Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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3answers
8k views

Why does boiling water in the microwave make a cup of tea go weird?

When I boil water in the kettle, it makes a nice cup of tea. Sometimes I need to use a microwave because a kettle isn't available. I boil the water in the mug and it looks pretty normal, but when I ...
14
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4answers
21k views

On a hot day, when it's cooler outside than in; is it better to put a fan in an open window pointing inwards or outwards?

If it's really hot inside, but cooler outside; what is the best way to place a single fan to try and cool a room down? I always assumed it would be better pointing inwards (and this thread suggests ...
5
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3answers
2k views

Determine the Dependence of S (Entropy) on V and T

Why can the equation $$dS= \frac{1}{T} dU + \frac{P}{T} dV$$ be expressed as $$dS= \left. \frac{\partial S}{\partial T} \right|_V dT + \left. \frac{\partial S}{\partial V} \right|_T dV \quad?$$
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2answers
804 views

Thermo-Emf variation with temperature

In the following experiment for seebeck effect After a certain temperature, the thermo-emf begins to fall. Why does this happen? What is happening microscopically at this level to cause such an ...
12
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7answers
28k views

Does hot air really rise?

"Heat rises" or "warm air rises" is a widely used phrase (and widely accepted phenomenon). Does hot air really rise? Or is it simply displaced by colder (denser) air pulled down by gravity?
10
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1answer
642 views

Why isn't temperature frame dependent?

In (non-relativistic) classical physics, if the temperature of an object is proportional to the average kinetic energy ${1 \over 2} m\overline {v^{2}}$of its particles (or molecules), then shouldn't ...
8
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4answers
812 views

Hot water freezing faster than cold water

This question has puzzled me for a long time. There is already a question like this on Physics.SE. John's answer to the question seems quite satisfying. But when I googled the cause I found this and ...
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1answer
2k views
6
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4answers
1k views

Can a single molecule have a temperature?

A show on the weather channel said that as a water molecule ascends in the atmosphere it cools. Does it make sense to talk about the temperature of a single molecule?
6
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3answers
2k views

Why does the law of increasing entropy, a law arising from statistics of many particles, underpin modern physics?

As far as I interpret it, the law of ever increasing entropy states that "a system will always move towards the most disordered state, never in the other direction". Now, I understand why it would ...
5
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1answer
285 views

Is this derivation of Black Hole entropy viable?

This question is motivated by this one. Suppose $l$ is the minimum measurable unit of length. What is entropy of a spinless particle contained in this interval? We know that entropy of a two-level ...
2
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1answer
1k views

Confused about fire?

Im confused about fire. The way I see it : Heat creates (kinetic) energy in mass and this creates stronger vibrations of atoms. When those vibrations are strong enough the electrons interact ...
9
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2answers
368 views

Why isn't in counting the no. of degrees of freedom, rotation about the axis running down the length of the molecule counted?

I was reading about the Equipartition Theorem. Then I got the following quotations from my books: A diatomic molecule like oxygen can rotate about two different axes. But rotation about the axis ...
8
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4answers
2k views

How can I understand a Vortex Tube and its efficiency?

A Vortex Tube takes a pressurized input stream, most typically of a gas, and creates two output streams with a temperature differential. Apparently, it has been described as a Maxwell's Demon. Both ...
7
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6answers
1k views

What's the best strategy to fully fill the fridge with beer bottles and have them all cooled?

I'm having a party. Suppose I'd like to have a fridge full of cold ($6~^\circ\text{C}$ or below) beer bottles, in as short a time frame as possible. The fridge indicates that it is targeting (and ...
7
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4answers
7k views

What equation of state is needed for liquid states?

I'm familiar with the ideal gas law $$PV=nRT$$ but I don't think it applies to liquids like water. If I'm wrong, please correct me! If I'm right, then what equation of state applies to liquids such ...
6
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3answers
4k views

How does cold air move through a room

If you turn on a fan in a warm room, it feels as if cold air is being pushed from the fan out in the direction that it's facing, but what's actually happening on a molecular level? When an object is ...
5
votes
1answer
222 views

What pressure or tension occurs in a glass jar when I pour boiling water inside?

