Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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175 views

Building free energy directly from lagrangian

Energy can be built from lagrangian when considering the symmetry of time $(\frac{\partial L}{\partial t}=0)$. Free energy is a generalization of energy when the system exchanges heat with the ...
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421 views

How much energy does it take to cook a steak?

Grilling in the park today I started to wonder just how implausible a portable battery-powered grill would be. There are of course a lot of parameters in this question, so let's narrow it down for now:...
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680 views

Irreversible heat engines strictly less efficient than reversible ones

I understand how Carnot's theorem implies that irreversible heat engines must be no more efficient than reversible one's, but it is less clear why they need to be less efficient, as I have seen stated ...
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501 views

Heat transfer from hot water through a copper pipe to oil in a tank

I want to build a geyser attached to a pump with copper tubing running into an oil tank. This is done because the oil solidifies at a temperature below 15 degrees Celsius. I have done a few ...
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32 views

Experimental results regarding non-extensivity in small systems

From a statistical mechanics point of view, the extensivity of thermodynamics arises from the fact that we can neglect interaction terms in the Hamiltonian. This allows us to infer that when we put ...
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153 views

Thermodynamics - convection current

please could someone help explain the mechanism of a convection current as I keep finding conflicting explanations. Is a convection current caused by differences in density or differences in pressure? ...
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66 views

Thermalising a sub-system of a larger, interacting system

I'm considering a joint system consisting of a spin-1/2 particle (qubit) and a spin-l particle (reference) coupled via a Hamiltonian $H_0$. At a certain point I want to couple the qubit to a bosonic ...
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253 views

Second derivative of vapor pressure from a cubic equation of state

It is quite easy to compute the first derivative of vapor pressure with respect to temperature from a cubic equation of state at least at the critical point since there is a continuity with the ...
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965 views

How do I determine the Internal Energy of ammonia at a pressure in temperature when the steam table doesn't say it

I just bought a steam table for my thermodynamics class since they don't allow use to use the one from the book for the tests. This one is different from the one in my textbook as it doesn't give the ...
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858 views

How do I derive the critical temperature for bose condensation in two dimensions?

In class we derived the 3D case, but there's a step I don't understand: $$ N = g \cdot {V \over (2 \pi \hbar)^3} \cdot \int\limits_{0}^{\infty}{1 \over{e^{\left( E_p \over{K_B T}\right)}-1}} d^3 p = ...
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442 views

Maxwell's Demon - laser cooling

There’s an interesting article on Scientific American that tells how to cool individual atoms to within a very tiny fraction of Absolute Zero. It uses two laser beams acting on a very cold rarified ...
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22 views

Is the free energy density analytic in temperature at the Kosterlitz-Thouless phase transition?

I know that the KT transition is infinite-order so the free energy density is a smooth (i.e. infinitely differentiable) function of temperature, but is the function actually analytic at the critical ...
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39 views

Lorentz Invariance of Entropy

So I am working on Relativistic Thermodynamics and I have skimmed through a few papers by Hamity, Callen, etc. People are not in agreement as far as I know, but I don't understand why people don't ...
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67 views

How to calculate the minimum kinetic energy required by a surface molecule to escape the liquid (during evaporation)?

Evaporation occurs when surface molecules have enough Kinetic Energy to escape the surface of the liquid. Given a certain volume of liquid at a certain temperature, is it possible to determine this ...
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38 views

When does $E=\frac{3}{2}pV$ hold?

I only know that it holds for classical (monatomic) ideal gas and quantum ideal gas. But does it hold for interacting classical gas (e.g. van der Waals gas)?
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30 views

A micro-reversible stochastic process that models transitions between states with variable energies

Suppose we have a system with 3 possible states A, B and C (there could be $n$ states as well) with energies $E_a(t)$, $E_b(t)$ and $E_c(t)$ that vary with time. If our system has a constant finite ...
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17 views

Fermi-Pasta-Ulam for the beam equation

The Fermi-Pasta-Ulam numerical experiment is based upon the discrete wave equation, with a small non-linearity added to the forcing term. Does anybody know of similar research performed on the beam ...
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20 views

