The study of large systems through coarse graining microscopic descriptions, providing a more detailed understanding of thermodynamics.

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Probability distribution of two particle types system

Suppose that particles of two different species, A and B, can be chosen with probability $p_A$ and $p_B$, respectively. What would be the probability (and distribution) $p(N_A;N)$ that $N_A$ out of ...
2
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1answer
65 views

Statistical count

I am reading the book"Heat and Thermodynamics" by Mark Waldo Zemansky and Richard Dittman. In the chapter "Statistical Mechanics" it says if I have $N_{i}$ distinguishable particles in any of $g_{i}$ ...
2
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1answer
55 views

Is there a known equation for evolution of classical particle probability density?

Suppose we have some very imprecise knowledge of classical particle's coordinates and momentum: what we can only tell is the probability density to find it in some point of phase space. This is ...
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1answer
447 views

Occupied lattice sites, determining number of microstates and energy

A solid consisting of $N$ molecules on a lattice of $N$ sites is isolated from its environment, and has energy $E$. Each molecule is fixed in position and independent of all others. It can be in any ...
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2answers
98 views

What are correlated magnetic moments?

My book has the following sentence and I don't understand what correlation or lack of correlation means: At high temperature the magnetic moments of adjacent atoms are uncorrelated (to maximize ...
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1answer
55 views

Failure of a simple stat mech simulation

so I did a simple simulation that I thought would yield a Boltzmann distribution, but it failed to, and I was wondering if anyone has insight into why it failed. Ok, so I had a simple discrete system ...
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0answers
32 views

Is it possible to define a notion of temperature in a microcanonical ensemble?

I am thinking of a mircrocanonical ensemble as a finite system for which the number of particles, volume and the total energy is fixed. Is there a more refined view of this? Can I think of ...
2
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1answer
59 views

RMS Free Path vs Mean Free Path

I am trying to determine the mathematical difference between mean free path and root-mean-square free path. For an ideal gas, the relaxation time is $$\tau=\frac{1}{\sqrt2 \pi nd^2 \bar v}$$ and the ...
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0answers
16 views

What real experimental systems are well-described by Glauber-Ising spins?

I'm hoping for references to actual physical systems in which all or at least most of the following can be simultaneously characterized: the spin flip rate, the temperature, and a relaxation or ...
4
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1answer
71 views

A real gas with gravitation-like interaction

Consider a system (a gas) of point-like particles with a gravitation-like interaction (potential) $V(r) \sim \frac{1}{r}$ between pairs of them. One can rule out statistically that two particles will ...
2
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48 views

Statistical mechanics of a coin toss

I'd like to ask some questions about flipping two coins related to statistical mechanics, e.g. microcanonical distribution, phase space distribution function etc... after I rephrase the coin flipping ...
2
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1answer
83 views

Can I express the heat flow of a fluid in terms of estabilshed characteristics of the velocity distribution?

If $\rho$ is the mass density of a fluid and $A({\bf v})$ is an function of the velocity, which is distributed according to $f({\bf v})$, we have an averaging process $A\mapsto \langle A\rangle:=\int ...
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3answers
172 views

Distinguishable, Indistinguishable Paramagnetic Ideal Gas

In the canonical ensemble, the partition function for an ideal gas is given by: $$\frac{Z}{N!}$$ The factor $N!$ accounts for the indistinguishability of the particles of the ideal gas. What ...
2
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1answer
71 views

Thermodynamics, chaperones : How to model polymer fragmentation

Living polymers are well described by equilibrium statistical physics. Now I would like to consider a case were living polymers undergo fragmentation due to chaperones. I can think of a kinetic ...
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2answers
109 views

Entropy Maximization using undetermined multipliers

This is from Problems in Thermodynamics and Statistical Physics by P.T. Landsberg A system can be in any one of N states. Using the method of undetermined multipliers to show for the maximum ...
27
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4answers
691 views

How exact is the analogy between statistical mechanics and quantum field theory?

