The study of large systems through coarse graining microscopic descriptions, providing a more detailed understanding of thermodynamics.

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Discussions of the axioms of AQFT

The most recent discussion of what axioms one might drop from the Wightman axioms to allow the construction of realistic models that I'm aware of is Streater, Rep. Prog. Phys. 1975 38 771-846, "...
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3answers
2k views

What is the relationship between Maxwell–Boltzmann statistics and the grand canonical ensemble?

In the grand canonical ensemble one derives the expectation value $\langle \hat n_r\rangle^{\pm}$ for fermions and bosons of sort $r$: $$ \langle \hat n_r\rangle^{\pm} \ \propto \ \frac{1}{\mathrm{...
8
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1answer
316 views

Any open areas to work in non equilibrium thermodynamics for a Phd student? [closed]

I see that many papers written on fundamentals of thermodynamics(theory) nowadays are by some old professors somewhere(there may be exceptions). Most active young faculty don't seem to be seriously ...
8
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2answers
778 views

Spontaneous conversion of heat into work at negative temperatures

Consider a heavy macroscopic object moving in a gas. Friction causes its kinetic energy to be converted into heat. Thermodynamically, there is (effectively) no entropy associated with the kinetic ...
7
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2answers
374 views

Renyi entropy in physical systems

We know that the Shannon entropy $H(P)=- k_{\mathrm{B}}\sum_i p_i \ln p_i$ is mostly the entropy of the thermodynamic systems. Does the Renyi measure $H_{\alpha}(P)=\frac{1}{1-\alpha}\log \sum p_i^{\...
7
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1answer
396 views

What is the information geometry of 1D Ising model for a complex magnetic field?

Consider the one-dimensional Ising model with constant magnetic field and node-dependent interaction on a finite lattice, given by $$H(\sigma) = -\sum_{i = 1}^N J_i\sigma_i\sigma_{i + 1} - h\sum_{i = ...
7
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2answers
205 views

Why is chemical potential, μ=0 when calculating critical temperature of BECs?

How do we justify taking the chemical potential, $\mu$ as $0$ when calculating the critical temperature of Bose-Einstein Condensates (BECs)? I apologise as I do not how to use LaTeX, for if I did the ...
7
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3answers
4k views

What are the six degrees of freedom of the atoms in a solid?

A monoatomic ideal gas has heat capacity $C_v=1.5$ which comes from the three translational degrees of freedom. For solids at high temperature, $C_v=3$, implying six degrees of freedom. What are ...
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5answers
4k views

Is temperature in vacuum zero?

From Wikipedia entry on Kinetic Theory The temperature of an ideal monatomic gas is a measure of the average kinetic energy of its atoms. Now if I remove all the particles from the box shown ...
7
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1answer
252 views

Why are the eigenvalues of a linearized RG transformation real?

The RG transformation $R_\ell$ maps a set of coupling constants $[K]$ of a model Hamiltonian to a new set of coupling constants $[K']=R_\ell[K]$ of a coarse-grained model where the length scale is ...
6
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1answer
976 views

Why is it difficult to mix helium and nitrogen gases?

I recently learned an interesting fact: That it's difficult to mix helium and nitrogen gases in a compressed gas cylinder. Gas suppliers that need to mix the two gases have to rotate the cylinders for ...
6
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1answer
616 views

What's the most fundamental definition of temperature?

What's the most fundamental definition of temperature? Is it the definition concern about average energy, number of micro states, or what? By "fundamental", I mean "to be applied" in such general ...
6
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2answers
95 views

Understanding Gibbs $H$-theorem: where does Jaynes' “blurring” argument come from?

According to this Wikipedia article, the $H$-theorem was Boltzmann's attempt to demonstrate the irreversible increase in entropy in a closed system starting from reversible microscopic mechanics. ...
5
votes
1answer
112 views

Intuitively, why does removing solutes cost $k_B T$ of free energy per molecule?

