The study of large systems through coarse graining microscopic descriptions, providing a more detailed understanding of thermodynamics.

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Brownian Ratchet Plausibility

Alright I'm going to throw whatever reputation I have on the line here. And yes this is a serious question. Apologies for the shoddy imagery. I had a couple ideas to get the Brownian Ratchet to ...
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42 views

Applying Statistical Mechanics to Formulate Corrosion (Rusting)

I wanted to try and take my current knowledge of statistical mechanics (first quarter undergraduate course completed, beginning researcher in far from equilibrium statistical mechanics, basic ...
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66 views

Interpretation of partition function and thermodynamic potential

So in the microcanonical ensemble the partition function $\Omega$ counts the number of microstates for a given $(NVE)$ configuaration and $S = k_B \ln (\Omega)$ is the entropy. The most likely state ...
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48 views

Chemical potential related with quantum and classical limit in ideal gas

For ideal gas we have chemical potential $\mu = \tau \ln \left(\frac{n}{n_Q}\right) $ where $n = N/V$ number density and $n_Q = \left(\frac{M\tau}{2\pi \hbar^2}\right)^{\frac{3}{2}} $ Note we call ...
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42 views

classical and quantum correlation functions

Quantum Field, quantum fluctuation even with no temperature In QFT, the correlation function $<0|\hat{\phi} (x)\hat{\phi} (y)|0>$ describes the fluctuation correlations of vacuum state ...
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75 views

Bose Enhancement Factor

How may one explain the fact that the probability of a boson transferring to a state with an occupation number n is 'enhanced' by a factor of (1+n), compared to the classical case? (In the classical ...
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70 views

Reduced phase space density

I have a dimensional problem with the single particle phase space density The partition function in the microcanonical ensemble is of course dimensionless Thus $$ \rho ( q, p ) = ...
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61 views

Meaning of phase space density

I am trying to understand Liouville's theorem physically. It says that $\frac{\partial \rho}{\partial t} + \{\rho,H\} = 0$. Thus, we have $\frac{d \rho(q(t),p(t),t)}{dt}=0$. I would like to ...
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15 views

Distribution and different ways of distribution

Is "the number of ways of of distributing $N$ things across a fixed set of energy levels the same as "the number of ways a particular distribution can be realised? My book seems to say that $W$ is ...
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37 views

Boltzmann factor predicts arbitrarily large numbers of electrons at high potential?

In deriving the Debye shielding length we are told that the Boltzmann factor for particles of charge $q$ is: $n_{q}=n_{0}\exp(-q\phi/kT)$ If we assume the potential $\phi$ is positive, then the ...
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35 views

Entropy of this system

We have a system with two energy states $E_0$< $E_1=0$. We also know that state $E_0$ can only take at most $m$ particles. Curently, there are $n<m$ particles in $E_0$. Now, I am supposed to ...
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27 views

When would the Gross-Pitaevskii equation break down as $a\rightarrow \infty$?

It is now common to use Feshbach resonance to tune the s-wave scattering length of a Bose-Einstein condensate. Apparently as $a\rightarrow \infty$, the GPE would break down. The reason is that it ...
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84 views

ensembles and lagrange multipliers

In the derivation of maxwell-boltzmann distributions, the method of Lagrange multiplier is $\sum n_i = N$ $\sum n_i E_i = E$ where $N$ is the total number of particles, and $E$ is the total ...
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63 views

What excactly is a “fourier component of a density fluctuation”?

Light scattering texts say depending on the scattering angle, you are seeing a certain fourier component of a density fluctuation. This density fluctuation varies sinusoidally due to Brownian motion ...
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107 views

What algorithms can be used to compute the binodal in a ternary Flory-Huggins theory?

