Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].
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515 views
Is there a relativistic (quantum) thermodynamics?
Does a relativistic version of quantum thermodynamics exist? I.e. in a non-inertial frame of reference, can I, an external observer, calculate quantities like magnetisation within the non-inertial ...
8
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4answers
727 views
What happens when you heat vodka in a microwave?
Since ethanol has a lower dielectric constant than water would the water heat up and boil before the ethanol? Would the water transfer heat to the ethanol and, since ethanol has a lower boiling point, ...
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2answers
393 views
What is the status of Mpemba effect investigations?
There is this puzzling thing that is called Mpemba effect: paradoxically, warm (35°C) water freezes faster than cold (5°C) water. As a physisist, I've been asked about it several times already. And I ...
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3answers
180 views
Is “equilibrium state” equivalent to “well-defined state variables”?
Follow up to
Intuitively, why is a reversible process one in which the system is always at equilibrium?
and
How slow is a reversible adiabatic expansion of an ideal gas?
Suppose you have a ...
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3answers
260 views
Could temperature have been defined as $-\partial S/\partial U$?
When coming up with a definition of temperature, it's typical to start with an empirical definition that a system with a hotter temperature tends to lose heat to a system with a colder temperature. ...
8
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1answer
91 views
Are Carnot engine efficieny and Fourier heat trasmission law related?
It just occured to me that the efficiency of Carnot cycles is $\eta= \frac{T_1 - T_2}{T_1}$, that is, the efficiency decreases as the difference between reservoir temperatures decreases. On the other ...
8
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1answer
148 views
Trying to understand a step in deriving Maxwell-Boltzman statistics
In the Wikipedia article on Maxwell–Boltzmann statistics, there is a point in the derivation that stumps me. When I get to where
$\displaystyle W=N!\prod\frac{g^{N_i}}{N_i!}$
is quoted as a count ...
8
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3answers
322 views
Thermodynamically reversed black holes, firewalls, Casimir effect, null energy condition violations
Scott Aaronson asked a very deep question at Hawking radiation and reversibility about what happens if black hole evolution is reversed thermodynamically. Most of the commenters missed his point ...
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3answers
621 views
Why does thermal resistance go down as temperature goes up?
Here is the thermal resistance data for three speaker coils disengaged from the speaker cone. Any ideas? I would think it would be a horizontal line.
http://en.wikipedia.org/wiki/Thermal_resistance
...
8
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1answer
302 views
How is information defined from a thermodynamics point of view?
How is information defined from a thermodynamics point of view ? I came across some definitions using the concept of free energy of a system. If I have information stored in a finite volume of space ...
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3answers
1k views
Why does the low entropy at the big bang require an explanation? (cosmological arrow of time)
I have read Sean Carrol's book. I have listened to Roger Penrose talk on "Before the Big Bang". Both are offering to explain the mystery of low entropy, highly ordered state, at the Big Bang.
Since ...
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0answers
145 views
How is the logarithmic correction to the entropy of a non extremal black hole derived?
I`ve just read, that for non extremal black holes, there exists a logarithmic (and other) correction(s) to the well known term proportional to the area of the horizon such that
$S = \frac{A}{4G} + K ...
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3answers
3k views
Why does a thermometer in wind not show a lower temperature than one shielded from it?
I'm a little familiar with the physics and thermodynamics of the wind chill effect, but this question seems to come up from time to time:
Why, given two temperature sensors or thermometers in the ...
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6answers
927 views
References about rigorous thermodynamics
Can you suggest some references for rigorous treatment of thermodynamics? I want things like reversibility, equilibrium to be clearly defined in terms of the basic assumptions of the framework.
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4answers
667 views
Why does pizza cheese seem hotter than the crust?
When I eat hot pizza or a melted cheese sandwich, the cheese feels a lot hotter than the crust or bread: in particular, the cheese might scald the roof of my mouth. but the crust will not. Is this
...
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5answers
1k views
Can a single classical particle have any entropy?
recently I have had some exchanges with @Marek regarding entropy of a single classical particle.
I always believed that to define entropy one must have some distribution. In Quantum theory, a single ...
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1answer
307 views
Entropy increase and end of the universe
While taking thermodynamics our chemistry teacher told us that entropy is increasing in day by day (as per second law of thermodynamics), and when it reaches its maximum the end of the world will ...
