2
votes
1answer
60 views

RMS Free Path vs Mean Free Path

I am trying to determine the mathematical difference between mean free path and root-mean-square free path. For an ideal gas, the relaxation time is $$\tau=\frac{1}{\sqrt2 \pi nd^2 \bar v}$$ and the ...
2
votes
1answer
50 views

Microcanonical Ensemble

I'm having difficulty understanding a statistical mechanics problem. I'm missing some basic understanding of counting the minimum energy states. My thought is that there are three states to choose ...
2
votes
0answers
48 views

Statistical Mechanics: Most probable orientation of grain particle in gas chamber?

I'm in an introductory statistical mechanics course, and we've been posed the following situation: Long-shaped dust particle (so imagine something like a grain of rice) is placed in a gas chamber (so ...
3
votes
1answer
93 views

Fermi-Dirac distribution derivation?

I am trying to derive the Fermi-Dirac statistics using density matrix formalism. I know that $$<A>= Tr \rho A.$$ So I started from $$<n(\epsilon_i)>= Tr \rho n(\epsilon_i)=\frac {1}{Z} ...
1
vote
2answers
44 views

Temperature limit on entropy of a paramagnet

We have $$S=Nk_B[\ln(2 \cosh(x)) - x \tanh(x)]$$ where $$x = \frac{\mu B}{k_BT}$$ In need to show that at low temperatures entropy $$S \approx Nk_B2xe^{-2x}$$ I wrote out the $\cosh(x)$ in terms of ...
0
votes
2answers
74 views

Entropy of a chain

A chain has N segments which can be oriented in either the x or y directions. For each segment oriented along y, there is an energy penalty of $\epsilon$. We also know the end segment is at $(L_x, ...
1
vote
1answer
59 views

Calculating energy U from $\partial U/\partial q$

Imagine $N$ oscillators with only two possible energies, $\epsilon_0$ and $ \epsilon_1$, with $\epsilon_1 > \epsilon_0$. Taking $\epsilon_0 = 0$ for now I showed $\Omega(q\epsilon_1) = ...
3
votes
1answer
74 views

Canonical partition sum for two fermions in harmonic potential

In an old exam, I found the following problem: Two Particles in a potential well We look at a onedimensional harmonic potential well that hold two spinless particles that do not interact with ...
0
votes
1answer
93 views

Quantum Mechanics mistake in partial trace

I have a given a density matrix by $\rho:=\frac{1}{2} |\psi_1 \rangle \langle \psi_1|+\frac{1}{8} |\psi_2 \rangle \langle \psi_2|+\frac{3}{8} |\psi_3 \rangle \langle \psi_3|.$ Where $|\psi_1\rangle ...
2
votes
1answer
106 views

Why do we get the same result using different ensembles?

There are different kinds of ensembles: microcanonical, canonical, grand-canonical... But for a particular system, no matter whether the system is isolated or closed, they just give the same result of ...
2
votes
2answers
343 views

Probability of Different States - Canonical Ensemble - Partition Function

Consider a canonical ensemble of $N$ ideal gas atoms, which could have spin up or spin down. Why is it that the probability of finding the particle in a spin up state generally only involves the ...
1
vote
0answers
144 views

Average number of spin up particles

In a paramagnetic system, where $N = N_\uparrow + N_\downarrow$ is fixed, how does one calculate the average number of spin-up particles $\langle N_\uparrow \rangle$? You can assume we have the ...
2
votes
1answer
423 views

Partition Function for Two Level System

I have a system with $N_s$ sites and $N$ particles, such that $N_s >> N >> 1$. If a site has no particle, then there is zero energy associated with that site. The $N$ particles occupy the ...
1
vote
2answers
138 views

Paramagnetism and large N

In a paramagnetic system, we have: $$N = N_\uparrow + N_\downarrow$$. If we have a large system, with $N >> 1$, is it generally okay to assume $N_\uparrow \approx \frac{N}{2}$ and ...
1
vote
3answers
172 views

Distinguishable, Indistinguishable Paramagnetic Ideal Gas

In the canonical ensemble, the partition function for an ideal gas is given by: $$\frac{Z}{N!}$$ The factor $N!$ accounts for the indistinguishability of the particles of the ideal gas. What ...
4
votes
1answer
448 views

Paramagnetism Spin-1/2 Particles - Partition Function

I'm trying to come up with an expression for the partition function of a system of spin-1/2 ideal gas particles on a line of length $L$. The total number of particles $N$ is fixed, with $N = ...
2
votes
1answer
253 views

Equation of state of a rubber band

I have the following question that I attached in png format. I have done part (a), but I am having difficulties in part (b) when I proceed according to the book. I have non zero tension at ...
1
vote
2answers
498 views

Must a reversible engine be a carnot engine?

