The study of large systems through coarse graining microscopic descriptions, providing a more detailed understanding of thermodynamics.

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1answer
83 views

Can I express the heat flow of a fluid in terms of estabilshed characteristics of the velocity distribution?

If $\rho$ is the mass density of a fluid and $A({\bf v})$ is an function of the velocity, which is distributed according to $f({\bf v})$, we have an averaging process $A\mapsto \langle A\rangle:=\int ...
0
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1answer
93 views

General way to model baths? Harmonic Oscillators valid?

I am trying to model an open system interaction without making strong assumptions on coupling strength or temperature. In general i understand that open systems are modeled by a Lindbladian, but as ...
9
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0answers
175 views

Can Lee-Yang zeros theorem account for triple point phase transition?

Now the prominent Lee-Yang theorem (or Physical Review 87, 410, 1952) has almost bocome standard ingredient of any comprehensive statistical mechanics textbook. If the volume tends to infinity, ...
3
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3answers
240 views

Entropy increase vs Conservation of information (QM)

Unitarity of quantum mechanics prohibits information destruction. On the other hand, the second law of thermodynamics claims entropy to be increasing. If entropy is to be thought of as a measure of ...
4
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1answer
449 views

Paramagnetism Spin-1/2 Particles - Partition Function

I'm trying to come up with an expression for the partition function of a system of spin-1/2 ideal gas particles on a line of length $L$. The total number of particles $N$ is fixed, with $N = ...
6
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2answers
303 views

Is there a phase transition between a gas and plasma?

Does a phase transition occur as a gas is heated to create a plasma? If so, is this a first or second order phase transition? Also, does the presence of a phase transition depend on the pressure or ...
4
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2answers
142 views

What information is lost in the symmetrization necessary to derive the BBGKY hierarchy?

The book on Kinetic theory I'm reading derives the BBGKY hierarchy after introducing the reduced distribution functions $f_s(q^1,p_1,q^2,p_2,\dots,q^s,p_s):=\int\ \rho\ \ \mathrm d q^{s+1} \mathrm d ...
2
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1answer
109 views

Ergodicity of the Drude model

The Drude model of electric conduction in solids deals with independent free electrons subject to random collisions with the crystal lattice (the direction where the electrons are scattered after a ...
2
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3answers
188 views

How does that Boltzmann distribution interact with entropy?

In an ideal gas, the Boltzmann distribution predicts a distribution of particle energies $E_i$ proportional to $ge^{-E_i/k_bT}$. But, doesn't entropy dictate that the system will always progress ...
1
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1answer
165 views

Logical understanding of the canonical probability distribution (canonical ensemble) [duplicate]

I am having problems in understanding the logic of this distribution: $P(\Psi_{j})=\displaystyle\frac{e^{-E_{j}/kT}}{\displaystyle\sum_{j'}e^{-E_{j'}/kT}}$ The book I am studying use the case of a ...
8
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3answers
274 views

What is the relationship between Maxwell–Boltzmann statistics and the grand canonical ensemble?

In the grand canonical ensemble one derives the expectation value $\langle \hat n_r\rangle^{\pm}$ for fermions and bosons of sort $r$: $$ \langle \hat n_r\rangle^{\pm} \ \propto \ ...
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0answers
54 views

What is known about the statistical mechanics of systems with normally distributed energies?

Consider a system taking on N states with energies $\epsilon \sim \mathcal{N}(\mu,\sigma^2)$. Are such systems well-studied in any context? I ask because I'd like to be able to take certain ...
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3answers
282 views

Is there really such a thing as an irreversible process?

If an isolated system goes from a state A to B, will it always eventually fluctuate back to state A? If not, give an simple example. Is it right to say that entropy only says that the probability ...
-1
votes
1answer
120 views

How does physicists calculate the gravitational self collapsing force of a star?

The nuclear fusion taking place inside the stars opposes its gravitational self collapsing force. But, how does physicists calculate it? I just know the classical gravitational theory and not a bit of ...
0
votes
2answers
367 views

Why doesnt this violate 2nd law of thermodynamics?

