Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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30 views

Different materials have different temperatures?

Why do two materials, under the same weather, have different temperatures? I have a small clue about it. For example, iron and wood supposed under the sun's radiation, and if we touch both of them, ...
2
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2answers
83 views

Why is the outside run of high presure line on a ductless mini-split airconditioner insulated?

On every ductless mini-split air conditioner I've ever seen, both the high and low pressure lines are insulated between the compressor and the building. It seems like the liquid refrigerant coming ...
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1answer
47 views

Changing the melting point of ice

Myself and a friend have been stuck on this problem for a while now. We know that we should end up with an answer of $-0.007K$ however, cannot get to this solution. Help with the method we should use ...
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2answers
79 views

What is the heat sink in an internal combustion engine?

I believe that the heat source is the spark plug because it heats up the fuel-air mixture and that the working substance is the fuel-gas mixture. Then, I know that the explosion created by the fuel ...
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2answers
45 views

derivation qm canonical ensemble

In classical mechanics the canonical ensemble can be derived from the microcanonical ensemble of two systems in weak interaction. Is a similar thing possible in quantum mechanics? Is there any good ...
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6answers
731 views

Why does the bathroom become hot after a bath?

I have noticed many times that whenever I enter into the bathroom just after someone else bathed the temperature inside it would be high. Is it that the body heat comes out when we pour a lot of ...
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5answers
174 views

Entropy Change in an irreversible process

I have just started learning thermodynamics and the concept of entropy confuses me. Suppose I have a gas in a cylindrical container fitted with a piston. I take it through an adiabatic irreversible ...
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0answers
29 views

Specific heat at constant volume

Me and my friend came across this derivation is some lecture notes of our thermal physics module. We have been trying to calculate the partial differential of the internal energy but cannot get the ...
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0answers
22 views

Work done by a gas in an expansion

1) Consider a gas expanding quasistatically and reversibly from $V_1$ to $V_2$ at constant temperature. I want to calculate the work done. So by convention work done by a system is a negative quantity ...
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0answers
8 views

What is the heated added and changes in internal energy? thermodynamics

A piston + cylinder initially contains 2 x 10-3 m3 of helium gas at the pressure of 1.01 x 105 Pa and with a temperature of 60'C. The gas is heated allowed to expand at a constant pressure until its ...
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0answers
13 views

Heat energy question [on hold]

An aluminium block of mass 1 kg is heated by an electric heater for 3 minutes and a temperature rise of 15 °C is recorded. If the electric heater is connected to a voltmeter which gives a reading of ...
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1answer
935 views

Physics-based derivation of the formula for entropy

I am looking for a derivation of the formula $$S~=~-\Sigma_ip_i \log (p_i).$$ for entropy, from first principles. I only wish to assume the laws of physics, and without involving concepts in ...
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0answers
20 views

Classifying solutions of equation of state as functions of temperature

I've got an exam in 2 days and the past papers don't have solutions. I'm given this equation of state: $$ p + a\frac{N}{V} = \frac{Nk_BT}{V-bN}$$ and asked to classify the solutions as functions of ...
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1answer
33 views

Find the velocity of the escape of the bullet

A gun has a muzzle 0.8 meters long and with a diameter of 0.006 m. A bullet with mass 0.002 kg is initially 0.01 m away from the end of the muzzle. As a result of a gunshot, the pressure of the gas ...
2
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2answers
44 views

what is the temperature (and pressure) of the oxygen inside an oxygen bottle?

In the hospital or in a lab, one can see the huge oxygen bottles. A question is, what is the temperature of the oxygen inside the bottle? And what is the pressure inside? We know the critical ...
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0answers
17 views

Find the molar specific heat for each gas [on hold]

A mixture of two ideal gases, the first one atomic and the second two atomic are put in normal conditions in a calorimeter with volume 1 liter hermetically closed. After it is given 10J thermal energy ...
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0answers
23 views

Find the time needed to warm the water to a temperature [on hold]

An electrical resistence has a power of 1 kW. It is put inside a container that has 10 liters water. The water is in temperature 20C with pressure 1 atm. Find the time to warm the water to the ...
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1answer
333 views

