Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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104 views

What would be non-ergodic physics processes?

As the title says, what would be non-ergodic processes that occur in statistical physics? Many textbooks do not really cover ergodicity really well so I ask this question. I can't suddenly remember ...
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1answer
35 views

What does adding a visible light blocking IR filter do with heat?

Lets say I have a strong halogen light source which has a lot of IR radiation (e.g. a construction lamp). If I change the transparent front glass from the enclosure with a IR filter that blocks ...
8
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2answers
155 views

What conditions do a bunch of atoms need to satisfy to have a temperature?

What conditions do a bunch of atoms need to satisfy to have a temperature? Suppose that we have a beam of helium atoms travelling in a common straight line, equally spaced with the same velocity. If ...
0
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1answer
24 views

Macro-Level Explanation of Fluid Heat Transfer

Here's something I've been struggling with for a while. Say you have a hot fluid and cold surface (or the reverse, so long as there is a temperature difference) where the fluid flows over the ...
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1answer
21 views

Do the characteristic vibrational modes of a material define how much will a material heat up upon radiation excitation?

Do, and if yes how, does the intensity and energy of the Raman modes of a material make it to heat more by radiation excitation. I see phonons and vibrations of the lattice as heat, but maybe I'm ...
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1answer
108 views

How do heated showers/faucets work? [on hold]

I'm not sure if this question is for Physics SE, but I'd go ahead and ask. I was wondering how the heated showers work (the ones with the hot and cold knobs). I have always been curious and this may ...
2
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1answer
72 views

Which air will give more effective cooling ? Dry or Moist?

Yesterday, I had an innovative idea. I live in India, and in summer season, the temperature can reach up to 45 degree Celsius. We use Split 1.5 Ton AC in our small office. The idea is to put an ...
0
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1answer
18 views

Energy comparison, evaporate water vs compress air, same mass

I would like to compare the energy requirements of the 2 following tasks: Total energy to evaporate 1 litre of water at normal atmospheric pressure at normal temperature? Total energy to compress ...
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3answers
134 views

Why is Entropy's Definition Useful?

I have somewhat of an understanding for other physical quantities, but as far as entropy goes I only know it to be "disorder". Why is the change in entropy formula an appropriate/useful definition, ...
0
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1answer
52 views

Enthalpic Excess - Regular Solution Upon Mixing

My professor, in his handout, says the following about this diagram : For $\beta>+2$ there are two minima and phase separation occurs driven by unfavourable enthalpic interactions. I ...
0
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1answer
51 views

conducting heat to infinity

I am modeling a situation in which an object that is a small object that is spherical in shape is receiving heat at a constant rate and then conducting it away into a medium that can be model as ...
6
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3answers
388 views

Hot water freezing faster than cold water

This question has puzzled me for a long time. There is already a question like this on Physics.SE. John's answer to the question seems quite satisfying. But when I googled the cause I found this and ...
3
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1answer
59 views

Radiation emission and absorption

Any object can emit and absorb radiation and the power of emission can be represented by the Stefan-Boltzmann law: $$P=A\epsilon\sigma T^4$$ In many texts the net power radiated is the difference ...
0
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3answers
194 views

Why change in internal energy is zero in isothermal process

In isothermal process $\Delta U =0$. But I am having trouble understanding it. Say we have an ideal gas, and say my temperature is constant but I move the pressure, volume from $(P, V) \to (P-dP, ...
2
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2answers
222 views

Phase volume contraction in dissipative systems

I am confused about phase-volume contraction in dissipative systems. Please help me catch the flaw in my understanding. From a macroscopic point of view I understand that a dynamic system tends to go ...
0
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1answer
27 views

How many state configurations are possible for $N$ particles in completely different states?

