# Tagged Questions

The study of large systems through coarse graining microscopic descriptions, providing a more detailed understanding of thermodynamics.

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### grand-canonical ensemble

I was wondering if the following reasoning is correct for example for electrons in the classical or qm grand-canonical ensemble? Is it always valid in the grandcanonical ensemble to calculate the ...
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### How to apply Wick's theorem in 2nd quantization for Spin Density Operators?

I am trying to work out a correlation function consisting of two spin density operators. Once I rewrite everything in 2nd quantized form, I am unsure of how to apply wicks theorem because the paul ...
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### Is information a form of energy? [closed]

To better describe my question, do the following experiment: Calculate x=12+26+67+71 Now you might have spent some time in getting the answer. You burnt sugar, you used up energy to get the ...
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### Extensive variables in thermodynamics

Extensive variables in thermodynamics are those which scale linearly with the system size. It is known that a ratio of two extensive variables is an intensive variable. Now, the number of particles (...
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### Definition of Fermion [closed]

Recently, I encounter a problem about the definition of Fermion operator. In our standard textbooks, the Fermions are defined by their exchange/braiding property, that is, if a minus sign appears by ...
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### Thermodynamics vs Kinetics

As a chemical reaction approaches equilibrium, one of forward or backward reactions dominate the other. According to thermodynamics, this is because the gibbs free energy change for one is negative. ...
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### Entropy and Gibbs Free Energy

I've been struggling with the notion of entropy and gibbs free energy for almost three days now. Different sources on and off the internet say different things about entropy. Gibbs Free Energy is ...
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### Grand canonical Hamiltonian

How to explain introducing "grand canonical" Hamiltonian $$\hat{H'}= \hat{H}-\mu \hat{N}$$ when we study a quantum system with fixed chemical potential? I understand such a substitution in a ...
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### Does it make sense to define the mean free path in quantum mechanics?

The mean free path defined in classical molecule dynamics has a strong classical flavor. Is it sensible to generalize the idea to quantum mechanics?
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### Fermi distribution and ideal gas

I was wondering about the following: If we have ideal gas particles, then $E \ge 0$, so one would expect that the state $E=0$ is occupied with probability one for low temperatures, but this is not ...
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### Calculating the heat transfer into CO$_2$ gas at a constant pressure

I am having trouble with a homework question and I am just not sure how to attack it. We have not covered how to deal with non-ideal gases yet, and we are expected to answer this question without that ...
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### Specific Heat of a Fermi Liquid

Let me give a bit of context before asking the actual questions: In the second edition of Condensed Matter Physics, Michael P. Marder derives the specific heat of Fermi liquids in chapter 17.5.4. He ...