Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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What is the entropy of the universe today?

What's the entropy of the universe today? How does one go about calculating this? I've heard the statement that black holes account for the bulk of the entropy in the universe today, but don't know ...
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3answers
662 views

Are negative temperatures typically associated with negative absolute pressures?

Negative temperatures and negative absolute pressures are both possible in physical systems. Negative temperatures arise in (for example) populations of two-state systems, which have a maximum amount ...
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1answer
231 views

A thermodynamic transformation that can be represented by a continuous quasistatic path in its state space may still be irreversible. Why?

A thermodynamic transformation that has a path (in its state space) that lies on the surface of its equation of state (e.g., $PV=NkT$) is always reversible (right?). However, if the path is a ...
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1answer
266 views

Flory-Huggins ternary phase diagram with a neutral component

I am searching the literature for the Flory-Huggins phase diagram with the following components : polymer, solvent, and a third component that does not interact with the other components (just entropy ...
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2answers
991 views

Heat transfer between two surfaces

Suppose I have surface A in contact with surface B, if I apply Fourier's law of heat transfer, which $K$ should I use, $K_a$ or $K_b$? Essentially asking whether the same block of material heats ...
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1k views

Understanding the Seebeck effect

Thermoelectricity is, as I understand it, the difference in voltage between the hot and cold ends of two dissimilar materials. If two materials are connected at two different junctions, the hot ...
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260 views

Is quantum uncertainty principle related to thermodynamics?

Would like to ask a question, but first i would like to say Hello Everybody in a way that plays the system, since some geniouses decided that one should not be able to say hello in a question. The ...
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2answers
467 views

Why a mono-atomic crystal layer (2D) can't be stable?

According to Peierls and Landau, 2D crystals were thermodynamically unstable. They can't exist! Of course, this theory was disapproved in 2004 (example: graphene). What is the general definition of ...
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1answer
342 views

Should entropy have units and temperature in terms of energy? [duplicate]

I've been thinking about entropy for a while and why it is a confusing concept and many references are filled with varying descriptions of something that is a statistical probability (arrows of time, ...
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1answer
120 views

Heat preserving performance of container relative to content

This question has been addressed in the case of a thermos bottle: Performance of a thermos bottle relative to contents I am asking the question again without the hypothesis that it is a thermos ...
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16answers
135k views

How Does Mass Leave the Body When you Lose Weight?

When your body burns calories and you lose weight, obviously mass is leaving your body. In what form does it leave? In other words, what is the physical process by which the body loses weight when ...
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7answers
1k views

How is $\frac{dQ}{T}$ measure of randomness of system?

I am studying entropy and its hard for me to catch up what exactly is entropy. Many articles and books write that entropy is the measure of randomness or disorder of the system. They say when a gas ...
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3answers
2k views

What is the minimum pressure of a medium for which a sound wave can exist?

At what pressure will be particles in a medium be unable to form a sound wave when disturbed? How can this pressure be described mathematically? My guess is that this would correspond to the point at ...
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3answers
592 views

Intuitive understanding of the entropy equation

In thermodynamics, entropy is defined as $ d S = \dfrac{\delta q_{\rm }}{T}$. This definition guarantees that heat will transfer from hot to cold, which is the second law of thermodynamics. But, why ...
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3answers
4k views

Is there any proof for the 2nd law of thermodynamics?

Are there any analytical proofs for the 2nd law of thermodynamics? Or is it based entirely on empirical evidence?
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3answers
416 views

Proof of existence of lowest temperature $0 K$

Im mathematics there is a concept of infinity meaning that whenever you pick a number and say that it is the smallest/Largest there is a way to further reduce/increase that number by ...
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6answers
1k views

Do all massive bodies emit Hawking radiation?

It is known that any accelerated observer is subject to a heat bath due to Unruh radiation. The principle of equivalence suggests that any stationary observer on the surface of a massive body should ...
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5answers
2k views

Can a single classical particle have any entropy?

recently I have had some exchanges with @Marek regarding entropy of a single classical particle. I always believed that to define entropy one must have some distribution. In Quantum theory, a single ...
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3answers
511 views

Could temperature have been defined as $-\partial S/\partial U$?

When coming up with a definition of temperature, it's typical to start with an empirical definition that a system with a hotter temperature tends to lose heat to a system with a colder temperature. ...
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1answer
525 views

Why is (von Neumann) entropy maximized for an ensemble in thermal equilibrium?

Consider a quantum system in thermal equilibrium with a heat bath. In determining the density operator of the system, the usual procedure is to maximize the von Neumann entropy subject to the ...
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4answers
569 views

Entropy as an arrow of time

From what I understand, entropy is a concept defined by the experimentalist due to his ignorance of the exact microstate of a system. To say the number of accessible microstates $W$ of the universe is ...
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6answers
4k views

Why does ice form on bridges even if the temperature is above freezing?

So with this "arctic blast" continuing, I've noticed that for my area, the temperature drops below freezing just long enough to cause freezing rain, but then the sun comes out and the temperature ...
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1answer
1k views

Clear up confusion about the meaning of entropy

So I though, and was told, that entropy is the amount of disorder in a system. Specifically the example of heat flow and it flows to maximize entropy. To me this seemed odd. This seemed more ordered ...
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3answers
372 views

What is temperature?

Recently I read an interesting article about negative temperature. I was puzzled because I thought before that temperature has definite meaning in thermodynamics: it tells about how fast atoms jiggle. ...
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4answers
8k views

On a hot day, when it's cooler outside than in; is it better to put a fan in an open window pointing inwards or outwards?

