Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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35 views

time factor of heat increase (specific heat)

It takes 4 joules to bring 1 gram of water up 1 degree, but for how much time - 1 second? If not, how much and how to calculate it?
0
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0answers
39 views

heat transfer between objects

when we touch a very hot object, the edges of our skin interact with the object's high energy and velocity particles and molecules. why is it physically that we get "burned" by extremely cold objects ...
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0answers
58 views

Partition function for a two state system

We have a system of two energy states and we treat classical distinguishable and indistinguishable particles respectively. For the distinguishable case I thought that all in the left one one left ...
2
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1answer
57 views

thermodynamics trace calculation [closed]

I'm trying to calculate a trace to get the average energy. The Hamiltonoperator is $H = \sum\limits_k \varepsilon_k a_k^\dagger a_k$ and $N = \sum\limits_k a_k^\dagger a_k$. The trace to calculate is ...
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1answer
210 views

Reversible and Quasi-static processes

Do we have any proof that reversible processes are always quasi-static or is it just a fact that hasn't been violated till date? If there is a proof then please provide a link.
0
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1answer
94 views

Blowing on a hot liquid [duplicate]

Lets say you have a nice bowl of piping hot soup. You use your spoon and take a sip and realize its too hot. So you blow on it a few times and now its cooled enough that it doesnt burn your mouth. ...
0
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1answer
89 views

When does exergy destruction occur?

I am doing a project on developing a code for the first and second law analysis of the Brayton Simple and Modified cycles. The first law part is simple. But I have run into a roadblock when I started ...
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1answer
127 views

Where do limits of integration come from in the equation of heat transfer by conduction?

I was watching the third lecture of Diffrential equations on OCW. As an application, the model of heat transfer by conduction is provided. We derived this equation which models the system where $T$ is ...
5
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4answers
269 views

Thermodynamics thought experiment

There is some ideal gas in a container moving with some velocity on a smooth surface and you suddenly stop it( say by using your hands) , will the temperature of the gas increase? It seems to me that ...
2
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1answer
168 views

Is Carnot engine the only reversible engine?

Is Carnot engine the only form of reversible engine? Is it possible to have a different form of reversible engine that goes through different processes? For a standard Otto cycle working with ideal ...
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0answers
46 views

Heat loss from hot cast iron oven

I am considering an unconventional pizza oven made from cast iron. What is a good formula for estimating non-radiative heat loss from a 450C/850F surface in a 20C outdoor environment? I am looking ...
2
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2answers
340 views

How to use the first law of thermodynamics for simple mechanical systems?

I'm confused about what exactly is $Q$ and $U$ and their signs. Consider a block initially having some kinetic energy which we stop and we want to find by how much amount its temperature increases. ...
2
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1answer
37 views

pV work in reversible processes. Why is $p_{ext}=p_{internal}$ in a contraction?

My textbook uses newtons third law to say to prove this. I think that's completely wrong. What I think happens is that we are doing an approximation that $p=p+dP$. In case you haven't figured it out, ...
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1answer
3k views

Can a liquid boil in a closed container?

The title says it all. When one fills a container (with water for example) and closes it so no air can escape from it, then heats the container continuously, can the liquid boil or completely ...
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0answers
37 views

Question about fluid expansion

Hy, When a hot and dense fluid suddenly expands, how much can it cool down. Lets take for example an expansion valve from an AC, does the fluid do work when passing through the valve or does it not ...
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1answer
157 views

Joule Thomson effect

I have difficulties to understand the Joule Thomson coefficient given on the wikipedia page. It says that $(\partial_p T) = \frac{V}{C_p}( T \alpha -1)$. Now my problem is that I don't know about ...
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1answer
153 views

Thermodynamics and Internal Energy

I've been working on this problem for quite some time trying to figure out the most efficient way of answering it, So here goes the problem: There is a container, containing a monoatomic gas with ...
13
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2answers
461 views

Definition of stress at the microscale

Take, for simplicity, a Lennard-Jones fluid below the critical temperature, which is to say that there is a phase separation into fluid and gas and thus an interface is formed. The macroscale picture ...
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2answers
256 views

Symplectic geometry in thermodynamics

There seems to be analogues between Hamiltonian dynamics and thermodynamics given the Legendre transforms between Lagrangian and Hamiltonian functions and all of Maxwell's relations. Poincarè tried to ...
2
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1answer
105 views

Why are heat-shields on re-entry vehicles smooth and not textured to increase drag?

