Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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12 views

Heat equation with Neumann boundary conditions

I would like to explore some ideas with different geometries exchaging energy mainly by radiation. This means solving Laplace equation for the steady state. However the boundary conditions are always ...
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0answers
43 views

Thermodynamics - Volume expansion [closed]

A glass flask (not completely filled) contains a volume of mercury $V_m$ at a certain temperature $T_0$. If the maximum volume that the glass flask can hold at this temperature is $V_g$, what should ...
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3answers
519 views

Best way to chill a cup of coffee with cold water and 5 minutes [duplicate]

Initial data 1 x 3/4 full cup of hot coffee / tea / your favorite morning beverage cold water 5 minutes Considering that it's starting to get hot outside, and we all want to drink reasonably cold ...
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3answers
118 views

What is the deal with heat capacity?

For some time now I've been confused about heat capacity. The way I understand it, if I put in an amount of heat energy into the system, $dQ$, its temperature will change by $CdT$. But now, ...
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0answers
57 views

Chemical Equilibrium - Why does changing the temperature shift the equilibrium? [migrated]

I know that raising the temperature in a reversible chemical reaction causes the equilibrium to shift to the endothermic side. I know that $\Delta G = \Delta H - T \Delta S$ but I don't know how to ...
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1answer
26 views

Gas in movement

Suppose I have a gas contained in a solid box and I drop it from a certain height, is the temperature of the gas going to change because of the velocity that it acquires during the fall? If so, by how ...
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2answers
51 views

on Brownian motors

From this review on Brownian motors, there is such a statement without detailed explanation: (I think this statement is general enough so that one does not need to read the article) "Apart from ...
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2answers
40 views

A box with cooler and heater on opposite faces

Suppose there's a box with one face cold, and the opposite face hot. So when the air molecules hit the cooler face, it will transfer its momentum and energy to the wall, bouncing back with less ...
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3answers
68 views

Office Air Conditioning and Open Windows

Today is nice and sunny and the air con is on in the office. It's a fairly large office seating 20 people, 30x30x15ft with 20 small windows and a single large AC unit on the back wall where there are ...
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0answers
25 views

Is there a source that provides data for the temperature coefficient of resistivity at different temperatures?

I'm looking for a source where I can find the temperature coefficient of resistivity at different temperatures for pure metals. Tables are everywhere for 20$\,^{\circ}$C, but I'm having difficulties ...
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1answer
48 views

Fluids in thermodynamic equlibrium

I am reading about the Euler Equations of Fluid dynamics from Leveque's numerical methods for conservation laws. After introducing the mass, momentum and energy equations, some thermodynamic ...
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2answers
85 views

Is there a general form for heat capacity?

Can you derive a general form (not keeping either volume or pressure constant) for heat capacity from the first law of thermodynamics? Do you have to make any assumptions to do so? It sounds trival, ...
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1answer
69 views

Gibbs Paradox - why should the change in entropy be zero?

The Gibbs paradox deals with the fact that for an ideal gas with $N$ molecules in a volume $V$ seperated by a diaphragm into two subvolumes $V_1,V_2$ with $N_1,N_2$ particles in each subvolume, ...
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0answers
32 views

What's the domain of usability of these two expressions for entropy

$$dS=\frac{dQ}{T}$$ $$S=k\ln \Omega$$ What assumptions are being made about the system/process that allow for using those expressions?
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0answers
31 views

Thermal physics question for calculating temperature [closed]

If iron rod and copper rod are heated up to 400 C° and 500 C° respectively, and their ends are joined, what will be the temperature of the resulting system? Would would be the formula to solve this?
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0answers
24 views

Thermal Penetration Depth discrepancy

I've been working on a project that involves thermoacoustics, and one of the commonly-used values in this field is know as the thermal penetration depth. It is calculated as follows: $$\delta_k = ...
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1answer
38 views

Deriving work done on a solid

For a homework problem, I've been asked to show that the work done by increasing pressure isothermally on a solid of mass m is: $$W \approx -\frac{m\bar{\kappa}}{2\bar{\rho}}(P_f^2 - P_i^2)$$ where ...
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3answers
143 views