Sometimes it happens that when you pour a boiling water into a glass jar, it cracks. Since glass is very hard material and resilient to pressure, the tension must be very high. Is it possible to ...
4
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2answers
459 views

Difference between irreversible and entropy?

Cedric Villani recently wrote an article on Landau damping, where at least one topic discussed confused me. Besides discussing the issue of how a process can be microscopically reversible and ...
4
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2answers
2k views

Why does an electric motor burn up when you physically stop it?

As an electric motor spins, the energy from the electricity is 'conducted' to the rotor by the magnetic fields. However, when the motor is stopped, the energy becomes heat and burns up to motor. ...
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4answers
2k views

Why the breath sometimes warm and sometimes cold? (2 different explanations!)

If you blow air against your hand with your mouth open, you feel warm breath. If you do with with your lips closed except for a small opening, you feel cold breath. One explanation from here says ...
3
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2answers
1k views

Energy of unmixing

Mixing of two different fluids is associated with an increase of entropy. Conversely, separation of two gases must be associated with a decrease of the entropy of the two fluids. Is there a minimum ...
2
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4answers
284 views

Why does a bubble take a spherical shape?

I suspect this has something to do with thermodynamics and the isoperimetric inequality and I'm interested in a mathematical derivation of this result.
2
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1answer
1k views

Isentropic Processes

I'm having trouble understanding why reversible adiabatic processes are isentropic. I understand that in a reversible adiabatic process there is no heat exchange and so $dQ = TdS = 0$. However, if ...
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2answers
1k views

Is there an equation to calculate the average speed of liquid molecules?

I seem to remember from first year physics that we can calculate the RMS speed of a stationary, ideal gas with $v=\sqrt{\frac{3RT}{M}}$. Does a similar equation exist for liquids?
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3answers
534 views

Mathematical proof of non-negative change of entropy $\Delta S\geq0$

I understand that we can prove that for any process that occurs in an isolated and closed system it must hold that $$\Delta S\geq0$$ via Clausius' theorem. My question is, how can I prove this in a ...
0
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2answers
139 views

How can Maxwell's Demon erase information while a black hole can not?

It is stated, that information can't disappear even in black holes. On the other hand, it is stated, that mystic beings, like Maxwell demons, can easily erase any information if they just pay with ...
0
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1answer
82 views

Isothermal compressibility

How does one get from the thermodynamics definition : $$ \chi_T = -\frac{1}{V} \left(\frac{\partial V}{\partial p}\right)_T$$ to the fluid dynamics definition : $$ \chi_T = \frac{1}{\rho} ...
10
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3answers
989 views

Best way to chill a cup of coffee with cold water and 5 minutes [duplicate]

Initial data 1 x 3/4 full cup of hot coffee / tea / your favorite morning beverage cold water 5 minutes Considering that it's starting to get hot outside, and we all want to drink reasonably cold ...
8
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3answers
746 views

Why must the particles of an ideal gas be point-like?

Why is a gas of elastically colliding hard balls of finite size not ideal? Respectively: Why is it essential that the particles of an ideal gas are point-like? Especially: Which ...
5
votes
1answer
174 views

Thermodynamics: heat transfer

I hope this question isn't too simplistic but I've been in a discussion with someone who claims that no energy is transferred between a cool object and a warm one (either by radiation or conduction) ...
5
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1answer
419 views

Maxwell demon : how can the demon move the door without doing any work ?

Here is something that I never understood about Maxwell's demon paradox : in order to contradict the second law of thermodynamics, the demon must open and close the door without doing any work... But ...
5
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1answer
164 views

Dropping condition

Imagine opening a water tap in order to have a smooth and cylindrical outflow and then slowly decrease the flow by adjusting the knob. At a certain moment, the side profile of the flow will become ...
4
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4answers
261 views

What is the actual energy content of the Sun?

