The study of large systems through coarse graining microscopic descriptions, providing a more detailed understanding of thermodynamics.

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3answers
356 views

Results of Statistical Mechanics first obtained by formal mathematical methods

I have a question that seems natural in Physics and Mathematics mainly in Statistical Mechanics of Equilibrium. Results that are proven by formal mathematical methods that were already seem intuitive ...
0
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0answers
225 views

Ground and first excited state of non interacting spin system Hamiltonian

For a non interacting spin system containing two $\frac{1}{2}$ spin particles I am trying to determine its Hamiltonian. If the energy of a up spin is $+\mu {\bf B}$ and a down spin is $-\mu {\bf B}$, ...
0
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1answer
421 views

Ground states of the Hamiltonian of a two spin system

For the spin system shown in this graph (http://i.stack.imgur.com/3lg1R.png), the Hamiltonian is $$S^{(1)}_z\cdot S^{(1)}_z=\frac{1}{4}\begin{pmatrix} 1 & 0 &0 &0 \\ 0&-1 &0 ...
2
votes
1answer
150 views

Eigenvalues of a mean correlation matrix (integral over correlation matrices with arbitrary density)

Consider a stationary dynamic system with state $s(t)$ and correlation structure described by $C_{ij}(\tau)=\mathbb{E}[(s_i(t+\tau)-\bar{s_i})(s_j(t)-\bar{s_j})]$. Given an arbitrary density function ...
0
votes
1answer
622 views

Pure state - density matrix - real life example of boxes in warehouse

So if there are a billion boxes in a warehouse, I would like to know conceptually how to tell if it is in a pure state. I know that if it is in a pure state (not mixed) that the density matrix has ...
1
vote
2answers
7k views

The number of degrees of freedom of a monatomic gas

Suppose that I have a monatomic gas sample consisting of $N$ atoms (e.g., $N$ argon atoms); thus there are no vibrations or rotations. How many degrees of freedom does the system have? Does the ...
1
vote
1answer
138 views

Hamiltonian of a simple graph

I have a spin system: As shown in the picture, there are two spins S1 and S2, and a pair of interactions between them. One is a ferromagnetic interaction and the other is anti ferromagnetic ...
2
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0answers
249 views

Spontaneous symmetry breaking in the quantum 1D XX model?

The ground states of the quantum 1D Ising and Heisenberg models exhibit spontaneous magnetization. Is this also true for the 1D XX model?
2
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2answers
2k views

Absolute zero and Heisenberg uncertainty principle

I got to read Feynman vol I and there was written that at absolute zero, molecular motion doesn't cease at all, because if so happens, we will be able to make precise determination of position and ...
2
votes
1answer
2k views

Significance of the the Lagrange multipliers in statistical mechanics

In classic thermodynamics one can derive the Maxwell Boltzmann statistics by solving a Lagrange multipliers equation. In this process a new parameter $\beta$ is introduced to take account of the total ...
2
votes
3answers
1k views

Why the temperature is getting lower when the universe is expanding

As we know, if an ideal gas expands in vacuum, as its energy is unchanged, the temperature remains the same. An ideal gas's energy does not depend on volume. In general, the energy is $kT$ times the ...
2
votes
1answer
168 views

Reaction coordinate as a function of atomic positions

I'm going over some (molecular dynamics) related literature - specifically the derivation of the Weighted Histogram Analysis Method (WHAM). As a quick backdrop WHAM is a method for stitching ...
4
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1answer
322 views

Classical blackbody radiation 'solution'

I never understood how the equipartition theorem was applied electromagnetic waves inside the metallic blackbody. As hyperphysics puts it ...
6
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2answers
1k views

Is there a formal definition of a macroscopic variable in statistical mechanics?

Intuitively it's easy to accept that the usual variables like temperature, internal energy, etc. are 'macroscopic', but does there exist a formal definition of a macroscopic variable? In other ...
4
votes
2answers
469 views

Renormalization Group and Ising with d=1 and D=1 [closed]

I have a question about the results of RG on Ising model. I know it's possible to obtain two couple of relations $K'(K)$, $q(K')$ $K(K')$, $q(K)$ between the coupling costants. My problem arise ...
3
votes
2answers
930 views

Canonical partition of a boson gas

I have a 1D gas made of $N$ particles placed in a harmonic potential well, so the Hamiltonian is: $$ \mathcal H = \sum_{j=1}^N \left ( \frac{p_j^2}{2m} + \frac{1}{2}m\omega^2 x_j^2 \right )$$ The ...
1
vote
0answers
81 views

Partition function for multidimensional scaling energy

Let $D_{ij}$ a random matrix with i.i.d positive coefficients. One can take for instance $D_{ij}$ uniformly distributed in [0,1]. We consider the following energy function $H(x)$ defined for ...
7
votes
0answers
357 views

Is the “particle number” of “electrons” well defined in Wen's string-net theory of elementary particles?