What are the most popular algorithms used to obtain a binodal curve for the ternary mixture (starting from Flory-Huggins theory)? I would like to obtain a plot similar to the one calculated here ...
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107 views

Ergodic Hypothesis; canonical ensemble

I'm currently studying for an exam in thermodynamics/classic statistical mechanics and 2 things came up which are confusing me. First the ergodic hypothesis states that it is equal to take the mean ...
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30 views

Methods for quantifying a network of coupled oscillators

I usually am more on the statistics part of things, so pardon my misuse of the terminology. I am simulating a network of non-pulse coupled non-linear oscillators ( I am not sure what the correct term ...
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83 views

Diamagnetism of a degenerate electron gas for weak fields

In the book "Statistical Physics, Part I ($3^{{\rm rd}}$ edition)" by Landau and Lifshitz, at $\S59$ when he treats the diamagnetic part of the magnetisation of a degenerate electron gas for weak ...
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55 views

Free energy a continuous function of temperature but may not be differentiable everywhere?

So according to my understanding, the free energy of the system should be a continuous function of temperature. This is because if the free energy is not continuous at temperature T, then at this ...
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68 views

Effusion of particles from one box to another - pressure calculation

Suppose we have a container divided into equal halves. Right half is fixed at temperature $T$, volume $\frac{V}{2}$. Initially it has pressure $P_0$, a hole of area $A$ is opened between them. I ...
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97 views

Connection between String theory and Statistical Physics

I would like to think via standard transitivity arguments that there should be a deep connection between String theory and Statistical Physics. Why? Statistical Physics $\rightarrow$ QFT 2d QFT ...
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111 views

Calculating heat capacity from the equation of state

It is known that within thermodynamics alone, given the equation of the state of a system, one cannot explicitly determine the heat capacity. What is the mathematical reason for this? Intuitively, it ...
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72 views

Derivation of Higher-order correlation functions from definition

I'm trying to understand the definition of the n-th order correlation function. My aim is to translate the math into a numerical implementation in order to compute the correlation function $g^{(n)}$ ...
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15 views

Coarse-graining on a second channel decreases mutual information?

Let $X_1,B_1,X_2,B_2$ and $Y_1,A_1,Y_2,A_2$ and $C_1$ and $C_2$ be binary random variables. Suppose: $I(X_2:B_2|C_2=0)+I(Y_2:A_2|C_2=1) \leq 1$. This can be thought of as a bound on the capacity ...
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177 views

Fluctuations in energy for macro and micro canonical ensembles

I was thinking about fluctuations in energy for a system in thermal equilibrium. I think that the Boltzmann distribution itself has an standard deviation approximately equal to the mean, as it is ...
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88 views

Fluctuation-Dissipation theorems in an infinite quantum system

So for a quantum spin chain, one can easily prove via the partition function that you have a fluctuation-dissipation type relation between the magnetic susceptibility and the variance of the ...
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122 views

Understanding the product of partition functions by making sense of the maths and the physics

I have $N$ distinguishable particles in a 1D harmonic oscillator potential with 'proper' frequency $\omega$. The particles also have internal spin-$\frac12$ degrees of freedom in a magnetic field $B$ ...
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49 views

Condensate fraction and single-particle density matrix

In Bose–Einstein condensation (BEC), how to prove the largest eigenvalue of the single-particle density matrix $$\rho_{ij}=\frac{\langle\Psi|a_i^{\dagger}a_j|\Psi\rangle}{N}$$ is ...
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95 views

Ising model. What is large fluctuations of magnetization?

My background is in mathematics. I have studied the Ising model in $\mathbb{Z}^2$. The main model of statistical mechanics. Yesterday, I was reading the preliminary notes of the book Statistical ...
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72 views

Is it possible to define a notion of temperature in a microcanonical ensemble?

I am thinking of a mircrocanonical ensemble as a finite system for which the number of particles, volume and the total energy is fixed. Is there a more refined view of this? Can I think of ...
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182 views

Boltzmann distribution: derivation from canonical distribution

I'm trying to understand the Maxwell-Boltzman Distribution, and in particular the derivation from the boltzman distribution for energy. I have successfully created an incorrect derivation, but I'm not ...
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59 views

What is conductivity?

I read that if we have spin $\frac{1}{2}$-particle, where a magetic force acts on, then the force is given by a drift speed times a conductivity. This conductivity is determined to be $\frac{kT}{D}$, ...
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111 views

Fugacity of the fermi gas

It can be shown that in the high temperature exploration of the Fermi gas, the Fermi function may be expanded to second order in $e^{\beta \mu}$, where $\beta = 1/kT$ and $\mu$ is the chemical ...
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28 views

Can the short-time dynamics of an open quantum system be approximately unitary?

