The study of large systems through coarse graining microscopic descriptions, providing a more detailed understanding of thermodynamics.

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2answers
114 views

What are correlated magnetic moments?

My book has the following sentence and I don't understand what correlation or lack of correlation means: At high temperature the magnetic moments of adjacent atoms are uncorrelated (to maximize ...
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3answers
127 views

Why is Entropy's Definition Useful?

I have somewhat of an understanding for other physical quantities, but as far as entropy goes I only know it to be "disorder". Why is the change in entropy formula an appropriate/useful definition, ...
4
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1answer
125 views

Counting Problems in Physics

What are some classic counting problems in physics? I'm trying to think of interesting examples to give in a math class on the matter, and I feel as if physics should have some ones to offer.
1
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1answer
37 views

Proof of Liouville's theorem: Relation between phase space volume and probability distribution function

I understand the proof of Liouville's theorem to the point where we conclude that Hamiltonian flow in phase-space is volume preserving as we flow in the phase space. Meaning the total derivative of ...
2
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2answers
222 views

Phase volume contraction in dissipative systems

I am confused about phase-volume contraction in dissipative systems. Please help me catch the flaw in my understanding. From a macroscopic point of view I understand that a dynamic system tends to go ...
1
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2answers
31 views

Correlation in electron gas

In the textbooks that I read (namely Ashcroft/Mermin , Marder, etc.) it seems that a distinction is made between the correlations in electron gas and a Couloumb interaction between the electrons. What ...
5
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1answer
57 views

Is there any model in statistical physics which has the ratio of specific heat exponent to correlation length exponent, $\alpha/\nu \approx 2.44$?

I am simulating a disordered ising-like model in 2d whose phase transition is expected to be continuous, whose universality class is as yet unknown. By plotting the Specific heat scaling function, ...
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1answer
22 views

Thomas - Fermi screening

I read in Ashcroft & Mermin's Solid State text that for the Thomas-Fermi approximation to be applicable, the external potential needs to be "slowly varying," What does it mean for a function (in ...
2
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3answers
73 views

Is thermodynamic free energy and potential energy the same thing?

The equation for free energy $F$ and potential energy $E_{pot}$ are: $$ F=U-TS \\ E_{pot} = E_{tot} -E_{kin} $$ But the temperature $T$ is proportional to the average kinetic energy of a system. So ...
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41 views
+100

Equivalence of Mori's formalism and Zwanzig's heat bath procedure

In [1], Zwanzig introduced the derivation of a generalised Langevin equation for a simple model Hamilton function ...
4
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3answers
186 views

Mathematical proof of the Second Law of Thermodynamics

Is there some book or paper that formalizes statistical mechanics, like some people have done with relativity, and proves the second law of thermodynamics from more foundational axioms?
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0answers
52 views

Ergodic Hypothesis; canonical ensemble

I'm currently studying for an exam in thermodynamics/classic statistical mechanics and 2 things came up which are confusing me. First the ergodic hypothesis states that it is equal to take the mean ...
3
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1answer
44 views

Evaluating low-temperature dependence of the BCS gap function

How does one go about evaluating the behavior of the BCS gap $ \Delta = \Delta(T) $ for $ T \to 0^+ $ under the weak coupling approximation $ \Delta/\hbar\omega_D \ll 1 $? In Fetter & Walecka, ...
2
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1answer
99 views

Thermodynamics, chaperones : How to model polymer fragmentation

Living polymers are well described by equilibrium statistical physics. Now I would like to consider a case were living polymers undergo fragmentation due to chaperones. I can think of a kinetic ...
2
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0answers
41 views

Statistical Mechanics with Gravity [closed]

What complications arise when examining the statistical mechanics of a system under the influence of gravity? Is it significantly different from the classical treatment of statistical mechanics?
4
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2answers
332 views

Renormalization Group and Ising with d=1 and D=1

I have a question about the results of RG on Ising model. I know it's possible to obtain two couple of relations $K'(K)$, $q(K')$ $K(K')$, $q(K)$ between the coupling costants. My problem arise ...
0
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1answer
35 views

Canonical ensemble, energy, heat bath

I am studying through the book Thermodynamics and Statistical Mechanics by Walter Greiner and I’ve got a couple of doubts when I was reading about the classical ensembles, specially the Canonical ...
0
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1answer
23 views