Consider an ideal gas in a cylindrical container in a gravitational field, with a piston on top pushing down by gravity. The piston has some locking mechanism that locks it in place if it is displaced ...
2
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3answers
108 views

Configuration space of particles in the box

The notion of entropy says that we can count microstates that correspond to macrostate. But, I do not understand how this can be done. Does it imply that the state space is discrete (finite or ...
-1
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1answer
50 views

What is the difference between scale-free network and small-world network? [closed]

What is the difference between scale-free network and small-world network? I can't understand from the definitions around the web if they are both the same name for one thing. Do both follow a ...
2
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1answer
145 views

Percolation and number of phases in the 2D Ising model

Update. As my previous figure had conceptual mistakes I decided to change the picture to another, more instructive. After a long time I came back to try to understand an article on the Ising model. ...
6
votes
1answer
280 views

``What is life?'' by a physicist definition [closed]

The question is about defining ``What is life?'' in the field of Physics. Whether there is any (insightful) way of defining ``What is life?'' from physicists. There are pioneer works, including ...
2
votes
1answer
91 views

Meaning of Lagrange Multiplier in Ou-Yang and Helfrich's Shape equation for Membrane

Dear people in Physics Stackexchange, My question is mostly related to the following papers: U. Seifert, Z. Phys. B 97, 299 (1995). "The concept of effective tension for fluctuating vesicles". U. ...
15
votes
5answers
1k views

Why isn't absolute $0 K$ temperature possible?

So $T$ is defined as $$T = \left(\frac{\partial E}{\partial S}\right)$$ and $S$ is defined as $$S = k_B \ln \Omega$$ where $\Omega$ is the number of accessible states of the system for a given ...
8
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5answers
465 views

How do you prove the second law of thermodynamics from statistical mechanics?

How do you prove the second law of thermodynamics from statistical mechanics? To prove entropy will only increase with time? How to prove? Please guide.
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0answers
71 views

How to formally write down the Boltzmann equation?

Can someone write down the Boltzmann equation, not neglecting any of the variables of the involved functions and integrals? Specifically, how to concisely capture the "primed" variables in a sensible ...
7
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1answer
278 views

The virial theorem and a delta function potential

So the virial theorem tells us that: $2\langle T\rangle = \langle \textbf{r}\cdot\nabla V\rangle$. Now I was wondering what would happen if V has te form: $V(\textbf{r}-\textbf{r}') = ...
2
votes
1answer
261 views

Equation of state of a rubber band

I have the following question that I attached in png format. I have done part (a), but I am having difficulties in part (b) when I proceed according to the book. I have non zero tension at ...
6
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1answer
144 views

Is it always possible to express an operator in terms of creation/annihilation operators?

I'm referring to "Path integral approach to birth-death processes on a lattice", L. Peliti, J. Physique 46, 1469-1483 (1985), available at: http://people.na.infn.it/~peliti/path.pdf The article is ...
7
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2answers
688 views

What are the six degrees of freedom of the atoms in a solid?

A monoatomic ideal gas has heat capacity $C_v=1.5$ which comes from the three translational degrees of freedom. For solids at high temperature, $C_v=3$, implying six degrees of freedom. What are ...
13
votes
1answer
320 views

Does this type of phase transition exist?

The short version of this question is: Is there, or could there be, a system with a phase transition where adding a small amount of heat causes a discontinuous jump in its temperature? Below are ...
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2answers
250 views

naive question on Boltzmann equation and conservation laws

The Boltzmann equation in absence of external force reads: $\frac{\partial f}{\partial t} + \vec{v} \cdot \frac{\partial f}{\partial \vec{r}} = \left( \frac{\partial f}{\partial t}\right)_{coll}$ ...
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2answers
110 views

Entropy Maximization using undetermined multipliers

This is from Problems in Thermodynamics and Statistical Physics by P.T. Landsberg A system can be in any one of N states. Using the method of undetermined multipliers to show for the maximum ...
0
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0answers
55 views

Is it possible to derive fermi-dirac or bose-einstein statistics using quantum operator formulations?

I've been looking through theory on identical particles to get a better grasp of the uncertainty principle but it would be very interesting if these results could be extracted from the formalism as ...
0
votes
1answer
63 views

Justifications for different Monte Carlo trial moves

Why do we perform different trial moves in Monte Carlo simulations in Statistical Mechanics? For example, in NVT ensemble simulations, Why only atom displacement moves? In NPT ensemble, why do we need ...
4
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3answers
2k views

First and second order phase transitions

Recently I've been puzzling over the definitions of first and second order phase transitions. The Wikipedia article (at the time of writing) starts by explaining that Ehrenfest's original definition ...
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1answer
294 views

Why do pressure and chemical potential depend on temperature, instead of having symmetric definitions?

