Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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Temperature behavior over time of black or white cars in hot, sunny regions

How does the color of a car influence its inner temperature change over time when parked outside in windless, hot and sunny regions? I know what's the common idea about that: black cars are supposed ...
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2answers
696 views

Is it possible for the entropy in an isolated system to decrease?

As far as I can tell, the concept of entropy is a purely statistical one. In my engineering thermodynamics course we were told that the second law of Thermodynamics states that "the entropy of an ...
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3answers
217 views

Colder surface radiates to warmer surface

When radiation from a colder source arrives at a warmer surface there is some debate about what happens next. To make the question more concrete lets say that the colder source is at temperature 288K. ...
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2answers
201 views

Lowest temperature possible in the universe?

The third law of thermodynamics states that nothing can reach to absolute zero temperature. What is the lowest possible temperature that can be in the universe? Has any experiment reached to a ...
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2answers
52 views

Gas Circulation Using Pressure Difference

Dear all, see attached picture Please, is it possible to have the gas recirculated from the gas phase to the liquid as described in the diagram assuming the gas is not soluble in the water. These ...
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2answers
1k views

Possible colors of fire?

I have learnt that depending on the various gases those are involved in the reaction that produces fire, different colors (yellow, red or blue) of flames become visible. I have a question .. what are ...
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1answer
1k views

How much oxygen would be consumed on a 1 cm squared surface which is on fire?

I'm trying to figure out how much oxygen the Human Torch produces when he is on fire. I figure if I knew how much oxygen on average (per second?) is consumed by a 1 cm squared surface which is ...
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1answer
135 views

What's the relationship between the energy density of a black-body and its radiant exitance?

Through a bit calculation we can derive that in a cavity, the energy density $$u(f,T)=\overline{E(f)}\times G(f)=\frac{8\pi h}{c^3}\frac{f^3}{e^{h\nu /kT}-1}$$ If we take the integral over all ...
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2answers
1k views

What is the physical or mathematical meaning of the Gibbs-Duhem equation?

The Gibbs-Duhem equation states $$0~=~SdT-VdP+\sum(N_i d\mu_i),$$ where $\mu$ is the chemical potential. Does it have any mathematical (about intensive parameters) or physical meaning?
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1answer
35 views

Problem Boltzmann distribution [closed]

I am trying to solve a problem about boltzmann distribution. If(A)=0.74 Uf(V)=0.037 Ia(A)=0.130 I have to find ...
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1answer
241 views

What does 1/k represent regarding Newtons Law of Cooling?

What does 1/k represent regarding Newtons Law of Cooling? I know k represents the cooling constant. I think the inverse of k is the time taken for the liquid to cool from its maximum temperture to ...
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1answer
274 views

Do ideal gases at zero Kelvin have potential energy?

Do ideal gases at zero Kelvin have potential energy?
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1answer
7k views

How much work is needed to compress a certain volume of gas?

I want to know the formula (and what does the symbols stand for) for how much work is needed to compress a certain volume of gas?
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5answers
9k views

Why am I not burned by a strong wind?

So I was thinking... If heat I feel is just lots of particles going wild and transferring their energy to other bodies, why am I not burned by the wind? When I thought about it more I figured out ...
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1answer
9k views

Rubber band stretched produces heat and when released absorbs heat.. Why?

I always used to wonder why this happens.. when one stretches a rubberband to nearly it snapping point holding it close to your skin - preferably cheek(helps feel the heat), it emits heat. While ...
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4answers
3k views

Why does the nature always prefer low energy and maximum entropy?

Why does the nature always prefer low energy and maximum entropy? I've just learned electrostatics and I still have no idea why like charges repel each other. ...
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3answers
5k views

Is it possible to start fire using moonlight?

You can start fire by focusing the sunlight using the magnifying glass. I searched the web whether you can do the same using moonlight. And found this and this - the first two in Google search ...
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3answers
848 views

Is there a relativistic (quantum) thermodynamics?

