The study of large systems through coarse graining microscopic descriptions, providing a more detailed understanding of thermodynamics.

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59 views

How to prove the Bose enhancement factor $(1+f)$ and the Pauli blocking factor $(1-f)$ in Boltzmann equation?

For the collision integral in the Boltzmann equation for particles obeying different statistic, the factor is 1 for classical particles , 1-f for fermions, 1+f for Boson. While why it's exactly this ...
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17 views

Physical meaning of RG transformation

When we do RG transformation in Statistical mechanics we eliminate unnecessary degrees of freedom and it leads us to the fixed point. How can I visualize it physically?
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65 views

Langevin equation

A molecule consists of two atoms whose centers are located at $\mathbf{r}_1$ and $\mathbf{r}_2$ respectively. The atoms are connected by a bond that can be approximated by a harmonic spring, so that ...
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2answers
124 views

Difference between heat and work

According to the Kinetic Theory of Matter, temperature is nothing but a measure of the kinetic energy of matter. My textbook says that the change in internal energy of a system is the heat gained plus ...
2
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1answer
83 views

error propagation and collision in ideal gas

When dealing with gas, a statistical approach is needed because For N particles, you have to solve 6N equations which cant be done analytically. To know our time step for numerical solving, you can ...
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30 views

Partial derivative of energy in the grand canonical ensemble

I am struggling with basics in here: I know that $U=U(N,V,T)$ and $z=z(N,V,T)$ so that $N=N(z,V,T)$. Now, I want to do partial differentiation using chain rule involving three variables so that I ...
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16 views

Free bosons with an attractive/repulsive defect

Consider a system of non-interacting bosons hopping in a qubic lattice in 2D or 3D. A single site of the lattice is an attractive/repulsive defect. Formally, let $H=-t\sum_{<i,j>}(a_i^\dagger ...
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28 views

How to derive the Bhatnagar-Gross-Krook collision integral from Boltzmann one?

Let's have Boltzmann collision integral: $$ I_{coll} =\int d \sigma d^{3}\mathbf p_{1}(ff_{1} - f{'}f{'}_{1})|\mathbf v_{rel}|.\tag{1}\label{1} $$ How to transform $\eqref{1}$ to BGK collision ...
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1answer
29 views

Why are large scale structures isotropic in the Ising model?

I have at least a qualitative understanding of why the critical state of the Ising model is scale invariant, by arguments to do with renormalisation, which I understand only very roughly. However, in ...
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175 views

Fluctuations of an interface with hammock potential

This question is related to that one. I ask it here since comments are too short for the extended discussion that was going on there. I am interested in a very simple interface model. To each ...
4
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1answer
257 views

Scaling with the Ising Model

I am stuck with one formula in the CFT book by Di Francesco and al. Chapter 3. Equation 3.46 third step, for those who don't have the book, he integrates out degrees of freedom from the Ising Model by ...
3
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2answers
81 views

What materials are used in non thermal plasma?

While reading about non-thermal plasmas, I came across their ionization potentials(~1%), and other capabilities, such as their non Maxwellian energy distributions. At what temperatures, and pressures ...
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24 views

How is energy transferred in Joules law of heating?

Joule's law of heating states that an accelerated electron loses its energy, which is then converted into heat energy, by colliding with vibrating atom i.e ions in their lattice site. but we know atom ...
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3answers
250 views

Distinguishable, Indistinguishable Paramagnetic Ideal Gas

In the canonical ensemble, the partition function for an ideal gas is given by: $$\frac{Z}{N!}$$ The factor $N!$ accounts for the indistinguishability of the particles of the ideal gas. What ...
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4answers
226 views

Is thermodynamic free energy and potential energy the same thing?

The equation for free energy $F$ and potential energy $E_{pot}$ are: $$ F=U-TS \\ E_{pot} = E_{tot} -E_{kin} $$ But the temperature $T$ is proportional to the average kinetic energy of a system. So ...
2
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1answer
117 views

H-theorem and Boltzmann equation applied to Boltzmann distribution

Using the Boltzmann equation: $$ \frac{dH}{dt} = \int_0^{\infty} dr \int_0^{\infty} ds W(r,s)[p_r - p_s][\ln{p_r} - \ln{p_s}],$$ and assuming $p_r = e^{-\beta r}$, the equation looks like $$ ...
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3answers
282 views

In what limit do we *really* get Maxwell-Boltzmann statistics from Bose-Einstein and Fermi-Dirac?

