The study of large systems through coarse graining microscopic descriptions, providing a more detailed understanding of thermodynamics.

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2answers
102 views

Nontrivial critical exponents in exactly solvable models?

Are there any exactly solvable models in statistical mechanics that are known to have critical exponents different from those in mean-field theory, apart from the two-dimensional Ising model? I wonder ...
4
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0answers
121 views

Wilson's Renormalization Group and Lie's Third Theorem

If you think of a one-parameter group of transformations along a curve in the plane as a (Lie) group, and the tangent vector to the curve as a generator of the curve we can intuitively understand ...
1
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0answers
256 views

Calculating heat capacity from the equation of state

It is known that within thermodynamics alone, given the equation of the state of a system, one cannot explicitly determine the heat capacity. What is the mathematical reason for this? Intuitively, it ...
1
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0answers
121 views

Derivation of Higher-order correlation functions from definition

I'm trying to understand the definition of the n-th order correlation function. My aim is to translate the math into a numerical implementation in order to compute the correlation function $g^{(n)}$ ...
1
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1answer
69 views

Calculation of the differential of the entropy

In this review (for those who wants a precise reference see page 8 eq 21), the Author says that: \begin{equation*} S=-\sum_{i}P\left(i\right)\ln P\left(i\right) \end{equation*} and using the ...
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0answers
22 views

Coarse-graining on a second channel decreases mutual information?

Let $X_1,B_1,X_2,B_2$ and $Y_1,A_1,Y_2,A_2$ and $C_1$ and $C_2$ be binary random variables. Suppose: $I(X_2:B_2|C_2=0)+I(Y_2:A_2|C_2=1) \leq 1$. This can be thought of as a bound on the capacity ...
4
votes
1answer
329 views

Entropy is constant. How to express this equation in terms of pressure and density?

In hydrodynamics of an ideal, non-compressive flow we use 5 variables: pressure $p$, density $\rho$ and velocity field $\mathbf{v}$. So we need 5 equations. Landau's "Hydrodynamics" states that the ...
2
votes
1answer
146 views

Equation of state not linear in energy or system size [duplicate]

Which of these two equations of state are valid? $$S_1 = L_0 \gamma (\theta E/L_0)^{1/2} - L_0\gamma\left[\frac{1}{2} \left(\frac{L}{L_0}\right)^2 + \frac{L_0}{L} - \frac{3}{2}\right]$$ $$S_2 = L_0 ...
1
vote
1answer
1k views

Speed distribution in 1 dimension

In 3D, the maxwell velocity distribution is: $$f = \left(\frac{\alpha}{\pi} \right)^{\frac{3}{2}} e^{-\alpha v^2} d^3 \vec v$$ To get the speed distribution in 3D, we simply expand $d^3\vec v = 4\pi ...
0
votes
1answer
84 views

What's wrong with this simple derivation of energy flux in a photon gas?

In a photon gas, we know that pressure, $P$, and energy density, $u$, are related by: $$P=\frac{u}{3}$$ We also know from relativity that the momentum of a photon is $$p=\frac{E}{c}$$ Finally, the ...
4
votes
0answers
96 views

Reference for stochastic processes which helps moving from a basic level to a measure theory one

I'm looking for a reference (books, notes, lectures) which helps a physicist to understand the language of measure theory in the context of stochastic processes (in particular markov chains). I've ...
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0answers
43 views

state occupation rate $n_{i}=\frac{1}{e^{\beta (\varepsilon _{i}-\mu )}+{[1/-1/0]}}$ & density matrix $\rho _{m}=\frac{e^{-\frac{E_{m}}{kT}}}{Z(T)}$

Three kinds of distributions. The states occupation rates: F.D. $n_{i}=\frac{1}{e^{\beta (\varepsilon _{i}-\mu )}+1}$ B.E. $n_{i}=\frac{1}{e^{\beta (\varepsilon _{i}-\mu )}-1}$ Boltzmann ...
2
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0answers
46 views

How to load Bose-Einstein Condensates into an optical lattice?

In cold atom experiments, what techniques are used to load Bose-Einstein Condensates into an optical lattice??
9
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0answers
303 views

2d Ising model in CFT and statistical mechanics

When I recently started to read about conformal field theory, one of the basic examples there is the so called Ising model. It is characterized by certain specific collection of fields on the plane ...
1
vote
1answer
150 views

Partition function for composite systems

I want to understand the derivation of the partition function for two distinguishable non-interacting particles. Let the energy of particles $1$ and $2$ be $E_1$ and $E_2$ respectively. Setting ...
1
vote
0answers
307 views

Fluctuations in energy for macro and micro canonical ensembles

I was thinking about fluctuations in energy for a system in thermal equilibrium. I think that the Boltzmann distribution itself has an standard deviation approximately equal to the mean, as it is ...
3
votes
3answers
185 views

What does “an average over noise” mean in Zwanzig's book

This is a very specific question about Robert Zwanzig's book Nonequilibrium Statistical Mechanics. Specifically, what is he talking about in equation 1.25 on page 10 that he calls "an average over ...
6
votes
1answer
81 views

Minimum connectivity required for mean field to be a good approximation?