Meteorites naturally texture themselves via the formation of regmaglypts, 'thumbprint-shaped' indentations caused by ablation of their surface, during entry into the atmosphere. This appears to ...
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1answer
7k views

Why is black the best emitter?

Why are emitters colored black better emitters than other colors? Why is white a worse emitter?
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1answer
633 views

Calculate mass of ice needed to cool water $\Delta$T degrees

I have a question about a thermodynamics formula I'd like to apply in my solution to a problem. The problem is "Determine how much ice one needs to toss into boiling water of mass $m_{w}$ such that ...
3
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4answers
420 views

Can a single molecule have a state?

I was studying a book about thermodynamics of nanosystems and I got stuck with this question in my mind which I couldn't find an answer for. For instance, does a single water molecule have a state, ...
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1answer
47 views

Can a Fermi gas and a Bose gas be both at the same pressure and temperature?

The title says it all: can a Fermi gas and a Bose gas be both at the same pressure and temperature? It comes from a quiz about statistical mechanics
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2answers
463 views

transfer of heat from lower to higher temperature [duplicate]

Can heat be transfer from low temperature body to high temperature body? Because according to second law of thermodynamics it can be transfered. But how?
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1answer
295 views

Meaning of chemical equilibrium between two phases

Suppose two phases 1 and 2 of water, say ice and water, are kept in a closed container, at a fixed temperature $T$ and fixed pressure $P$? Then I have the following question: Is phase 1 in ...
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2answers
95 views

Free Expansion - Paradox?

Let's say I have an isolated, adiabatic chamber which is divided into two parts with a massless, frictionless piston. One part has vacuum, while the other has a gas. In the beginning, they are at ...
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1answer
1k views

Does tin foil keep heat out?

For example, if i were mailing a box of chocolates and lined the inside of the box with foil, then wrapped the chocolate in bubble wrap and placed it inside the foil lined box, would the box heat up ...
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0answers
221 views

What is the minimum temperature of a metal surface to ignite a cigarette touching it perpendicularly?

Suppose you have a cigarette tip touching a metal surface at a 90 degree angle, exposed to air at 25C / 1atm, no wind, normal oxygen concentration. Cigarette is a regular brand, tobacco with paper ...
3
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2answers
257 views

Why doesn't a glass french press shatter when boiling water is poured in?

When I was little, I accidentally shattered a glass cooking instrument due to applying far too drastic a temperature change to it. Since then, I've been a bit afraid of doing it again. Of late, I've ...
2
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1answer
130 views

Difference between collisional and collisionless Boltzmann equations?

Reading an excellent answer, I've read about there are different Boltzmann statistics for a collision-less system (f.e. stars in a galaxy) and in a system with collisions (f.e. gas in a closed box). ...
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1answer
88 views

Thermodynamics - mass of gas expelled

Question: An open vessel contains 200 mg of air at 17 degrees Celsius. What percentage of weight of air would be expelled if the vessel is heated to 117 degrees Celsius if the pressure is to ...
3
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1answer
132 views

Is there a “high temperature” variant of 0 degrees Kelvin? [duplicate]

I know that -273.15 degrees celsius, also known as Absolute Zero or 0K is the low temperature limit for objects, but is it possible that there is a 'highest temperature?' I would have to guess that ...
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2answers
891 views

If an object falls - regarding air resistance - does the Potential or Kinetic energy get converted into thermal energy as it is falling?

