The study of large systems through coarse graining microscopic descriptions, providing a more detailed understanding of thermodynamics.

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115 views

Why do phase transitions even exist? Why not smooth density change curves?

Why do phase transitions even exist? Why not smooth density change curves? What properties of matter, quantum or otherwise, predicts that matter will undergo phases at different pressures and ...
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1answer
38 views

Liouville's theorem and preservation of topology

What might be a simple proof showing that the time evolution of the phase space volume can't lead to splitting off of the phase space volume? I don't know much about topology and stuff.
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0answers
23 views

What is the fluctuations of the energy of a simple harmonic oscillator? [on hold]

$$\begin{align} \varepsilon&=\frac{\vec{p}^{\,2}}{2m}+\frac{K}{m}\vec{q}^{\,2}\\ \rho(q,p)&=\biggl(\frac{\omega}{2\pi k_BT}\biggr)^3e^{-\frac{\varepsilon}{k_bT}} \end{align}$$ where ...
0
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1answer
24 views

compressibility of cold atoms in optical lattices

The compressibility of cold bosons in an optical lattice is defined as $\kappa = \frac{\partial \langle n\rangle}{\partial \mu}$, where $\langle n\rangle$ is the density and $\mu$ is the chemical ...
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3answers
213 views

Distinguishable, Indistinguishable Paramagnetic Ideal Gas

In the canonical ensemble, the partition function for an ideal gas is given by: $$\frac{Z}{N!}$$ The factor $N!$ accounts for the indistinguishability of the particles of the ideal gas. What ...
3
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1answer
88 views

How does statistical mechanics predict that hot air rises?

Does hot air rise -- from a statistical-mechanical viewpoint Question #6329 asks whether and why hot air rises. The consensus answer is straightforward: - hot air is less dense than cold air - ...
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1answer
35 views

MIcrocanonical and Canonical - The thermodynamic limit

Considering a two level system with energies $ 0 $ and $ \epsilon$, we write out the single particle partition function with ease to be, also N-particle partition function for non-interacting ...
0
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1answer
56 views

Resources on Master Equations

Presently I am reading about "Introduction to dynamical process theory and simulation" which uses the notion of Master Equations to solve Markov process. I am very new to this. Can someone provide me ...
2
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1answer
132 views

Reaction coordinate as a function of atomic positions

I'm going over some (molecular dynamics) related literature - specifically the derivation of the Weighted Histogram Analysis Method (WHAM). As a quick backdrop WHAM is a method for stitching ...
4
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1answer
106 views

Strange definition of microcanonical partition function

I always thought that the microcanonical partition function would measure the number of states that correspond to some fixed energy. Despite, I found in this paper (equation 3.4) that we integrate ...
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5answers
741 views

Is there a classical analog to quantum mechanical tunneling?

In comments to a Phys.SE question, it has been written: 'Tunneling' is perfectly real, even in classical physics. [...] For sufficiently large temperatures this can put the system above a hump in ...
1
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1answer
46 views

How is free energy built into a Metropolis Monte Carlo simulation of an Ising model?

In the Metropolis algorithm, the change in the energy given by the hamiltonian is compared for flipping a spin. This is not the free energy, but for systems above absolute zero you are trying to ...
2
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1answer
56 views

H-theorem and Boltzmann equation applied to Boltzmann distribution

Using the Boltzmann equation: $$ \frac{dH}{dt} = \int_0^{\infty} dr \int_0^{\infty} ds W(r,s)[p_r - p_s][\ln{p_r} - \ln{p_s}]$$ and assuming $p_r = e^{-\beta r}$, the equation looks like $$ ...
0
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1answer
52 views

Helmholtz free energy from a relation for entropy

The Legendre transformation defines the helmholtz free energy (at least according to my lectures) as: $F(T,V,N)=E-TS$ It also says to start with $E(S,V,N)$ and $T=\frac{\partial{E}}{\partial{S}}$ ...
0
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1answer
36 views

How can entropic effects be prevalent at low temperatures?

I read in a book that at low temperature the hydrophobic effect (for example) is entropic but at high temperatures it is enthalpic. I thought that entropy should decrease at very low temperatures. ...
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2answers
49 views

What materials are used in non thermal plasma?