In spin models, it is known that mean field becomes a better approximation as the connectivity increases. My question is: Is there an estimate for the threshold connectivity (as a function of the ...
4
votes
2answers
607 views

Quantum entropy in term of density matrix

Why in von Neumann expression of quantum entropy we have trace of density matrix expression? Why don't off diagonal term play a role?
1
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0answers
258 views

Fluctuation-Dissipation theorems in an infinite quantum system

So for a quantum spin chain, one can easily prove via the partition function that you have a fluctuation-dissipation type relation between the magnetic susceptibility and the variance of the ...
6
votes
1answer
261 views

What is the phenomenological logic behind Fermi liquid theory

I am a super beginner when it comes to Solid State Physics and when wanting to learn more on the subject, I end up reading on Landau's Fermi liquid theory that supposedly justifies the quasi-free ...
6
votes
2answers
205 views

How can the microstates be measured with zero energy expenditure?

James P. Sethna. Statistical Mechanics. Exercise 5.2: What prevents a Maxwellian demon from using an atom in an unknown state to extract work? The demon must first measure which side of the ...
5
votes
1answer
142 views

Is temperature discrete

Because an object's temperature is inversely proportional to the wavelength of blackbody radiation which it emits, physicists have theorized the existence of Planck temperature at around $1.4×10^{32}$ ...
3
votes
1answer
689 views

Flory-Huggins ternary phase diagram with a neutral component

I am searching the literature for the Flory-Huggins phase diagram with the following components : polymer, solvent, and a third component that does not interact with the other components (just entropy ...
1
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2answers
2k views

Entropy and chemical potential of an ideal gas

I am reading Schroeder's book "Thermal Physics". One calculation in the text was not quite clear to me. The entropy of an ideal gas is given by the Sackur-Tetrode equation: $$ ...
6
votes
2answers
453 views

Classical and Semi-classical treatments of the ideal gas

In the semi-classical treatment of the ideal gas, we write the partition function for the system as $$Z = \frac{Z(1)^N}{N!}$$ where $Z(1)$ is the single particle partition function and $N$ is the ...
6
votes
2answers
1k views

Grand canonical partition functions for Bose-Einstein statistics vs. Maxwell-Boltzmann statistics

In Bose-Einstein statistics, the grand canonical partition function is $$\mathcal{Z}=1+e^{-\beta(\epsilon-\mu)}+e^{-2\beta(\epsilon-\mu)}+e^{-3\beta(\epsilon-\mu)}+\cdots$$ In Maxwell-Boltzmann ...
3
votes
2answers
371 views

Why are there gapless excitations in the anti-ferromagnetic Heisenberg model while the true ground state is a singlet?

The true ground state of the anti ferromagnetic quantum Heisenberg Model (nearest neighbor only)is known to be a singlet (I think this is Liebs theorem.) Since a singlet is invariant under rotations, ...
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1answer
482 views

I'm getting weird autocorrelations when simulating an Ising model below the critical temperature

So I'm simulating an Ising model using Monte Carlo and the Metropolis algorithm. After letting it reach equilibrium, I try to calculate the autocorrelation of the magnetization. As long as the system ...
5
votes
1answer
112 views

Intuitively, why does removing solutes cost $k_B T$ of free energy per molecule?

I can calculate that if you want to, for example, desalinate water, you will have to pay a free energy cost of $k_B T$ for each ion you remove. In other words, removing an ion from a volume of water ...
5
votes
1answer
302 views

Energy fluctuations in quantum canonical ensemble

How would you go about showing that in the quantum canonical ensemble (that is, in the density matrix and operator formulation), the energy fluctuations, namely $\langle H^2\rangle - \langle ...
35
votes
7answers
4k views

Homemade salad dressing separates into layers after it sits for a while. Why doesn't this violate the 2nd law of thermodynamics?

The oil, vinegar and other liquids in homemade salad dressing separate into layers after sitting for a while, making the mixture become more organized as time evolves. Why doesn't this violate the ...
1
vote
1answer
493 views

The “replica trick” initial formula?

