The study of large systems through coarse graining microscopic descriptions, providing a more detailed understanding of thermodynamics.

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108 views

Randomly sampling a “well-mixed” solution of Brownian particles

I place $N$ Brownian particles in $V$ liters of solution, shake until I assume that the particles are "well-mixed", and sample and randomly sample an $S$ liter volume. What is the probability ...
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83 views

Factorization of fermionic scattering integral in 2d momentum rep

the scattering integrals for fermions involves both momentum ($k$) and energy ($k^2$) conservation and a nonlinear phase space factor of a distribution function $f(k)$. $$\begin{multline}I(k) = ...
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228 views

How is the “negative dispersion” derived?

I'm looking at Kopfermann H., Ladenburg R., Nature, 122, 338-339 (1928) and it appears Ladenburg in Ladenburg R., Z.Physik, 4, 451-468 (1921) was the first to discover the phenomenon of "negative ...
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20 views

What conditions are needed for Onsager reciprocal relations?

I often find a thorough discussion of the conditions that must hold for a theorem lacking, especially in the sense of what they actually mean physically. Could anyone write up what kind of systems ...
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33 views

Time evolution of a classical system

For a harmonic oscillator the Liouville operator is given by $$L = p \partial_q- q \partial_p.$$ Now I have a phase space distribution $f(t,q,p)$ for which it holds (in general) $$f(t+\tau,q,p)= ...
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37 views

Statistical physics Susskind lecture question? Proof of Boltzmann distribution

In lecture 3 of the following series by Susskind on statistical physics, at 36 minutes in he takes the following step and spends the next 5 minutes discussing it, \begin{equation} f(P_i)=-N\sum ...
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17 views

Statistical field theories on topological defects

Systems like superconductors and superfluids are often treated by specifying some phenomenological mean field theory where the free energy is given as a functional of some order parameter field. Given ...
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58 views

In the derivation of canonical distribution why does one linearize entropy (and not something else?)

I know that there are (at least) two ways to derive the canonical distribution. I am interested in the one where one considers the entropy of the reservoir (with which the system we are considering ...
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33 views

Thermal Equilibrium of two thin sheets

While reading Gibbs' Elementary Principles in Statistical Mechanics I came across this footnote: The most simple test of the equality of temperature of two bodies is that they remain in ...
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46 views

Quantum Monte Carlo for harmonic oscillator

I'm trying to calculate harmonic oscillator using quantum monte carlo (path integral and metropolis algorithm). It's one particle in harmonic potential. I know the theory. One divides the partition ...
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35 views

How to derive entropy transport equation from heat equation?

Suppose I have heat equation: $$ \rho (\partial_{t} + (u \cdot \nabla)) T = -\nabla \cdot \mathbf R, $$ where $\mathbf R$ - some vector and $T$ - temperature. How to get the equation for entropy $S$ ...
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70 views

How is partition function related to ordinary generating function?

Ordinary generating function can be used to solve combinatorial enumeration problems. Now if the energy levels are discrete, say $g_i$, and if one want to count how many ways one can add up $g_i$ ...
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54 views

Proving the Virial theorem

Consider the expectation in the canonical ensemble defined by $$\left\langle x_i\frac{\partial \mathcal{H}}{\partial x_j} \right\rangle=\frac{1}{Z}\int d\Gamma x_i\frac{\partial ...
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19 views

why can noise induce multistability, particularly in (bio)chemical systems

There are several instances that people claim that a system is monostable in a deterministic model, but when they consider stochastic models, from either master equations or Fokker-Planck equations, ...
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31 views

Time evolution of the density of phase points for an ensemble

I want to calculate the time evolution of the density of phase points for an ensemble of N harmonic oscillators. However, I intended to do so without using the Liouville equation. Sure, I want to ...
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32 views

Debye-Huekel Theory and the continuum approximation

This question stems from a problem I was doing on the Debye-Hueckel theory. It says that the continuum approximation which underlies the Debye-Hueckel theory is valid provided that $\lambda_D \gg ...
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45 views

grand-canonical ensemble

I was wondering if the following reasoning is correct for example for electrons in the classical or qm grand-canonical ensemble? Is it always valid in the grandcanonical ensemble to calculate the ...
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49 views

How to apply Wick's theorem in 2nd quantization for Spin Density Operators?

