-1
votes
0answers
22 views

Runs of a vacuum pump? [on hold]

After how many runs of a vacuum pomp with volume $v$, the initial pressure $p_i$ of a balloon is reduced to a final pressure $p_f$? Baloon's volume is $V$ ($V>v$).
2
votes
1answer
19 views

Thermal expansion coefficient times temperature: under which condition is it unity?

In Landau's Fluid Mechanics p. 8 (2nd edition) he writes for the thermal expansion coefficient $\beta = (1/V) (\partial V/\partial T)_P$: For a column of gas in equilibrium which can be taken as a ...
5
votes
3answers
82 views

Can we apply $pV^\gamma$=const only for quasistatic adiabatic process?

But If this is so, I have often seen people applying this formula for quick processes where no heat exchange is possible. Here is an example from where I am quoting the following: we will assume ...
0
votes
1answer
17 views

Perfect Ideal Gas Modelization of Air

I'm solving a Thermodynamic problem. I have Air at temperature of 293.15 K, and pressure of 20 MPa. I would understand if is possible to consider this an Ideal Gas or not (and if is possible which are ...
1
vote
0answers
17 views

Effusion of particles from one box to another - pressure calculation

Suppose we have a container divided into equal halves. Right half is fixed at temperature $T$, volume $\frac{V}{2}$. Initially it has pressure $P_0$, a hole of area $A$ is opened between them. I ...
0
votes
2answers
41 views

Not Quasi-static, yet reversible process? Is this a valid example?

Imagine a gas (at room temp. and pressure) enclosed in a thermally insulating spherical container. At some instant, the container instantly expands symmetrically (radially outward) to, say, twenty ...
0
votes
2answers
40 views

Question about Charles' law:

Charles's law says that the volume of a given mass of a gas is directly proportional to its absolute temperature. This means if we increase one, the other one is automatically increased. So the ...
1
vote
2answers
35 views

Temperature in an isobaric process

I have a certain conceptual issue - I'm solving heat engine problems and I found something difficult to understand. Let's take an isobaric part of a cycle of an engine, let's say that the ideal gas is ...
3
votes
1answer
135 views

How do you explain the fact that when air expands freely into an evacuated chamber from a constant pressure atmosphere, its temperature increases?

I came across this paper: Baker, B. (1999). An easy to perform but often counterintuitive demonstration of gas expansion. American Journal of Physics, 67(8), 712-713. ...
6
votes
1answer
113 views

Doubts about the ideal gas law

EDITED AND SOLUTION: In fact my stupid mistake was to take the wrong value for my $P_1$ and I was getting an 1.2998 that finally is a 1,9178 within just a difference about 7%. So at the end they are ...
1
vote
1answer
143 views

Understanding collision terms in Boltzmann equation

I am reading a paper that deals with the Boltzmann equation. They add a collision which is supposed to account for collisions which happen when particles are within a radius of $d$ from each other. ...
1
vote
2answers
34 views

Infinite heat from gas?

Does any type of gas keep the same temperature if is constantly exposed to same force? In other words, must we change the applied force in some moment to get heat again, or is the same constant force ...
0
votes
1answer
68 views

How do we know that the Virial Expansion exists?

How do we know that the Virial Expansion exists? How do we know that we may always write $\frac{p}{kT}$ as a power series in $\frac{N}{V}$? That is, how do we know that there exists $B_{i}$ so that ...
0
votes
1answer
361 views

Enthalpy Change in Reversible, Isothermal Expansion of Ideal Gas

For the reversible isothermal expansion of an ideal gas: $$ (1)\ {∆H}={∆U}=0 $$ This is obvious for the case of internal energy because $$ (2)\ {∆U} = \frac {3}{2} n R {∆T} = 0 $$ and $$ (3)\ {∆U} = ...
3
votes
5answers
448 views

Does it take infinite energy to create a perfect vacuum?

Question is inspired by a recent burst of perpetuum mobile-type questions. It would be nice if one could simply discard them all by an argument that shows it's impossible to create a perfect vacuum. ...
0
votes
1answer
194 views

Do ideal gases at zero Kelvin have potential energy?