Famously, the path integral of quantum field theory is related to the partition function of statistical mechanics via a Wick rotation and there is therefore a formal analogy between the two. I have a ...
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0answers
24 views

phase-space volumes or cells for N particle system

For N non interacting spinless particles in a volume, we have 3N degrees of freedom and we can divide the phase space into 6N dimensional cells of volume h raised to power 3N. And each cell ...
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1answer
122 views

Virial Theorem and the Energy in a Gas

I clearly am interpreting the Virial Theorem incorrectly, but I don't know how. In dipole gases, the molecules can exhibit five kinetic modes, while they can only experience 2 potential modes. Doesn't ...
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1answer
113 views

Reaction coordinate as a function of atomic positions

I'm going over some (molecular dynamics) related literature - specifically the derivation of the Weighted Histogram Analysis Method (WHAM). As a quick backdrop WHAM is a method for stitching ...
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0answers
56 views

Quantum Fourier Transform and Entropy

QFT is a nonlocal unitary transformation and so can generate entanglement in a system. It means a separable pure state can be converted into an entangled pure state. Now since the presence of ...
2
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0answers
30 views

Three-body correlation function in kinetic theory

In Kinetic Theory, one studies the evolution of a system of $N$ particles interacting with each other. We use the notation $\boldsymbol{w}_{i}$ to describe the coordinates in phase-space of each ...
2
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1answer
100 views

Connection between QFT and statistical physics of phase transitions

I have heard that there is a deep connection between QFT (emphasized by its path-integral formulation) and statistical physics of critical systems and phase transitions. I have only a basic course in ...
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1answer
93 views

General way to model baths? Harmonic Oscillators valid?

I am trying to model an open system interaction without making strong assumptions on coupling strength or temperature. In general i understand that open systems are modeled by a Lindbladian, but as ...
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2answers
74 views

Statistical Mechanics - Distribution of Energies

Consider a state space $\mathbb{X}$. The probability density function under a canonical ensemble is given by the Boltzmann distribution $$\pi_{\mathbb{X}}(x)=\frac{e^{-\beta ...
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2answers
35 views

Is there an analogue to the role of vapor in liquids and gases, but for solids and liquids?

It seems common for an ordered phase to have some amount of disorder present. For example, the average moment of a ferromagnet is less than maximum except at T=0 due to the presence of fluctuations. ...
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65 views

Nonequilibrium thermodynamics in a Boltzmann picture

The Boltzman approach to statistical mechanics explains the fact that systems equilibriate by the idea that the equillibrium macrostate is associated with an overwhelming number of microstates, so ...
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2answers
81 views

Non-Equilibrium Statistical Mechanics

Can anybody please explain what is the difference between equilibrium state and steady state, as quoted by book by Degroot and Mazur. Also, does violation of Principle of Detailed Balance means the ...
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Suggestions about these books [duplicate]

Which are the best books for the following( introductory level)? quantum mechanics classical mechanics statistical physics particle physics
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3answers
285 views

Leap from photon gas energy distribution to black body radiation?

I remember considering in class in college, the case of a photon gas trapped in a d-dimensional box as a subject of interest, whose energy distribution, heat capacity, etc. should be calculated. ...
2
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1answer
62 views

Lennard-Jones induced pseudo-molecules

It can be shown that the Lennard-Jones potential - which describes the interaction between particles in non-ideal gases - gives rise to pseudo-molecules: after a triple "collision" of three ...
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4answers
3k views

What are distinguishable and indistinguishable particles in statistical mechanics?

What are distinguishable and indistinguishable particles in statistical mechanics? While learning different distributions in statistical mechanics I came across this doubt; Maxwell-Boltzmann ...
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0answers
30 views

Boltzmann distribution: derivation from canonical distribution

I'm trying to understand the Maxwell-Boltzman Distribution, and in particular the derivation from the boltzman distribution for energy. I have successfully created an incorrect derivation, but I'm not ...
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5answers
98 views

How can point-like particles in an ideal gas reach thermodynamical equilibrium?

