The study of large systems through coarse graining microscopic descriptions, providing a more detailed understanding of thermodynamics.

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Is thermodynamic free energy and potential energy the same thing?

The equation for free energy $F$ and potential energy $E_{pot}$ are: $$ F=U-TS \\ E_{pot} = E_{tot} -E_{kin} $$ But the temperature $T$ is proportional to the average kinetic energy of a system. So ...
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3answers
200 views

Distinguishable, Indistinguishable Paramagnetic Ideal Gas

In the canonical ensemble, the partition function for an ideal gas is given by: $$\frac{Z}{N!}$$ The factor $N!$ accounts for the indistinguishability of the particles of the ideal gas. What ...
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2answers
156 views

Why is the Gibbs Free Energy $F-HM$?

With magnetism, the Gibbs Free Energy is $F-HM$, where $F$ is the Helmholtz Free Energy, $H$ is the auxiliary magnetic field, and $M$ is magnetization. Why is this? Normally, in thermodynamics, we ...
4
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2answers
332 views

Renormalization Group and Ising with d=1 and D=1

I have a question about the results of RG on Ising model. I know it's possible to obtain two couple of relations $K'(K)$, $q(K')$ $K(K')$, $q(K)$ between the coupling costants. My problem arise ...
2
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2answers
57 views

Modeling a list with a tunable degree of disorder/shuffling

Imagine we have a list of ordered numbers $L = (1, 2,\dots, N)$. I want to add an arbitrary amount of "disorder" to that list. For instance: Adding a little bit of disorder would permute a few ...
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2answers
266 views

Fermi-Dirac Statistics

In Fermi-Dirac statistics the probability of being in a certain energy state is $$f(E) = \left[1 + \exp\left(\frac{E-E_F}{k T}\right)\right]^{-1}$$ In the area that I'm looking at the texts always ...
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2answers
213 views

Calculating the change in entropy in a melting process

I have a homework question that I'm completely stumped on and need help solving it. I have a $50\, \mathrm{g}$ ice cube at $-15\, \mathrm{C}$ that is in a container of $200\, \mathrm{g}$ of water at ...
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2answers
107 views

What are correlated magnetic moments?

My book has the following sentence and I don't understand what correlation or lack of correlation means: At high temperature the magnetic moments of adjacent atoms are uncorrelated (to maximize ...
14
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1answer
142 views

Fluctuations of an interface with hammock potential

This question is related to that one. I ask it here since comments are too short for the extended discussion that was going on there. I am interested in a very simple interface model. To each ...
13
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1answer
276 views

How is the logarithmic correction to the entropy of a non extremal black hole derived?

I`ve just read, that for non extremal black holes, there exists a logarithmic (and other) correction(s) to the well known term proportional to the area of the horizon such that $S = \frac{A}{4G} + K ...
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1answer
39 views

Minimum connectivity required for mean field to be a good approximation?

In spin models, it is known that mean field becomes a better approximation as the connectivity increases. My question is: Is there an estimate for the threshold connectivity (as a function of the ...
4
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1answer
144 views

Semi-conductors

Suppose there is a semiconductor with Fermi energy $E_f$ and that there are $N$ bound electron states. I'd like to know why the mean number of excited electrons takes the form $$\bar n={N\over ...
4
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1answer
393 views

upper critical dimension in field theory

Is there field theory which describe a second order phase transition without upper critical dimension ? Mermin-Wagner says something about lower critical dimension but nothing about upper dimension.
4
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1answer
929 views

Infinite-range 1D Ising model + Hubbard-Stratonovich-Transformation

I have a probably quite simple question RE the HST. After some work, I obtain as the partition function for the infinite range 1D Ising model $$Z = \int_{-\infty}^\infty \frac{dy}{\sqrt{2\pi / ...
3
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1answer
42 views

Problems with units of entropy in statistical thermodynamics

The statistical thermodynamics definition of entropy: $S = kN \ln (W)$ troubles me a lot with the problem of dimenstions. where $S$ is entropy; $k$, the Boltzmann constant; $N$ the number of particles ...
3
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1answer
74 views

Cluster Expansion vs Cluster Decomposition

Are the cluster expansion (which we encounter in Statistical Physics), and cluster decomposition (in Quantum Field Theory) related to each other? (I have a reason to believe they are)
3
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1answer
44 views

What is an intuitive explantion for the fact that the Maxwell-Boltzmann distribution of energies is independent of mass?

If you take the Maxwell-Boltzmann distribution of velocities (which depends on the mass) and substitute $v=\sqrt{\frac{2E}{m}}$ you get the distribution for the energies, which turns out to be ...
3
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1answer
53 views

Spin drift velocity?

