1
vote
0answers
75 views

Free Energy of N Spin 3/2 Particles

This question is from the book "Introductory Statistical Mechanics" by Bowley and Sanchez. The question is as follows: Calculate the free energy of a system with N particles, each with spin 3/2 with ...
28
votes
4answers
705 views

How exact is the analogy between statistical mechanics and quantum field theory?

Famously, the path integral of quantum field theory is related to the partition function of statistical mechanics via a Wick rotation and there is therefore a formal analogy between the two. I have a ...
0
votes
0answers
54 views

What is known about the statistical mechanics of systems with normally distributed energies?

Consider a system taking on N states with energies $\epsilon \sim \mathcal{N}(\mu,\sigma^2)$. Are such systems well-studied in any context? I ask because I'd like to be able to take certain ...
0
votes
1answer
57 views

Can a distribution with sharper energy maximum than the exp-function give an equivalent theory?

Because for many particles the distribution $\varrho\sim\mathrm e^{-\beta\ H}$ has an extremely sharp maximum, the expectation values of the canonical ensemble agrees with that of the microcanonical ...
4
votes
2answers
175 views

Continuous phase transition only hold for infinite systems. Real systems are finite, hence, a paradox

Second-order or continuous transitions are usually identified with non-analyticies within the free energy (which is proportional to the logarithm of the sum of exponentials). Such singularities are ...
2
votes
1answer
290 views

Accessible microstates of harmonic oscillator in microcanonical enemble

While reading up on statistical physics, I am going through the calculation of the partition function of the harmonic oscillator in the microcanonical ensemble. The result for the partition function ...
3
votes
2answers
392 views

Canonical partition of a boson gas

I have a 1D gas made of $N$ particles placed in a harmonic potential well, so the Hamiltonian is: $$ \mathcal H = \sum_{j=1}^N \left ( \frac{p_j^2}{2m} + \frac{1}{2}m\omega^2 x_j^2 \right )$$ The ...
2
votes
1answer
822 views

Helmholtz Free Energy, Partition Function

I'm trying to develop some basic intuition here, so this comes mostly as a jumble of commentary/questions. Hope its acceptable. Helmholtz Free Energy: $A = -{\beta ^{-1}}lnZ$. I find this statement ...
1
vote
1answer
1k views

Partition function of bosons vs fermions

I have two atoms, both of which are either bosons or fermions, with four allowed energy states: $E_1 = 0$, $E_2 = E$, $E_3 = 2E$, with degeneracies 1, 1, 2 respectively. What's the difference between ...
4
votes
1answer
403 views

How do I calculate the probability that the oscillator is in a certain state using partition function?

So let's say I have a single ($N=1$) quantum harmonic oscillator and the energy is determined by $E_n = (n + 1/2) \cdot \hbar \omega$ (where $n$ is the quantum number and $n$ = $0, 1, 2, \ldots$) ...
2
votes
1answer
906 views

Calculating partition function of ultra-relativistic 1D gas

This is a problem (Problem 3.16) from the book Statistical Mechanics 2nd Ed. by Pathria. In the problem I have to calculate the partition function of an ultra-relativistic 1D gas ($E_i=cp_i$) ...
4
votes
1answer
326 views

Integration of partition-function over many momentum variables

My integral looks like $$Z(\beta) = \frac{1}{h^3}\int d^3p\ \exp{\left(-\frac{\beta}{2m}\sum^{3N}_{i=1}p_i^2\right)}.$$ I'm confused about how to integrate over seemingly 3N variables in only a ...
2
votes
1answer
231 views

Partition function of an interacting gas

By reading an article, I found a partition function that, according to the author, describes an interacting with random variables as coupling constant. $$Z =\int \mathrm{d} \lambda_i ...
8
votes
0answers
135 views

Measure of Lee-Yang zeros

Consider a statistical mechanical system (say the 1D Ising model) on a finite lattice of size $N$, and call the corresponding partition function (as a function of, say, real temperature and real ...
1
vote
1answer
155 views

Quantum Stat-Mech Proof of an Inequality for the Partition Function

I have the following problem that I was unable to solve for class, but I had a couple first steps that I started with that I am unable to finish. I know I can't get this since it's already been ...
2
votes
4answers
1k views

What does third law of thermodynamics tell us?

I just have a question concerning the third law of thermodynamics. The third law describes that the entropy should be a well defined constant if the system reaches the ground state which depends ...
3
votes
1answer
176 views

From spectrum/dispersion relation to the partition function

I know the spectrum/dispersion relation for a bosonic system. $$E \left( \mathbf{k} \right) = \cdots$$ Is there a general method for writing down the partition function when the spectrum of the ...