Having learned that the particles of an ideal gas must be point-like (for the gas to be ideal) I wonder how they can reach thermodynamical equilibrium (by "partially" exchanging momentum and energy). ...
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3answers
331 views

Mathematical proof of non-negative change of entropy $\Delta S\geq0$

I understand that we can prove that for any process that occurs in an isolated and closed system it must hold that $$\Delta S\geq0$$ via Clausius' theorem. My question is, how can I prove this in a ...
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3answers
3k views

Is there any proof for the 2nd law of thermodynamics?

Are there any analytical proofs for the 2nd law of thermodynamics? Or is it based entirely on empirical evidence?
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1answer
21 views

Can electrons coincidentally flow along a circuit to cause current?

My understanding of circuits which are not supplied an e.m.f. is that the electrons randomly just flow about in random directions, and since there's so many of them, probability dictates that any ...
8
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3answers
591 views

Why must the particles of an ideal gas be point-like?

Why is a gas of elastically colliding hard balls of finite size not ideal? Respectively: Why is it essential that the particles of an ideal gas are point-like? Especially: Which ...
4
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1answer
107 views

Which transformations are canonical?

Which transformations are canonical? Why do canonical transformations preserve the measure of integration in phase space?
4
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1answer
298 views

Renormalization Group and Ising with d=1 and D=1

I have a question about the results of RG on Ising model. I know it's possible to obtain two couple of relations $K'(K)$, $q(K')$ $K(K')$, $q(K)$ between the coupling costants. My problem arise ...
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2answers
85 views

How are degrees of freedom and energy related in classical theory?

How are degrees of freedom and energy related in classical theory? How do we come to know that each quadratic degree of freedom classically contributes a factor of $\frac{k_{B}T}{2}$.
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0answers
19 views

What is Fermi energy and Fermi level? [duplicate]

What is meant by Fermi level and Fermi energy? And what is the difference between the two?
12
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1answer
124 views

Fluctuations of an interface with hammock potential

This question is related to that one. I ask it here since comments are too short for the extended discussion that was going on there. I am interested in a very simple interface model. To each ...
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0answers
49 views

What is conductivity?

I read that if we have spin $\frac{1}{2}$-particle, where a magetic force acts on, then the force is given by a drift speed times a conductivity. This conductivity is determined to be $\frac{kT}{D}$, ...
4
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1answer
101 views

Semi-conductors

Suppose there is a semiconductor with Fermi energy $E_f$ and that there are $N$ bound electron states. I'd like to know why the mean number of excited electrons takes the form $$\bar n={N\over ...
2
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0answers
32 views

Spin drift velocity?

I am currently reading this Phys Rev paper by H C Torrey. In this paper, he derives the Bloch equations with an additional diffusion term. He says that the current density is given by $$\mathbf ...
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2answers
60 views

System in mechanical but not thermal equilibrium

Let's say there are two systems which can interact by a moving wall but cannot exchange heat. Then the system will be in mechanical, but not necessarily in thermal equilibrium. The maximality of ...
3
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2answers
80 views

Why is the Gibbs Free Energy $F-HM$?

With magnetism, the Gibbs Free Energy is $F-HM$, where $F$ is the Helmholtz Free Energy, $H$ is the auxiliary magnetic field, and $M$ is magnetization. Why is this? Normally, in thermodynamics, we ...
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3answers
270 views

What is the relationship between Maxwell–Boltzmann statistics and the grand canonical ensemble?

In the grand canonical ensemble one derives the expectation value $\langle \hat n_r\rangle^{\pm}$ for fermions and bosons of sort $r$: $$ \langle \hat n_r\rangle^{\pm} \ \propto \ ...
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0answers
15 views

Relation between solutions to Yang-Baxter equations, integrability and exact solvability?

Wikipedia mentions that there is an implication: Yang-Baxter solutions yield integrable models, what 1D systems concerns. In arbitrary dimensions, what is the relation, if any, between solutions to ...
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1answer
219 views

Fermi-Dirac Statistics

In Fermi-Dirac statistics the probability of being in a certain energy state is $$f(E) = \left[1 + \exp\left(\frac{E-E_F}{k T}\right)\right]^{-1}$$ In the area that I'm looking at the texts always ...