How many state configurations are possible for $N$ particles in completely different states? I cannot remember if the total number of state configurations for $N$ particles in completely different ...
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0answers
21 views

P-N junction voltage under polarization

All the books that deal with the p-n junction under applied bias asume that the same equations used for the equilibrium case (no bias) can be used for the biased case provided that the juntcion ...
2
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1answer
1k views

Finding electric power generated using heat transfer

I'm working through an example I have been given to study. Suppose I have a 2m X 4m photovoltaic panel on my roof that is irradiated with a solar flux of $G_s = 700W/m^2$. Given: $\alpha_s = 0.83$ ...
2
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0answers
23 views

Electrochemical cell potential - Prigogine book

I'm trying to understand equation 10.2.14 from Prigogine book "Moder thermodynamics": $V=\frac{\tilde{A}}{nF}=\frac{1}{nF}\left(\mu_X^R+\mu_Y^L-\mu_{Xred}^R-\mu_{Yox}^L\right) - \left( \phi^R-\phi^L ...
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3answers
56 views

Convective heat transfer coeficient equation

I am attempting to model a situation, in which a sphere of some material of identifiable thermal properties is receiving heat at a constant rate. And that material is coming into equilibrium with the ...
2
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1answer
39 views

Gas pressure and centrifugal force

I think about a rotating torus (simplified tire) filled with ideal gas. Mass of gas is $m$ and molar mass is $M$. Pressure in non rotating torus is $p_0$. Temperature is constant $T$. Inner radius of ...
3
votes
2answers
105 views

Why does blowing on hot coffee cool it down?

And will it cool off faster if you blow across the top of the cup or directly into the coffee? Does it have to do with the fact that when you blow across the top of the cup the velocity of the air ...
2
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3answers
92 views

Where is the potential energy due to internal interactions in total energy?

In thermodynamics the total energy of a system consists of kinetic energy of motion of the system as a whole, potential energy of the system as a whole due to external force fields, and energy ...
2
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3answers
73 views

Is thermodynamic free energy and potential energy the same thing?

The equation for free energy $F$ and potential energy $E_{pot}$ are: $$ F=U-TS \\ E_{pot} = E_{tot} -E_{kin} $$ But the temperature $T$ is proportional to the average kinetic energy of a system. So ...
3
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1answer
297 views

Does a negative line tension in a 3-fluid immiscible interface make sense?

This question is inspired by this question/answer pair: Is this formula for the energy of a configuration of 3 fluids physically reasonable? Consider three immiscible fluids forming contact surfaces, ...
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0answers
19 views

Heat engine efficiency, compression ratio vs temperatures

I want to understand the role or even existence of a cold reservoir in the Otto cycle gasoline engine. The efficiency of the Otto engine is given as a function of compression ratio $$ ...
4
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3answers
186 views

Mathematical proof of the Second Law of Thermodynamics

Is there some book or paper that formalizes statistical mechanics, like some people have done with relativity, and proves the second law of thermodynamics from more foundational axioms?
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0answers
41 views

Confusion on entropy in the universe [closed]

I was researching about the heat-death of the universe, and I was wondering if my understanding of it so far is factual to the theory? However, the 3rd Law of Thermodynamics prevents the universe’s ...
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0answers
52 views

Ergodic Hypothesis; canonical ensemble

I'm currently studying for an exam in thermodynamics/classic statistical mechanics and 2 things came up which are confusing me. First the ergodic hypothesis states that it is equal to take the mean ...
0
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1answer
79 views

Boltzmann Distribution of Electrons in Confining Potential

I have a particle simulation wherein many non-interacting electrons are trapped in a electric potential well. I would expect, and therefore I initialize according to this, that the electrons would ...
7
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1answer
121 views

Is there a true parallel between Gibbs' phase rule and Euler's polyhedral formula?

Gibbs' phase rule states: $$F=C-P+2$$ where $F$ is number of degrees of freedom, $C$ is number of components, $P$ is number of phases. Euler's polyhedral formula states: $$V+F-E=2$$ where $V$ is ...
65
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16answers
123k views

How Does Mass Leave the Body When you Lose Weight?

When your body burns calories and you lose weight, obviously mass is leaving your body. In what form does it leave? In other words, what is the physical process by which the body loses weight when ...
5
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4answers
130 views

I still don't understand how a gas with an equation of state f(T,p,V)=0 can change if 2 state functions are fixed?

Just like classical potential, it's stated that equilibrium is obtained when the corresponding thermodynamics potential reaches the minimum. Explicitly, according to Wikipedia, in particular: ...
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4answers
50 views

Why does my house seem to warm faster in summer than it cools in winter?

