Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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276 views

Is this derivation of Black Hole entropy viable?

This question is motivated by this one. Suppose $l$ is the minimum measurable unit of length. What is entropy of a spinless particle contained in this interval? We know that entropy of a two-level ...
3
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2answers
691 views

Thermo-Emf variation with temperature

In the following experiment for seebeck effect After a certain temperature, the thermo-emf begins to fall. Why does this happen? What is happening microscopically at this level to cause such an ...
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1answer
906 views

Confused about fire?

Im confused about fire. The way I see it : Heat creates (kinetic) energy in mass and this creates stronger vibrations of atoms. When those vibrations are strong enough the electrons interact ...
13
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7answers
26k views

Does hot air really rise?

"Heat rises" or "warm air rises" is a widely used phrase (and widely accepted phenomenon). Does hot air really rise? Or is it simply displaced by colder (denser) air pulled down by gravity?
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6answers
928 views

What's the best strategy to fully fill the fridge with beer bottles and have them all cooled?

I'm having a party. Suppose I'd like to have a fridge full of cold ($6~^\circ\text{C}$ or below) beer bottles, in as short a time frame as possible. The fridge indicates that it is targeting (and ...
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3answers
2k views

How can I understand a Vortex Tube and its efficiency?

A Vortex Tube takes a pressurized input stream, most typically of a gas, and creates two output streams with a temperature differential. Apparently, it has been described as a Maxwell's Demon. Both ...
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2answers
865 views

Radiation– white vs black house, hot or cool?

In my book's thermodynamics chapter, it says that an "object that radiates heat faster also absorbs heat faster. This means that an object that is a more efficient radiator comes to equilibrium ...
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1answer
215 views

What pressure or tension occurs in a glass jar when I pour boiling water inside?

Sometimes it happens that when you pour a boiling water into a glass jar, it cracks. Since glass is very hard material and resilient to pressure, the tension must be very high. Is it possible to ...
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4answers
2k views

Why the breath sometimes warm and sometimes cold? (2 different explanations!)

If you blow air against your hand with your mouth open, you feel warm breath. If you do with with your lips closed except for a small opening, you feel cold breath. One explanation from here says ...
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2answers
1k views

Energy of unmixing

Mixing of two different fluids is associated with an increase of entropy. Conversely, separation of two gases must be associated with a decrease of the entropy of the two fluids. Is there a minimum ...
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1answer
1k views

Isentropic Processes

I'm having trouble understanding why reversible adiabatic processes are isentropic. I understand that in a reversible adiabatic process there is no heat exchange and so $dQ = TdS = 0$. However, if ...
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2answers
1k views

Is there an equation to calculate the average speed of liquid molecules?

I seem to remember from first year physics that we can calculate the RMS speed of a stationary, ideal gas with $v=\sqrt{\frac{3RT}{M}}$. Does a similar equation exist for liquids?
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3answers
512 views

Mathematical proof of non-negative change of entropy $\Delta S\geq0$

I understand that we can prove that for any process that occurs in an isolated and closed system it must hold that $$\Delta S\geq0$$ via Clausius' theorem. My question is, how can I prove this in a ...
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2answers
123 views

How can Maxwell's Demon erase information while a black hole can not?

It is stated, that information can't disappear even in black holes. On the other hand, it is stated, that mystic beings, like Maxwell demons, can easily erase any information if they just pay with ...
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1answer
81 views

Isothermal compressibility

How does one get from the thermodynamics definition : $$ \chi_T = -\frac{1}{V} \left(\frac{\partial V}{\partial p}\right)_T$$ to the fluid dynamics definition : $$ \chi_T = \frac{1}{\rho} ...
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3answers
714 views

Why must the particles of an ideal gas be point-like?

Why is a gas of elastically colliding hard balls of finite size not ideal? Respectively: Why is it essential that the particles of an ideal gas are point-like? Especially: Which ...
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4answers
7k views

What equation of state is needed for liquid states?

