Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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247 views

System in mechanical but not thermal equilibrium

Let's say there are two systems which can interact by a moving wall but cannot exchange heat. Then the system will be in mechanical, but not necessarily in thermal equilibrium. The maximality of ...
2
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1answer
162 views

Immediately after the Big Bang, was the universe in a state of extremely low or extremely high entropy?

Phase space theory suggests that the largest course-graining region, $p$, in a phase space, $P$, is the point in the phase space with the highest entropy. As such, it is in thermal equilibrium with ...
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3answers
833 views

Why is the Gibbs Free Energy $F-HM$?

With magnetism, the Gibbs Free Energy is $F-HM$, where $F$ is the Helmholtz Free Energy, $H$ is the auxiliary magnetic field, and $M$ is magnetization. Why is this? Normally, in thermodynamics, we ...
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0answers
100 views

Adiabatic Expansion with expanding control volume

I have a tube with a length $L$ and diameter $d$ that is open on 1 side. At a certain point (say $x$) from the closed end of the tube, I have a gas with a high pressure. At this point, $x$, there is ...
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1answer
150 views

Aerodynamics and thermodynamic [closed]

Why can we refer an object as being aerodynamic but we can't refer an object as being thermodynamic, and if an object is thermodynamic what does it even means?
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1answer
88 views

Ideal gas system with diathermic piston externally manipulated

I wanted to ask about the following problem: An ideal monatomic gas is separated into two volumes $V_{1}$ and $V_{2}$ through a diathermic piston, such that each volume containing $N$ atoms and the ...
15
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1answer
901 views

Why doesn't breath condense around poop of flies on the window's glass?

One day it was raining outside and I was breathing on the glass of my window. I noticed that around the spots of fly poop there is a circle where vapor does not condense. With time the circle becomes ...
2
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1answer
113 views

Enthalpy in thermodynamics!

What does enthalpy tell us about? According to definition; it is the total heat content of a system, if it is the total heat content of a system then what is Internal Energy? Since we know, ...
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2answers
98 views

EM Radiation and Heat

If there is EM radiation, will there always be a heat exchange between the wave and its surroundings? If you have an extremely energy-efficient light bulb that converts ALL the energy it receives into ...
2
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1answer
642 views

Specific heat of aluminium as a function of temperature

I am trying to find the curve describing the specific heat of aluminum as a function of temperature between about 50K to 300K(or room temperature) for an experiment I am doing. Ultimately I need to ...
9
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4answers
455 views

Can we detect whether food has previously been heated in a microwave oven?

An acquaintance told me that she refuses to eat microwaved food because she read that the microwave changes the molecules of the food somehow. Her statement is vague and her sources are dubious but I ...
2
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0answers
103 views

Lennard-Jones induced pseudo-molecules

It can be shown that the Lennard-Jones potential - which describes the interaction between particles in non-ideal gases - gives rise to pseudo-molecules: after a triple "collision" of three ...
3
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2answers
617 views

Can you extinguish a fire by cooling down the fuel?

I know that temperature plays a crucial role in the process of ignition, as most combustible materials will spontaneously start burning in presence of enough oxygen when heated above the kindling ...
3
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1answer
272 views

How do you explain the fact that when air expands freely into an evacuated chamber from a constant pressure atmosphere, its temperature increases?

I came across this paper: Baker, B. (1999). An easy to perform but often counterintuitive demonstration of gas expansion. American Journal of Physics, 67(8), 712-713. ...
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2answers
527 views

Physical significance of negative temperature

I read some answers regarding negative temperatures but I think my question is new. I want to know that what is the physical significance of negative temperature. Suppose I say a body has ...
2
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2answers
235 views

Heating effects of microwaves

I understand the heating effect(dielectric heating) of microwaves. This heating is caused by using a frequency of 2.45 GHz and this is the same frequency at which Bluetooth works and the L and S ...
1
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1answer
106 views

Definition of entropy

In my textbook there is written $$\Delta S = \int_R \frac{\delta Q}{T}$$ where the $R$ means calculated along a reversible transformation. The variation of entropy only depends upon the ...
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2answers
770 views

Why is the direction of a flame is always upward? [duplicate]

why a candle's flame direction is always upward? What is the coposition of fire? Don't say it's energy. There is something else.
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3answers
357 views

Why does ice melts, waits for 100 degrees and THEN vaporises? Why is not the process of expansion of things continuous?