I am trying to work out a correlation function consisting of two spin density operators. Once I rewrite everything in 2nd quantized form, I am unsure of how to apply wicks theorem because the paul ...
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36 views

Books/resources for statistical field theory

I was wondering if anyone knows good, approachable textbook or other resources about statistical field theory (topics like in Kardar's Statistical physics of fields: lattice models, mean field theory, ...
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173 views

Confusing Chemical potential of mixtures

I feel that there are very few textbook that treat the chemical potential of mixtures in an understandable clear way, which is why I wanted to ask here about certain things? Although I do not have a ...
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24 views

Can a gas be modelled as a low density blackbody, if we want to consider how detectable it will be in space?

The answer to this question taught me about the sort of parameters I need to consider if I want to consider how "detectable" an object in space is. I want to consider the detectability of a ...
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0answers
47 views

Entropy Inequalities

Hey I am reading this paper Entropy Inequalities by Araki and Lieb. I am trying to prove the following lemma: $$S^1+S^2\leq S^{12}+S^{23}$$ using the following lemmas: ...
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50 views

How can energy be partitioned equally when energy is relative?

According to the Equipartition theorem in a system at equilibrium the energy should be on average be divided equally between the available degrees of freedom. The most common examples are the three ...
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33 views

Why is it inappropriate to calculate free energy change from end points alone?

In molecular dynamics, free energy changes are estimated using a variety of protocols to establish a path between the starting and ending states. The classic example is umbrella sampling in which a ...
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42 views

Brownian Ratchet Plausibility

Alright I'm going to throw whatever reputation I have on the line here. And yes this is a serious question. Apologies for the shoddy imagery. I had a couple ideas to get the Brownian Ratchet to ...
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50 views

Applying Statistical Mechanics to Formulate Corrosion (Rusting)

I wanted to try and take my current knowledge of statistical mechanics (first quarter undergraduate course completed, beginning researcher in far from equilibrium statistical mechanics, basic ...
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77 views

Interpretation of partition function and thermodynamic potential

So in the microcanonical ensemble the partition function $\Omega$ counts the number of microstates for a given $(NVE)$ configuaration and $S = k_B \ln (\Omega)$ is the entropy. The most likely state ...
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78 views

Chemical potential related with quantum and classical limit in ideal gas

For ideal gas we have chemical potential $\mu = \tau \ln \left(\frac{n}{n_Q}\right) $ where $n = N/V$ number density and $n_Q = \left(\frac{M\tau}{2\pi \hbar^2}\right)^{\frac{3}{2}} $ Note we call ...
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66 views

classical and quantum correlation functions

Quantum Field, quantum fluctuation even with no temperature In QFT, the correlation function $<0|\hat{\phi} (x)\hat{\phi} (y)|0>$ describes the fluctuation correlations of vacuum state ...
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89 views

Reduced phase space density

I have a dimensional problem with the single particle phase space density The partition function in the microcanonical ensemble is of course dimensionless Thus $$ \rho ( q, p ) = ...
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87 views

Meaning of phase space density

I am trying to understand Liouville's theorem physically. It says that $\frac{\partial \rho}{\partial t} + \{\rho,H\} = 0$. Thus, we have $\frac{d \rho(q(t),p(t),t)}{dt}=0$. I would like to ...
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17 views

Distribution and different ways of distribution

Is "the number of ways of of distributing $N$ things across a fixed set of energy levels the same as "the number of ways a particular distribution can be realised? My book seems to say that $W$ is ...
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39 views

Boltzmann factor predicts arbitrarily large numbers of electrons at high potential?

In deriving the Debye shielding length we are told that the Boltzmann factor for particles of charge $q$ is: $n_{q}=n_{0}\exp(-q\phi/kT)$ If we assume the potential $\phi$ is positive, then the ...
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41 views

Entropy of this system

We have a system with two energy states $E_0$< $E_1=0$. We also know that state $E_0$ can only take at most $m$ particles. Curently, there are $n<m$ particles in $E_0$. Now, I am supposed to ...
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71 views

What excactly is a “fourier component of a density fluctuation”?