Does a relativistic version of quantum thermodynamics exist? I.e. in a non-inertial frame of reference, can I, an external observer, calculate quantities like magnetisation within the non-inertial ...
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7answers
2k views

Introduction to differential forms in thermodynamics

I've studied differential geometry just enough to be confident with differential forms. Now I want to see application of this formalism in thermodynamics. I'm looking for a small reference, to learn ...
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8answers
3k views

Why is absolute zero considered to be asymptotical? Wouldn't regions such as massive gaps between galaxy clusters have temperatures of absolute zero?

Why is absolute zero considered to be asymptotical? Wouldn't regions such as massive gaps between galaxy clusters have temperatures of absolute zero? I just do not see why our model must work the way ...
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6answers
8k views

How do whisky stones keep your drink cold?

From a discussion in the DMZ (security stack exchange's chat room - a place where food and drink are important topics) we began to question the difference between how ice and whisky stones work to ...
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6answers
3k views

Is a suit that hides a soldier's heat signature fundamentally possible?

I recently played "Crysis", a game where the protagonist wears a suit that allows the player to hide both himself and his heat signature. Then I watched Iron Man 3, where a kid suggests that Tony ...
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5answers
2k views

Why isn't absolute $0 K$ temperature possible?

So $T$ is defined as $$T = \left(\frac{\partial E}{\partial S}\right)$$ and $S$ is defined as $$S = k_B \ln \Omega$$ where $\Omega$ is the number of accessible states of the system for a given ...
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2answers
480 views

Quantum entaglement and the arrow of time

I have seen several claims to that quantum mechanics is required to explain the arrow of time which I take to mean the macroscopic irreversibility of physical systems. This is presumably to resolve ...
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2answers
622 views

How does a gas of particles with uniform speed reach the Maxwell-Boltzmann distribution?

Take an empty container and fill it with $N$ gas particles (ideally a monoatomic gas), each having the same kinetic energy $E$, then isolate the container. Since initially the speeds don't follow the ...
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3answers
231 views

Why does ice melts, waits for 100 degrees and THEN vaporises? Why is not the process of expansion of things continuous?

What I am asking is this: Why can't a body be solid, then solid-ish, then solid-like, then liquid-like, then liquid-ish, then liquid, then vapor-like and then vapor? Why is there a rigid temperature ...
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1answer
337 views

How does Landauer's Principle apply in quantum (and generally reversible) computing

I understand that a reversible computer does not dissipate heat through the Landauer's principle whilst running - the memory state at all times is a bijective function of the state at any other time. ...
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4answers
5k views

How close can you get to lava before burning?

As the title asks: How close can you get to lava before burning? I know that it depends on an number of factors; speed of lava flow, wind direction/strength, type(?) of lava flow (related to speed, ...
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5answers
2k views

Perpetual motion machine of the second kind possible in nano technology?

First of all sorry for my English - it is not my native language. During my engineering studies at the university the thermodynamics professor told us that the "second law of thermodynamics is not ...
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5answers
1k views

How is thermodynamic entropy defined? What is its relationship to information entropy?

I read that thermodynamic entropy is a measure of the number of microenergy states. What is the derivation for $S=k\log N$, where $k$ is Boltzmann constant, $N$ number of microenergy states. How is ...
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2answers
380 views

Why sound does not heat up the air?

Both thermal energy and air are propagated through vibration of particles so why sound does not heat up the air e.g loud musical instrument does not generate much heat ?
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3answers
369 views

How to think physically about basic “fields”

"Field" is a name for associating a value with each point in space. This value can be a scalar, vector or tensor etc. I read the wikipedia article and got that much, but then it goes it into more ...
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7answers
9k views

Does an empty refrigerator require more power to stay cold than a full one?