I have this homework question: "Show that any reversible engine operating between T1 and T2 is a carnot engine." I think I have a solution, but it feels very hand-wavy. We know that any process that ...
0
votes
1answer
138 views

Entropy of a particle with two energy states [closed]

A particle has two energy states having energies $E_0$ and $E_1$ with degeneracies $g_0$ and $g_1$. The respective probabilities are $p_1$ and $p_2$. What is the entropy in terms of $p_1$, ...
1
vote
1answer
302 views

Ensemble of harmonic oscillators

I have some problems with problem 2.3 from Reif's Fundamentals of statistical and thermal physics: Consider an ensemble of classical one-dimensional harmonic oscillators. a) If we assume ...
0
votes
1answer
103 views

Derivation of Pressure/Kinetic Therory problem involving hole in box

A box of volume $V_0$ has a small hole of area $A_0$. The box initially has one mole of an ideal gas at $t = 0$, which is at an initial temperature $T (t = 0)$. Find the rate of energy flow through ...
1
vote
1answer
113 views

Magnetic Susceptibility at Arbitrary Temperature

I'm currently working on an assignment where the questions is: Consider a gas of N noninteracting electrons in a uniform magnetic field B = B$\hat{z}$ in a macroscopic system. Assume that the ...
4
votes
1answer
383 views

Chemical Potential of Ideal Fermi Gas

In Wikipedia's article on Fermi Gases, they have the following equation for the chemical potential: $$\mu = E_0 + E_F \left[ 1- \frac{\pi ^2}{12} \left(\frac{kT}{E_F}\right) ^2 - \frac{\pi^4}{80} ...
0
votes
0answers
332 views

Density of states of a photon gas in volume V and temperature T

I have a question on the density of states for a photon gas: Suppose I have a photon gas in a box of volume $V$ at temperature $T$. If I enumerate the total number of states accessible to the system ...
1
vote
2answers
392 views

1 dimensional Ising model

How to solve the Ising model in 1D by low temperature, and high temperature expansion, and by change of variable method? Can you please give me some reference links?
1
vote
1answer
143 views

Bose–Einstein statistics exercise

I've a basic Bose–Einstein statistics exercise. I've tried to solve it in two ways, but each way gives a different result. We have $n$ identical bosons without interactions at temperature $T$. There ...
2
votes
0answers
54 views

error propagation and collision in ideal gas

When dealing with gas, a statistical approach is needed because For N particles, you have to solve 6N equations which cant be done analytically. To know our time step for numerical solving, you can ...
1
vote
0answers
137 views

Maxwell-Boltzmann distribution

The short story is, that I have to calculate some transport coefficients, but using the the MB distribution as my distribution function. What I currently need to solve is: ${{\mathcal{L}}^{\,\left( ...
1
vote
0answers
104 views

Maxwell-Boltzmann distribution for transport equations

I have to calculate the transport coefficients for the Maxwell-Boltzmann distribution. But I'm not sure what distribution I have to use. As far as I know it should not be the MB distribution for ...
1
vote
1answer
180 views

Calculating the change in entropy in a melting process

I have a homework question that I'm completely stumped on and need help solving it. I have a $50\, \mathrm{g}$ ice cube at $-15\, \mathrm{C}$ that is in a container of $200\, \mathrm{g}$ of water at ...
2
votes
1answer
187 views

Energy density of a quantum mechanical ensemble

How do we determine the energy density of a given system? I have seen that the density operator $$\rho~=~\frac{\exp(-\beta \hat{H})}{\text{tr}(\exp(-\beta \hat{H}))}.$$ What does this mean exactly ...
1
vote
1answer
167 views

Basic energy calculation for N identical spin system

We have a system that has N identical spins $n_i$, and each spin can be in state 1 or 0. The overall energy for the system is $\epsilon\sum_{i=1}^{N}n_i$. My understanding: There is only one ...
1
vote
1answer
40 views

How can I find the temperature of this system?

A system was given a small amount of thermal energy dE, and its number of states G grew by 25%. How can I find the system temperature? The system contains gas particles, I know that $dE << ...
1
vote
1answer
131 views

Maximizing Multiplicity of Einstein Solid == (Temperature = $\infty$)?

