The study of large systems through coarse graining microscopic descriptions, providing a more detailed understanding of thermodynamics.

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Books/resources for statistical field theory

I was wondering if anyone knows good, approachable textbook or other resources about statistical field theory (topics like in Kardar's Statistical physics of fields: lattice models, mean field theory, ...
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24 views

Can a gas be modelled as a low density blackbody, if we want to consider how detectable it will be in space?

The answer to this question taught me about the sort of parameters I need to consider if I want to consider how "detectable" an object in space is. I want to consider the detectability of a ...
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56 views

Entropy Inequalities

Hey I am reading this paper Entropy Inequalities by Araki and Lieb. I am trying to prove the following lemma: $$S^1+S^2\leq S^{12}+S^{23}$$ using the following lemmas: ...
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46 views

Why is it inappropriate to calculate free energy change from end points alone?

In molecular dynamics, free energy changes are estimated using a variety of protocols to establish a path between the starting and ending states. The classic example is umbrella sampling in which a ...
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63 views

Applying Statistical Mechanics to Formulate Corrosion (Rusting)

I wanted to try and take my current knowledge of statistical mechanics (first quarter undergraduate course completed, beginning researcher in far from equilibrium statistical mechanics, basic ...
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87 views

Interpretation of partition function and thermodynamic potential

So in the microcanonical ensemble the partition function $\Omega$ counts the number of microstates for a given $(NVE)$ configuaration and $S = k_B \ln (\Omega)$ is the entropy. The most likely state ...
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119 views

Chemical potential related with quantum and classical limit in ideal gas

For ideal gas we have chemical potential $\mu = \tau \ln \left(\frac{n}{n_Q}\right) $ where $n = N/V$ number density and $n_Q = \left(\frac{M\tau}{2\pi \hbar^2}\right)^{\frac{3}{2}} $ Note we call ...
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100 views

classical and quantum correlation functions

Quantum Field, quantum fluctuation even with no temperature In QFT, the correlation function $<0|\hat{\phi} (x)\hat{\phi} (y)|0>$ describes the fluctuation correlations of vacuum state ...
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112 views

Reduced phase space density

I have a dimensional problem with the single particle phase space density The partition function in the microcanonical ensemble is of course dimensionless Thus $$ \rho ( q, p ) = ...
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166 views

Meaning of phase space density

I am trying to understand Liouville's theorem physically. It says that $\frac{\partial \rho}{\partial t} + \{\rho,H\} = 0$. Thus, we have $\frac{d \rho(q(t),p(t),t)}{dt}=0$. I would like to ...
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46 views

Boltzmann factor predicts arbitrarily large numbers of electrons at high potential?

In deriving the Debye shielding length we are told that the Boltzmann factor for particles of charge $q$ is: $n_{q}=n_{0}\exp(-q\phi/kT)$ If we assume the potential $\phi$ is positive, then the ...
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43 views

Entropy of this system

We have a system with two energy states $E_0$< $E_1=0$. We also know that state $E_0$ can only take at most $m$ particles. Curently, there are $n<m$ particles in $E_0$. Now, I am supposed to ...
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67 views

probability of sequence for given rate constants

lets consider a copolymer, $C_{r,s}^A$ containing r number of A monomers and s number of B monomers with A at the reactive end of the polymer. The equilibrium constant for A-A, A-B, B-A, and B-B bonds ...
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83 views

What excactly is a “fourier component of a density fluctuation”?

Light scattering texts say depending on the scattering angle, you are seeing a certain fourier component of a density fluctuation. This density fluctuation varies sinusoidally due to Brownian motion ...
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236 views

What algorithms can be used to compute the binodal in a ternary Flory-Huggins theory?

What are the most popular algorithms used to obtain a binodal curve for the ternary mixture (starting from Flory-Huggins theory)? I would like to obtain a plot similar to the one calculated here ...
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35 views

Methods for quantifying a network of coupled oscillators

I usually am more on the statistics part of things, so pardon my misuse of the terminology. I am simulating a network of non-pulse coupled non-linear oscillators ( I am not sure what the correct term ...
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90 views

Diamagnetism of a degenerate electron gas for weak fields

In the book "Statistical Physics, Part I ($3^{{\rm rd}}$ edition)" by Landau and Lifshitz, at $\S59$ when he treats the diamagnetic part of the magnetisation of a degenerate electron gas for weak ...
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78 views

Free energy a continuous function of temperature but may not be differentiable everywhere?