What I am asking is this: Why can't a body be solid, then solid-ish, then solid-like, then liquid-like, then liquid-ish, then liquid, then vapor-like and then vapor? Why is there a rigid temperature ...
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1answer
686 views

Meaning of heat sink in engine analysis [closed]

I am confused with the meaning of sink. What part of vehicle engine acts as reservoir and what does as sink?
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1answer
167 views

Comparing unknown temperature scales [closed]

Source: Principles of Physics by Resnick, Halliday, Walker. $9^{th}$ edition. Chapter 18. Problem 6. On a linear $X$ temperature scale, water freezes at $-125.0^0X$ and boils at $360.0^0X$. On a ...
47
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5answers
13k views

Why does a candle blow out when we blow on it? Our breath is 16% oxygen and only 4% CO2

Don't say that a layer of carbon dioxide covers the flame, because our breath has more oxygen than carbon dioxide. Also, our breath does not cool the flame as it is itself warm. So what is happening ...
6
votes
1answer
145 views

Doubts about the ideal gas law

EDITED AND SOLUTION: In fact my stupid mistake was to take the wrong value for my $P_1$ and I was getting an 1.2998 that finally is a 1,9178 within just a difference about 7%. So at the end they are ...
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1answer
410 views

Understanding collision terms in Boltzmann equation

I am reading a paper that deals with the Boltzmann equation. They add a collision which is supposed to account for collisions which happen when particles are within a radius of $d$ from each other. ...
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0answers
55 views

Explain Heat Transfer

I would like to know what are these formulas used for. There is no intro about it in my book at all, and I am reading Heat Transfer book. If needed Q. can be edited.
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1answer
170 views

Does thermal energy include the kinetic energy of the electrons?

Or is the kinetic energy of the electrons not counted towards the thermal energy? (In other words only the energy of the lattice structure is counted)
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0answers
58 views

What's the connection between being homogeneous in energy and having a proper time scale?

Towards the end of page 8 of this scientific paper, I have found the following sentence: ...given the fact that the system is homogeneous in energy, or equivalently, that it has no proper time ...
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0answers
277 views

Determine pipe outlet temperature without length?

Let's say I am flowing a fluid through a pipe that has a constant surface temperature. Is it possible to determine the heat flux on the inner surface without knowing the pipe's length when the only ...
2
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2answers
116 views

Container divided in two parts with ideal gas

I wanted to ask your help with the following problem: Consider a closed container, that is, with insulated walls impervious, and rigid. The container is divided into two parts by a wall having the ...
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0answers
65 views

Applied / environmental question: direction of exhaust fumes

I'm not sure the Physics StackExchange is the perfect place for this environmental/applied physics question, but as I found no forum more fitting I ask my question here. Otherwise please move my ...
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3answers
211 views

Turbofan: Efficiency wrt. the bypass ratio: “a lot of slow air > a little faster air”?

Reading / viewing up on how jet engines work, this video explains at the 9:02 mark that, for turbofan engines, ".. it is more aerodynamically efficient to have a lot of air moving relatively slowly ...
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1answer
88 views

Why is $\left.\frac{\partial C_V}{\partial V}\right|_T$ different in these derivations?

I want to show that $\delta q$ is not an exact differential. Starting from $dE = \delta q - pdV$ and because $E := E(V, T)$ is a state function, which allows to express the exact differential as $$ ...
0
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1answer
82 views

Density as a function of Temperature?

