# Tagged Questions

The study of large systems through coarse graining microscopic descriptions, providing a more detailed understanding of thermodynamics.

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### Entropy increase vs Conservation of information (QM)

Unitarity of quantum mechanics prohibits information destruction. On the other hand, the second law of thermodynamics claims entropy to be increasing. If entropy is to be thought of as a measure of ...
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### Ergodicity of the Drude model

The Drude model of electric conduction in solids deals with independent free electrons subject to random collisions with the crystal lattice (the direction where the electrons are scattered after a ...
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### How does that Boltzmann distribution interact with entropy?

In an ideal gas, the Boltzmann distribution predicts a distribution of particle energies $E_i$ proportional to $ge^{-E_i/k_bT}$. But, doesn't entropy dictate that the system will always progress ...
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### Logical understanding of the canonical probability distribution (canonical ensemble) [duplicate]

I am having problems in understanding the logic of this distribution: $P(\Psi_{j})=\displaystyle\frac{e^{-E_{j}/kT}}{\displaystyle\sum_{j'}e^{-E_{j'}/kT}}$ The book I am studying use the case of a ...
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### Practical difference between canonical and grand canonical ensembles

I'm currently doing some calculations which require evaluating various standard thermal expectation values in the canonical ensemble (both bosons and fermions). Now, in order to make my theoretical ...
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### Grand canonical ensemble with interaction, simulation doubts

First of all, this is a follow-up of my first question. The idea is the same, every state would consist of some particles in a line (with an energy associated) and the particles can not be nearer than ...
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### Definition of phase transitions in statistical mechanics

Phase transitions in statistical mechanics are usually taught by working through a bunch of examples. I decided to try and think about them from a more "fundamental" point of view - but I've run into ...
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### What is off-diagonal long range order in superfluid?

From Wikipedia: [...]Off-diagonal long-range order (ODLRO) [...] exists whenever there is a macroscopically large factored component (eigenvalue) in a reduced density matrix of any order. How to ...
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### Rate of effusion in kinetic molecular theory?

According to the kinetic molecular theory obeying Maxwell-Boltzmann distribution of speeds, the rate of effusion through a pinhole of area $A$ is $$R=\frac{PA}{\sqrt{2\pi M R T}}$$ where $M$ is the ...
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### detailed balance in the context of the ising model

I am having a very basic problem understanding the idea of detailed balance, particularly in the context of the Ising model. Most references I have found contain the following phrase: "In equilibrium,...
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### Can the correlation for the Potts model be bounded?

I am studying a $d$-state Potts model. A configuration $\sigma$, which assigns for each $x\in \mathbb{Z}^2$ a value $\sigma(x)\in [1,2,\ldots,d]$, with the probability on a finite lattice defined as ...
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### Any open areas to work in non equilibrium thermodynamics for a Phd student? [closed]

I see that many papers written on fundamentals of thermodynamics(theory) nowadays are by some old professors somewhere(there may be exceptions). Most active young faculty don't seem to be seriously ...
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### Is “detailed balance” equivalent with a continuity equation in state space?

I have a talk tomorrow in which detailed balance is needed and I don't want to bore my audience with elaborate explanations for it so I'm looking for simpler explanations. As far as I understood it ...
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### Research on ground state configuration of Ising model

I want to do mathematical research (algorithm construction and mathematical analysis) on Ising model ground state configuration. From what I know, the state of art research is using graph theory ...
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### Entropy as an arrow of time

From what I understand, entropy is a concept defined by the experimentalist due to his ignorance of the exact microstate of a system. To say the number of accessible microstates $W$ of the universe is ...
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### Casimir effect as an entropic force

When I first learned about the depletion interaction, my initial reaction was that it looks very similar to the Casimir effect. On making this remark to the professor, he replied somewhat mystically: "...
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### Calculating the ideal mixing entropy using Gibbs' entropy formula

Two distinguishable gases are in separate volumes $xV$ and $(1-x)V$ $(x\in [0,1])$ respectively, and the number of particles on each side is $xN$ and $(1-x)N$ respectively. The volumes are separated ...
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### Boltzmann distribution with interaction between particles?

First of all, I would like to apologize in advance if I make stupid mistakes. I am a mathematician and I am trying to apply the Boltzmann distribution to places where I am not sure if it is applicable ...
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### A thermodynamic transformation that can be represented by a continuous quasistatic path in its state space may still be irreversible. Why?

A thermodynamic transformation that has a path (in its state space) that lies on the surface of its equation of state (e.g., $PV=NkT$) is always reversible (right?). However, if the path is a ...
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### Should entropy have units and temperature in terms of energy? [duplicate]

I've been thinking about entropy for a while and why it is a confusing concept and many references are filled with varying descriptions of something that is a statistical probability (arrows of time, ...
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### Must a reversible engine be a carnot engine?

I have this homework question: "Show that any reversible engine operating between T1 and T2 is a carnot engine." I think I have a solution, but it feels very hand-wavy. We know that any process that ...
Because for many particles the distribution $\varrho\sim\mathrm e^{-\beta\ H}$ has an extremely sharp maximum, the expectation values of the canonical ensemble agrees with that of the microcanonical ...