Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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218 views

Does the black body emit more than any other type of body?

I found this on Wikipedia article on black bodies: A black body in thermal equilibrium (that is, at a constant temperature) emits electromagnetic radiation called black-body radiation. The ...
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1answer
344 views

What happens to pipe outlet temperature here?

I have a fluid flowing through a pipe in the ocean and there is heat transfer from the ocean to the fluid in the pipe. I prepared a simulation and the results show that if I increase the mass flow ...
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7answers
9k views

Does an empty refrigerator require more power to stay cold than a full one?

Given that everything else is equal (model of fridge, temperature settings, external temperature, altitude), over a given duration of having the door closed, does it require more electricity to cool ...
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1answer
332 views

How is the index of refraction dependence in Planck's law compatible with thermodynamics?

In various formulae for black-body radiation where $c$ appears, there is an implicit index of refraction dependence, since $c=c_0/n$, where $c$ is the speed of light, $c_0$ is the speed of light in ...
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2answers
106 views

Why not assimilate nuclear waste into “igneous” rock?

I was reading a question about why not to drop nuclear waste into volcanoes; the short answer is it would come back out and not be rendered safe. Ignoring the cost and energy requirements, why can't ...
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0answers
554 views

what's the difference between linear n-atom molecule and nonlinear n-atom molecule?

I am reading a material about the degree of freedom for linear n-atom molecule and nonlinear n-atom molecule. Here is my analysis for a diatomic molecule, if there are two atoms, we have to use 3 ...
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0answers
37 views

Henry's Law in metals

For fixed temperature the concentration of a gas dissolved in a solution is directly proportional to the gas pressure $p$, i.e. $c_s (T,p) = f(T)p$. Since $H_2$ only dissolves in metals as single ...
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2answers
200 views

Heating and Recooling of an Object

Consider a piece of metal of length $L$ and linear thermal expansion coefficient $\alpha$. We eat the metal $\Delta T$ degrees, causing the metal to increase to length $$ L' = L + L \alpha \Delta T$$ ...
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1answer
188 views

What happens at the interface between two universes with opposite thermodynamic arrows of time? [closed]

I was trying to think but cannot figure it out. For instance, if the interaction is small, for instance limited to a windows, the observers in each universe will see that the other goes in reverse. ...
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0answers
111 views

What temperatures can be reached in an air-to-air thermocompressor nozzle and why?

People are generally of the opinion that the boiler injector cannot be redesigned to run on air. In other words, an air-to-air thermocompressor that puts fresh air into a tank without a mechanical ...
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1answer
150 views

Uncertainty and Thermodynamics

Dilemma The uncertainty principle of energy and the 2nd law of thermodynamics don't add up : the uncertainty principle of energy says that $\Delta \tau \cdot \Delta E \ge \frac{h}{4\pi} = ...
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2answers
552 views

Computer cooling with dry ice, ideas and question; thermodynamics

I am designing a cooling system for my computer and had a few questions. So I have a computer water cooling radiator and I want to cool it as much as I can. My first two ideas were an old window A/C ...
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2answers
806 views

What are the units of these virial coefficients?

I'm reading some papers for calculating the vapor pressure of alkali metals as a function of temperature, and I've come across some familiar-looking virial expansions, but when I tried to work out the ...
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6answers
2k views

Why isn't temperature measured in Joules?

If we set the Boltzmann constant to $1$, then entropy would just be $\ln \Omega$, temperature would be measured in $\text{joules}$ ($\,\text{J}\,$), and average kinetic energy would be an integer ...
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1answer
156 views

Maximizing Multiplicity of Einstein Solid == (Temperature = $\infty$)?

If I have a system consisting of 2 Einstein solids (A and B) is it equivalent to say that maximizing the multiplicity of the ...
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0answers
49 views

Heat of adsorption from fugacity data

I have a set of data relating the fugacity ($\approx$ pressure) to the loading for a given set of temperatures. There are three temperature sets each having five fugacity vs. loading points. The ...
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0answers
62 views

Increase in number of micro states explanation or restatement of second law?