So according to my understanding, the free energy of the system should be a continuous function of temperature. This is because if the free energy is not continuous at temperature T, then at this ...
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141 views

Effusion of particles from one box to another - pressure calculation

Suppose we have a container divided into equal halves. Right half is fixed at temperature $T$, volume $\frac{V}{2}$. Initially it has pressure $P_0$, a hole of area $A$ is opened between them. I ...
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130 views

Connection between String theory and Statistical Physics

I would like to think via standard transitivity arguments that there should be a deep connection between String theory and Statistical Physics. Why? Statistical Physics $\rightarrow$ QFT 2d QFT ...
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208 views

Calculating heat capacity from the equation of state

It is known that within thermodynamics alone, given the equation of the state of a system, one cannot explicitly determine the heat capacity. What is the mathematical reason for this? Intuitively, it ...
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111 views

Derivation of Higher-order correlation functions from definition

I'm trying to understand the definition of the n-th order correlation function. My aim is to translate the math into a numerical implementation in order to compute the correlation function $g^{(n)}$ ...
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20 views

Coarse-graining on a second channel decreases mutual information?

Let $X_1,B_1,X_2,B_2$ and $Y_1,A_1,Y_2,A_2$ and $C_1$ and $C_2$ be binary random variables. Suppose: $I(X_2:B_2|C_2=0)+I(Y_2:A_2|C_2=1) \leq 1$. This can be thought of as a bound on the capacity ...
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269 views

Fluctuations in energy for macro and micro canonical ensembles

I was thinking about fluctuations in energy for a system in thermal equilibrium. I think that the Boltzmann distribution itself has an standard deviation approximately equal to the mean, as it is ...
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213 views

Fluctuation-Dissipation theorems in an infinite quantum system

So for a quantum spin chain, one can easily prove via the partition function that you have a fluctuation-dissipation type relation between the magnetic susceptibility and the variance of the ...
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147 views

Understanding the product of partition functions by making sense of the maths and the physics

I have $N$ distinguishable particles in a 1D harmonic oscillator potential with 'proper' frequency $\omega$. The particles also have internal spin-$\frac12$ degrees of freedom in a magnetic field $B$ ...
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135 views

Ising model. What is large fluctuations of magnetization?

My background is in mathematics. I have studied the Ising model in $\mathbb{Z}^2$. The main model of statistical mechanics. Yesterday, I was reading the preliminary notes of the book Statistical ...
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117 views

Is it possible to define a notion of temperature in a microcanonical ensemble?

I am thinking of a mircrocanonical ensemble as a finite system for which the number of particles, volume and the total energy is fixed. Is there a more refined view of this? Can I think of ...
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364 views

Boltzmann distribution: derivation from canonical distribution

I'm trying to understand the Maxwell-Boltzman Distribution, and in particular the derivation from the boltzman distribution for energy. I have successfully created an incorrect derivation, but I'm not ...
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63 views

What is conductivity?

I read that if we have spin $\frac{1}{2}$-particle, where a magetic force acts on, then the force is given by a drift speed times a conductivity. This conductivity is determined to be $\frac{kT}{D}$, ...
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221 views

Fugacity of the fermi gas

It can be shown that in the high temperature exploration of the Fermi gas, the Fermi function may be expanded to second order in $e^{\beta \mu}$, where $\beta = 1/kT$ and $\mu$ is the chemical ...
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38 views

Can the short-time dynamics of an open quantum system be approximately unitary?