While reading about non-thermal plasmas, I came across their ionization potentials(~1%), and other capabilities, such as their non Maxwellian energy distributions. At what temperatures, and pressures ...
2
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1answer
121 views

${1 \over T} e^{-i/T}$ for Boltzmann-Gibbs distribution

There is a book from Tom Carter on entropy. In the Economics I application (page 111), he ingeniously computes that the distribution of fixed amount of M money over N individual tends to $$p_i = {1 ...
2
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1answer
89 views

Lennard-Jones induced pseudo-molecules

It can be shown that the Lennard-Jones potential - which describes the interaction between particles in non-ideal gases - gives rise to pseudo-molecules: after a triple "collision" of three ...
2
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2answers
138 views

How do you measure numerically the central charge of a system?

Let's say that you are doing some Monte-Carlo simulations of a statistical system on a lattice and you observe scale invariance, meaning that you are at a conformal point. Can you get a numerical ...
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3answers
101 views

Why does the Metropolis algorithm allow changes even for ∆E > 0?

In the Metropolis Monte Carlo algorithm, why can you accept changes even for ∆E > 0 (provided that a random number is less than a given probability ratio, e.g. exp(-β∆E))?
0
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1answer
168 views

Virial Theorem and the Energy in a Gas

I clearly am interpreting the Virial Theorem incorrectly, but I don't know how. In dipole gases, the molecules can exhibit five kinetic modes, while they can only experience 2 potential modes. Doesn't ...
3
votes
1answer
66 views

Definition of entropy in nonequilibrium states

Thermodynamical definition of entropy $$S(p)=-\int p\ln p~dx$$ is defined only on equilibrium system. But why can't we use it for non-equilibrium system? Is there a well-accepted definition for it?
14
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1answer
304 views

How is the logarithmic correction to the entropy of a non extremal black hole derived?

I`ve just read, that for non extremal black holes, there exists a logarithmic (and other) correction(s) to the well known term proportional to the area of the horizon such that $S = \frac{A}{4G} + K ...
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2answers
290 views

Fermi-Dirac Statistics

In Fermi-Dirac statistics the probability of being in a certain energy state is $$f(E) = \left[1 + \exp\left(\frac{E-E_F}{k T}\right)\right]^{-1}$$ In the area that I'm looking at the texts always ...
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1answer
62 views

Question about Metropolis Monte Carlo in the case of equal energies

If configuration A is equal to configuration B in a Metropolis Monte Carlo method, do you still do the attempted update?
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1answer
31 views

Spontaneity / Free Energy of Non-Isothermal Process

I'm trying to determine a lower bound for the work input necessary to make an entropy-reducing process "spontaneous" in the sense that the 2nd law is not violated. For a constant temperature and ...
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1answer
32 views

The BBGKY Hierarchy

The collision term in the Boltzmann equation can be derived from the BBGKY hierarchy. Wikipedia says: In statistical physics, the BBGKY hierarchy [...] is a set of equations describing the ...
15
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1answer
161 views

Fluctuations of an interface with hammock potential

This question is related to that one. I ask it here since comments are too short for the extended discussion that was going on there. I am interested in a very simple interface model. To each ...
1
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1answer
37 views

Statistical mechanics: What is a “microscopic realization” of a system?

What is a "microscopic realization" of a system? The context is statistical mechanics. The microscopic system consists of many atoms (too many to track individually) with an assigned probability ...
3
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2answers
99 views

Statistical mechanics: Meaning of “accessible” in “accessible microstates”

What does "accessibility" mean in statistical mechanics? Is it an equivalent concept to accessibility in mathematical control theory? I'll provide an example: When two systems A and B interact on a ...
2
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2answers
67 views

Modeling a list with a tunable degree of disorder/shuffling

Imagine we have a list of ordered numbers $L = (1, 2,\dots, N)$. I want to add an arbitrary amount of "disorder" to that list. For instance: Adding a little bit of disorder would permute a few ...
6
votes
1answer
48 views

Minimum connectivity required for mean field to be a good approximation?

In spin models, it is known that mean field becomes a better approximation as the connectivity increases. My question is: Is there an estimate for the threshold connectivity (as a function of the ...
0
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1answer
30 views

Basics of osmosis. What about excluded volume?

I may not understand osmosis very well. Let us suppose two compartments filled with water, separated by a semi-permeable membrane. At equilibrium, both levels are equals. Let us introduce now a given ...
0
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1answer
42 views

Which function denotes the energy of thermal motion within a system?