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3answers
290 views
Why does the Boltzmann factor $e^{-E/kT}$ seem to imply that lower energies are more likely?
I'm looking for an intuitive understanding of the factor $$e^{-E/kT}$$ so often discussed. If we interpret this as a kind of probability distribution of phase space, so that $$\rho(E) = ...
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2answers
9k views
How can a wooden spoon be used to prevent water from over boiling?
This is an image I found via StumbleUpon
Does this actually work? If so, why?
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3answers
336 views
Intuitively, why is a reversible process one in which the system is always at equilibrium?
A process is reversible if and only if it's always at equilibrium during the process. Why?
I have heard several specific example of this, such as adding weight gradually to a piston to compress the ...
7
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1answer
209 views
Modification of Newton's Law of Cooling
Yesterday I randomly started thinking about Newton's Law of Cooling. The problem I realized is that it assumes the ambient temperature stays constant over time, which is obviously not true. So what I ...
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5answers
841 views
How do we perceive hotness or coldness of an object?
Some objects, especially metallic ones, feel cold on touching and others like wood, etc. feel warm on touching. Both are exposed to same environment and are in their stable state, so some kind of ...
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6answers
3k views
Explanation of “thermite vs ice” explosion
There are several videos of the reaction, where some amount of burning thermite explodes on a contact with ice.
An "original" video: http://www.youtube.com/watch?v=IuPjlYxUWc8
A Mythbusters ...
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3answers
293 views
If I take a handful of salt and wait for an infinite time will it become a single crystal?
That pretty much says it.
Suppose I have some powder of $NaCl$. It is kept in contact with itself in vacuum. You are free to remove all the disturbances that bother you.
Is that true that, well, ...
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2answers
385 views
How much more energy does it take for a human body to heat 0C ice vs 0C water?
I'm trying to determine if going through the trouble of ingesting ice is worth the hassle versus ingesting ice-cold water, but my physics skills are rusty.
If I drink a gram of ice water at ~0C, my ...
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1answer
612 views
Why is compressible flow near the choke point so efficient?
Imagine a steady state, one-dimensional, compressible flow in a horizontal pipe of constant cross sectional area. This flow can be isothermal, adiabatic (Fanno), or diabatic (Rayleigh). As an ...
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3answers
594 views
Imaginary time in quantum and thermodynamics
The following question is about chapter 2 of Sakurai's Modern Quantum Mechanics. I wish I could link to the Google book, but it doesn't seem to have a satisfactory preview to be able to read the ...
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3answers
3k views
Why do lightbulbs continue to glow after the light is turned off?
I've noticed that whenever I turn the lamp off in my room at night, the lightbulb seems to continue to glow for a minute or so after that. It's not bright though; the only way I even notice it is if ...
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5answers
698 views
How is thermodynamic entropy defined? What is its relationship to information entropy?
I read that thermodynamic entropy is a measure of the number of microenergy states. What is the derivation for $S=k\log N$, where $k$ is Boltzmann constant, $N$ number of microenergy states.
How is ...
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4answers
416 views
What equation of state is needed for liquid states?
I'm familiar with the ideal gas law $$PV=nRT$$ but I don't think it applies to liquids like water. If I'm wrong, please correct me! If I'm right, then what equation of state applies to liquids such ...
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5answers
894 views
How does the temperature of the triple point of water depend on gravitational acceleration?
Suppose I do two experiments to find the triple point of water, one in zero-g and one on Earth. On Earth, water in the liquid or solid phase has less gravitational potential per unit mass than water ...
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2answers
1k views
How long does it take an iceberg to melt in the ocean?
This is a quantitative question. The problem is inspired by this event:
On August 5, 2010, an enormous chunk of ice, roughly 97 square miles (251 square kilometers) in size, broke off the Petermann ...
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4answers
350 views
Second Law of Thermodynamics and the Arrow of Time: Why isn't time considered fundamental?
I've come across this explanation that the "arrow of time" is a consequence of the second law of thermodynamics, which says that the entropy of an isolated system is always increasing. The argument is ...
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2answers
278 views
Is temperature quantized?
I'm learning quantum mechanics on my own. I've known that energy is quantized and I've started wondering about temperature. From thermodynamics we have:
$$U=\frac{3}{2}NkT $$
(for ideal gas, of ...
