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Can a distribution with sharper energy maximum than the exp-function give an equivalent theory?

Because for many particles the distribution $\varrho\sim\mathrm e^{-\beta\ H}$ has an extremely sharp maximum, the expectation values of the canonical ensemble agrees with that of the microcanonical ...
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What is the minimal set of expectation values I need in a statistical model?

At least if $\vec v$ is really only a one dimensional parameter, measuring all the moments $\langle v^n \rangle_f$ seems to give me all the information to compute $\langle A \rangle_f$ with $A(v)$ ...