1
vote
0answers
48 views

Understanding the phase separation of a chemically reactive mixture

Let's consider a mixture of solvent and components $A$ and $B$ such that $A$ can transform into $B$ with a rate $k_1$, and the reverse reaction with a rate $k_2$. $A \rightleftharpoons^{k_1}_{k_2} B ...
3
votes
1answer
52 views

Simple estimation of the critical temperature of water

I'm trying to develop fermi estimation skills and I came up with a question for which I don't even know where to start from. Here goes: Is it possible to estimate the critical temperature (say in ...
2
votes
1answer
34 views

What is an order parameter?

I've seen order parameter used in two different ways. One is to distinguish between an ordered and an unordered phase, like whether the net magnetization is stable or not. The second way is to ...
2
votes
1answer
51 views

Does the q-states Potts become the XY model in large q state?

I have met several times in papers, the order of the phase transition of the $q$-state Potts model depends on $q$. E.g., in two dimensions, for $q = 2$ (the Ising model), $3$, $4$ the order-disorder ...
6
votes
1answer
124 views

Why do phase transitions even exist? Why not smooth density change curves?

Why do phase transitions even exist? Why not smooth density change curves? What properties of matter, quantum or otherwise, predicts that matter will undergo phases at different pressures and ...
1
vote
0answers
66 views

What algorithms can be used to compute the binodal in a ternary Flory-Huggins theory?

What are the most popular algorithms used to obtain a binodal curve for the ternary mixture (starting from Flory-Huggins theory)? I would like to obtain a plot similar to the one calculated here ...
5
votes
1answer
89 views

Is there any model in statistical physics which has the ratio of specific heat exponent to correlation length exponent, $\alpha/\nu \approx 2.44$?

I am simulating a disordered ising-like model in 2d whose phase transition is expected to be continuous, whose universality class is as yet unknown. By plotting the Specific heat scaling function, ...
2
votes
1answer
60 views

What is a 'height field'?

I encountered a few times the expression of 'height fields' in statistical physics, without ever reading a proper definition. My textbooks don't seem to talk about that, and googling it hasn't been ...
3
votes
2answers
51 views

Nontrivial critical exponents in exactly solvable models?

Are there any exactly solvable models in statistical mechanics that are known to have critical exponents different from those in mean-field theory, apart from the two-dimensional Ising model? I wonder ...
2
votes
1answer
222 views

Flory-Huggins ternary phase diagram with a neutral component

I am searching the literature for the Flory-Huggins phase diagram with the following components : polymer, solvent, and a third component that does not interact with the other components (just entropy ...
3
votes
2answers
208 views

Connection between QFT and statistical physics of phase transitions

I have heard that there is a deep connection between QFT (emphasized by its path-integral formulation) and statistical physics of critical systems and phase transitions. I have only a basic course in ...
0
votes
2answers
47 views

Is there an analogue to the role of vapor in liquids and gases, but for solids and liquids?

It seems common for an ordered phase to have some amount of disorder present. For example, the average moment of a ferromagnet is less than maximum except at T=0 due to the presence of fluctuations. ...
1
vote
1answer
91 views

Infinite heat capacity or susceptibility means fluctuation on all scales

I remember reading in an introductory text to phase transition (sorry I don't remember the name) that at a second order phase transition the specific heat and the magnetic susceptibility become ...
5
votes
1answer
107 views

Do we have a fundamental Hamiltonian for the system of H$_2$O molecules?

From the quantum mechanics(QM) viewpoint, does there exist a Hamiltonian $H$ for the system of H$_2$O molecules? Assume that the number of H$_2$O molecules is fixed. Imagine that by calculating the ...
15
votes
0answers
288 views

Can Lee-Yang zeros theorem account for triple point phase transition?

Now the prominent Lee-Yang theorem (or Physical Review 87, 410, 1952) has almost become a standard ingredient of any comprehensive statistical mechanics textbook. If the volume tends to infinity, ...
6
votes
2answers
626 views

Is there a phase transition between a gas and plasma?

Does a phase transition occur as a gas is heated to create a plasma? If so, is this a first or second order phase transition? Also, does the presence of a phase transition depend on the pressure or ...
13
votes
1answer
353 views

Does this type of phase transition exist?

The short version of this question is: Is there, or could there be, a system with a phase transition where adding a small amount of heat causes a discontinuous jump in its temperature? Below are ...
7
votes
3answers
6k views

First and second order phase transitions

Recently I've been puzzling over the definitions of first and second order phase transitions. The Wikipedia article (at the time of writing) starts by explaining that Ehrenfest's original definition ...
10
votes
1answer
489 views

Definition of phase transitions in statistical mechanics

Phase transitions in statistical mechanics are usually taught by working through a bunch of examples. I decided to try and think about them from a more "fundamental" point of view - but I've run into ...
1
vote
2answers
121 views

What are correlated magnetic moments?

My book has the following sentence and I don't understand what correlation or lack of correlation means: At high temperature the magnetic moments of adjacent atoms are uncorrelated (to maximize ...
2
votes
3answers
517 views

Why the free energy is called 'free'?

