. I was wondering if anyone can explain the one question I ...
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1answer
2k views

Can water exist as liquid in a vacuum chamber at room temperature?

I know boiling point at vacuum is far below the room temperature. But I still wondering if the humidity reaches the saturated humidity (100% relative humidity), will the vapor condense to liquid, ...
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3answers
1k views

Melting and freezing point

Why is the melting and freezing point of a substance are always the same ? This was quoted in my textbook but they didn't give a reason for this being so. Thank you.