The study of large systems through coarse graining microscopic descriptions, providing a more detailed understanding of thermodynamics.

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In the Leidenfrost effect why dropplets of water can travel uphill?

The Leidenfrost effect is a phenomenon in which a liquid, in near contact with a mass significantly hotter than the liquid's boiling point, produces an insulating vapor layer keeping that liquid from ...
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0answers
105 views
+50

How to understand singularities in physics?

The question is probably two-folded and I will try not to make it too vague, but nonetheless the question remains general. First fold: In most physical laws, that we have analytic mathematical ...
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3answers
286 views

Distinguishable, Indistinguishable Paramagnetic Ideal Gas

In the canonical ensemble, the partition function for an ideal gas is given by: $$\frac{Z}{N!}$$ The factor $N!$ accounts for the indistinguishability of the particles of the ideal gas. What ...
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40 views

Thermodynamics and Axioms and the like

Can thermodynamics and any important related information be expressed as a set of axioms with various 'rules of manipulation'?
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1answer
28 views

Entropy $S$ for canonical (NVT) and isobaric (NPT) ensemble

In case of non-isolates system (NVT or NPT ensemble), I learned I can calculate the entropy, $$S=-k_B\sum_jp_j\ln(p_j)$$ where $p_j$=probability at $j$ state. but I saw that the entropy is also ...
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1answer
208 views

Fluctuations of an interface with hammock potential

This question is related to that one. I ask it here since comments are too short for the extended discussion that was going on there. I am interested in a very simple interface model. To each ...
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0answers
22 views

Magnetic susceptibility in ising model as magnetization change

Let's say I have a standard 2D Ising model with $$ H(\sigma) = - \sum_{<i~j>}\sigma_i \sigma_j - h\sum_{j} \sigma_j $$ With the metropolis algorithm, I can compute various things like energy ...
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9answers
3k views

Is it theoretically possible to reach 0 kelvin?

I'm having a discussion with someone. I said that it is -even theoretically- impossible to reach 0K, because that would imply that all molecules in the substance would stand perfectly still. He said ...
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1answer
98 views

How to prove the Bose enhancement factor $(1+f)$ and the Pauli blocking factor $(1-f)$ in Boltzmann equation?

For the collision integral in the Boltzmann equation for particles obeying different statistic, the factor is 1 for classical particles , 1-f for fermions, 1+f for Boson. While why it's exactly this ...
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1answer
31 views

1D Ising model and degenerate states

I am studying the Ising model in 1D, in the absence of magnetic interaction but in presence of an external magnetic field. The Hamiltonian for an Ising chain with $n$ sites is hence described by $$H = ...
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2answers
33 views

Entropy change in an irreversible process between 2 equilibrium state

Calculating entropy change in an irreversible process between 2 states requires computing the change in entropy for any reversible process between the 2 same states, but why? If someone could provide ...
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0answers
32 views

Maxwell Relations in Thermodynamics - Specific Heat [closed]

I am not able to solve that question: Using Maxwell relations and the fact that $C_p = T \dfrac{\partial S}{\partial T}\Big|_p$ $C_V = T \dfrac{\partial S}{\partial T}\Big|_V$ Show that I can ...
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1answer
88 views

Ising model on lattices with (vertical side length) $\neq$ (horizontal side length)

Consider the Ising model with nearest neighbours interactions on a rectangular lattice $L\times M$. If $L=M$ (2-dimensional square lattice), it is known (e.g. by Peierls argument or Onsager explicit ...
3
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1answer
99 views

Spin drift velocity?

I am currently reading this Phys Rev paper by H C Torrey. In this paper, he derives the Bloch equations with an additional diffusion term. He says that the current density is given by $$\mathbf ...
2
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1answer
33 views

Coset construction of Tricritical Ising CFT

In http://iopscience.iop.org/1742-5468/2008/03/P03010 the authors state that the Tricritical Ising Model (TIM) CFT can be obtained from a Wess Zumino Witten construction based in the coset ...
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1answer
122 views

Thermal radiation in the Unruh Effect

The following formula has been given in 't Hooft's black holes notes ($|\Omega \rangle$ is the vacuum state of Minkowski space, O is a operator): $$\langle \Omega| O|\Omega \rangle = \sum_{n \ge 0} ...
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2answers
106 views