I know that volume = mass/density....and density is the function of temperature. Is there any standard equation that describes density as a function of temperature? The system I am interested in is ...
6
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2answers
357 views

What is the resolution to Gibb's paradox?

This question is essentially a duplicate of Gibbs Paradox - why should the change in entropy be zero?. The question concerns the following situation: I have some gas of identical particles and they ...
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0answers
58 views

How hot is it on the slopes of an erupting volcano?

I was watching The Return of the King and just after Frodo and Sam destroy the One Ring, they run out of the mountain and hide on top of a rock as the volcano erupts and lava flows past them. Is this ...
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0answers
29 views

where i can find thermodynamics properties of octane

where can I find thermodynamics properties for octane at $T_s$? I need this properties or where can i find all ? $$liquid-density=\rho_l=?$$ $$vapor-density=\rho_v=?$$ ...
3
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0answers
31 views

Experimental results regarding non-extensivity in small systems

From a statistical mechanics point of view, the extensivity of thermodynamics arises from the fact that we can neglect interaction terms in the Hamiltonian. This allows us to infer that when we put ...
3
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1answer
55 views

What is the equivalent of a eutectic point for a (two-liquid)+solids system?

I deal with complex phase equilibria involving solid and liquid phases at high temperature. Below is a simplified temperature-XH2O diagram for a multicomponent system at constant pressure. (Note: ...
0
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2answers
732 views

Auto-refrigeration

I'm reading about the auto-refrigeration effect and can't find a really good explanation. Is the idea that when you have your condensed liquid, and then release it into a low pressure environment, ...
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1answer
134 views

Fluid Temperature as a function of Mass and Ambient Temperature

Problem I am trying to create an equation to calculate fuel temperature based on ambient temperature, heat exchange rate, and mass. The idea is very simple; when the mass is heated, depending on how ...
0
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1answer
52 views

Thermodynamics of zinc chloride to zinc

I am trying to deposit zinc metal from zinc chloride using chemical vapor deposition. But it is thermodynamically feasible to obtain zinc from zinc chloride?
3
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2answers
95 views

Prove identity of partial derivatives

I can not do the following problem: Prove the identity: $$\left( \frac{\partial x}{\partial y} \right)_{z}\left( \frac{\partial y}{\partial z} \right)_{x}\left( \frac{\partial z}{\partial x} ...
5
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3answers
1k views

Does evaporation decrease entropy?

I have a container of water in thermal equilibrium (there are no temperature fluctuations inside the container). Some molecules will evaporate out of the container of water thus decreasing its ...
2
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3answers
678 views

work equals heat in isothermal process only for ideal gas?

Is it only for an ideal gas that the work equals negative the heat in an isothermal process or is this general for all kinds of systems? Or put differently, how do I know that for an ideal gas the ...
4
votes
2answers
915 views

Why does my kettle only make a noise when it is turned on

Almost as soon as I turn my kettle on it starts to make the familiar kettle noise, yet very shortly after turning off the power the boiling noise stops and the kettle is totally silent. The ...
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2answers
194 views

How does electric current generate thermal energy?

How does free electrons moving through a wire cause random vibrational motion of the positive ions?
3
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5answers
2k views

Does entropy increase or decrease as our Universe is expanding?

Scientists say that entropy of our universe is increasing as it is expanding and our universe is cooling down gradually from the time of its birth. If something is getting cooler and cooler, then how ...
0
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2answers
199 views

Inequality of Clausius

I'm having some trouble understanding the inequality of Clausius. My treatment of the inequality applies to an engine operating in a cycle between two temperatures (i.e. like a Carnot engine). The ...
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2answers
87 views

Coupling constant is turned off adiabatically?

To me, adiabatic processes are idealisation. What do people mean with statements such as: "turning off the coupling constant (in QED say) adiabatically"?
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2answers
627 views

Why does welding produce UV light?

Looking directly at a welder is dangerous because large amounts of UV light is produced. What makes this light? Is it electrons from the current that excites metal atoms, and these atoms sends out UV ...