Light scattering texts say depending on the scattering angle, you are seeing a certain fourier component of a density fluctuation. This density fluctuation varies sinusoidally due to Brownian motion ...
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145 views

What algorithms can be used to compute the binodal in a ternary Flory-Huggins theory?

What are the most popular algorithms used to obtain a binodal curve for the ternary mixture (starting from Flory-Huggins theory)? I would like to obtain a plot similar to the one calculated here ...
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144 views

Ergodic Hypothesis; canonical ensemble

I'm currently studying for an exam in thermodynamics/classic statistical mechanics and 2 things came up which are confusing me. First the ergodic hypothesis states that it is equal to take the mean ...
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33 views

Methods for quantifying a network of coupled oscillators

I usually am more on the statistics part of things, so pardon my misuse of the terminology. I am simulating a network of non-pulse coupled non-linear oscillators ( I am not sure what the correct term ...
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87 views

Diamagnetism of a degenerate electron gas for weak fields

In the book "Statistical Physics, Part I ($3^{{\rm rd}}$ edition)" by Landau and Lifshitz, at $\S59$ when he treats the diamagnetic part of the magnetisation of a degenerate electron gas for weak ...
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68 views

Free energy a continuous function of temperature but may not be differentiable everywhere?

So according to my understanding, the free energy of the system should be a continuous function of temperature. This is because if the free energy is not continuous at temperature T, then at this ...
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91 views

Effusion of particles from one box to another - pressure calculation

Suppose we have a container divided into equal halves. Right half is fixed at temperature $T$, volume $\frac{V}{2}$. Initially it has pressure $P_0$, a hole of area $A$ is opened between them. I ...
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110 views

Connection between String theory and Statistical Physics

I would like to think via standard transitivity arguments that there should be a deep connection between String theory and Statistical Physics. Why? Statistical Physics $\rightarrow$ QFT 2d QFT ...
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132 views

Calculating heat capacity from the equation of state

It is known that within thermodynamics alone, given the equation of the state of a system, one cannot explicitly determine the heat capacity. What is the mathematical reason for this? Intuitively, it ...
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84 views

Derivation of Higher-order correlation functions from definition

I'm trying to understand the definition of the n-th order correlation function. My aim is to translate the math into a numerical implementation in order to compute the correlation function $g^{(n)}$ ...
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16 views

Coarse-graining on a second channel decreases mutual information?

Let $X_1,B_1,X_2,B_2$ and $Y_1,A_1,Y_2,A_2$ and $C_1$ and $C_2$ be binary random variables. Suppose: $I(X_2:B_2|C_2=0)+I(Y_2:A_2|C_2=1) \leq 1$. This can be thought of as a bound on the capacity ...
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217 views

Fluctuations in energy for macro and micro canonical ensembles

I was thinking about fluctuations in energy for a system in thermal equilibrium. I think that the Boltzmann distribution itself has an standard deviation approximately equal to the mean, as it is ...
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140 views

Fluctuation-Dissipation theorems in an infinite quantum system

So for a quantum spin chain, one can easily prove via the partition function that you have a fluctuation-dissipation type relation between the magnetic susceptibility and the variance of the ...
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135 views

Understanding the product of partition functions by making sense of the maths and the physics

I have $N$ distinguishable particles in a 1D harmonic oscillator potential with 'proper' frequency $\omega$. The particles also have internal spin-$\frac12$ degrees of freedom in a magnetic field $B$ ...
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55 views

Condensate fraction and single-particle density matrix

In Bose–Einstein condensation (BEC), how to prove the largest eigenvalue of the single-particle density matrix $$\rho_{ij}=\frac{\langle\Psi|a_i^{\dagger}a_j|\Psi\rangle}{N}$$ is ...
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106 views

Ising model. What is large fluctuations of magnetization?

My background is in mathematics. I have studied the Ising model in $\mathbb{Z}^2$. The main model of statistical mechanics. Yesterday, I was reading the preliminary notes of the book Statistical ...