I can calculate that if you want to, for example, desalinate water, you will have to pay a free energy cost of $k_B T$ for each ion you remove. In other words, removing an ion from a volume of water ...
5
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1answer
248 views

Calculate the entropy per atom in Bohmian Mechanics

Bohmian mechanics description of a large number of interacting atoms would require a large phase space due to the large number of classical degrees of freedom. The entropy per atom is given as the ...
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2answers
615 views

Physical significance of negative temperature

I read some answers regarding negative temperatures but I think my question is new. I want to know that what is the physical significance of negative temperature. Suppose I say a body has ...
4
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1answer
1k views

Chemical Potential of Ideal Fermi Gas

In Wikipedia's article on Fermi Gases, they have the following equation for the chemical potential: $$\mu = E_0 + E_F \left[ 1- \frac{\pi ^2}{12} \left(\frac{kT}{E_F}\right) ^2 - \frac{\pi^4}{80} \...
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3answers
1k views

Does entropy really always increase (or stay the same)? [duplicate]

Consider this image. If the big (grey) molecules were all to spontaneously move to the left, and the small ones were to move to the right, there would be an increase in order. While unlikely, wouldn'...
4
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1answer
141 views

What it means to integrate over $n$ variables out of $N$, where $N>n$?

I was reading Theory of Simple Liquids, when I came across BBGKY hierarchy. In deriving the expression for the hierarchy, they integrate an integration of N variables over N-n variables to make the ...
3
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1answer
682 views

Why the chemical potential of massless boson is zero? [duplicate]

In Bose-Einstein condensation, the chemical potential is less than the ground state energy of the system($\mu<\epsilon_g$). But why does the massless boson such as photon have zero chemichal ...
2
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2answers
9k views

Change in entropy adiabatic expansion

I think that an adiabatic expansion of a gas should cause the entropy to increase. On the other hand we have for adiabatic processes that $dQ = 0$ and therefore $dS= 0$, which is why I thought that ...
2
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3answers
153 views

Does the second law of thermodynamics take into consideration of attractive interactions between particles?

If one searches Google or textbooks on 2nd Law of Thermodnamics, one usually finds a statement that is either equivalent or implies the following. The entropy of the universe always increases. But ...
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3answers
2k views

Definition of Fluctuations and Perturbations

The terms fluctuations and perturbations are frequently used in physics with different meanings. But they are confusing. Both terms seems to be same. Is there any one who can explain lucidly these ...
2
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1answer
2k views

Significance of the the Lagrange multipliers in statistical mechanics

In classic thermodynamics one can derive the Maxwell Boltzmann statistics by solving a Lagrange multipliers equation. In this process a new parameter $\beta$ is introduced to take account of the total ...
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1answer
200 views

Uncertainty and Thermodynamics

Dilemma The uncertainty principle of energy and the 2nd law of thermodynamics don't add up : the uncertainty principle of energy says that $\Delta \tau \cdot \Delta E \ge \frac{h}{4\pi} = \frac{\...
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2answers
159 views

Calculating quantum partition functions

...By quantizing we the get the following Hamiltonian operator $$\hat{H}=\sum_{\mathbf{k}}\hbar \omega(\mathbf{k})\left(\hat{n}(\mathbf{k})+\frac{1}{2} \right)$$ where $\hat{n}(\mathbf{k})=\hat{...
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4answers
487 views

Irreversible expansion and time reversal symmetry

Suppose there are N non-interacting classical particles in a box, so their state can be described by the $\{\mathbf{x}_i(t), \mathbf{p}_i(t) \}$. If the particles are initially at the left of the box, ...
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1answer
827 views

Ensemble of harmonic oscillators

I have some problems with problem 2.3 from Reif's Fundamentals of statistical and thermal physics: Consider an ensemble of classical one-dimensional harmonic oscillators. a) If we assume ...
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2answers
257 views

Reconstruction of information stored in an evaporating black hole from the emission spectrum?

For simple setups, where the radiation field deviates not too far from thermodynamic equilibrium (< 10 %), corrections to the Planckian thermal emission spectrum can be calculated (and measured) ...
0
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1answer
83 views

Is Boltzmann constant $k_B$ constant?

I heard in a lecture that Boltzmann constant $k_B$ is not constant in some special cases. Do you know the title of the article which contains this one? Do you think this idea is true?
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2answers
71 views

Counting classical microstates

In my notes it states that the convention for summing over the classical states is $$\sum_{\Gamma} \longrightarrow \frac{1}{N!}\int \prod_{i=1}^N \frac{d^3q_id^3p_i}{h_0^3} \tag1$$ Now I know that ...
8
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2answers
175 views

Do gravitational waves have entropy?

We know, according the current understanding of black holes and General Relativity, as well as quantum fields in General Relativity, that black holes have an entropy proportional to the area of the ...
8
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3answers
840 views

Why must the particles of an ideal gas be point-like?