Is the boltzmann's expression of entropy as log of micro states leading to the formulation that system is more likely to be in a macrostate with more no. Of micro states really is an explanation or ...
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2answers
491 views

Spontaneous conversion of heat into work at negative temperatures

Consider a heavy macroscopic object moving in a gas. Friction causes its kinetic energy to be converted into heat. Thermodynamically, there is (effectively) no entropy associated with the kinetic ...
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2answers
118 views

Is it possible to “add cold” or to “add heat” to systems?

Amanda just poured herself a cup of hot coffee to get her day started. She took her first sip and nearly burned her tongue. Since she didn't have much time to sit and wait for it to cool down, ...
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0answers
1k views

Joule-Thomson effect of Van der Waals gas

I'm supposed to calculate the inversion pressure $p_i$ of a Van der Waals gas. The state equation of the Van der Waals gas is: $$(p + \frac{a}{V^2})(V-b) = RT.$$ To get a hold of the inversion ...
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2answers
133 views

gravity affecting a molecules speed? [closed]

Why are the poles colder than the rest ofthe planet?Is the gravity stronger making molecules spin slower?How does gravity affect heat and hydrogen bonds? And what affects gravity?A little off topic ...
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1answer
160 views

Liquid oxygen how do they use it as fuel?

Rockets are said to be using liquid oxygen as fuel. How do they use liquid oxygen since it's just oxygen, it only helps in the combustion process. How can it be a fuel on its own?
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2answers
4k views

Hot Air Balloon and Buoyancy

This is a conceptual question in a solution I am trying to understand. Problem statement: I have a balloon with a volume of V $m^3$. The outside air temp is $K$ kelvin and mass to lift is $m$ kg. I ...
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1answer
189 views

What is the term for heat generation by a flowing fluid?

I would like to know more about the heat distribution over time in a flowing liquid. To this end, I consider the Navier-Stokes equation (where the coefficients may be temperature dependent) and the ...
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1answer
1k views

How long does it take a warm object to cool in air?

This is a work-related question. A warm steel torus of a given diameter & thickness is left in a room held at a controlled temperature, how long does it take to reach equilibrium? Assume the air ...
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3answers
310 views

How can I determine the coefficient $k$ in $ \dfrac{dT}{dt} = -k(T - 100 \mathrm{^\circ C}) $?

I recently spend some time on cooking and I'm curious about the time evolution of the temperature of the water. I did some experiment and the temperature is of the form $$ T = 100 \mathrm{^\circ C} + ...
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2answers
573 views

Which form of the first law of thermodynamics should I use?

I usually wonder which thermodynamics first law is better to use ? The one given by physics : $\Delta U=Q-\Delta W$ or the one by chemistry : $\Delta U=Q+\Delta W$ In other words, should I take ...
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1answer
1k views

How does a thermal temperature gun work?

I once worked as a kitchen porter over a winter season. We had fun with thermal temperature guns (like these) which I learned can be used for measuring the temperature of something a reasonable ...
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3answers
751 views

How hot is the water in the pot?

Question: How hot is the water in the pot? More precisely speaking, how can I get a temperature of the water as a function of time a priori? Background & My attempt: Recently I started spend ...
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1answer
375 views

Why does $U = T S - P V + \sum_i \mu_i N_i$?

From the first law of thermodynamics: $$ dU = TdS - PdV + \sum_i\mu_i dN_i.$$ Quoting Wikipedia: As conjugate variables to the composition $N_{i}$ the chemical potentials are intensive ...
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0answers
50 views

Interface condition for heat exchange

I would like to compute the heat distribution of a piece of metal with some surrounding material. The heat is assumed to propagate by diffusion, so inside the metal piece and also on the outside, the ...
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2answers
2k views

Increase thermal efficiency of combustion engine by using heat of coolant/exhaust?

I can't be the only one who's ever thought of this, but obviously it hasn't caught on: In terms of energy density, fossil fuels are the best thing around short of enriched uranium (and, flammability ...
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1answer
238 views

Math for Thermodynamics Basics

I am studying Statistical Mechanics and Thermodynamics from a book that i am not sure who has written it, because of its cover is not present. There is a section that i can not understand: ...
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3answers
857 views

Why is Entropy expressed in terms of Enthalpy?