Given that everything else is equal (model of fridge, temperature settings, external temperature, altitude), over a given duration of having the door closed, does it require more electricity to cool ...
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5answers
2k views

Entropy of radiation emitted into space

In several papers I see something equivalent to the following expression for the entropy of radiation given by an astronomical object such as the Sun (assuming the object can be approximated as a ...
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3answers
754 views

Light “diode” and 2nd law of thermodynamics

If I had a light "diode" - an object that only allowed light (at least for a range of frequencies) to travel through it in one direction, would this necessarily allow violations of the 2nd Law of ...
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3answers
630 views

Where does the kinetic energy go?

A uniform cylinder was placed on a frictionless bearing and set to rotate about its vertical axis. After a cylinder has reached a specific state of rotation it is heated without any mechanical support ...
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2answers
226 views

radiation thermodynamics paradox

This question is concerned with a thermodynamic paradox for radiating bodies and radiation in a cavity of a specific shape. Consider two nested shells that are axisymmetric ellipsoids with the same ...
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8answers
14k views

Why does the gas get cold when I spray it?

When you spray gas from a compressed spray, the gas gets very cold, even though, the compressed spray is in the room temperature. I think, when it goes from high pressure to lower one, it gets cold, ...
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2answers
6k views

Does tea stay hotter with the milk in it?

A little thought experiment, similar to this one: Imagine you are making a cup of tea when the door bell rings. You've poured the boiling water into a cup with a teabag in it. As you're just about to ...
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5answers
13k views

The difference between heat and temperature

So as I understand it, heat energy of an object is the SUM of all the kinetic energies of the molecules of the object (upto constant factor). The temperature on the other hand is the AVERAGE of the ...
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1answer
663 views

Microwave oven + water: dielectric heating or ion drag?

When you place a water or food in a microwave oven, it heats. Which process commits more energy to that: dielectric heating, or ion drag i.e. resistive heating? AFAIK, in distilled water (which is a ...
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4answers
923 views

Water in vacuum (or space) and temperature in space

So, water in vacuum will boil first and then freeze. I don't know how the freeze happens. As pressure lowers to zero, what happened to freezing point? (I know heat taken by vapor, and the water cool ...
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3answers
976 views

What does it take to derive the ideal gas law in themodynamics?

How can the ideal gas law be derived from the following assumptions/observations/postulates, and these only ? I'm able to measure pressure $P$ and volume $V$ for gases. I notices that if ...
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3answers
319 views

Axioms behind entropy!

The concept of entropy is very ubiquitous, we learn about its uses starting from Information Theory (Shannon entropy) up to its basic definition in statistical mechanics in terms of number of ...
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2answers
395 views

The statistical nature of the 2nd Law of Thermodynamics

Ok, so entropy increases... This is supposed to be an absolute statement about entropy. But then someone imagines a box with a 10 particle gas, and finds that every now and then all particles are in ...
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3answers
751 views

How hot is the water in the pot?

Question: How hot is the water in the pot? More precisely speaking, how can I get a temperature of the water as a function of time a priori? Background & My attempt: Recently I started spend ...
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2answers
351 views

Chemical potential in Thermodynamics

In many scenarios, on computing the partial derivative of the internal energy (U) with respect to mole number (N) is negative. This implies that adding more moles of the substance decreases the U of ...
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4answers
3k views

Is energy the ability to do work?

Here was my argument against this, the second law of thermodynamics, in effect says that, there is no heat engine that can take all of some energy that was transferred to it by heat and do work on ...
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3answers
544 views

Can temperature be defined as propensity to transmit thermal energy?

I was recently surprised to learn that defining temperature isn't easy. For a long time, it was defined operationally: how much does a thermometer expand. Also surprising, temperature isn't a ...
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4answers
640 views

Mathematical proof of the Second Law of Thermodynamics [duplicate]

Is there some book or paper that formalizes statistical mechanics, like some people have done with relativity, and proves the second law of thermodynamics from more foundational axioms?