Beside the energy released by nuclear fusion in the core, the Sun is a hot plasma of hydrogen and helium ranging from thousands to million of degrees. So how does that translate into energy ? I have ...
4
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3answers
217 views

Why does the air pressure at the surface of the earth exactly equal the weight of the entire air column above it

Why does the air pressure at the surface of the earth (resulting from collisions of molecules on the surface of the earth which has to do with the velocity of the particles) exactly equal the weight ...
4
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3answers
247 views

Problem about entropy

Combining the first and second law of thermodynamics we can get the following equation $$TdS=dU-P_{ext}dV$$ First question: Is this equation applicable for irreversible processes such that that ...
4
votes
1answer
211 views

What happens at the interface between two universes with opposite thermodynamic arrows of time? [closed]

I was trying to think but cannot figure it out. For instance, if the interaction is small, for instance limited to a windows, the observers in each universe will see that the other goes in reverse. ...
3
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2answers
1k views

Why does blowing on hot coffee cool it down?

And will it cool off faster if you blow across the top of the cup or directly into the coffee? Does it have to do with the fact that when you blow across the top of the cup the velocity of the air ...
3
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2answers
1k views

Is it possible for the entropy in an isolated system to decrease?

As far as I can tell, the concept of entropy is a purely statistical one. In my engineering thermodynamics course we were told that the second law of Thermodynamics states that "the entropy of an ...
3
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2answers
485 views

How to reconcile the two definitions of work? (mechanical and thermodynamical)

When studying classical mechanics, work is defined as: $W_M=\int F_{tot} \hspace{2 mm} dx$. However, for thermodynamics, work is defined as: $W_T=\int -F_{ext} \hspace{2 mm} dx$. I'm having trouble ...
3
votes
3answers
224 views

Colder surface radiates to warmer surface

When radiation from a colder source arrives at a warmer surface there is some debate about what happens next. To make the question more concrete lets say that the colder source is at temperature 288K. ...
2
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2answers
241 views

Why does a substance expands upon freezing? What conditions necessitate this?

Why does a substance expands upon freezing? What conditions necessitate this? For example, how does the slope of sublimation or fusion curve in a P-T diagram affect this?
2
votes
3answers
263 views

How to combat the black-body temperature of an object?

I'm trying to model the temperature of a large spacecraft for a space colony simulation game I'm working on. In another question, I checked my calculations for the steady-state black-body temperature ...
2
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2answers
215 views

Lowest temperature possible in the universe?

The third law of thermodynamics states that nothing can reach to absolute zero temperature. What is the lowest possible temperature that can be in the universe? Has any experiment reached to a ...
2
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2answers
226 views

What happens when a black hole dies?

It just vanishes into space leaving nothing behind or does it expel some material? Also, talking more about black holes, as far as i understand the term "temperature", it is defined by the amount of ...
2
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2answers
55 views

Gas Circulation Using Pressure Difference

Dear all, see attached picture Please, is it possible to have the gas recirculated from the gas phase to the liquid as described in the diagram assuming the gas is not soluble in the water. These ...
2
votes
1answer
1k views

When a color LCD/LED display is off it is black, when on it is colored. What color to light is an LCD/LED display

When a modern display using pixels is turned on its colors are different than the black that the screen is actually made up of. When put in light, such as sunlight, does the screen react to the color ...
2
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1answer
1k views

How much oxygen would be consumed on a 1 cm squared surface which is on fire?

I'm trying to figure out how much oxygen the Human Torch produces when he is on fire. I figure if I knew how much oxygen on average (per second?) is consumed by a 1 cm squared surface which is ...
1
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3answers
88 views

Speed of heat / quantification of heat and other magnitudes

Is the speed of heat infinite? When solving the heat equation in a semi-infinite bar, we can see that a pulse in the finite end draws an immediate change in every point of the bar. So, at any given ...
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2answers
82 views

The 1st law of thermodynamics

If a gas expands adiabatically will the work done be positive or negative? I think it will be positive as $\delta W=p dV$ and we have a positive sign due to the work done by the gas is positive as it ...