Do ideal gases at zero Kelvin have potential energy?
3
votes
4answers
1k views

Deriving combined gas law from Boyle's and Charles' laws

I know that the combined gas law, $$\frac{PV}{T}=k$$ should be derivable from Boyle's Law and Charles' Law. Since these are very basic equations, I presumed that it would be a simple matter, so I ...
2
votes
2answers
72 views

Work done by isothermal expansion from two different viewpoints

Consider an adiabatic system as follows. It consists of a gas in a container and a piston. Initially, the system is at equilibrium and the gas inside it occupies a volume $V_i$ at a pressure $p_i$ ...
0
votes
1answer
152 views

Why do real gases deviate from ideal behavior above the Boyle temperature?

My textbook says that Boyle temperature is the temperature at which a real gas shows maximum ideal gas behavior. Below the Boyle temperature, molecules come too close and intermolecular forces skew ...
3
votes
4answers
180 views

Heat transfer by conduction is not possible for gases?

Today one of my instructor told me that gases cannot have heat transfer thru conduction because molecules are far apart and so it cannot transfer heat,infact the diffusion process of gases transfers ...
1
vote
0answers
39 views

Help wanted achieving cryogenic temperatures [closed]

My son's science project involves liquifying air. I found the Linde process which is the way it was done first. We are trying and not getting very far so I am looking for advice. I have an air ...
0
votes
0answers
39 views

How does pressurized gas constantly push?

If a gas, such as hydrogen, is pressurized into an air tight container, a force in terms of pascals (or whatever unit you want to use) is exerted, correct? That is what pushes against every surface ...
0
votes
2answers
639 views

How do you calculate the change in temperature of an adiabatic system?

I really don't even know how to start doing this problem. I understand PV=nRT and I understand that if either T, V, or P is kept constant, then the other 2 change at the same rate, and I understand ...
1
vote
1answer
236 views

Is temperature-induced change in the volume of balloons dependent on gas?

Which balloon will have higher relative change in volume, helium balloon immersed in liquid nitrogen or air balloon immersed in liquid nitrogen? Since volume is directly proportional to temperature ...
1
vote
2answers
397 views

Why doesnt this violate 2nd law of thermodynamics?

Consider an ideal gas in a cylindrical container in a gravitational field, with a piston on top pushing down by gravity. The piston has some locking mechanism that locks it in place if it is displaced ...
2
votes
1answer
155 views

Volume quotient in Carnot-cycle

Problem: One kilomole of an ideal, monatomic gas undergoes a reversible Carnot-processes between temperatures 300 °C and 20 °C. The work done during one cycle is 1500 kJ. a) Find the ...
0
votes
1answer
245 views

Problem involving 1st law of thermo and ideal gas law

Problem: $1.0 \text{ kg}$ of air at pressure $10^6 \text{ Pa}$ and temperature $398 \text{ K}$ expands to a five times greater volume. The expansion occurs such that in every instance the added ...
0
votes
3answers
75 views

Behavior of gasses, ideal and otherwise

I'm trying to help a child research a science project on refrigeration. Refreshing my incredibly rusty thermodynamics skills.... The ideal gas law: $PV=nRT$. Let's take air at STP: $P = 101\,kPa$ $V ...
1
vote
1answer
136 views

Why is there a sign error in my derivation? Adiabatic expansion of ideal gas: $TV^{1-\gamma}$ is constant

This is the last part of a derivation of the equation for an ideal gas undergoing reversible adiabatic expansion. I'm trying to prove that $T V^{\gamma-1}$ is constant, but my result is that $T ...
6
votes
2answers
162 views

Would the temperature of a gas change when accelerated in a train?

I was thinking about a situation where some gas is enclosed inside a container and kept in a train at rest. The train accelerates, gains a maximum speed and then suddenly stops. Would the temperature ...
4
votes
1answer
436 views

Simple explanation of relation between speed of sound and r.m.s. speed?

In an ideal gas, the speed of sound $v_s$ is related to the r.m.s. molecular speed $v_m$ by $$\frac{v_s}{v_m}=\sqrt{\frac{\gamma}{3}} \qquad ,$$ where $\gamma=C_p/C_v=7/5$ for a diatomic gas. I ...
1
vote
2answers
323 views

Adiabatic filling of a container

Suppose a thermally insulated container is filled with atmospheric air until the pressure reaches 5000 psi. This could represent the filling of a diving cylinder, before thermal dissipation becomes ...
7
votes
2answers
540 views

How does a gas of particles with uniform speed reach the Maxwell-Boltzmann distribution?