Constancy of Coefficients of Additive Integrals Throughout Subsystems of a Closed System

I'm studying Landau and Lifshitz's Statistical Physics, Part 1, 3rd edition and am looking for clarification on the following statement, which appears on page 11 in the section on The Significance of ...
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25 views

Ratio of Stagnation to Normal Flow Properties in Incompressible Flows

I know in compressible flows the ratio of stagnation to normal flow variables is a function of the Mach number and usually the specific heat ratio. Does this ratio mean anything for incompressible ...
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62 views

If a system has an internal energy equal to 0, does this mean it doesn't exist?

Enthalpy is a measure of energy in a thermodynamic system: It includes the internal energy, which is the energy required to create > a system, and the amount of energy required to make room for it ...
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43 views

Does entropy flatten spacetime?

Forgive me if this is a non-question, but I could not find anything regarding this. I only know parts of GR, and I am not familiar with the math. Since energy and matter density curve spacetime, ...
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16 views

Conduction shape factors - textbooks inconsistent

I'm working through a energy flow problem, and need to use the conduction shape factor for 'Row of N long cylinders against planar surface'. However two different texts give two different formulas for ...
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26 views

How can one induce rapid temperature changes in a controlled environment?

What kind of processes are there using which it is possible to change the temperature of a material as fast as possible. You are allowed to use any material you want. Constraints - It should ...
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113 views

Why does hot water and cold water makes different sounds while filling a bucket from a tap

When I fill hot water in a bucket while bathing, there is a difference in the noise it makes compared to cold water. Is there any Relation between temperature of water and sound it makes during ...
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133 views

Why does the characteristic curve (V vs I) for a light bulb backbend?

When teaching Ohm's Law, I have students do an exploration of a small, incandescent light bulb with a low frequency (1-2 Hz) sine wave. It's a simple series circuit of source and light bulb, ...
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127 views

specific heat of water and ice

We know that denser objects have lower specific heat capacity. Since water is more dense than ice, water must have lower specific heat capacity than ice but we know that water's heat capacity is $4....
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74 views

Partial derivatives of Internal energy

If we look at fundamental thermodynamic equation we see that $$dU=\left(\frac{\partial U}{\partial S}\right)dS+\left(\frac{\partial U}{\partial V}\right)dV.$$ We call $\left(\dfrac{\partial U}{\...
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112 views

The formula for calculating work transfer for a reversible adiabatic compression

Should we not be using Pdv for calculating the work done during a reversible adiabatic process ? Why are we using Vdp ? Can some one please explain this ? (P.S. I'm taking an introductory course on ...
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29 views

Lens-Mirror systems and conservation of specific intensity

This came out of a discussion I started yesterday and a related discussion I found. I'll recap the problem quickly: Consider two blackbodies, with surface areas $A_1$ and $A_2$ and temperatures $T_1$ ...
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52 views

Car Heating due to the sun: comparison of different contributions

Let's imagine that we need to choose a car in order to minimize the Temperature that the inner part of the car will reach after some hours under the sun. We know that two factors (if we suppose that ...
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86 views

How to relate internal energy to atomic motion?

I am trying to conceptualize how atomic motion leads to the thermodynamically-defined internal energy (denoted as $U$ below) through some broad mathematical relationships. I get that the internal ...
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25 views

How do I calculate temperature diffusion in a gas contained in a heatsink?

To simplify the problem, consider a sphere with a diameter of $25\mathrm{mm}$ inside an infinite heatsink at $300\mathrm{K}$. At $t=0$ I instantaneously raise the temperature of the gas in the ...
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82 views

Is the diffusion coefficient time-dependent?

It is known that in the partial differential equation: $$u_t=au_{xx} $$ within the limits $0<x<1$ and $a>0$, the diffusion coefficient, arises in the mathematical modelling of a process of ...
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543 views

Molecular structure correction factor in Mass Flow Controller

This question concerns device called Mass Flow Controller (or Mass Flow Meter). For a video explaining the principle: see https://www.youtube.com/watch?v=G62ma2IFh9o These devices are factory ...
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196 views

Confusing Chemical potential of mixtures

I feel that there are very few textbook that treat the chemical potential of mixtures in an understandable clear way, which is why I wanted to ask here about certain things? Although I do not have a ...
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128 views

What does the net force do with this droplet in magnetic field?