Considering the physics of an open quantum system described by a Hamiltonian $H=H_S+H_E+H_{SE}$, where the subscript $S$ refers to the system of interest, $E$ to the environment and $SE$ to the ...
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192 views

The Maxwell and the Boltzmann distributions

I am trying to understand where the Boltzmann distribution comes from. I recently learned some interesting things of which my interpretation follows below. Did I interpret correctly? If so, is this ...
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98 views

Langevin equation

A molecule consists of two atoms whose centers are located at $\mathbf{r}_1$ and $\mathbf{r}_2$ respectively. The atoms are connected by a bond that can be approximated by a harmonic spring, so that ...
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121 views

How does the Lennard Jones Potential changes for interaction between particles of different sizes?

I am interested in incorporating a Lennard-Jones potential in a simulation. When the interaction only involves the same type of particle, with same characteristics, we can use reduced units, scaling ...
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311 views

Free Energy of N Spin 3/2 Particles

This question is from the book "Introductory Statistical Mechanics" by Bowley and Sanchez. The question is as follows: Calculate the free energy of a system with N particles, each with spin 3/2 with ...
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187 views

Average number of spin up particles

In a paramagnetic system, where $N = N_\uparrow + N_\downarrow$ is fixed, how does one calculate the average number of spin-up particles $\langle N_\uparrow \rangle$? You can assume we have the ...
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44 views

Ergodicity Breaking in Supercooled Liquids

What is a ergodic system? What is Onset temperature of ergodicity breaking in super cooled liquids when we go towards lower temperature?
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114 views

Is there a systematic way to determine the relevant variables needed to describe a nonequilibrium system?

In strong nonequilirium, the statistical operator describing the system depends on an infinite number of variables (BBGKY-hierarchy), contains information about all the previous states starting from ...
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279 views

Peierls Argument for Absence of Long Range Order

I'm really confused about the argument in Cardy's book for why there can't be long range order in 1D for discrete models. Let me just copy it out, and hopefully someone can explain it to me. He ...
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127 views

Traditional Transfer Matrix on the Potts model — how it grows for strip lattices?

What is the transfer matrix size for a strip lattice of width $n$ vertices, with arbitrary $q$?? I am not sure if it is $q^n$ x $q^n$ or something else. Any reference is also welcome.
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224 views

Maxwell-Boltzmann distribution

The short story is, that I have to calculate some transport coefficients, but using the the MB distribution as my distribution function. What I currently need to solve is: ${{\mathcal{L}}^{\,\left( ...
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235 views

Maxwell-Boltzmann distribution for transport equations

I have to calculate the transport coefficients for the Maxwell-Boltzmann distribution. But I'm not sure what distribution I have to use. As far as I know it should not be the MB distribution for ...
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35 views

Is there anything to prevent paired-up neutrons from a complete overlap

The reason "neutrons don't overlap", as DarenW explained it, has to do with intricate forces at play that take into account the spins, iso-spins and symmetry of the wavefunctions. However, assume I ...
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557 views

Rotational Constant and Moment of Inertia of Fluorine gas

I have come across some homework question on thermodynamics which needs me to calculate $B$ of $F_2$ My attempt: $B= \frac{h}{8\pi^2cI}$ where $I=\mu r^2=\frac{m_1m_2}{m_1+m_2} r^2$ Atomic mass of ...
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81 views

Partition function for multidimensional scaling energy

Let $D_{ij}$ a random matrix with i.i.d positive coefficients. One can take for instance $D_{ij}$ uniformly distributed in [0,1]. We consider the following energy function $H(x)$ defined for ...
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113 views

Statistical Mechanic

One can define entropy as $$S=k\log{\omega(E)},$$ where $\omega(E)$ is the numbers of states with energy equal $E$; and the canonical partition function for a set of N particles is defined ...
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207 views

helmholtz free energy of a polymer

You have a polymer chain of $N$ units, which is represented by $N$ independent springs in series. The springs are Hookean, with spring constant $L$, and the end to end vector is $\mathbf r$. So the ...
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169 views

Fock picture of bosonification in condensates

I want to understand how bosonification in a condensate must be interpreted in the Fock states picture Say i have uncoupled fermions in a set of states $E_1$, $E_2$ ... over the vacuum $E_0$. They ...
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111 views

What is meant by correlation propagation?

What is meant by correlation propagation in physics? I have an intuitive understanding but are there any introductory notes ( more mathematical oriented) and with some physical examples?