Take an empty container and fill it with $N$ gas particles (ideally a monoatomic gas), each having the same kinetic energy $E$, then isolate the container. Since initially the speeds don't follow the ...
0
votes
0answers
15 views

Calimetric Perfect Ideal Gas

What is the energy equation when you have a ridgid adiabatic open system where you have a mass flow rate in and a mass static inside the system?
0
votes
2answers
109 views

Combined gas law in an open atmosphere

The question was asked about pressure vs. Volume increasing in an ideal gas as temperature is increased. My question then is this. What is the formula to determine how much volume and pressure will ...
2
votes
2answers
3k views

In an ideal gas, if temperature increases, will pressure or volume increase?

This question came up when I was talking about the atmosphere. Someone had mistakenly claimed that as temperature increases, the density of the atmosphere should increase as well. I reasoned from the ...
0
votes
1answer
289 views

Understanding Charles's Law

Charles's law states that, The volume of a given mass of an ideal gas is directly proportional to its temperature on the absolute temperature scale (in Kelvin) if pressure and the amount of gas ...
-1
votes
1answer
456 views

Costant volume gas thermometer [closed]

I have two constant volume gas thermometers, one with an ideal gas $pv=RT$ and the other following the Van der Waals equation $(p+\frac{a}{v^2})(v-b)=RT$. They are calibrated using the freezing point ...
1
vote
0answers
163 views

ideal gas law modelization in a vacuum chamber

I am trying to model a pressure sensor in COMSOL. The basic work is that there is current flowing inside it, if the pressure of the gas around it drops down, the temperature goes down as well (ideal ...
1
vote
3answers
2k views

Air pressure in balloon

I have to calculate the air pressure inside of an hot air balloon. After some searching I found out that I can use the ideal gas law: PV = nRT (from Wikipedia) So to get the pressure in the balloon I ...
3
votes
2answers
609 views

What are the units of these virial coefficients?

I'm reading some papers for calculating the vapor pressure of alkali metals as a function of temperature, and I've come across some familiar-looking virial expansions, but when I tried to work out the ...
0
votes
2answers
497 views

Temperature change inside pressure chamber

Let's say there is a pressure chamber with some sort of sample / specimen (e.g. protein crystal) in it. Now I apply a certain amount of gas pressure, e.g. 10 or 20 atm. Let's say I use xenon as a gas. ...
0
votes
1answer
74 views

In $PdV$, what is the value of $P$? $P_1$ or $P_2$?

Say I have an ideal gas that has a known $P_1$, $P_2$, $T_1$, and $T_2$ undergoing a reversible adiabatic process. I want to find the work done so I must use $PV = RT$ to get the change in $V$, so ...
0
votes
1answer
250 views

Ideal gas temperature and pressure gradients?

Consider an ideal gas in a $d\times d\times L$ box with the $L$ dimension in the $x$-direction. Suppose that the opposite $d\times d$ sides of the box are held at temperatures $T_1$ and $T_2$ with ...
4
votes
2answers
365 views

Ideal gas concentration under temperature gradient

I'm trying to calculate the concentration of an ideal gas in an adiabatic container as a function of position where the top and bottom plates of the container are fixed at temperatures $T_1$ and ...
3
votes
2answers
779 views

With ideal gases, varying quantity of moles, and having a constant volume how do temperature and pressure behave?

I'm trying to build a simulation of gases so I ended-up trying to use law of ideal gases ($PV = nRT$). In my scenario: volume is constant ($V=1\rm{m}^3$); a known quantity of moles are being added ...
3
votes
3answers
650 views

Understanding mathematically the free expansion process of an ideal gas

I'm trying to understand mathematically that for the free expansion of an ideal gas the internal energy $E$ just depends on temperature $T$ and not volume $V$. In the free expansion process the ...
0
votes
0answers
93 views

Using thermodynamics and Kinematics together to solve a parachuter problem?

I need to find a parachutist's displacement after a given height (nearly 37000m) and at a given latitude. I have his mass, area, parachute area, drop height, parachute deployment height, data about ...
1
vote
1answer
94 views

Problem evaluating moles in a an isochor transformation

I have a problem with an isochor transformation. Me and my group of study made an experiment that want to check Gay-Lussac’s law. We registered the equilibrium states and fitted the $P = nRT / V$, ...
1
vote
1answer
110 views

Thermodynamic process when nebula is heated

The basic thermodynamics problem is stated as follows. The nebula contains a very tenuous gas of a given number density (atoms per volume) that is being heated to a given temperature. What is the ...