I am currently reading this Phys Rev paper by H C Torrey. In this paper, he derives the Bloch equations with an additional diffusion term. He says that the current density is given by $$\mathbf ...
3
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1answer
270 views

Are black hole states completely mixed?

A completely mixed state is a statistical mixture with no interference terms, and (QMD, McMahon, pg 229): $$\rho = \dfrac{1}{n}I$$ $$Tr(\rho^2) = \dfrac{1}{n}$$ Are black hole quantum states ...
2
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1answer
40 views

Numerical Ising Model: Swendsen–Wang algorithm, Percolationtheory?

When you look at the original paper of Swendsen and Wang in 1987: "Nonuniversal critical dynamics in Monte Carlo simulations" it is somewhat mentioned that the proposed algorithm uses percolation ...
2
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1answer
99 views

Thermodynamics, chaperones : How to model polymer fragmentation

Living polymers are well described by equilibrium statistical physics. Now I would like to consider a case were living polymers undergo fragmentation due to chaperones. I can think of a kinetic ...
2
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1answer
85 views

Lennard-Jones induced pseudo-molecules

It can be shown that the Lennard-Jones potential - which describes the interaction between particles in non-ideal gases - gives rise to pseudo-molecules: after a triple "collision" of three ...
2
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1answer
125 views

Reaction coordinate as a function of atomic positions

I'm going over some (molecular dynamics) related literature - specifically the derivation of the Weighted Histogram Analysis Method (WHAM). As a quick backdrop WHAM is a method for stitching ...
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1answer
22 views

Proof of Liouville's theorem: Relation between phase space volume and probability distribution function

I understand the proof of Liouville's theorem to the point where we conclude that Hamiltonian flow in phase-space is volume preserving as we flow in the phase space. Meaning the total derivative of ...
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1answer
21 views

Thomas - Fermi screening

I read in Ashcroft & Mermin's Solid State text that for the Thomas-Fermi approximation to be applicable, the external potential needs to be "slowly varying," What does it mean for a function (in ...
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1answer
40 views

How can the microstates be measured with zero energy expenditure?

James P. Sethna. Statistical Mechanics. Exercise 5.2: What prevents a Maxwellian demon from using an atom in an unknown state to extract work? The demon must first measure which side of the ...
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1answer
106 views

What is the probability of ice in boiling water?

Ice crystals are spatially ordered, and in every randomness there is a low possibility of temporarily order. If given enough boiling water, and sufficient time, could local clusters water molecules ...
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1answer
95 views

2nd order phase transition trouble deriving coefficient in fluctuations analysis

I can't get one of the coefficients in the equation for $T < T_c$ in the bottom, specifically the equation with the factor of two. any help appreciated. Consider an ising type expansion of the ...
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1answer
161 views

Bose–Einstein statistics exercise

I've a basic Bose–Einstein statistics exercise. I've tried to solve it in two ways, but each way gives a different result. We have $n$ identical bosons without interactions at temperature $T$. There ...
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1answer
34 views

Canonical ensemble, energy, heat bath

I am studying through the book Thermodynamics and Statistical Mechanics by Walter Greiner and I’ve got a couple of doubts when I was reading about the classical ensembles, specially the Canonical ...
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1answer
41 views

Statistical Mech Problem

i need to derive a formula for the photon gas correlation function $\left\langle\partial n_i\partial n_j\right\rangle $ where $\partial n_i=n_i -\left \langle n_i \right \rangle$ whilst solving i ...
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1answer
148 views

Virial Theorem and the Energy in a Gas

I clearly am interpreting the Virial Theorem incorrectly, but I don't know how. In dipole gases, the molecules can exhibit five kinetic modes, while they can only experience 2 potential modes. Doesn't ...
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1answer
876 views

Partition function for a microcanonical ensemble

Is it possible to write down a partition function for a microcanonical ensemble?
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184 views

Ground and first excited state of non interacting spin system Hamiltonian

For a non interacting spin system containing two $\frac{1}{2}$ spin particles I am trying to determine its Hamiltonian. If the energy of a up spin is $+\mu {\bf B}$ and a down spin is $-\mu {\bf B}$, ...
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122 views

Number of microstates of discretized paths

Let us consider a square grid, which has been rotated by 45deg. On this grid we define a path, the directed polymer, which starts at the origin ($t = 0$) and extends in the positive $t$-direction ...
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0answers
68 views

Why is the transition into N proportional to N+1?

I am having trouble understanding the origin of the bosonic stimulated emission. How can I qualitatively understand why bosons Boson's attract each other into similar quantum states. The furtherst I ...
0
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0answers
67 views

Edwards-Anderson Hamiltonian of a Hopf link

I was calculating the Edwards-Anderson Hamiltonian of a Hopf link. A hopf link is like attachment 1. I have drawn the Seifert surface of that link. The surface is shown in attachment 2. It also ...