Consider a spherical droplet with radious $R_d$ which is coated with an immiscible ferrofluid with volume equal to $2v_f$. While the droplet is in rest on a surface, if I approach two magnets in ...
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349 views

Diffusion in a chemical potential gradient

I am having troubles to understand to connection between equilibrium and non equilibrium thermodynamics. I am studying a mixture of molecules $A,B,C$ and solvent $S$. The free energy $F$ is given by ...
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63 views

Positivity of Bulk modulus and shear modulus in isotropic materials

I have been searching through many resources, but could not find a proper thermodynamic reasoning for why bulk and shear moduli for isotropic materials should be positive. Some resources like eFunda ...
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34 views

Thermal Conduction with multilayered system

Sorry this question probably has a really simple answer but I have been looking and I can't figure out how to solve this problem. I know that the equation for power loss through conduction is $\frac{(...
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34 views

Heat Transfer in Cylindrical Coordinates

Lets say one has an infinitely long cylinder with some boundary heat terms on $r=r_0$ of the form $T(r=r_0, \phi,z)=T_0(\phi,z)$. What is the general solution for this type of equation? The general ...
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39 views

In supersonic flow, why must area increase in order to have velocity increase?

Based on the area velocity relation: $\frac{dA}{A}=(M^2-1)\frac{du}{u}$ For M > 1, in order to increase u, we must increase A. I'm wondering what the explanation is physically and why it is opposite ...
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234 views

Heat Transfer, Water in a pot

I have a question I've been pondering for a while. How can I determine the temperature in a pot filled with water? I know these things: I have a known mass of water, of mass $m_w$ I have a pot of ...
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75 views

Evaluate functional integral in partition function of thermal $\phi^4$ theory (Kapusta/Gale p.34-35)

my question is about some steps in the book "Finite Temperature Field Theory" by Kapusta and Gale. To explain the setting, I how to evaluate the functional integrals in the expression $$ \ln Z_1=\...
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48 views

Electrochemical cell potential - Prigogine book

I'm trying to understand equation 10.2.14 from Prigogine book "Moder thermodynamics": $V=\frac{\tilde{A}}{nF}=\frac{1}{nF}\left(\mu_X^R+\mu_Y^L-\mu_{Xred}^R-\mu_{Yox}^L\right) - \left( \phi^R-\phi^L \...
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265 views

Ergodic Hypothesis; canonical ensemble

I'm currently studying for an exam in thermodynamics/classic statistical mechanics and 2 things came up which are confusing me. First the ergodic hypothesis states that it is equal to take the mean ...
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99 views

Could water physically makeup the core of a planet or otherwise large celestial mass?

Knowing very little about the nature of water, wondering how it might behave at the centre of a planet or centre of an another massive gravitational body. Could water take such pressures or might it ...
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88 views

Could CP violation be exploited to violate the second law?

I don't understand well CP-violation, but since it introduces a microscopic irreversible process, couldn't it be somehow exploited to decrease entropy? For instance, if we could somehow use it to bias ...
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506 views

VdW Gas Entropy/Enthalpy/Gibbs Free Energy of Mixing in 2 Chamber Experiment

What are the equations for $\Delta S_{mix}$, $\Delta G_{mix}$, and $\Delta H_{mix}$ for a real gas? Explanation: In one of the most well known experiments in thermodynamics, two chambers are ...
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104 views

Lennard-Jones induced pseudo-molecules

It can be shown that the Lennard-Jones potential - which describes the interaction between particles in non-ideal gases - gives rise to pseudo-molecules: after a triple "collision" of three (classical)...
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60 views

What's the connection between being homogeneous in energy and having a proper time scale?

Towards the end of page 8 of this scientific paper, I have found the following sentence: ...given the fact that the system is homogeneous in energy, or equivalently, that it has no proper time ...