The free energy, $F$ of a thermodynamic system at a given temperature $T$, is defined as, \begin{equation} e^{-\beta F} = \mathcal{Z} = \sum_{\{configuration\}} e^{-\beta E(configuration) } ...
3
votes
2answers
396 views

1D Ising Model with different boundary conditions

The Hamiltonian for one-dimensional Ising model is given by, \begin{equation} \mathcal{H} = -J\sum_{<ij>} S_iS_j; \quad i,j=1,2,...,N+1 \end{equation} where $<ij>$ denotes that there is ...
2
votes
0answers
238 views

Phase transitions. Conceptual link of my intuitive notions and definition of Georgii's book in terms of probabilities

In his classic book O. H. Georgii (Gibbs Measures and Phase Transitions) in Chapter 2 p. 28 define the concept of phase transition follows. Definition A potencial $\Phi$ will be said exhibit a ...
1
vote
1answer
100 views

2nd order phase transition trouble deriving coefficient in fluctuations analysis

I can't get one of the coefficients in the equation for $T < T_c$ in the bottom, specifically the equation with the factor of two. any help appreciated. Consider an ising type expansion of the ...
4
votes
2answers
250 views

Continuous phase transition only hold for infinite systems. Real systems are finite, hence, a paradox

Second-order or continuous transitions are usually identified with non-analyticies within the free energy (which is proportional to the logarithm of the sum of exponentials). Such singularities are ...
4
votes
0answers
130 views

Lattice model completely constrained by boundary data

I am dealing with a lattice model that has the peculiar property that if I specify all the spins on the boundary, by local conservation laws, the whole lattice configuration (throughout the whole ...
0
votes
0answers
56 views

Lambda transition data points of $\require{mhchem}\ce{^4He}$

I'm looking to get some data on the lambda transition of $\require{mhchem}\ce{^4He}$. I need the data points of the specific heat vs. temperature graph, if that makes sense.
2
votes
0answers
97 views

Spin Glass Transitions in Random Bond Ising Model (RBIM)

In brief, is there a list of spin glass transition properties for the RBIM on different lattices? Is there any know results about the relationships between these probabilities for a graph and its ...
3
votes
2answers
366 views

Any example of lower symmetry in high temperature phase than the low temperature phase?

All the phase transition cases I came across so far have this property: the lower temperature phase has lower symmetry than the higher temperature one. But it is nowhere explicitly said that, lower ...
3
votes
2answers
696 views

Can a first order phase transition have an order parameter?

Order parameter is used to describe second order phase transition. It seems that in some papers it is used in the first order phase transitions. Can first order phase transition have an order ...
4
votes
1answer
264 views

Reasons for violation of universality in statistical mechanics

The Universality in statistical mechanics is nicely explained by the renormalization group theory. However, there are fair amount of numerical and theoretical studies show that it can be violated in ...
1
vote
1answer
114 views

Parameter determining argon phase

Currently I am working a molecular simulation to determine phases of an argon NPT ensemble using Lennard Jones potential. Mainly I use the radial distribution function to determine solid, liquid, or ...
4
votes
2answers
836 views

What is a bulk phase transition?

I have been able to google "bulk phase transition" and get plenty of results that verify that something called a bulk phase transition exists, however, I cannot seem to find a precise definition of ...
2
votes
4answers
185 views

What is the simplest system that has both, discontinous and continous phase transitions?

I am looking the simplest system that has both discontinous phase transition and a continous phase transition between the same phases (you can change one parameter). discontinous transition: first ...
3
votes
2answers
888 views

Latent heat vs temperature of phase transitions?

Is the latent heat associated with phase transitions correlated with the temperature at which they occur? The latent heat is related to the difference in energy between the two phases, and the ...
6
votes
1answer
487 views

Mean-field theory in 1D Ising model

A mean-field theory approach to the Ising-model gives a critical temperature $k_B T_C = q J$, where $q$ is the number of nearest neighbours and $J$ is the interaction in the Ising Hamiltonian. Setting ...
1
vote
1answer
177 views

What kind of phases nanoparticles have (gas-solid-liquid)?

If a phase transition requires a number of particles that is in the TD-limit, can nanoparticles (~10 atoms) have phase transitions? What kind of phases and transitions nanoparticles have?
4
votes
3answers
352 views

How many particles is needed to observe a phase transition?

This is a question that was rised when we were discussing "what is melting actually". How many particles you need to form a liquid or solid. I have some remarks to point out what I want to know. Q: ...
2
votes
1answer
140 views

renormalization group in d=3

Do we really understand why the renormalization group in $d=2+\varepsilon$ and $d=4-\varepsilon$ taking $\varepsilon=1$ gives "good" values for critical exponents in $d=3$? Are they exceptions? Is it ...
4
votes
1answer
294 views

What are conditions for the existence of a critical value (for a phase transition)?

Can there only be a critical temperature if there is some natural unit for an observable in the model, i.e. if there is a natural scale for something? Otherwise I don't see how for a system there ...
14
votes
1answer
136 views

Phase Transition in the Ising Model with Non-Uniform Magnetic Field

Consider the Ferromagnetic Ising Model ($J>0$) on the lattice $\mathbb{Z}^2$ with the Hamiltonian with boundary condition $\omega\in\{-1,1\}$ formally given by $$ ...
4
votes
4answers
607 views

Where can I find a good classification for phase transitions?

I'm having a hard time to find a good (and modern) classification scheme for phase transitions and related universality classes. Can someone recommend a paper/book/site? Detailed mathematical aspects ...
8
votes
2answers
264 views

What happens for the spins around the phase transition

Suppose we now consider a lattice of spin, say Ising model, and the phase transition at the critical temperature $T_c$. There are few scaling laws describe the regime around the critical temperature ...