Compute convective heat transfer coefficient for a condensing steam

I have a question about convective heat transfer coefficients. I am trying to figure out how much steam I can condense in this specific heat exchanger. Steam at 9 MPa is condensed in a 1 shell pass, ...
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1answer
28 views

Show that change in internal energy equals zero for an adiabatic process with incompressible fluid

I have a problem when solving an exercise in thermodynamics. I am supposed to show that when we have an open system, where the process is adiabatic with an incompressible fluid, it follows that the ...
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1answer
165 views

Liquid column “recoils” in a sealed cylinder when hit by a piston — is it possible?

Consider a cylinder filled partially with a liquid (e.g. water). The cylinder is sealed, and is at held at room temperature (e.g 298K). At equilibrium (or when no external disturbance is imparted to ...
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1answer
143 views

How does enthalpy help us to find the state of equilibrium?

For an adiabatic system with constant external (generalized) forces, in a state out of equilibrium we have: $$\delta H\leq 0 $$ If I understand correctly, derivation of this inequality does not rely ...
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1answer
37 views

Struggling with whether its $\pm p dV $

I am struggling to understand when calculating the work done by a gas whether it is postive or negative p. It my notes and in many other notes sometimes it is $-pdV$ and sometimes it is $pdV$. I ...
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0answers
13 views

Chemical potentials of SM particles at high temperatures

Recently I've heard the statement that chemical potentials of SM particles on $T > 1 \text{ GeV}$ are very small, so that Gibbs potential reduces to free energy. How to prove this statement? Does ...
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3answers
12k views

Why do lightbulbs continue to glow after the light is turned off?

I've noticed that whenever I turn the lamp off in my room at night, the lightbulb seems to continue to glow for a minute or so after that. It's not bright though; the only way I even notice it is if ...
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2answers
52 views

clausious inquality

Take a reservoir which gains a heat Q irreversibly at temp T from a surrounding at temp T0 then the entropy change of reservoir is given by Q/t and that of the surrounding is -Q/T0...How is this ...
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1answer
80 views

Does time stand still at a phase transition?

For second order phase transition thermodynamic properties can be described in very general terms by their critical exponents. So at every transition the correlation length $\xi$ should diverge as ...
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1answer
24 views

entropy change during irreversible heat loss [duplicate]

When a thermodynamic system gains heat if the heat gain is irreversible then there is a entropy generation along with the entropy transfer..so is there a similar entropy generation associated with ...
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0answers
15 views

Superficial velocity as a function of position along flow path

I am wanting to estimate the superficial velocity of a fluid as a function of position. The system I'm trying to evaluate is as shown below: A cylinder of porous media with the source acting on ...
0
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0answers
26 views

Why the heat capacity doesn't diverge in the Kosterlitz-Thouless (KT) phase transition?

The KT transition has a special properties that, during the phase transition the heat capacity stay finite (so the behaviour of the heat capacity cannot reflect any critical behaviours). However, the ...
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1answer
30 views

Helmholtz Free Energy vs Gibbs Free Energy in Landau Theory

When I was studying thermodynamics potentials for the first time, I learned that keeping the pressure and the temperature constant, the Gibbs Free Energy is a minimum, also, if we maintain the ...
4
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1answer
329 views

Hysteresis and dissipation

Hysteretic phenomena are often linked to dissipation. When there is an hysteresis loop, the dissipated energy can usually be computed as the area of the cycle. For example, in ferromagnetic ...
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0answers
20 views

Internal energy of a molecule and bonding strength

I had a lecture on thermodynamics. I was told that the bond strength, $\epsilon$, is related to the latent heat of sublimation, $L_s$. $L_s\approx L_f+L_v$ if the melting and boiling points are close, ...
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5answers
2k views

Crash course in classical thermodynamics

I've been working on some projects lately where it would be very handy to know more about thermodynamics than I do, but sadly I never had a chance to take a proper thermodynamics course in college. ...
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2answers
92 views

How does temperature relate to the kinetic energy of molecules?