Surface energy as thermodynamic potential

Consider free energy of sharp interface $\Gamma$ $$ \int_\Gamma \sigma\;\mathrm{d}S $$ or also free energy of diffuse interface of characteristic width $\epsilon$ given by Cahn-Hilliard/Allen-Cahn ...
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1answer
88 views

What exactly heats a pool of water on a sunny day

On a sunny day an outdoor swimming pool will heat up fairly quickly. My question is, what is the exact mechanism for this and can we put numerical figures on it? Given that water is clear and ...
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0answers
26 views

How to work with photolithography to develop a microprocessor? [closed]

I am trying to learn this but it's too much. How does photolithography play a part in electrical micro-circuit design for a microprocessor? Also, how do components like diodes and transistors shrink ...
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0answers
33 views

How can I derive an expression for $du$ as function of $T$ and $P$? [closed]

I have to start with an expression of $dq$ and the gas may be seen as ideal.
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1answer
29 views

Which is more efficient cooling? Cooling yourself from cold water from Referigerator or Airconditioning? [closed]

Case a: You chill a glass of water in refrigerator to a certain temperature and drink it.. it lowers your body temperature by X degrees. Case b: You switch on the a/c for a certain duration.. it ...
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1answer
58 views

Forms of the first law of thermodynamics

The first law of thermodynamics states that $$\frac{D}{Dt}(K+U)=W+H,$$ where K is the kinetic energy, U is the internal energy, W is the power of the external forces and H is the heat flux. I have ...
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0answers
51 views

heat conductivity experiment [closed]

We did an experiment at University which I feel very confused about: The image should explain it well. One end of a metal bar insulated in a cover is left in touch with a $160\,\mathrm{W}$ heat ...
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0answers
51 views

Why does the water diffuse at right angles in my coffee? [closed]

I purchase an espresso shot each morning at my local coffee shop, and I usually water it down slightly to take the edge off as well as to cool it. Recently, I have noticed that when I pour the cold ...
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2answers
111 views

How to reconcile the two definitions of work? (mechanical and thermodynamical)

When studying classical mechanics, work is defined as: $W_M=\int F_{tot} \hspace{2 mm} dx$. However, for thermodynamics, work is defined as: $W_T=\int -F_{ext} \hspace{2 mm} dx$. I'm having trouble ...
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1answer
40 views

How to homegrow large, momocrystalline water ice crystals

This is a follow up to this question:Can one get clear ice crystals from a dirty suspension?. How could one grow a large - meaning visible with the naked eye - water ice crstal with common household ...
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5answers
217 views

Having a problem about entropy, thermodynamics

I am a high school student. So, while studying about thermodynamics, I got a little curious about entropy. As I read, entropy is the rate of change of chaos. So, if the entropy change of a system is ...
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2answers
68 views

Can a hybrid vehicle ever be more efficient than a hydrocarbon-only vehicle built with the same parts?

Based on the laws of thermodynamics, shouldn't it be theoretically impossible for a non plug-in hybrid vehicle to ever be more fuel-efficient than a vehicle that connects the same engine directly to ...
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1answer
23 views

heat spread from hot coil: diffusion, radiation?

When modeling the heat spread from a hot object through a vacuum (or a gas), what is the dominant physical process for heat energy transportation? Thermal diffusion, thermal radiation, a mix of the ...
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1answer
31 views

Mass fraction of fuel on a fuel droplet surface

Concerning combustion of fuel droplets: Why is the mass fraction of fuel on a fuel droplet surface slightly less than one? It is known that the temperature is below the boiling point at the fuel ...
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1answer
34 views

Newton's law of cooling: changing temperature of environment

A metal ball having temperature of $80^\circ C$ is placed into $m$ grams of water at $0^\circ C$. After ten minutes, it was found that the temperature of ball and water are $60^\circ C$ and ...
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1answer
44 views

Function for heating of a planet by its star

I'm looking for an algorithmic model which will gives rough estimate of the average temperature of a planet's atmosphere (good enough to say whether there will be liquid water anywhere, or if metals ...
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1answer
86 views

How does the boiling time depend on the number of eggs

My nephew showed me an exercise from his school-textbook about boiling eggs. Here is the exercise (translated from german): To make one hard-boiled egg in a pot of water one has to put it for 8 ...
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1answer
116 views

Clear up confusion about the meaning of entropy

So I though, and was told, that entropy is the amount of disorder in a system. Specifically the example of heat flow and it flows to maximize entropy. To me this seemed odd. This seemed more ordered ...
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3answers
54 views

Consistent application of Microscopic evolution with the definition of Macrostates?