Fermi-Dirac and Bose-Einstein energy occupation number $n(\epsilon)$ in natural units ($[T]=[\epsilon]$) read $$n(\epsilon) = \frac{D(\epsilon)}{e^{(\epsilon-\mu)/T}\pm 1},$$ where $D(\epsilon)$ is ...
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2answers
330 views

Fermi-Dirac Statistics

In Fermi-Dirac statistics the probability of being in a certain energy state is $$f(E) = \left[1 + \exp\left(\frac{E-E_F}{k T}\right)\right]^{-1}$$ In the area that I'm looking at the texts always ...
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1answer
54 views

Ising model 2-dimensional - ground state configuration

I have to prove something about the 2-dimensional ising model. The problem is the following: Prove that every nearest-neighbour and next-nearest-neighbour interaction on the square lattice ...
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1answer
37 views

Canonical Distribution (Partition Function)

For the canonical distribution $$ w_{n}=e^{(F-E_{n})/T}, $$ is the sum $$ Z=\sum_{n}e^{E_{n}/T} $$ a sum over energies or a sum over states? Perhaps this is a silly question, but Landau and Lifshitz ...
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1answer
55 views

Spontaneity / Free Energy of Non-Isothermal Process

I'm trying to determine a lower bound for the work input necessary to make an entropy-reducing process "spontaneous" in the sense that the 2nd law is not violated. For a constant temperature and ...
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1answer
26 views

Simulating Phase Space Evolution

I am interested in modeling the time evolution of phase-space $\rho(\vec{q},\vec{p},t)$. I have attempted to use Liouville's theorem $\partial_t\rho=-\sum_{i=1}^{3}(\partial_{q_i}\rho)\dot ...
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0answers
31 views

Applying Statistical Mechanics to Formulate Corrosion (Rusting)

I wanted to try and take my current knowledge of statistical mechanics (first quarter undergraduate course completed, beginning researcher in far from equilibrium statistical mechanics, basic ...
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19 views

How to find Entropy of system in terms of Magnetic Field and Temperature

I'm studying for final exams and I have a question about how to find the entropy of a particular system. The system is a lattice of paramagnetic atoms fixed to the lattice sites, with an external ...
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1answer
25 views
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1answer
31 views

Periodic ground state 1-dim ising model

Good evening! I'm at the beginning of my study about the Ising model and it has been proposed to me this problem: Find all periodic ground-state configuration for the following one-dimensional Ising ...
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29 views

How can one approximate integral def. of Z by the max value of the integrand?

I am taking a course in statistical physics, and while reviewing my notes from the lectures I came across something that I cannot get my head around. We arrive at an integral expression for the ...
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1answer
36 views

Subtraction In Quadrature?

I have a system of particles (electrons) with an initial RMS energy spread (say "1"). It goes through a section of constant magnetic field (bend magnet) and the electrons radiate. The electrons lose ...
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1answer
190 views

Virial Theorem and the Energy in a Gas

I clearly am interpreting the Virial Theorem incorrectly, but I don't know how. In dipole gases, the molecules can exhibit five kinetic modes, while they can only experience 2 potential modes. Doesn't ...
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1answer
23 views

Change in entropy adiabatic expansion

I think that an adiabatic expansion of a gas should cause the entropy to increase. On the other hand we have for adiabatic processes that $dQ = 0$ and therefore $dS= 0$, which is why I thought that ...
6
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1answer
63 views

Minimum connectivity required for mean field to be a good approximation?

In spin models, it is known that mean field becomes a better approximation as the connectivity increases. My question is: Is there an estimate for the threshold connectivity (as a function of the ...
3
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1answer
76 views

Simple estimation of the critical temperature of water

I'm trying to develop fermi estimation skills and I came up with a question for which I don't even know where to start from. Here goes: Is it possible to estimate the critical temperature (say in ...
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2answers
54 views

From Quantum Mechanics to Statistical Mechanics in a Specific Case

I'd like to know how to get to statistical mechanics from the many-particle Schrodinger equation using a specific example, without using any Hamiltonian mechanics, phase spaces or ensembles, as a ...
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3answers
271 views

Does entropy have a physical meaning?