In thermodynamics, the heat $Q$ is defined as a type of energy in transfer, and is not a state function, which function denotes the energy of thermal motion within a system? 1) $TS$, (there is a ...
0
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1answer
62 views

What does the behavior of the pair correlation function look like in the vicinity of the critical point?

What does the g(r) look like near the critical point? I know what the pair correlation function (radial distribution function) should look like for a solid, which has regular packing and therefore ...
3
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3answers
246 views

Axioms behind entropy!

The concept of entropy is very ubiquitous, we learn about its uses starting from Information Theory (Shannon entropy) up to its basic definition in statistical mechanics in terms of number of ...
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0answers
29 views

How do you obtain the fluctuation spectrum of a tubular membrane?

I am reading through a paper. A tubular membrane, submitted to tension $\sigma$ acting as a Lagrange multiplier to conserve area, fluctuates around a cylindrical shape of length L and radius R. ...
2
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1answer
39 views

Can an Ergodic dynamical system approach equilibrium?

An ergodic dynamical system $(\Omega,\phi^t,\mu)$ is such that the time average $\bar{f}$ of every function $f\in L_1(\Omega,\mu)$ equal the space average $\langle f \rangle_\mu$, i.e. the system ...
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1answer
49 views

How to calculate the ground-state energy for the Ising model?

I'm learning about the 2D ferromagnetic Ising model in zero field and trying to verify what I know by calculating the ground-state energy for the state with all 'up' spins in a 3x3 lattice. $$H = ...
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2answers
224 views

Calculating the change in entropy in a melting process

I have a homework question that I'm completely stumped on and need help solving it. I have a $50\, \mathrm{g}$ ice cube at $-15\, \mathrm{C}$ that is in a container of $200\, \mathrm{g}$ of water at ...
0
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0answers
34 views

Entropy of an oscillator in Einstein's solid

This is a homework problem and I need help with it. A solid's (Einstein's model) oscillators are in the first excited state on average. How much entropy does one oscillator have? What I've tried so ...
3
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1answer
96 views

Cluster Expansion vs Cluster Decomposition

Are the cluster expansion (which we encounter in Statistical Physics), and cluster decomposition (in Quantum Field Theory) related to each other? (I have a reason to believe they are)
4
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1answer
62 views

What is an intuitive explantion for the fact that the Maxwell-Boltzmann distribution of energies is independent of mass?

If you take the Maxwell-Boltzmann distribution of velocities (which depends on the mass) and substitute $v=\sqrt{\frac{2E}{m}}$ you get the distribution for the energies, which turns out to be ...
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2answers
53 views

Thomas - Fermi screening

I read in Ashcroft & Mermin's Solid State text that for the Thomas-Fermi approximation to be applicable, the external potential needs to be "slowly varying," What does it mean for a function (in ...
3
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1answer
65 views

Spin drift velocity?

I am currently reading this Phys Rev paper by H C Torrey. In this paper, he derives the Bloch equations with an additional diffusion term. He says that the current density is given by $$\mathbf ...
0
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0answers
54 views

Thermal fluctuations in metals

My professor said that the $k_BT$ displacement in the energy levels of the band electrons is due to the space-thermal displacement of the potential of the ion host. I think that this displacement is ...
2
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2answers
118 views

Who invented the perfume bottle thought experiment?

A common thought experiment used to explain the second law of thermodynamics, the "arrow of time", etc. is perfume escaping from an opened perfume bottle; the perfume is likely to diffuse into the ...
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3answers
96 views

Is thermodynamic free energy and potential energy the same thing?

The equation for free energy $F$ and potential energy $E_{pot}$ are: $$ F=U-TS \\ E_{pot} = E_{tot} -E_{kin} $$ But the temperature $T$ is proportional to the average kinetic energy of a system. So ...
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5answers
520 views

Entropy increase vs Conservation of information (QM)

Unitarity of quantum mechanics prohibits information destruction. On the other hand, the second law of thermodynamics claims entropy to be increasing. If entropy is to be thought of as a measure of ...
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1answer
90 views

Proof of Liouville's theorem: Relation between phase space volume and probability distribution function

I understand the proof of Liouville's theorem to the point where we conclude that Hamiltonian flow in phase-space is volume preserving as we flow in the phase space. Meaning the total derivative of ...