If I have a system consisting of 2 Einstein solids (A and B) is it equivalent to say that maximizing the multiplicity of the ...
1
vote
2answers
270 views

Energy of particle in electric field

I'm taking a physics class and the professor teaches us really basic things in lecture and then gives homework way beyond what he taught in lecture. Obviously I need to find some resource other than ...
2
votes
0answers
330 views

Pauli paramagnetism for electrons with external magnetic field

Apparently it is to be shown that for electrons under an external magnetic field, in the limit as $B\to 0 $ $$ \chi = \frac{dM}{dB} \approx \frac{n\,\mu^{*^2}}{k\,T}\,\frac{f_{1/2}(z)}{f_{3/2}(z)} $$ ...
1
vote
0answers
246 views

Rotational Constant and Moment of Inertia of Fluorine gas

I have come across some homework question on thermodynamics which needs me to calculate $B$ of $F_2$ My attempt: $B= \frac{h}{8\pi^2cI}$ where $I=\mu r^2=\frac{m_1m_2}{m_1+m_2} r^2$ Atomic mass of ...
3
votes
2answers
385 views

Canonical partition of a boson gas

I have a 1D gas made of $N$ particles placed in a harmonic potential well, so the Hamiltonian is: $$ \mathcal H = \sum_{j=1}^N \left ( \frac{p_j^2}{2m} + \frac{1}{2}m\omega^2 x_j^2 \right )$$ The ...
0
votes
0answers
117 views

Number of microstates of discretized paths

Let us consider a square grid, which has been rotated by 45deg. On this grid we define a path, the directed polymer, which starts at the origin ($t = 0$) and extends in the positive $t$-direction ...
1
vote
2answers
1k views

Constant pressure and temperature mixing of 2 different ideal gases - possible work and heat?

A simple question I hope... Initially, have two separate containers of 2 different ideal gases, 1.) N1, P, T, V1 and 2.) N2, P, T, V2. After mixing, the pressure and temperature are still P and T, ...
1
vote
3answers
1k views

Partition function for quantum harmonic oscillator

Hi guys I'm currently trying to solve a mock exam for an exam in a few days and am a bit confused by the solutions they gave us for this exercise: Exercise: A solid is composed of N atoms which ...
1
vote
1answer
1k views

Calculate temperature of the earth through blackbody radiation

I don't understand the solutions to a problem about blackbody radiation and was wondering if anybody could help me out. Here is the question: The sun can be considered as a blackbody radiation ...
1
vote
0answers
119 views

helmholtz free energy of a polymer

You have a polymer chain of $N$ units, which is represented by $N$ independent springs in series. The springs are Hookean, with spring constant $L$, and the end to end vector is $\mathbf r$. So the ...
1
vote
1answer
447 views

Occupied lattice sites, determining number of microstates and energy

A solid consisting of $N$ molecules on a lattice of $N$ sites is isolated from its environment, and has energy $E$. Each molecule is fixed in position and independent of all others. It can be in any ...
6
votes
1answer
271 views

few fermions in a harmonic trap — position density matrix from diagrammatics

I'm trying to calculate the momentum distribution of a 1D system of non-interacting identical fermions in a harmonic trap. Given Feynman's answer (from his Statistical Mechanics book) for the ...
1
vote
1answer
1k views

Partition function of bosons vs fermions

I have two atoms, both of which are either bosons or fermions, with four allowed energy states: $E_1 = 0$, $E_2 = E$, $E_3 = 2E$, with degeneracies 1, 1, 2 respectively. What's the difference between ...
0
votes
1answer
596 views

A problem from Pathria, canonical ensemble, how to calculate $\left\langle \left(\Delta E\right)^{3}\right\rangle $

This is problem 3.18, from the book Statistical Mechanics by Pathria. Show that for a system in the canonical ensemble $$\left\langle \left(\Delta E\right)^{3}\right\rangle =k^{2}\left\{ ...
3
votes
1answer
401 views

What is non-thermal plasma?

I read about non-thermal plasma, but I still have some questions: The ions and neutral particles are not in thermal equilibrium with the electron, does that mean that the overall temperature is low ...
2
votes
0answers
91 views

Randomly sampling a “well-mixed” solution of Brownian particles

I place $N$ Brownian particles in $V$ liters of solution, shake until I assume that the particles are "well-mixed", and sample and randomly sample an $S$ liter volume. What is the probability ...
0
votes
1answer
834 views

Ideal gas with two kinds of particles, Grand canonical partition function

Consider an ideal gas contained in a volume V at temperature T. If all particles are identical the Grand canonical partition function can be calculated using $$Z_g(V,T,z) := \sum_{N=0}^\infty z^N ...