Microscopic definition/expression of/for the heat current

Often I see the following microscopic definition/expression of/for a heat current due to an external field $$ {\bf j}_Q = 2 \int \frac{\text{d}{\bf k}}{(2\pi)^3} \frac{\hbar {\bf k}}{m} ...
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3answers
200 views

Distinguishable, Indistinguishable Paramagnetic Ideal Gas

In the canonical ensemble, the partition function for an ideal gas is given by: $$\frac{Z}{N!}$$ The factor $N!$ accounts for the indistinguishability of the particles of the ideal gas. What ...
3
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1answer
42 views

Problems with units of entropy in statistical thermodynamics

The statistical thermodynamics definition of entropy: $S = kN \ln (W)$ troubles me a lot with the problem of dimenstions. where $S$ is entropy; $k$, the Boltzmann constant; $N$ the number of particles ...
0
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1answer
114 views

General way to model baths? Harmonic Oscillators valid?

I am trying to model an open system interaction without making strong assumptions on coupling strength or temperature. In general i understand that open systems are modeled by a Lindbladian, but as ...
3
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3answers
157 views

Existence of negative temperatures and the definition of entropy

How negative temperatures can be possible has been treated on StackExchange before (several times in fact), but in light of some recent academic discussion, most of these answers seem to be possibly ...
2
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0answers
33 views

Why does decay of correlations imply absence of order?

In a few articles I have read, a two-point correlation function $\langle g(x)g(y) \rangle$ is shown to decay with increasing distance of $x$ and $y$, and this is then taken to imply an absence of the ...
2
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1answer
125 views

Reaction coordinate as a function of atomic positions

I'm going over some (molecular dynamics) related literature - specifically the derivation of the Weighted Histogram Analysis Method (WHAM). As a quick backdrop WHAM is a method for stitching ...
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0answers
24 views

Methods for quantifying a network of coupled oscillators

I usually am more on the statistics part of things, so pardon my misuse of the terminology. I am simulating a network of non-pulse coupled non-linear oscillators ( I am not sure what the correct term ...
2
votes
1answer
40 views

Numerical Ising Model: Swendsen–Wang algorithm, Percolationtheory?

When you look at the original paper of Swendsen and Wang in 1987: "Nonuniversal critical dynamics in Monte Carlo simulations" it is somewhat mentioned that the proposed algorithm uses percolation ...
0
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1answer
148 views

Virial Theorem and the Energy in a Gas

I clearly am interpreting the Virial Theorem incorrectly, but I don't know how. In dipole gases, the molecules can exhibit five kinetic modes, while they can only experience 2 potential modes. Doesn't ...
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0answers
28 views

Wolff vs Swendsen Wang Algorithm

Following the orginal paper of Swendsen Wang, their dynamical critical exponent $z$ is about $z=0.35$, whereas the Wolff Algorithm seems to have $z=1.19$. When I calculate the Correlation time though, ...
4
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5answers
1k views

Second law of Thermodynamics: Why is it only “almost” always true that entropy is non-decreasing? [duplicate]

Wikipedia - Second law of thermodynamics: ...the entropy of any closed system not in thermal equilibrium almost always increases. I understand that the second law of thermodynamics is based on ...
30
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4answers
943 views

How exact is the analogy between statistical mechanics and quantum field theory?

Famously, the path integral of quantum field theory is related to the partition function of statistical mechanics via a Wick rotation and there is therefore a formal analogy between the two. I have a ...
2
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1answer
85 views

Lennard-Jones induced pseudo-molecules

It can be shown that the Lennard-Jones potential - which describes the interaction between particles in non-ideal gases - gives rise to pseudo-molecules: after a triple "collision" of three ...
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0answers
54 views

Diamagnetism of a degenerate electron gas for weak fields

In the book "Statistical Physics, Part I ($3^{{\rm rd}}$ edition)" by Landau and Lifshitz, at $\S59$ when he treats the diamagnetic part of the magnetisation of a degenerate electron gas for weak ...
4
votes
1answer
144 views

Semi-conductors

Suppose there is a semiconductor with Fermi energy $E_f$ and that there are $N$ bound electron states. I'd like to know why the mean number of excited electrons takes the form $$\bar n={N\over ...
3
votes
3answers
127 views

In what limit do we *really* get Maxwell-Boltzmann statistics from Bose-Einstein and Fermi-Dirac?