If it's really hot inside, but cooler outside; what is the best way to place a single fan to try and cool a room down? I always assumed it would be better pointing inwards (and this thread suggests ...
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4answers
375 views

Discontinuities and nondifferentiability in thermodynamics

In physics and engineering sources, calculus-based formalisms - whether differential forms on a manifold, or "differentials" of functions of several variables - are presented as a way of modeling and ...
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2answers
2k views

Does a cooling mass lose mass as it radiates?

Assume we have a red hot cannonball in space. It starts off with mass M at 1000K. Later it has cooled by radiation to 100K. Has the mass decreased?
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518 views

Why isn't temperature frame dependent?

In (non-relativistic) classical physics, if the temperature of an object is proportional to the average kinetic energy ${1 \over 2} m\overline {v^{2}}$of its particles (or molecules), then shouldn't ...
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4answers
793 views

Can a single molecule have a temperature?

A show on the weather channel said that as a water molecule ascends in the atmosphere it cools. Does it make sense to talk about the temperature of a single molecule?
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3answers
1k views

Why does the law of increasing entropy, a law arising from statistics of many particles, underpin modern physics?

As far as I interpret it, the law of ever increasing entropy states that "a system will always move towards the most disordered state, never in the other direction". Now, I understand why it would ...
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2answers
352 views

Thermo-Emf variation with temperature

In the following experiment for seebeck effect After a certain temperature, the thermo-emf begins to fall. Why does this happen? What is happening microscopically at this level to cause such an ...
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1answer
649 views

Confused about fire?

Im confused about fire. The way I see it : Heat creates (kinetic) energy in mass and this creates stronger vibrations of atoms. When those vibrations are strong enough the electrons interact ...
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3answers
6k views

Internal energy according to the van der Waals equation

I am trying to derive the internal energy of a gas which obeys the van der Waals equation. I have however encountered some problems. I calculate the integral of $dU$ from $V=0,T=0$ to $V=V, T=\infty$ ...
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6answers
19k views

Does hot air really rise?

"Heat rises" or "warm air rises" is a widely used phrase (and widely accepted phenomenon). Does hot air really rise? Or is it simply displaced by colder (denser) air pulled down by gravity?
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How efficient is an electric heater?

How efficient is an electric heater? My guess: greater than 95%. Possibly even 99%. I say this because most energy is converted into heat; some is converted into light and kinetic energy, and ...
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6answers
750 views

What's the best strategy to fully fill the fridge with beer bottles and have them all cooled?

I'm having a party. Suppose I'd like to have a fridge full of cold ($6~^\circ\text{C}$ or below) beer bottles, in as short a time frame as possible. The fridge indicates that it is targeting (and ...
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3answers
2k views

How can I understand a Vortex Tube and its efficiency?

A Vortex Tube takes a pressurized input stream, most typically of a gas, and creates two output streams with a temperature differential. Apparently, it has been described as a Maxwell's Demon. Both ...
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2answers
559 views

Radiation– white vs black house, hot or cool?

In my book's thermodynamics chapter, it says that an "object that radiates heat faster also absorbs heat faster. This means that an object that is a more efficient radiator comes to equilibrium ...
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2answers
875 views

Energy of unmixing

Mixing of two different fluids is associated with an increase of entropy. Conversely, separation of two gases must be associated with a decrease of the entropy of the two fluids. Is there a minimum ...
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1answer
1k views

Isentropic Processes

I'm having trouble understanding why reversible adiabatic processes are isentropic. I understand that in a reversible adiabatic process there is no heat exchange and so $dQ = TdS = 0$. However, if ...
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1answer
134 views

Total and partial derivatives in thermodynamics and Maxwell relations

Consider the expression $$dS=\left(\frac{\partial S}{\partial T}\right)_VdT+\left(\frac{\partial S}{\partial V}\right)_TdV$$ I'm trying to understand how to derive an expression for $\left( ...
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2answers
521 views

Is there an equation to calculate the average speed of liquid molecules?

I seem to remember from first year physics that we can calculate the RMS speed of a stationary, ideal gas with $v=\sqrt{\frac{3RT}{M}}$. Does a similar equation exist for liquids?
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3answers
437 views

Mathematical proof of non-negative change of entropy $\Delta S\geq0$

I understand that we can prove that for any process that occurs in an isolated and closed system it must hold that $$\Delta S\geq0$$ via Clausius' theorem. My question is, how can I prove this in a ...
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2answers
411 views

How can it be that the sun emits more than a black body?

As far as I know, a black body is an ideal emitter. So how can it be that a non-ideal emitter emits more radiation than a black body? This happens only in a very limited area at around 500nm, but it ...
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3answers
676 views

Why must the particles of an ideal gas be point-like?

Why is a gas of elastically colliding hard balls of finite size not ideal? Respectively: Why is it essential that the particles of an ideal gas are point-like? Especially: Which ...
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1answer
356 views

Maxwell demon : how can the demon move the door without doing any work ?

Here is something that I never understood about Maxwell's demon paradox : in order to contradict the second law of thermodynamics, the demon must open and close the door without doing any work... But ...
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1answer
158 views

Dropping condition

Imagine opening a water tap in order to have a smooth and cylindrical outflow and then slowly decrease the flow by adjusting the knob. At a certain moment, the side profile of the flow will become ...
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3answers
207 views

Problem about entropy

Combining the first and second law of thermodynamics we can get the following equation $$TdS=dU-P_{ext}dV$$ First question: Is this equation applicable for irreversible processes such that that ...
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1answer
180 views

Is this derivation of Black Hole entropy viable?

This question is motivated by this one. Suppose $l$ is the minimum measurable unit of length. What is entropy of a spinless particle contained in this interval? We know that entropy of a two-level ...
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188 views

What happens at the interface between two universes with opposite thermodynamic arrows of time? [closed]

I was trying to think but cannot figure it out. For instance, if the interaction is small, for instance limited to a windows, the observers in each universe will see that the other goes in reverse. ...