Entropy is incredibly useful as a mathematical tool. But what does it actually mean? I understand that the Boltzmann entropy is defined by: $$S=k\ln{\Omega}$$ With $\Omega$ being the multiplicity ...
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1answer
41 views

chemical potential in BEC decreases in temperature

For a bose gas we can calculate the average number of particles through $$N = \int_0^\infty \rho(\varepsilon)n(\varepsilon) d\varepsilon$$ where $\rho(\varepsilon)$ is the particle density for energy ...
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3answers
48 views

Change in energy ideal gas

I am supposed to calculate the change in energy upon changing both the temperature from $T_1$ to $T_2$ and the volume from $V_1$ to $V_2$. Now I was wondering whether this solution is correct: We ...
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2answers
66 views

First law of thermodynamics [closed]

In the first law of thermodynamics, we learned that $W$ and $Q$ are path-dependent quantities, but how are $Q$ and $W$ defined? I mean $W = \int_{\gamma} p(s) ds$ would be one possibility, where ...
2
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1answer
62 views

Ising model on lattices with (vertical side length) $\neq$ (horizontal side length)

Consider the Ising model with nearest neighbours interactions on a rectangular lattice $L\times M$. If $L=M$ (2-dimensional square lattice), it is known (e.g. by Peierls argument or Onsager explicit ...
4
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1answer
75 views

Spin version of Maxwell's demon: Where's the energy?

I have confused myself about the following variant of Maxwell's demon and I can't seem to find out where the energy went. Consider this: You have a chain (one dimension) of spins (up/down) with a ...
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4answers
2k views

Exorcism of Maxwell's Demon

I am possessed! Yes, with the thinking that if there is actually a Maxwell's Demon, then it would open the negligible weighted door which would ultimately make the second law invalid. But really can ...
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2answers
74 views

Does QM needs refinement?

Suppose atoms of an ideal gas are represented by non overlapping wave function so that the system can be described classically. As time passes the packets spread. Therefore over a period of time we ...
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0answers
19 views

Volume in NVT ensemble

While solving a problem of ideal gas in canonical ensemble, I got stuck into this one. It may sound silly though- Why $$\int d^{3N}q$$ equals to $V^N$ but not $V^{3N}$
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15 views

Schottky Anomaly - Heat Capacity

I'm having a little bit of a difficulty understanding the origins of the schottky anomaly at low temperatures in the heat capacity of certain materials with restricted energy levels. As I understand, ...
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2answers
373 views

Renormalization Group and Ising with d=1 and D=1

I have a question about the results of RG on Ising model. I know it's possible to obtain two couple of relations $K'(K)$, $q(K')$ $K(K')$, $q(K)$ between the coupling costants. My problem arise ...
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1answer
61 views

Debye Model Density of States In One Dimension

I am trying to obtain the Density of states of the Debye model in one dimension I know the answer I am prepping for an exam and I am a bit stuck: The answer is: $\frac{L}{\pi*c_s}$ where $c_s$ is ...
0
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1answer
45 views

What is the density operator for an isothermal–isobaric ensemble (T,p,N)?

In the microcanonical ensemble $(E,V,N)$, the density operator is $$\hat{\rho}=\frac{\delta(\hat{H}-E\,\hat{I})}{Tr(\delta(\hat{H}-E\,\hat{I}))}$$ Where $\hat{H}$ is the Hamiltonian of the system and ...
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21 views

Independent boson model with an arbitrary finite-dimensional impurity

The independent boson model consists of the following Hamiltonian: $$ H_s = E \sigma^z $$ $$ H_b = \sum_k \omega_k b^{\dagger}_kb_k $$ $$H_{sb} = \sigma^z \sum_k (g_k b_k + g_k^{\ast}b^{\dagger}_k).$$ ...
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3answers
4k views

Is there any proof for the 2nd law of thermodynamics?

Are there any analytical proofs for the 2nd law of thermodynamics? Or is it based entirely on empirical evidence?
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71 views

How to derive the critical temperature for Bose-Einstein condensation of photon?

I found in Nature magazine that photon can have Bose-Einstein condensation. But I have a question how to derive the critical temperature for photon? Because the chemical potential of photon is zero ...
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1answer
72 views

What does Born Green equation signify physically?

What does Born Green equation obtained from YBG hierarchy for the equilibrium particle densities signify? I mean how can you model the equation into a physical problem?I understood the steps involved ...