I'm following an introduction to statistical mechanics and have seen the following definitions for fundamental temperature, pressure and chemical potential respectively: $$\frac{1}{\tau} := \left( ...
2
votes
1answer
373 views

Practical difference between canonical and grand canonical ensembles

I'm currently doing some calculations which require evaluating various standard thermal expectation values in the canonical ensemble (both bosons and fermions). Now, in order to make my theoretical ...
0
votes
2answers
95 views

Grand canonical ensemble with interaction, simulation doubts

First of all, this is a follow-up of my first question. The idea is the same, every state would consist of some particles in a line (with an energy associated) and the particles can not be nearer than ...
9
votes
1answer
309 views

Definition of phase transitions in statistical mechanics

Phase transitions in statistical mechanics are usually taught by working through a bunch of examples. I decided to try and think about them from a more "fundamental" point of view - but I've run into ...
2
votes
1answer
405 views

What is off-diagonal long range order in superfluid?

From Wikipedia: [...]Off-diagonal long-range order (ODLRO) [...] exists whenever there is a macroscopically large factored component (eigenvalue) in a reduced density matrix of any order. How to ...
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1answer
195 views

Rate of effusion in kinetic molecular theory?

According to the kinetic molecular theory obeying Maxwell-Boltzmann distribution of speeds, the rate of effusion through a pinhole of area $A$ is $$R=\frac{PA}{\sqrt{2\pi M R T}}$$ where $M$ is the ...
1
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1answer
81 views

detailed balance in the context of the ising model

I am having a very basic problem understanding the idea of detailed balance, particularly in the context of the Ising model. Most references I have found contain the following phrase: "In ...
4
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0answers
74 views

Can the correlation for the Potts model be bounded?

I am studying a $d$-state Potts model. A configuration $\sigma$, which assigns for each $x\in \mathbb{Z}^2$ a value $\sigma(x)\in [1,2,\ldots,d]$, with the probability on a finite lattice defined as ...
6
votes
1answer
168 views

Any open areas to work in non equilibrium thermodynamics for a Phd student? [closed]

I see that many papers written on fundamentals of thermodynamics(theory) nowadays are by some old professors somewhere(there may be exceptions). Most active young faculty don't seem to be seriously ...
6
votes
1answer
94 views

Is “detailed balance” equivalent with a continuity equation in state space?

I have a talk tomorrow in which detailed balance is needed and I don't want to bore my audience with elaborate explanations for it so I'm looking for simpler explanations. As far as I understood it ...
2
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1answer
108 views

Research on ground state configuration of Ising model

I want to do mathematical research (algorithm construction and mathematical analysis) on Ising model ground state configuration. From what I know, the state of art research is using graph theory ...
4
votes
4answers
411 views

Entropy as an arrow of time

From what I understand, entropy is a concept defined by the experimentalist due to his ignorance of the exact microstate of a system. To say the number of accessible microstates $W$ of the universe is ...
7
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2answers
194 views

Casimir effect as an entropic force

When I first learned about the depletion interaction, my initial reaction was that it looks very similar to the Casimir effect. On making this remark to the professor, he replied somewhat mystically: ...
0
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1answer
296 views

Calculating the ideal mixing entropy using Gibbs' entropy formula

Two distinguishable gases are in separate volumes $xV$ and $(1-x)V$ $(x\in [0,1])$ respectively, and the number of particles on each side is $xN$ and $(1-x)N$ respectively. The volumes are separated ...
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0answers
69 views

thermoelectric effect

The Absolute Seebeck effect states that an electric potential (voltage) is produced to any isolated conducting when subject to a temperature gradient.But why? My view of this is that when you apply ...
3
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1answer
82 views

Boltzmann distribution with interaction between particles?

First of all, I would like to apologize in advance if I make stupid mistakes. I am a mathematician and I am trying to apply the Boltzmann distribution to places where I am not sure if it is applicable ...
4
votes
1answer
168 views

A thermodynamic transformation that can be represented by a continuous quasistatic path in its state space may still be irreversible. Why?

A thermodynamic transformation that has a path (in its state space) that lies on the surface of its equation of state (e.g., $PV=NkT$) is always reversible (right?). However, if the path is a ...