I read a paragraph on the transfer of potential energy to kinetic energy and heat from this website: Even if air resistance slows down the ball, the potential energy is the same (Mb x g x H). ...
2
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0answers
318 views

Diffusion in a chemical potential gradient

I am having troubles to understand to connection between equilibrium and non equilibrium thermodynamics. I am studying a mixture of molecules $A,B,C$ and solvent $S$. The free energy $F$ is given by ...
2
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1answer
139 views

Blackbody radiation in thermally inhomogeneous environment

The power radiated by the backbody is according to Stefan-Boltzmann law $$ P = \sigma \varepsilon A (T^4-T_{env}^{4} ).$$ Is the parameter $T_{env}$ supposed to be only the temperature in the near ...
2
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2answers
220 views

Does radiating heat to outer space through the atmospheric transparency window have any impact on heat loss?

I was reading this article: Passive radiative cooling below ambient air temperature under direct sunlight The authors are improving upon the age-old idea of reflecting incoming sunlight while ...
6
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1answer
139 views

Do the stars in a galaxy have a thermal kinetic energy distribution?

I think, there is practically everything given to that: many point-like masses, able to exchange energy pseudo-randomly, and far long enough time to reach a thermodynamical equilibrium. Of course, ...
3
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1answer
184 views

Is temperature affected by gravitational potential?

Ok, I feel a bit silly asking this. I'm asking in relation to this question here on the molecular basis of hydrostatic pressure in a gas. There's been quite a bit of discussion and one of the ...
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0answers
100 views

Negative temperature thermodynamics

I asked this question about thermodynamics. I considered $$T=\frac{\partial U}{\partial S}$$ at constant $V$ and $N$ (number of particles), but now I can't figure out the change of $U$ with respect ...
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2answers
689 views

Where does the joules come from (ideal gas constant)?

I have not done any physics in ages and have recently started studying it. The first chapter in my book deals with the ideal gas constant: $$pV=nRT$$ It is rewritten as: $$R=\frac{pV}{nT}$$ When I ...
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1answer
51 views

Is the equilibrium state in thermodynamics a consequence of the second law of thermodynamics?

Is the thermal equilibrium state the state of maximum entropy? Is it a consequence of the second law of thermodynamics?
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1answer
94 views

Human body emits Radiation [closed]

Human being emits which type of waves and how to find that waves any possibility to detect this waves by Using sensors
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0answers
63 views

I need to remove water from a system [closed]

I work in an industry and I need to remove water from a system. The scenario: There is a washer and a blower on a conveyor belt. The item being washed is plastic (not sure what type) and can't be ...
2
votes
1answer
91 views

How can we describe or model the spread of ice during the freezing of the surface of a still lake?

Premise: I live in a place where it is unquestionably wintertime in every aspect of the phrase. I was driving down the street and I drove by a lake. There was a recent and sudden temperature drop ...
1
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2answers
138 views

Can kinetic energy in atoms result in emission of all types of EM radiation?

I already know the fact that when solid objects heat up, they emit thermal energy which is also known as infrared radiation. However, if the atoms in that solid were to begin gaining more or less ...
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1answer
888 views

What makes a thermodynamic canonical variable canonical?

The last paragraph of page 1352 of IUPAC Technical Report Use of Legendre transforms in chemical thermodynamics" (Alberty, R.A., Pure Appl. Chem., Vol. 73, No. 8, pp. 1349–1380, 2001) says that ...
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1answer
121 views

Thermodynamics - internal energy

What would the curve that describes the change of internal energy ($U$) with the volume ($V$) be like if the change in the temperature is negative? My try: For a ideal monoatomic gas, we have ...
1
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1answer
120 views

How is heat and temperature related? How will a thermometer react in the following conditions? [closed]

Consider the cooking stove and LPG fuel for example, all my questions will be related to it. Assume I have a frying pan made of steel which is kept on the the stove with the knob set to moderate. ...
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1answer
50 views

Closed system, gas change in time

I'm trying to find out how to determine how a pressure of gas changes in time, but I can't find a way. I have a system with constant volume $V$ (closed system, exchanges heat with environment through ...