In summers when we switch off the air conditioner, the room seems to instantly get hot again. But in winter, when we switch off the heater the room seems to remain hot for some time. Why this ...
2
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3answers
931 views

Would a Cup of Tea Be Hotter If you Add the Milk Before or After Boiling Water?

This is a bit of dispute between work colleagues. An answer would be greatly appreciated. My argument is as follows: If you add X amount of milk at a temperature of M to a mug at room temperature R ...
2
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1answer
99 views

Thermodynamics, chaperones : How to model polymer fragmentation

Living polymers are well described by equilibrium statistical physics. Now I would like to consider a case were living polymers undergo fragmentation due to chaperones. I can think of a kinetic ...
3
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4answers
288 views

Do objects gain and lose heat at the same rate?

For example, if I take an item out of the refrigerator, set it on the counter for a period of time, allow it to warm up a bit (but not so long that it reaches room temperature and stabilizes), and ...
2
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0answers
55 views

Does a cooler, submerged in water, keep beer colder, longer?

Looking around the web, I see some submerged bucket-like things, without insulation, and some floating coolers, where the actual cooler is not submerged. Given that your water temperature is lower ...
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1answer
85 views

How does enthalpy help us to find the state of equilibrium?

For an adiabatic system with constant external (generalized) forces, in a state out of equilibrium we have: $$\delta H\leq 0 $$ If I understand correctly, derivation of this inequality does not rely ...
340
votes
19answers
128k views

Cooling a cup of coffee with help of a spoon

During the breakfast with my colleagues, a question popped into my head: What is the fastest method to cool a cup of coffee, if your only available instrument is a spoon? A qualitative answer would ...
0
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2answers
36 views

Why doesn't the entropy of an isolated system of ideal gas change during isothermal compression/expansion?

Even if the system is isolated and there is no heat exchange with surroundings, shouldn't the decrease/increase of pressure result in increase/decrease of entropy ??? Does this property of an ...
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1answer
94 views

Calculating Phase Diagrams (Calphad)

I am calculating the phase diagrams for Li-Mg binary alloy with reference to the following text: http://ieeexplore.ieee.org/xpl/articleDetails.jsp?arnumber=5600701 In the equation used in the above ...
0
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1answer
37 views

Canonical ensemble, energy, heat bath

I am studying through the book Thermodynamics and Statistical Mechanics by Walter Greiner and I’ve got a couple of doubts when I was reading about the classical ensembles, specially the Canonical ...
2
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1answer
68 views

Is this theory about Universe information true?

I recently saw this video about information and randomness. At some point, it states that a completely predictable universe would infringe the second law of thermodynamics, because it would imply that ...
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0answers
29 views

SInce heat is a vibration in solids, isn't it just small scale sound? [duplicate]

On an atomic scale I think of electrons hitting positive ions in an electric lattice. Most energy there is heat energy. If I think of ball bearings flying through a large lattice, I think sound is ...
0
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1answer
47 views

How to prove R value for insulation?

I ran some tests on different types of insulation. I heated water, and placed it into an insulated box. The temperature was recorded every minute, for the water, as well as the air. The insulation ...
2
votes
3answers
174 views

Is it more efficient to stack two Peltier modules or to set them side by side?

Is it more efficient to stack two Peltier modules or to set them side by side? And why? I have a small box that I want to cool down about 20 K below ambient -- cold, but not below freezing. (I want ...
2
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2answers
3k views

Microwaves vs Gas or Electric Coil heating of a water boiler in a typical household

Wouldn't it be more energy efficient and or safe to use microwaves to heat our home's water boiler instead of using dangerous gas or hot electric coils that could catch other things on fire? I'm kinda ...
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0answers
23 views

Laws of Thermodynamics [duplicate]

According to the laws of thermodynamics (specifically the first law, law of conservation of energy), energy cannot be created or destroyed, it can only be redistributed and changed from one form to ...
9
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1answer
1k views

Why is compressible flow near the choke point so efficient?

Imagine a steady state, one-dimensional, compressible flow in a horizontal pipe of constant cross sectional area. This flow can be isothermal, adiabatic (Fanno), or diabatic (Rayleigh). As an ...