Considering the physics of an open quantum system described by a Hamiltonian $H=H_S+H_E+H_{SE}$, where the subscript $S$ refers to the system of interest, $E$ to the environment and $SE$ to the ...
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158 views

The Maxwell and the Boltzmann distributions

I am trying to understand where the Boltzmann distribution comes from. I recently learned some interesting things of which my interpretation follows below. Did I interpret correctly? If so, is this ...
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77 views

Langevin equation

A molecule consists of two atoms whose centers are located at $\mathbf{r}_1$ and $\mathbf{r}_2$ respectively. The atoms are connected by a bond that can be approximated by a harmonic spring, so that ...
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84 views

How does the Lennard Jones Potential changes for interaction between particles of different sizes?

I am interested in incorporating a Lennard-Jones potential in a simulation. When the interaction only involves the same type of particle, with same characteristics, we can use reduced units, scaling ...
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212 views

Free Energy of N Spin 3/2 Particles

This question is from the book "Introductory Statistical Mechanics" by Bowley and Sanchez. The question is as follows: Calculate the free energy of a system with N particles, each with spin 3/2 with ...
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52 views

Find out ground sates for large 2D classical spin model

Reaching the ground state of a large 2D classical spin model (e.g. classical Heisenberg model) might be a relatively difficult task while using conventional "flip/reject" Monte Carlo method. The ...
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167 views

Average number of spin up particles

In a paramagnetic system, where $N = N_\uparrow + N_\downarrow$ is fixed, how does one calculate the average number of spin-up particles $\langle N_\uparrow \rangle$? You can assume we have the ...
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36 views

Ergodicity Breaking in Supercooled Liquids

What is a ergodic system? What is Onset temperature of ergodicity breaking in super cooled liquids when we go towards lower temperature?
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72 views

Is there a systematic way to determine the relevant variables needed to describe a nonequilibrium system?

In strong nonequilirium, the statistical operator describing the system depends on an infinite number of variables (BBGKY-hierarchy), contains information about all the previous states starting from ...
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222 views

Peierls Argument for Absence of Long Range Order

I'm really confused about the argument in Cardy's book for why there can't be long range order in 1D for discrete models. Let me just copy it out, and hopefully someone can explain it to me. He ...
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113 views

Traditional Transfer Matrix on the Potts model — how it grows for strip lattices?

What is the transfer matrix size for a strip lattice of width $n$ vertices, with arbitrary $q$?? I am not sure if it is $q^n$ x $q^n$ or something else. Any reference is also welcome.
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191 views

Maxwell-Boltzmann distribution

The short story is, that I have to calculate some transport coefficients, but using the the MB distribution as my distribution function. What I currently need to solve is: ${{\mathcal{L}}^{\,\left( ...
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173 views

Maxwell-Boltzmann distribution for transport equations

I have to calculate the transport coefficients for the Maxwell-Boltzmann distribution. But I'm not sure what distribution I have to use. As far as I know it should not be the MB distribution for ...
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34 views

Is there anything to prevent paired-up neutrons from a complete overlap

The reason "neutrons don't overlap", as DarenW explained it, has to do with intricate forces at play that take into account the spins, iso-spins and symmetry of the wavefunctions. However, assume I ...
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410 views

Rotational Constant and Moment of Inertia of Fluorine gas

I have come across some homework question on thermodynamics which needs me to calculate $B$ of $F_2$ My attempt: $B= \frac{h}{8\pi^2cI}$ where $I=\mu r^2=\frac{m_1m_2}{m_1+m_2} r^2$ Atomic mass of ...
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76 views

Partition function for multidimensional scaling energy

Let $D_{ij}$ a random matrix with i.i.d positive coefficients. One can take for instance $D_{ij}$ uniformly distributed in [0,1]. We consider the following energy function $H(x)$ defined for ...
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106 views

Statistical Mechanic

One can define entropy as $$S=k\log{\omega(E)},$$ where $\omega(E)$ is the numbers of states with energy equal $E$; and the canonical partition function for a set of N particles is defined ...