I'm familiar with the ideal gas law $$PV=nRT$$ but I don't think it applies to liquids like water. If I'm wrong, please correct me! If I'm right, then what equation of state applies to liquids such ...
5
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1answer
162 views

Thermodynamics: heat transfer

I hope this question isn't too simplistic but I've been in a discussion with someone who claims that no energy is transferred between a cool object and a warm one (either by radiation or conduction) ...
5
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1answer
409 views

Maxwell demon : how can the demon move the door without doing any work ?

Here is something that I never understood about Maxwell's demon paradox : in order to contradict the second law of thermodynamics, the demon must open and close the door without doing any work... But ...
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1answer
162 views

Dropping condition

Imagine opening a water tap in order to have a smooth and cylindrical outflow and then slowly decrease the flow by adjusting the knob. At a certain moment, the side profile of the flow will become ...
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3answers
185 views

Why does the air pressure at the surface of the earth exactly equal the weight of the entire air column above it

Why does the air pressure at the surface of the earth (resulting from collisions of molecules on the surface of the earth which has to do with the velocity of the particles) exactly equal the weight ...
4
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3answers
229 views

Problem about entropy

Combining the first and second law of thermodynamics we can get the following equation $$TdS=dU-P_{ext}dV$$ First question: Is this equation applicable for irreversible processes such that that ...
4
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1answer
200 views

What happens at the interface between two universes with opposite thermodynamic arrows of time? [closed]

I was trying to think but cannot figure it out. For instance, if the interaction is small, for instance limited to a windows, the observers in each universe will see that the other goes in reverse. ...
3
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2answers
1k views

Why does blowing on hot coffee cool it down?

And will it cool off faster if you blow across the top of the cup or directly into the coffee? Does it have to do with the fact that when you blow across the top of the cup the velocity of the air ...
3
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2answers
882 views

Is it possible for the entropy in an isolated system to decrease?

As far as I can tell, the concept of entropy is a purely statistical one. In my engineering thermodynamics course we were told that the second law of Thermodynamics states that "the entropy of an ...
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2answers
439 views

How to reconcile the two definitions of work? (mechanical and thermodynamical)

When studying classical mechanics, work is defined as: $W_M=\int F_{tot} \hspace{2 mm} dx$. However, for thermodynamics, work is defined as: $W_T=\int -F_{ext} \hspace{2 mm} dx$. I'm having trouble ...
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3answers
224 views

Colder surface radiates to warmer surface

When radiation from a colder source arrives at a warmer surface there is some debate about what happens next. To make the question more concrete lets say that the colder source is at temperature 288K. ...
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2answers
186 views

Why does a substance expands upon freezing? What conditions necessitate this?

Why does a substance expands upon freezing? What conditions necessitate this? For example, how does the slope of sublimation or fusion curve in a P-T diagram affect this?
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3answers
245 views

How to combat the black-body temperature of an object?

I'm trying to model the temperature of a large spacecraft for a space colony simulation game I'm working on. In another question, I checked my calculations for the steady-state black-body temperature ...
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2answers
209 views

Lowest temperature possible in the universe?

The third law of thermodynamics states that nothing can reach to absolute zero temperature. What is the lowest possible temperature that can be in the universe? Has any experiment reached to a ...
2
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1answer
169 views

What happens when a black hole dies?

It just vanishes into space leaving nothing behind or does it expel some material? Also, talking more about black holes, as far as i understand the term "temperature", it is defined by the amount of ...
2
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2answers
54 views

Gas Circulation Using Pressure Difference

Dear all, see attached picture Please, is it possible to have the gas recirculated from the gas phase to the liquid as described in the diagram assuming the gas is not soluble in the water. These ...
2
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1answer
1k views

When a color LCD/LED display is off it is black, when on it is colored. What color to light is an LCD/LED display

When a modern display using pixels is turned on its colors are different than the black that the screen is actually made up of. When put in light, such as sunlight, does the screen react to the color ...
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1answer
1k views

How much oxygen would be consumed on a 1 cm squared surface which is on fire?