Fermi-Dirac and Bose-Einstein energy occupation number $n(\epsilon)$ in natural units ($[T]=[\epsilon]$) read $$n(\epsilon) = \frac{D(\epsilon)}{e^{(\epsilon-\mu)/T}\pm 1},$$ where $D(\epsilon)$ is ...
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2answers
266 views

Fermi-Dirac Statistics

In Fermi-Dirac statistics the probability of being in a certain energy state is $$f(E) = \left[1 + \exp\left(\frac{E-E_F}{k T}\right)\right]^{-1}$$ In the area that I'm looking at the texts always ...
4
votes
1answer
158 views

What's the most fundamental definition of temperature?

What's the most fundamental definition of temperature? Is it the definition concern about average energy, number of micro states, or what? By "fundamental", I mean "to be applied" in such general ...
13
votes
1answer
276 views

How is the logarithmic correction to the entropy of a non extremal black hole derived?

I`ve just read, that for non extremal black holes, there exists a logarithmic (and other) correction(s) to the well known term proportional to the area of the horizon such that $S = \frac{A}{4G} + K ...
4
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0answers
77 views

Chandrasekhar Limit [closed]

A white dwarf is essentially a degenerate electron gas, in which pressure of degenerate electrons supports gravitational pressure. As a simplified model of such an object, consider a spherical star of ...
0
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1answer
41 views

Statistical Mech Problem

i need to derive a formula for the photon gas correlation function $\left\langle\partial n_i\partial n_j\right\rangle $ where $\partial n_i=n_i -\left \langle n_i \right \rangle$ whilst solving i ...
2
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1answer
30 views

What's the critical temperature of the XY model on a triangular lattice

I've been looking deeply into many bibliographic references without finding the answer. I would be interested in knowing the numerical value of the critical 2d XY spin model on triangular lattice. ...
3
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0answers
39 views

Is there a general H-theorem?

In statistical mechanics, Boltzmann showed that for dilute gases the H-function increases. I remember from a lecture that there is no general H-theorem, e.g. for non-dilute gases or in the quantum ...
0
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1answer
24 views

Ideal gas and inelastic collisions

Why is it necessary that all inter-molecular collisions in an ideal gas be elastic? My understanding is that a gas behaves ideally so long as the potential energy arising from inter-molecular ...
5
votes
2answers
187 views

Ising model observables

Is there a formula or equation relating $\langle E\rangle$ and $\langle M\rangle$ (average spin per site) and $\langle E^2\rangle$ to temperature $T$ for the square lattice Ising model at zero ...
2
votes
1answer
128 views

Does the Bohr van Leeuwen Theorem also apply to ferromagnetism?

I know that the Bohr-van Leeuwen theorem shows that there could be not consistent pure classical explanation of dia- and paramagnetism. Does the same theorem also rule out a consistent classical ...
1
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1answer
49 views

Derivation of Landau diamagnetism

In deriving the magnetic susceptibility of free electrons, we need to calculate $$\chi = \left( \frac{\partial M}{\partial H} \right)_N = - \left( \frac{\partial^2 F}{\partial H^2} \right)_N.$$ ...
4
votes
3answers
302 views

What are the differences between indistinguishable and identical?

What is the difference between indistinguishable particles and identical particles?
3
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0answers
46 views

Critical temperature difference between Ising and XY model

The following formula gives the critical coupling (more precisely the ratio of the spin-spin coupling over the temperature) for $O(n)$ models on a triangular lattice: ...
1
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2answers
213 views

Calculating the change in entropy in a melting process

I have a homework question that I'm completely stumped on and need help solving it. I have a $50\, \mathrm{g}$ ice cube at $-15\, \mathrm{C}$ that is in a container of $200\, \mathrm{g}$ of water at ...
2
votes
2answers
57 views

Modeling a list with a tunable degree of disorder/shuffling

Imagine we have a list of ordered numbers $L = (1, 2,\dots, N)$. I want to add an arbitrary amount of "disorder" to that list. For instance: Adding a little bit of disorder would permute a few ...
4
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3answers
577 views

Chemical potential of a Bose gas

In my course, there is this fact : In a Bose gas, the chemical potential $\mu$ must always be lower than the smaller level of energy $\epsilon_0$. I find this strange, because if we put a Bose ...