# Tagged Questions

The study of large systems through coarse graining microscopic descriptions, providing a more detailed understanding of thermodynamics.

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### Definition of phase transitions in statistical mechanics

Phase transitions in statistical mechanics are usually taught by working through a bunch of examples. I decided to try and think about them from a more "fundamental" point of view - but I've run into ...
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### What is off-diagonal long range order in superfluid?

From Wikipedia: [...]Off-diagonal long-range order (ODLRO) [...] exists whenever there is a macroscopically large factored component (eigenvalue) in a reduced density matrix of any order. How to ...
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### Rate of effusion in kinetic molecular theory?

According to the kinetic molecular theory obeying Maxwell-Boltzmann distribution of speeds, the rate of effusion through a pinhole of area $A$ is $$R=\frac{PA}{\sqrt{2\pi M R T}}$$ where $M$ is the ...
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### detailed balance in the context of the ising model

I am having a very basic problem understanding the idea of detailed balance, particularly in the context of the Ising model. Most references I have found contain the following phrase: "In ...
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### Can the correlation for the Potts model be bounded?

I am studying a $d$-state Potts model. A configuration $\sigma$, which assigns for each $x\in \mathbb{Z}^2$ a value $\sigma(x)\in [1,2,\ldots,d]$, with the probability on a finite lattice defined as ...
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### Any open areas to work in non equilibrium thermodynamics for a Phd student? [closed]

I see that many papers written on fundamentals of thermodynamics(theory) nowadays are by some old professors somewhere(there may be exceptions). Most active young faculty don't seem to be seriously ...
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### Is “detailed balance” equivalent with a continuity equation in state space?

I have a talk tomorrow in which detailed balance is needed and I don't want to bore my audience with elaborate explanations for it so I'm looking for simpler explanations. As far as I understood it ...
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### Research on ground state configuration of Ising model

I want to do mathematical research (algorithm construction and mathematical analysis) on Ising model ground state configuration. From what I know, the state of art research is using graph theory ...
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### Entropy as an arrow of time

From what I understand, entropy is a concept defined by the experimentalist due to his ignorance of the exact microstate of a system. To say the number of accessible microstates $W$ of the universe is ...
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### Casimir effect as an entropic force

When I first learned about the depletion interaction, my initial reaction was that it looks very similar to the Casimir effect. On making this remark to the professor, he replied somewhat mystically: ...
1k views

### Calculating the ideal mixing entropy using Gibbs' entropy formula

Two distinguishable gases are in separate volumes $xV$ and $(1-x)V$ $(x\in [0,1])$ respectively, and the number of particles on each side is $xN$ and $(1-x)N$ respectively. The volumes are separated ...
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### Boltzmann distribution with interaction between particles?

First of all, I would like to apologize in advance if I make stupid mistakes. I am a mathematician and I am trying to apply the Boltzmann distribution to places where I am not sure if it is applicable ...
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### A thermodynamic transformation that can be represented by a continuous quasistatic path in its state space may still be irreversible. Why?

A thermodynamic transformation that has a path (in its state space) that lies on the surface of its equation of state (e.g., $PV=NkT$) is always reversible (right?). However, if the path is a ...
1k views

### Should entropy have units and temperature in terms of energy? [duplicate]

I've been thinking about entropy for a while and why it is a confusing concept and many references are filled with varying descriptions of something that is a statistical probability (arrows of time, ...
1k views

### Must a reversible engine be a carnot engine?

I have this homework question: "Show that any reversible engine operating between T1 and T2 is a carnot engine." I think I have a solution, but it feels very hand-wavy. We know that any process that ...
679 views

### What is the energy of a standing EM wave? Is it probabilistic?

In a cavity, the standing wave will constructively interfere with itself, so its energy gets higher while the oscillator is still vibrating. Since the vibration time is not a constant value, and ...
76 views

### Can a distribution with sharper energy maximum than the exp-function give an equivalent theory?

Because for many particles the distribution $\varrho\sim\mathrm e^{-\beta\ H}$ has an extremely sharp maximum, the expectation values of the canonical ensemble agrees with that of the microcanonical ...