Thomas - Fermi screening

I read in Ashcroft & Mermin's Solid State text that for the Thomas-Fermi approximation to be applicable, the external potential needs to be "slowly varying," What does it mean for a function (in ...
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1answer
28 views

Spin correlation function identity

The correlation function G between two spins is usually defined as $$ G=\langle \sigma_a \sigma_b\rangle - \langle \sigma_a\rangle \langle\sigma_b\rangle $$ The $\sigma$ are the value of the spins ...
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1answer
76 views

Spontaneity / Free Energy of Non-Isothermal Process

I'm trying to determine a lower bound for the work input necessary to make an entropy-reducing process "spontaneous" in the sense that the 2nd law is not violated. For a constant temperature and ...
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1answer
55 views

Can I use the grand canonical ensemble for a photon gas?

I have been reading about photon gases at https://www2.chem.utah.edu/steele/doc/chem7040/chandlerch4.pdf. They do the analysis using a canonical ensemble. Since photon numbers are not conserved, I ...
3
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1answer
156 views

H-theorem and Boltzmann equation applied to Boltzmann distribution

Using the Boltzmann equation: $$ \frac{dH}{dt} = \int_0^{\infty} dr \int_0^{\infty} ds W(r,s)[p_r - p_s][\ln{p_r} - \ln{p_s}],$$ and assuming $p_r = e^{-\beta r}$, the equation looks like $$ ...
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22 views

how will the distribution of the no. of particles be in a system ,(N,V,E) if N tends to infinity?

MB distribution is followed if there are N no. of non interacting and distinguishable particles. But if N tends to infinity why does the no. of micro states reduces? Is there any peak in the graph?
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24 views

Does spin degeneracy affect ideal Fermi gases in any way as T->Infinity?

In other words, given any system comprised of an ideal Fermi gas, in the high-temperature (classical) limit, are there any observable thermodynamic quantities (pressure, volume, energy, density, etc.) ...
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1answer
220 views

Virial Theorem and the Energy in a Gas

I clearly am interpreting the Virial Theorem incorrectly, but I don't know how. In dipole gases, the molecules can exhibit five kinetic modes, while they can only experience 2 potential modes. Doesn't ...
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1answer
35 views

What is the gas entropy as a functional of a one-particle distribution function?

There are some discrepancies on how to introduce entropy in classical kinetic theory. In what follows $f(r,p,t)$ is the usual one-particle distribution function of a monatomic gas, normalised to the ...
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1answer
137 views

Thermodynamics, chaperones : How to model polymer fragmentation

Living polymers are well described by equilibrium statistical physics. Now I would like to consider a case were living polymers undergo fragmentation due to chaperones. I can think of a kinetic ...
3
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1answer
182 views

Percolation and number of phases in the 2D Ising model

Update. As my previous figure had conceptual mistakes I decided to change the picture to another, more instructive. After a long time I came back to try to understand an article on the Ising model. ...
3
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1answer
73 views

Number $g(T)$ of relativistic degrees of freedom as a function of temperature $T$

Let us consider the total number of relativistic degrees of freedom $g(T)$ for particle species in our universe: $$g(T)=\left(\sum_Bg_B\right)+\frac{7}{8}\left(\sum_Fg_F\right)$$ Where the sums are ...
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1answer
67 views

What is the cause for mechanical equilibrium in statistical mechanics?

In classical thermodynamics, mechanical equilibrium is defined as the state of a system in which there is no net flow of volume as there should be no net pressure within the system. Ok. ...
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1answer
125 views

How to derive the critical temperature for Bose-Einstein condensation of photon?

I found in Nature magazine that photon can have Bose-Einstein condensation. But I have a question how to derive the critical temperature for photon? Because the chemical potential of photon is zero ...
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1answer
31 views

Reference about probability to study statistical mechanics

I've started studying statistical mechanics but I feel that I need to understand probability better. There are tons of books on probabilities out there, but some of them just talk too much, with tons ...
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0answers
29 views

Reference for Non-Hamiltonian treatment of Liouville's theorem

Does anyone know of any good books /lecture notes that include a section on Liouville's theorem with regard to non-Hamiltonian dynamics/systems, i.e. those with $\frac{d\rho}{dt} \neq 0$. Examples ...
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34 views

Number of particles in a box at thermal equalibrium

Consider a cube box of volume $V$ in thermal equilibrium at temperature $T$. We have 3 pieces of information: The probability of finding a particle of mass $m$ in the box having momentum in ...
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2answers
28 views

Is there any relation between temperature dependence of resistance and fermi energy in metals?