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6answers
623 views
Does the scientific community consider the Loschmidt paradox resolved? If so what is the resolution?
Does the scientific community consider the Loschmidt paradox resolved? If so what is the resolution?
I have never seen dissipation explained, although what I have seen a lot is descriptions of ...
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3answers
245 views
Is there a number that describes a gas's departure from the ideal gas law?
When judging if relativity is important in a given phenomenon, we might examine the number $v/c$, with $v$ a typical velocity of the object. If this number is near one, relativity is important. In ...
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3answers
586 views
Is there a relativistic generalization of the Maxwell-Boltzmann velocity distribution?
The Maxwell-Boltzmann velocity distribution in 3D space is
$$
f(v)dv = 4\pi \left(\frac{m}{2\pi k_B T}\right)^{3/2} v^2 \exp\left(-\frac{m v^2}{2k_B T}\right)dv$$
It gives the probability for a ...
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3answers
915 views
Maxwell's Demon Constant (Information-Energy equivalence)
New Scientist article: Summon a 'demon' to turn information into energy
The speed of light c converts between space and time and also appears in e=mc^2.
Maxwell's Demon can turn information supplied ...
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3answers
576 views
Why are the virial coefficients functions of temperature only?
I have read in multiple places that the virial coefficients in the virial equation of state, $Z=1+{B \over v}+{C \over v^2}...$, are functions of temperature only and are independent of pressure (or ...
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2answers
455 views
Can a water bubble be frozen into ice bubble?
To maintain the surface tension which formed our original bubble (in order to keep the bubble from breaking), we may change the temperature/pressure of air on both sides of the bubble varyingly, with ...
6
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1answer
188 views
Gas kinetic representation of trans-critical conditions
From a molecular point of view, can we think of the super-critical conditions as conditions where T and p are large enough that the collisions of gas molecules are frequent and powerful enough to ...
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2answers
797 views
Is there a simple way to derive a T-S diagram from a p-V diagram for arbitrary processes?
Often, for thermodynamic processes only a p-V diagram is shown.
Even without hard figures, the shape of the curve can be helpful to evaluate the process.
However, it is hard to figure out for real ...
6
votes
2answers
224 views
How much energy from extreme coldness?
Let's say I have:
1: one mole of extremely cold ideal gas
2: unlimited amount of ideal gas at temperature 300 K
3: one ideal heat engine
Can I generate for example 1 MWh of mechanical energy using ...
6
votes
1answer
241 views
Maximum Principle vs. Minimum Principle in Non-equilibrium Thermodynamics
Prigogine's Min. principle states that in steady-state non-equilibrium systems the entropy generation rate is at a minimum, i.e., a system will seek a steady-state that has min entropy generation. ...
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2answers
174 views
Why is temperature constant during melting?
This is an elementary question but I do not know the answer to it. During a phase transition such as melting a solid to a liquid the temperature remains constant. At any lower temperature the heat ...
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4answers
156 views
Is energy extensivity necessary in thermodynamics?
Given a partition of a system into two smaller systems, the energy $U$ is devided into $U_1$ and $U_2$, with
$$U=\mathcal{P}(U_1,U_2):=U_1+U_2,$$
so that $U_2$ is given by $U-U_1$. Here the ...
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5answers
926 views
Recommendations for Statistical Mechanics book
I saw Book recommendations
No reference to Statistical Mechanics there.
I learned thermodynamics and the basics of statistical mechanics but I'd like to
sit through a good advanced book/books.
Mainly ...
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3answers
5k views
How does a maple syrup evaporator work?
Some background info on what an evaporator is:
It is a system of metal pans set over a heat source. Sap constantly enters the first pan controlled by a float valve to keep a constant depth. The pans ...
6
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1answer
331 views
Microwave oven + water: dielectric heating or ion drag?
When you place a water or food in a microwave oven, it heats.
Which process commits more energy to that: dielectric heating, or ion drag i.e. resistive heating?
AFAIK, in distilled water (which is a ...
6
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1answer
79 views
Is there a relativity-compatible thermodynamics?
I am just wondering that laws in thermodynamics are not Lorentz invariant, it only involves the $T^{00}$ component. Tolman gave a formalism in his book. For example, the first law is replaced by the ...