In ideal gas model, temperature is the measure of average kinetic energy of the gas molecules. If by some means the gas particles are accelerated to a very high speed in one direction, KE certainly ...
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2answers
103 views

Thermodynamics : Work done on gas inside container by the force due to pressure exerted by external atmosphere

Suppose a container is fitted with a massless and frictionless piston lying on a table such that pressure due to gas is greater than pressure due to external atmosphere. Hence piston will move. Now ...
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1answer
283 views

Why does the Nusselt Number for a Constant Surface Temperature, Thermally Fully Developed Circular Pipe Converge To a Constant of 3.66?

I have flow in a pipe with a constant surface temperature boundary condition. The velocity profile is fully developed and the temperature profile is also fully developed. In my textbook, it says that ...
4
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2answers
294 views

What is the resolution to Gibb's paradox?

This question is essentially a duplicate of Gibbs Paradox - why should the change in entropy be zero?. The question concerns the following situation: I have some gas of identical particles and they ...
2
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1answer
7k views

Best way to solve P-V-T Question

Typically in an exam or problem set we have a problem that's like this: Determine the specified property at the indicated state of water. Locate the state on a sketch of the T-v and P-v diagram. p= 3 ...
6
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2answers
1k views

Gibbs Paradox - why should the change in entropy be zero?

The Gibbs paradox deals with the fact that for an ideal gas with $N$ molecules in a volume $V$ seperated by a diaphragm into two subvolumes $V_1,V_2$ with $N_1,N_2$ particles in each subvolume, ...
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1answer
89 views

Modelling multiple heat sources?

I am working on a project to model heat transfer in a data center. I have basic models for a one dimensional heat transfer using conduction and convection. Such as, taking a server and modelling the ...
5
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4answers
273 views

Definition of Entropy in thermodynamics

In most textbooks, the definition of entropy in reversible processes on a system $S$ is given simply as $$d S=\delta Q/T.$$ It seems to me this definition is insufficient since it does not specify ...
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2answers
192 views

How to understand the indeterminate process in thermodynamics?

Consider a closed composite system with an internal movable adiabatic wall. If we release the piston, thermodynamics cannot determine the final equilibrium state (the temperature cannot be ...
3
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0answers
52 views

What liquid would wick away heat most quickly?

I've read and seen on various "life hack" websites that if you've forgotten to chill drinks, wrapping them in a wet paper towel and sticking them in the freezer for a few minutes rapidly cools them ...
1
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1answer
128 views

Heat Transfer and Thermal Energy

Some hot water radiators have a single pipe connected to them. The steam comes to the radiator and the water leaves in the same pipe. The steam and the water are both at a temperature of 100°C. Where ...
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1answer
51 views

Why bodies lose heat faster in water than in air?

A simple question. In several places, including this very recent and already famous paper http://www.sciencemag.org/content/348/6236/786.short it is stated that bodies lose heat in water very fast ...
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1answer
155 views

Problem about thermodynamic relations

We know that for constant pressure thermodynamic processes, $dH=dQ_p$. My question is, does it implies that only reversible work is possible in this processes so that $dw=0$ because $dv$ is zero? In ...
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2answers
229 views

Why does the coefficient of performance need to be calculated with $W + Q$?

How much work must a heat pump with a COP of 2.50 do in order to extract 1.00 MJ of thermal energy from the outdoors (the cold reservoir)? The first formula that came into my mind after reading ...
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0answers
23 views

Magnetic moment of a paramagnetic crystal

I've been having some trouble with a paramagnetism problem from my Statistical Mechanics class textbook (F. Mandl, Statistical Physics, 2nd edition, p. 25). The problem is as follows Since the ...
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1answer
77 views

Does time freeze at Absolute Zero? [closed]

Time has many definitions per se, but the basic idea being it's "the measurement of change" so as we know, all matter looses it's ability of changing with the loss of kinetic energy. and the where it ...
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1answer
265 views

How hot would tritium water be?

I realize this is kind of a silly question, but if you have tritium water, with the tritium half life of 12.5 years, I expect it would be quite hot. (note, this is not a homework question, I'm just ...