In Spin-glass theory for pedestrians by Castellani and Cavagna, the initial formula used to introduce the replica trick is written as: $$\overline{\log ...
1
vote
2answers
3k views

Is there an equation to calculate the average speed of liquid molecules?

I seem to remember from first year physics that we can calculate the RMS speed of a stationary, ideal gas with $v=\sqrt{\frac{3RT}{M}}$. Does a similar equation exist for liquids?
1
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0answers
152 views

Understanding the product of partition functions by making sense of the maths and the physics

I have $N$ distinguishable particles in a 1D harmonic oscillator potential with 'proper' frequency $\omega$. The particles also have internal spin-$\frac12$ degrees of freedom in a magnetic field $B$ ...
8
votes
2answers
635 views

Chemical potential in Thermodynamics

In many scenarios, on computing the partial derivative of the internal energy (U) with respect to mole number (N) is negative. This implies that adding more moles of the substance decreases the U of ...
2
votes
2answers
653 views

Interpreting the Partition Function and Free Energy Mathematically

Given that The partition function in statistical mechanics tells us the number of quantum states of a system that are thermally accessible at a given temperature ...
3
votes
1answer
167 views

Definition of Information in Information Theory

I am not sure in which SE site I have to put this question. But since I have learnt Shannon Entropy in the context of Statistical Physics, I am putting this question here. In the case of Shannon ...
7
votes
2answers
235 views

Monte-Carlo and $O(n)$ models for non-integer n

$O(n)$ lattice statistical models can be generalized to non integer values of n, starting from their (expanded and resumed in graphs) partition function: $$Z = \sum_{\text{loop configurations}} n^{\# ...
0
votes
0answers
110 views

On the relationship between entropy and chaotic noise

I have few conceptual questions related to application of chaos in communications. Kolmogorov-Sinai Entropy1 , Kolmogorov-Sinai Entropy2 and Kolmogorov-Sinai Entropy3 KS is an entropy metric for ...
2
votes
1answer
98 views

Condensate fraction and single-particle density matrix

In Bose–Einstein condensation (BEC), how to prove the largest eigenvalue of the single-particle density matrix $$\rho_{ij}=\frac{\langle\Psi|a_i^{\dagger}a_j|\Psi\rangle}{N}$$ is ...
0
votes
2answers
84 views

Would it be possible to measure the change of entropy of a system? why?

To be more specific, what I mean is to measure it in a experiment. And if the answer is no, I want to know if it is principally impossible, or just impossible due to the technic limitation of our ...
2
votes
1answer
127 views

What happens to the free energy of the two-dimensional ising model with vortices?

The classical 2d Ising model has a Hamiltonian of the form: \begin{equation} H = -\sum_{m,n = 0}^{M,N} J_1 x_{m,n}x_{m+1,n} + J_2 x_{m,n}x_{m,n+1} \end{equation} The partition function for the model ...
3
votes
1answer
134 views

Solving non-linear ODE for divalent solution at a 1-D surface boudary

I am trying to solve the following equation for a positively charged plane with charge density $\sigma$ at $z = 0$. $$ \phi''(z)=-\frac{e}{\epsilon \epsilon_0} \big(z_+n_{+} e^{-\beta z_+ ...
5
votes
1answer
63 views

Vanishing Planets?

If we put a solid sphere in space, it will lose some molecules which will form a sort of an atmosphere around it so that we have the required vapour pressure for solid-vapour equilibrium (Temp. of ...
6
votes
2answers
199 views

In thermodynamic systems why must the free energy of the system be minimized?

Is this somehow a consequence of the second law of thermodynamics?
3
votes
3answers
836 views

Is there an upper limit to temperature in thermodynamics or statistical mechanics

In many presentations of statistical mechanics where we have a system of particles having mass, such as the molecules of an ideal gas, the temperature is often equated to the average relative velocity ...
8
votes
1answer
211 views

What precisely does the 2nd law of thermo state, considering that entropy depends on how we define macrostate?

Boltzmann's definition of entropy is $\sigma = \log \Omega$, where $\Omega$ is the number of microstates consistent with a given macrostate. If I understand correctly, this means that it only makes ...
11
votes
2answers
788 views

Quantum entaglement and the arrow of time

I have seen several claims to that quantum mechanics is required to explain the arrow of time which I take to mean the macroscopic irreversibility of physical systems. This is presumably to resolve ...
1
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0answers
146 views

Ising model. What is large fluctuations of magnetization?

My background is in mathematics. I have studied the Ising model in $\mathbb{Z}^2$. The main model of statistical mechanics. Yesterday, I was reading the preliminary notes of the book Statistical ...