According to professor Wen's string-net theory, electrons can be viewed as the elementary excitations of string-net objects. Just like the phonons and magnons are the elementary excitations of ...
6
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0answers
250 views

Drawing the RG flow diagram

In real-space renormalization group how does one find the complete RG flow exactly, (not schematically)? I understand it needs to be done on a computer. For example, I have the ising model on a ...
3
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0answers
78 views

Question about the derivation of an equation in full replica symmetry breaking solution

Using replica method and saddle point method, the free energy of a magnetic system can be expressed as $$-\beta[f]=\lim_{n\to0}\{\frac{-\beta^2J^2}{4n}\sum_{a\ne b}q_{\alpha\beta}^2-\frac{\beta ...
6
votes
1answer
3k views

The definition of Density of States

The density of states (DOS) is generally defined as $D(E)=\frac{d\Omega(E)}{dE}$, where $\Omega(E)$ is the number of states. But why DOS can also be defined using delta function, as ...
2
votes
2answers
1k views

Why is there a Global Minimum for the Morse Potential?

For Diatomic molecules, the Morse potential describes their potential energy as a function of separation distance between the two particles. My question is, what is the explanation of of the dip ...
2
votes
3answers
2k views

Why do we need different ensembles in statistical mechanics?

Why do we study these different ensembles, microcanonical, canonical, grand canonical ensemble ? Are they used for studying different physical system or scenarios?(e.g. in some system you can only ...
2
votes
1answer
228 views

How can dQ/T be interpreted as a system's level of disorder?

Long before statistical mechanics, entropy was introduced as: $dS = \frac{dQ}{T}$ At the time when entropy was introduced in this manner, was it known that entropy represents how "disordered" a ...
2
votes
1answer
646 views

Why is the free energy minimized by the Boltzmann distribution?

Can someone show me, without glossing over anything, why $F = E - TS$ is minimized when $p_i = e^{-U_i/k_bT}/\sum_ie^{-U_i/k_bT}$? I understand it conceptually, but am having difficulty showing it ...
2
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0answers
110 views

Spin Glass Transitions in Random Bond Ising Model (RBIM)

In brief, is there a list of spin glass transition properties for the RBIM on different lattices? Is there any know results about the relationships between these probabilities for a graph and its ...
2
votes
1answer
599 views

Maxwell-Boltzmann velocity PDF to CDF [closed]

I asked on Math.SE and was advised to try here instead. I need to draw from a Maxwell-Boltzmann velocity distribution to initialise a molecular dynamics simulation. I have the PDF but I'm having ...
2
votes
1answer
506 views

ultrarelativistic gas

Consider the ideal ultrarelativistic gas Hamiltonian $\mathbf{H = }\sum_{i = 1}^N \mathbf{c |\vec{p_{i}}|}$, now if we let molecules to interact with a potential term like $\mathbf{d|\vec{q_{i}}|}$; ...
15
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4answers
419 views

Comments on entropy and the direction of time in Landau and Lifshitz's Statistical Mechanics

In Landau and Lifshitz's Stat Mech Volume I is the comment: However, despite this symmetry, quantum mechanics does in fact involve an important non-equivalence of the two directions of time. ...
0
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2answers
2k views

Molecular Dynamics (MD) Simulation: energy fluctuations in NVE ensemble

I'm writing my first MD simulation (ever) for liquid Argon. The code is up and running. I am supposed to do the calculations in the NVE ensemble. Having implemented a 4th order symplectic integrator ...
0
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0answers
146 views

Number of microstates of discretized paths

Let us consider a square grid, which has been rotated by 45deg. On this grid we define a path, the directed polymer, which starts at the origin ($t = 0$) and extends in the positive $t$-direction ...
2
votes
1answer
1k views

Deriving the Sommerfeld expansion by contour integration (Le Bellac p. 277)

In Le Bellac's statistical physics book he derives the Sommerfeld expansion by a contour integral. The idea is to expand integrals of the type $I(\beta)\equiv \int_{0}^{\infty}d\epsilon\, ...
0
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2answers
517 views

How to compute configurations (entropy) of a system?