How does one use the concept of microstate evolution and definition of macrostate in a consistent manner. As my understanding goes the thermodynamic concepts are defined in equilibrium. How does one ...
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1answer
81 views

Dry Ice in Liquid States [closed]

If I melt the dry ice in a pool. I am thinking that Can I have bath without getting wet by melted dry ice?
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1answer
20 views

Solid in Liquid Heat Transfer

If there is a solid immersed in a large (but finite) pool of water, where the solid has temperature $T_s$ and the water has temperature $T_w$, with $T_w>T_s$, how can I calculate $T_s(t)$ and ...
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1answer
35 views

Do metals generally lose more heat by convection than non-metals?

I've been experimenting with radiative cooling lately and in my mind convection is always an enemy (especially forced convection since the modules are outdoors). Looking at Newton's law of cooling, ...
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0answers
23 views

Superconducting solenoid [closed]

I'm trying to solve the following exercise: A superconducting solenoid made of Ta is cooled by liquid Helium. The solenoid is made of a thin wire (diameter 1mm). The diameter of the solenoid is 3 cm, ...
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1answer
46 views

Second law of thermodynamics

I think this is a simple question. If I have that $E(L)=\tau L$ and we are told that $\tau=BTL$ would this mean that $E=BTL^2$ implies $dE=(2BTL)dL$ or should I sub $\tau$ straight into the second law ...
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2answers
64 views

Does fire create air resistance?

Does fire create air resistance/drag? So, for example, would it be harder to swing a flaming sword than a normal one?
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2answers
63 views

Minimization of energy and maximization of entropy

Are maximization of entropy and minimization of energy equivalent? Or are they contrary? Why should the thermodynamic potentials such as $G$, $A$, etc, be minimum at equilibrium? I am confused. ...
2
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2answers
59 views

Why increase pressure to go from liquid to steam?

Assume the following phase diagram $T-H$ of water At a nuclear engineering course, I was told that in order to increase the performance of a pressurized water reactor, one has to increase the ...
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1answer
35 views

Adding heat to a system doesn't equal the work done by gas?

So, I answered a physics question for a class that goes as follows: A gas in a cylinder is kept at a constant pressure of $250000\: \mathrm{Pa}$ while $300\: \mathrm{kJ}$ of heat are added to it, ...
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1answer
39 views

How long does the 2nd pot of water take to boil right after the 1st one finishes?

Say I have a pot of water that boils in 20 minutes, at whatever temperature. If I leave the fire on, take the pot off, pour the hot water into a container, refill the pot with tap water and put it ...
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0answers
51 views

Maths manipulations for thermodynamics introduction

I study thermodynamics and statistical physics introduction. I see statistical physics is considered by states. $ \Omega \left ( E \right ) $ below is the number of states whose energy lies between ...
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28 views

Constant Pressure lines in evaporation diagram

Assume that there is the following $T-H$ phase diagram with the constant pressure lines. Which is greater preasure? The preasure drops as we move to lower temperatures (i.e. from top to bottom)? ...
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1answer
45 views

Finding cooling time using an impulse of heat energy

A chip has a thermal resistance of 0.007 K/J s and thermal capacitance of 1.6 J/K. You give it an impulse of heat equal to 100 J. How long does it take for the chip to cool to within 10% of the ...
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42 views

Calculate heat loss of aquifer with unknown shape

I am trying to calculate the heat loss of an aquifer. An aquifer is basically a hot-cold storage $80\: \mathrm{meters}$ under the ground. It is an open system and utilizes groundwater. By pumping for ...

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