Why is a gas of elastically colliding hard balls of finite size not ideal? Respectively: Why is it essential that the particles of an ideal gas are point-like? Especially: Which ...
7
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1answer
181 views

Canonical averages in a Fermi gas aka generalized Fermi-Dirac distribution

I am in the process of applying Beenakker's tunneling master equation theory of quantum dots (with some generalizations) to some problems of non-adiabatic charge pumping. As a part of this work I ...
7
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4answers
621 views

Applying the Maxwell–Boltzmann statistics to astrophysical objects

Quoting Wikipedia: In statistical mechanics, Maxwell–Boltzmann statistics describes the statistical distribution of material particles over various energy states in thermal equilibrium, when the ...
6
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2answers
337 views

Mathematical probabilistic interepretation of probability amplitude

As a warning, I come from an "applied math" background with next to no knowledge of physics. That said, here's my question: I'm looking at the possibility of using probability amplitude functions to ...
6
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5answers
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Second law of Thermodynamics: Why is it only “almost” always true that entropy is non-decreasing? [duplicate]

Wikipedia - Second law of thermodynamics: ...the entropy of any closed system not in thermal equilibrium almost always increases. I understand that the second law of thermodynamics is based on ...
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3answers
6k views

Is there a phase transition between a gas and plasma?

Does a phase transition occur as a gas is heated to create a plasma? If so, is this a first or second order phase transition? Also, does the presence of a phase transition depend on the pressure or ...
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2answers
1k views

The analogy between temperature and imaginary time

There are many statements about the relation between time and temperature in statistical physics and quantum field theory, the basic idea is to interpret (inverse) temperature in statistics as "time" ...
5
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1answer
877 views

Intuition behind classical virial theorem

I am continuing to brush up my statistical physics. I just want to gain a better understanding. I have gone through the derivation of the classical virial theorem once more. I have thought about it, ...
5
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3answers
426 views

Physical intuition for independence of components of velocity in derivation of Maxwell–Boltzmann distribution

Maxwell derived the shape of the probability distribution of velocity of gas particles by starting with just two assumptions. These are: The probability distribution is rotation invariant. The ...
4
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1answer
1k views

quantum mechanics current operators

How to derive the charge current and the energy current operators in second quantized form in Quantum mechanics ? Also if you could comment in a similar way on the entropy current operator, that will ...
4
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2answers
490 views

Continuous phase transition only hold for infinite systems. Real systems are finite, hence, a paradox

Second-order or continuous transitions are usually identified with non-analyticies within the free energy (which is proportional to the logarithm of the sum of exponentials). Such singularities are ...
4
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1answer
345 views

Entropy is constant. How to express this equation in terms of pressure and density?

In hydrodynamics of an ideal, non-compressive flow we use 5 variables: pressure $p$, density $\rho$ and velocity field $\mathbf{v}$. So we need 5 equations. Landau's "Hydrodynamics" states that the ...
4
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4answers
545 views

Why can $\beta$ not be linearly proportional to $T$, that is $\beta = constant \times T$?

$\beta$ in statistical mechanics is equal to $\frac{1}{k_BT}$ in in thermodynamics, but I do not understand why $\beta\propto T^{-1}$ instead of, say, $\beta\propto T$?
4
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1answer
1k views

Calculating the heat capacity of a system

I have started reading Statistical Physics by F. Mandl and I would appreciate some help with the following exercise A system consists of $N$ weakly interacting subsystems. Each subsystem possesses ...
3
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3answers
191 views

Statistical Mechanics - Distribution of Energies

Consider a state space $\mathbb{X}$. The probability density function under a canonical ensemble is given by the Boltzmann distribution $$\pi_{\mathbb{X}}(x)=\frac{e^{-\beta E(x)}}{\mathbb{Z}(\beta)}$...
3
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1answer
154 views

Evaluating low-temperature dependence of the BCS gap function

How does one go about evaluating the behavior of the BCS gap $ \Delta = \Delta(T) $ for $ T \to 0^+ $ under the weak coupling approximation $ \Delta/\hbar\omega_D \ll 1 $? In Fetter & Walecka, ...
3
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1answer
1k views

Fermi-Dirac distribution derivation?

I am trying to derive the Fermi-Dirac statistics using density matrix formalism. I know that $$<A>= Tr \rho A.$$ So I started from $$<n(\epsilon_i)>= Tr \rho n(\epsilon_i)=\frac {1}{Z} ...
3
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2answers
1k views

RMS Free Path vs Mean Free Path

I am trying to determine the mathematical difference between mean free path and root-mean-square free path. For an ideal gas, the relaxation time is $$\tau=\frac{1}{\sqrt2 \pi nd^2 \bar v}$$ and the ...