I'm trying to figure out how much oxygen the Human Torch produces when he is on fire. I figure if I knew how much oxygen on average (per second?) is consumed by a 1 cm squared surface which is ...
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2answers
51 views

Speed of heat / quantification of heat and other magnitudes

Is the speed of heat infinite? When solving the heat equation in a semi-infinite bar, we can see that a pulse in the finite end draws an immediate change in every point of the bar. So, at any given ...
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2answers
69 views

Is there a portable method of preventing all IR radiation from being emitted?

Me and some friends were recently disuccing "How cool it would be to be invisible", from a military viewpoint, I said that Camouflage, when done correctly, works surprisingly well, so invisibility was ...
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1answer
156 views

What's the relationship between the energy density of a black-body and its radiant exitance?

Through a bit calculation we can derive that in a cavity, the energy density $$u(f,T)=\overline{E(f)}\times G(f)=\frac{8\pi h}{c^3}\frac{f^3}{e^{h\nu /kT}-1}$$ If we take the integral over all ...
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2answers
1k views

What is the physical or mathematical meaning of the Gibbs-Duhem equation?

The Gibbs-Duhem equation states $$0~=~SdT-VdP+\sum(N_i d\mu_i),$$ where $\mu$ is the chemical potential. Does it have any mathematical (about intensive parameters) or physical meaning?
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2answers
37 views

clausious inquality

Take a reservoir which gains a heat Q irreversibly at temp T from a surrounding at temp T0 then the entropy change of reservoir is given by Q/t and that of the surrounding is -Q/T0...How is this ...
0
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1answer
394 views

What does 1/k represent regarding Newtons Law of Cooling?

What does 1/k represent regarding Newtons Law of Cooling? I know k represents the cooling constant. I think the inverse of k is the time taken for the liquid to cool from its maximum temperture to ...
0
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1answer
399 views

Do ideal gases at zero Kelvin have potential energy?

Do ideal gases at zero Kelvin have potential energy?
0
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1answer
10k views

How much work is needed to compress a certain volume of gas?

I want to know the formula (and what does the symbols stand for) for how much work is needed to compress a certain volume of gas?
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1answer
53 views

Problem Boltzmann distribution [closed]

I am trying to solve a problem about boltzmann distribution. If(A)=0.74 Uf(V)=0.037 Ia(A)=0.130 I have to find ...
84
votes
5answers
9k views

Why am I not burned by a strong wind?

So I was thinking... If heat I feel is just lots of particles going wild and transferring their energy to other bodies, why am I not burned by the wind? When I thought about it more I figured out ...
39
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1answer
12k views

Rubber band stretched produces heat and when released absorbs heat.. Why?

I always used to wonder why this happens.. when one stretches a rubberband to nearly it snapping point holding it close to your skin - preferably cheek(helps feel the heat), it emits heat. While ...
16
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4answers
4k views

Why does the nature always prefer low energy and maximum entropy?

Why does the nature always prefer low energy and maximum entropy? I've just learned electrostatics and I still have no idea why like charges repel each other. ...
11
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2answers
793 views

How does a gas of particles with uniform speed reach the Maxwell-Boltzmann distribution?

Take an empty container and fill it with $N$ gas particles (ideally a monoatomic gas), each having the same kinetic energy $E$, then isolate the container. Since initially the speeds don't follow the ...
11
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3answers
984 views

Is there a relativistic (quantum) thermodynamics?

Does a relativistic version of quantum thermodynamics exist? I.e. in a non-inertial frame of reference, can I, an external observer, calculate quantities like magnetisation within the non-inertial ...
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7answers
2k views

Introduction to differential forms in thermodynamics

I've studied differential geometry just enough to be confident with differential forms. Now I want to see application of this formalism in thermodynamics. I'm looking for a small reference, to learn ...
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8answers
3k views

Why is absolute zero considered to be asymptotical? Wouldn't regions such as massive gaps between galaxy clusters have temperatures of absolute zero?

Why is absolute zero considered to be asymptotical? Wouldn't regions such as massive gaps between galaxy clusters have temperatures of absolute zero? I just do not see why our model must work the way ...