If we have a system $X$ consisting of subsystems $X_1$ and $X_2$. We also know that $X_1$ and $X_2$ have eigenstates $H_1 = 1 \times 10^{20}$ and $H_2 = 1 \times 10 ^{22}$. Can we calculate the ...
5
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0answers
110 views

Exact Beta Functions in Statistical Mechanics

I'm looking for analytically solvable models in statistical mechanics (classical or quantum) or related areas such as solid state physics in which the beta function for a certain renormalization ...
1
vote
1answer
419 views

relation between first law of thermodynamics and statistical mechanics definition of entropy

From the definition of entropy as $S= - Tr (\rho\, ln \rho)$ one obtains that $S = \frac{\langle E \rangle}{T} + \log Z.$ The first law of thermodynamics has $dS = {dE \over T}$. Why is there no ...
5
votes
2answers
515 views

Any example of lower symmetry in high temperature phase than the low temperature phase?

All the phase transition cases I came across so far have this property: the lower temperature phase has lower symmetry than the higher temperature one. But it is nowhere explicitly said that, lower ...
2
votes
1answer
91 views

What is the physical meaning of this simplification to calculate the effective coupling constants for a Gaussian model with quartic interactions?

To calculate the effective coupling constants $u'_2(q)$ and $u'_4(q)$ of the effective Hamiltinian eq (4.9) of this paper $$ H' = -\frac{1}{2}\int\limits_q u'_2(q)\sigma'_q\sigma'_{-q} - ...
1
vote
0answers
113 views

Statistical Mechanic

One can define entropy as $$S=k\log{\omega(E)},$$ where $\omega(E)$ is the numbers of states with energy equal $E$; and the canonical partition function for a set of N particles is defined ...
4
votes
3answers
462 views

Partition function of a gas of $N$ identical classical particles

Partition function of a gas of $N$ identical classical particles is given by $$ Z~=~\frac {1}{N! h^{3N}} \int \exp[-\beta H(p_1.......p_n, x_1....x_n)]d^3p_1...d^3p_n,d^3x_1...d^3x_n $$ in this ...
2
votes
0answers
188 views

Semiflexible discrete polymer chain

Suppose we have a 2D polymer model described by a set of 2D vectors {$\mathbf{t}_i$} ($i=1,2,\dots N$) of length $a$. The energy of the polymer is given by: $$ ...
11
votes
1answer
836 views

Why is (von Neumann) entropy maximized for an ensemble in thermal equilibrium?

Consider a quantum system in thermal equilibrium with a heat bath. In determining the density operator of the system, the usual procedure is to maximize the von Neumann entropy subject to the ...
0
votes
1answer
105 views

Indicators on how even the heat is distributed?

I'm wondering if there are any good indicators on how even the heat is distributed on an object (for simplicity, a flat object maybe)? What are the possibly reasonable ways to maximize the evenness if ...
4
votes
4answers
11k views

For an isolated system, can the entropy decrease or increase?

In any sizable system, the number of equilibrium states are much, much greater then the number of non-equilibrium states. Since each accessible micro state is equally probably, it is overwhelmingly ...
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vote
2answers
3k views

Why should the Fermi level of a n-doped semiconductor be below the one of a p-doped?

In a pn-junction, the difference in Fermi level between the p doped and the n doped regions causes the apparition of a built-in electric field at equilibrium. This electric field goes from the n to ...
1
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2answers
2k views

Constant pressure and temperature mixing of 2 different ideal gases - possible work and heat?

A simple question I hope... Initially, have two separate containers of 2 different ideal gases, 1.) N1, P, T, V1 and 2.) N2, P, T, V2. After mixing, the pressure and temperature are still P and T, ...
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3answers
3k views

Partition function for quantum harmonic oscillator

Hi guys I'm currently trying to solve a mock exam for an exam in a few days and am a bit confused by the solutions they gave us for this exercise: Exercise: A solid is composed of N atoms which ...
3
votes
1answer
260 views

Nonpertubative renormalization in quantum field theory versus statistical physics

I am trying to work my head around how renormalization works for quantum field theory. Most treatments cover perturbative renormalization theory and I am fine with this approach. But it is not the ...
6
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3answers
913 views

What are the differences between indistinguishable and identical?

What is the difference between indistinguishable particles and identical particles?
7
votes
1answer
1k views

Postulate of a-priori probabilities

In Statistical Mechanics, we often postulate that for an isolated system, the phase-space density of all accessible microstates (i.e all microstates consistent with the energy) is the same. This is ...
2
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0answers
89 views

Stat mech explanation for separation of one liquid from another in gravity?

If one mixes two distinct ideal gases above the Earth's surface, one with a higher molecular mass than the other, then at equilibrium, their number density gradients will be such that at low heights, ...