Given that the resistance varies linearly with temperature in metals, is there any way we can calculate the Fermi energy from this information?
2
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1answer
38 views

2 level atomic system interacting with Black body radiation. Relaxation time issue

I am studying the transient regime of a 2 level atomic system ($N_1,N_2$) interacting with a blackbody radiation from a source at constant temperature $T_{nr}$. The initial state of the atomic system ...
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1answer
309 views

phase-space volumes or cells for N particle system

For N non interacting spinless particles in a volume, we have 3N degrees of freedom and we can divide the phase space into 6N dimensional cells of volume h raised to power 3N. And each cell ...
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1answer
154 views

What happens in a gas of magnets?

This SMBC comic asks what happens if you make a gas of magnetic particles: I was wondering whether anyone has run into actual examples of this or something like it. A classical example similar to ...
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1answer
485 views

Pauli paramagnetism for electrons with external magnetic field

Apparently it is to be shown that for electrons under an external magnetic field, in the limit as $B\to 0 $ $$ \chi = \frac{dM}{dB} \approx \frac{n\,\mu^{*^2}}{k\,T}\,\frac{f_{1/2}(z)}{f_{3/2}(z)} $$ ...
5
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2answers
407 views

Renormalization Group and Ising with d=1 and D=1

I have a question about the results of RG on Ising model. I know it's possible to obtain two couple of relations $K'(K)$, $q(K')$ $K(K')$, $q(K)$ between the coupling costants. My problem arise ...
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1answer
54 views

Statistical mechanics vs. many-body theory

Where is the basic difference of statistical mechanics with many-body physics? What are the systems which cannot be studied in statistical mechanics but in many body theory? After all we know ...
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2answers
35 views

What is the theoretical instantaneous temperature of a gas?

When we measure the temperature of a gas we typically integrate the molecular collisions and wind up with an 'average' temperature due to the sensor comprising a relatively large thermal mass. And ...
2
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0answers
35 views

Landau's derivation of the law of entropy increase - clarification

In Landau&Lifshitz V: Statistical Physics the following derivation of the law of increase of entropy is given. I need help understanding several crucial steps; I'll briefly summarize the notations ...
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1answer
73 views

Phase Transition at Zero Temperature (Not QPT)

As is well known the Ising model exhibits a phase transition, except the one dimensional case in which the phase transition occurs strictly at $T=0$. Now I have always thought that this makes the case ...
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1answer
67 views

Partition function: Number of states? Doesn't add up for ising

While trying to really understanding the partition function in statistical mechanics, I tried looking at it for a 2D ising model, as that's been helpful for me for all kinds of thermodynamic values. ...
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1answer
73 views

Which function denotes the energy of thermal motion within a system?

In thermodynamics, the heat $Q$ is defined as a type of energy in transfer, and is not a state function, which function denotes the energy of thermal motion within a system? 1) $TS$, (there is a ...
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1answer
63 views

Calculating the entropy of a monatomic ideal gas

I am looking at the start of the consider how to calculate the entropy of a monatomic ideal gas. We need to determine the number of microstates in $E \leq \mathcal{H}(\Gamma) \leq E+\Delta$. The ...
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1answer
36 views

Definition of quantum microcanonical ensemble in Landau&Lifshitz

I'm reading the first chapters of Landau&Lifshitz 's [Statistical Physics][1] and I don't understand the definition of the quantum microcanonical ensemble. The microcanonical distribution for a ...
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1answer
33 views

What is quantum states of a gas? Is it the principle quantum no.?

When we write that the possible quantum states of a system are $S=1,2,3.\dots$, how is that related with the four quantum numbers, especially with the spin of a particle? Also according to BE ...
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1answer
29 views

Chemical reaction A+B$\leftrightarrow$C. Equilibrium VS Non Equilibrium

Could you please confirm or say why I am wrong? Let us consider the steady state of the chemical reaction $A+B \leftrightarrow^{k_+}_{k_-} C$, with $k_+$ and $k_-$ the forward and backward rates. ...
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1answer
36 views

Why is the number of phonon modes in a solid restricted to a finite value?

Kittel's Thermal Physics (Amazon link) makes the statement: There is no limit to the number of possible electromagnetic modes in a cavity, but the number of elastic modes in a finite solid is ...