Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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References about rigorous thermodynamics

Can you suggest some references for rigorous treatment of thermodynamics? I want things like reversibility, equilibrium to be clearly defined in terms of the basic assumptions of the framework.
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Temperature of a neutron star

In our everyday experience termperature is due to the motion of atoms, molecules, etc. A neutron star, where protons and electrons are fused together to form neutrons, is nothing but a huge nucleus ...
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Intuitive understanding of the definition of entropy

In Wikipedia, the definition of entropy goes like this: $ d S = \dfrac{\delta q_{\rm }}{T}$. The literal interpretation of this equation is that some amount of heat transferred into a system, if the ...
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On a hot day, when it's cooler outside than in; is it better to put a fan in an open window pointing inwards or outwards?

If it's really hot inside, but cooler outside; what is the best way to place a single fan to try and cool a room down? I always assumed it would be better pointing inwards (and this thread suggests ...
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A water drop in vacuum

Let's imagine the following situation: At an initial moment $t=0$, a large water drop with diameter for example $D=10\ \text{cm}$ is placed in deep space (Say an astronaut is experimenting). Let's ...
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Is the second law of thermodynamics a fundamental law, or does it emerge from other laws?

My question is basically this. Is the second law of thermodynamics a fundamental, basic law of physics, or does it emerge from more fundamental laws? Let's say I was to write a massive computer ...
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Why are materials that are better at conducting electricity also proportionately better at conducting heat?

It seems like among the electrical conductors there's a relationship between the ability to conduct heat as well as electricity. Eg: Copper is better than aluminum at conducting both electricity and ...
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Why is cooling much harder than heating?

I'm trying to invent a distillation apparatus that runs solely on electricity. Suddenly, I realized that cooling things is really hard, while heating them up is so easy. Actually, it seems that there ...
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The notion of an adiabatic process in thermodynamics -vs- quantum mechanics

I'm confused about the terminology in the two contexts since I can't figure out if they have a similar motivation. Afaik, the definitions state that quantum processes should be very slow to be called ...
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Thermodynamics of supercooled water

Now that it's been freezing outside for the last few days, I experimented a bit with supercooling. I've left a bottle of clean water outside for a few hours, and behold, when I shook the bottle, the ...
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Discontinuities and nondifferentiability in thermodynamics

In physics and engineering sources, calculus-based formalisms - whether differential forms on a manifold, or "differentials" of functions of several variables - are presented as a way of modeling and ...
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A formal procedure for thermodynamic relations

This is my third time taking a thermodynamics course (two in undergrad, one in grad), and I've finally become frustrated enough about something to post on here. A lot of thermodynamic questions want ...
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Is it possible to increase temperature of sun using radiation of sun itself?

We know that we can focus radiation of sun and can burn a paper. If we think of this thought experiment, will that happen? If someone constructs a concave mirror on the sun and concentrate radiation ...
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Light “diode” and 2nd law of thermodynamics

If I had a light "diode" - an object that only allowed light (at least for a range of frequencies) to travel through it in one direction, would this necessarily allow violations of the 2nd Law of ...
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Is there a relativistic (quantum) thermodynamics?

Does a relativistic version of quantum thermodynamics exist? I.e. in a non-inertial frame of reference, can I, an external observer, calculate quantities like magnetisation within the non-inertial ...
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Why does adding solutes to pure water lower the the specific heat?

We found that water with salt, sugar, or baking soda dissolved in it cools faster than pure water. Water has a very high specific heat; how do these solutes lower it? We heated a beaker (300ml) of ...
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Temperature below absolute zero?

I saw this Nature article today, which cites e.g. arXiv:1211.0545. And it makes no sense to me. The temperature of a collection of particles is the average kinetic energy of those particles. Kinetic ...
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How does dark matter collapse?: Entropy considerations

Inspired by this question. I believe that the usual explanation that preserves the second law of thermodynamics as an astrophysical gas cloud collapses under gravity is that the gas must heat and ...
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How does a gas of particles with uniform speed reach the Maxwell-Boltzmann distribution?

Take an empty container and fill it with $N$ gas particles (ideally a monoatomic gas), each having the same kinetic energy $E$, then isolate the container. Since initially the speeds don't follow the ...
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Explanation of “thermite vs ice” explosion

There are several videos of the reaction, where some amount of burning thermite explodes on a contact with ice. An "original" video: http://www.youtube.com/watch?v=IuPjlYxUWc8 A Mythbusters ...
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How do you prove the second law of thermodynamics from statistical mechanics?

How do you prove the second law of thermodynamics from statistical mechanics? To prove entropy will only increase with time? How to prove? Please guide.
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Is almost all entropy in our universe entanglement entropy?

Our observable universe, or a subregion of our universe many times larger than the observable universe, originated from inflating from a very tiny inflationary patch. Being so small, the initial ...
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Quantum entaglement and the arrow of time

I have seen several claims to that quantum mechanics is required to explain the arrow of time which I take to mean the macroscopic irreversibility of physical systems. This is presumably to resolve ...
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Thermodynamically possible to hide a Dyson sphere?

You build a Dyson sphere around a star to capture all its energy. The outer surface of the Dyson sphere still radiates heat at much higher temperature than the cold space background, so you're easy to ...
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How badly could someone be injured by concentrated sunlight?

Recently-ish, I stumbled across an interesting short story (by way of Science Fiction & Fantasy Stack Exchange) where a soccer referee is apparently incinerated by concentrated sunlight. Where ...
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Why is pale coloured skin said to absorb more UV?