Why does ${\Delta}S_{m(fusion)} = \frac{{\Delta}H_{m(fusion)}}{T}$ ? I always thought ${\Delta}S = \frac{dQ}{T}$ In this case does it mean $dQ = {\Delta}H$ ?? Why is it so?
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3answers
484 views

Is there a mechanism for time symmetry breaking?

Excluding Thermodynamic's arrow of time, all mathematical descriptions of time are symmetric. We know the arrow of time is real and we know the equations describing physics are real so is there any ...
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1answer
629 views

What determines bubble locations in boiling water?

Something a little different to our usual fare. I was boiling a pan of water for cookery the other day, and got to wondering what caused the location of the bubble streams from the bottom of the pan. ...
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1answer
112 views

Can Joule's First Law of Thermodynamics be Applied to Atomic Charges?

James Joule established that all forms of energy were basically the same and interchangeable. My question is if thas law is relevant in particle physics. Can a positive charge and a negative charge be ...
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2answers
571 views

Dispersion relation and Heat Capacity

I have seen case studies of the 3D Debye model where the vibrational modes of a solid is taken to be harmonic with dispersion relation $\omega = c_sk$. It is said that for temperatures much less than ...
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3answers
1k views

Human as a heat engine

humans are heat engines. heat engines can't operate when the source and the sink are at the same temperatures and also if the temperature of the sink is higher than that of the source. in humans' ...
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1answer
356 views

Maxwell demon : how can the demon move the door without doing any work ?

Here is something that I never understood about Maxwell's demon paradox : in order to contradict the second law of thermodynamics, the demon must open and close the door without doing any work... But ...
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2answers
651 views

Temperature change inside pressure chamber

Let's say there is a pressure chamber with some sort of sample / specimen (e.g. protein crystal) in it. Now I apply a certain amount of gas pressure, e.g. 10 or 20 atm. Let's say I use xenon as a gas. ...
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6answers
2k views

What are the various physical mechanisms for energy transfer to the photon during blackbody emission?

By conservation of energy, the solid is left in a lower energy state following emission of a photon. Clearly absorption and emission balance at thermal equilibrium, however, thermodynamic equilibrium ...
3
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1answer
363 views

Net work output of an engine performing Carnot cycle?

My problem gives me a Carnot cycle heat engine with water as its working fluid, with $T_H$, $T_L$, and the fact that it starts from saturated liquid to saturated vapor in the heating process. I need ...
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1answer
74 views

In $PdV$, what is the value of $P$? $P_1$ or $P_2$?

Say I have an ideal gas that has a known $P_1$, $P_2$, $T_1$, and $T_2$ undergoing a reversible adiabatic process. I want to find the work done so I must use $PV = RT$ to get the change in $V$, so ...
2
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1answer
491 views

Difficulties with understanding total entropy change and unavailabillty

Of course, I know the fact that the entropy of an isolated system never decreases. Neverthless what makes me confused about the entropy(or change of entropy) of an isolated system is the explanation ...
0
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1answer
203 views

Information bearing degrees of freedom of a quantum simple harmonic oscillator

I am trying to make sense of arXiv:physics/0210005. I am confused with the concept of information bearing degrees of freedom of a system mentioned at the very beginning. To verify the arguments of the ...
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1answer
872 views

Why is the equation for Entropy of an ideal gas that undergoes reversible change in T at constant Pressure like this?

Why is the equation for change in Entropy for a reversible change in $T$ at constant $P$ described as $$\Delta S = n C_p \ln\frac{T_f}{T_i}$$
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1answer
101 views

Landauer's principle vs Wien's displacement law

Can we argue based on Landauer's principle that if one bit information is changed inside a blackbody, the total radiated energy should be at least or in order of kTln2? If it is so, can we also argue ...
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0answers
88 views

Landauer's principle vs Rayleigh–Jeans law

Can we argue based on Landauer's principle that if one bit information is changed inside a blackbody, the total radiated energy should be at least or in order of $kTln2$? If it is so, can we also ...
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2answers
248 views

Behaviour of individual terms in Einstein-Smoluchowski fluctuation-dissipation relation

Consider a bath of Brownian particles at temperature $T$. If we sprinkle some larger particles in this (eg: pollen grains in water or dust motes in air), they'll diffuse with diffusion constant $D$ ...