Many resources state that light skin/pale skin absorbs more UV than dark-colour skin. Doesn't black absorb maximum radiation? For an example, see this article: Natural selection therefore ...
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Why do lightbulbs continue to glow after the light is turned off?

I've noticed that whenever I turn the lamp off in my room at night, the lightbulb seems to continue to glow for a minute or so after that. It's not bright though; the only way I even notice it is if ...
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How efficient is a desktop computer?

As I understand it (and admittedly it's a weak grasp), a computer processes information irreversibly (AND gates, for example), and therefore has some minimum entropy increase associated with its ...
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Best way to chill a cup of coffee with cold water and 5 minutes [duplicate]

Initial data 1 x 3/4 full cup of hot coffee / tea / your favorite morning beverage cold water 5 minutes Considering that it's starting to get hot outside, and we all want to drink reasonably cold ...
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How hot is the water in the pot?

Question: How hot is the water in the pot? More precisely speaking, how can I get a temperature of the water as a function of time a priori? Background & My attempt: Recently I started spend ...
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Is temperature of a single molecule defined? [duplicate]

Is temperature of a single molecule defined? This question just cropped up in my mind as I have often heard of laws being violated when it comes to the scale of a single molecule. Does this happen in ...
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The difference between heat and temperature

So as I understand it, heat energy of an object is the SUM of all the kinetic energies of the molecules of the object (upto constant factor). The temperature on the other hand is the AVERAGE of the ...
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Why does heat added to a system at a lower temperature cause higher entropy increase?

Entropy is defined in my book as $\Delta\ S = \frac{Q}{T}$. To derive the formula it says that entropy should be directly proportional to the heat energy as with more energy the particles would be ...
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What happens to ice cream when you stir it?

I hope this is the appropriate forum for my question. I also considered posting it in the chemistry forum. When I eat ice cream I often stir it into a texture similar to that of soft serve. During ...
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Which direction does air flow?

I remember learning this in high school, but have forgotten it, and can't seem to find it anywhere online. Air travels from areas of high pressure to low pressure...correct? So if I have a cold room ...
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How can it be that the sun emits more than a black body?

As far as I know, a black body is an ideal emitter. So how can it be that a non-ideal emitter emits more radiation than a black body? This happens only in a very limited area at around 500nm, but it ...
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What's the difference between different speeds of sound?

In astrophysics, I often come across the speed of sound. I understand that, broadly, it represents the speed at which perturbations travel through a medium. But there's more than one speed of sound. ...
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How cold does it need to be for spit to freeze before hitting the ground?

What is the dominant form of heat transfer between warm water and cold air? If a $100 mg$ drop of water falls through $-40 C$ air, how quickly could it freeze? Is it credible that in very cold ...
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Is the liquid/solid line infinite?

Starting from the triple point, is the melting line between solid-phase and liquid-phase infinite? If not, why does it end? Because pressures are so high that classical inter-molecular interactions ...
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Energy from man-made tornadoes

Peter Thiel just paid $300,000 to Canadian inventor Louis Michaud who is working to construct useful "man-made tornadoes" or "atmospheric vortex engines" which could be components of future power ...
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In a large city how much hotter on average is it outside due to the air conditioning of all the buildings?

Title pretty much states the question. How much hotter do air conditioning units make it outside in a large city like NYC, Chicago, etc?
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Why is (von Neumann) entropy maximized for an ensemble in thermal equilibrium?

Consider a quantum system in thermal equilibrium with a heat bath. In determining the density operator of the system, the usual procedure is to maximize the von Neumann entropy subject to the ...
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Principle of Caratheodory and The Second Law of Thermodynamics

Background Constantin Carathéodory formulated thermodynamics on a purely mathematical axiomatic foundation. His statement of the second law is known as the Principle of Carathéodory, which may be ...
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Is there a true parallel between Gibbs' phase rule and Euler's polyhedral formula?

Gibbs' phase rule states: $$F=C-P+2$$ where $F$ is number of degrees of freedom, $C$ is number of components, $P$ is number of phases. Euler's polyhedral formula states: $$V+F-E=2$$ where $V$ is ...
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Why is compressible flow near the choke point so efficient?

Imagine a steady state, one-dimensional, compressible flow in a horizontal pipe of constant cross sectional area. This flow can be isothermal, adiabatic (Fanno), or diabatic (Rayleigh). As an ...
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If I take a bottle of air into space, and open it, where does it go?

It seems to me that space doesn't have any/much air, and if my bottle is full of air, when I open it, where does the air go?
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Why does a thermometer in wind not show a lower temperature than one shielded from it?

I'm a little familiar with the physics and thermodynamics of the wind chill effect, but this question seems to come up from time to time: Why, given two temperature sensors or thermometers in the ...
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Do photons lose energy while travelling through space? Or why are planets closer to the sun warmer?

My train of thought was the following: The Earth orbiting the Sun is at times 5 million kilometers closer to it than others, but this is almost irrelevant to the seasons. Instead, the temperature ...
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Crash course in classical thermodynamics

I've been working on some projects lately where it would be very handy to know more about thermodynamics than I do, but sadly I never had a chance to take a proper thermodynamics course in college. ...
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Why do power lines sag when they are heated up?

I was reading some information about the 2003 power blackout in the Northeastern US. Beginning early in the afternoon of August 14, 2003 big transmission lines began to fail in First Energy's ...