1
vote
1answer
35 views

Do Monte-Carlo updates have a physical significance in stat. mech?

One of the archetypical example to introduce Monte-Carlo methods in stat. mech. is to work out the properties of the 2D square lattice Ising model and compare the obtained results with Onsager's exact ...
2
votes
1answer
94 views

H-theorem and Boltzmann equation applied to Boltzmann distribution

Using the Boltzmann equation: $$ \frac{dH}{dt} = \int_0^{\infty} dr \int_0^{\infty} ds W(r,s)[p_r - p_s][\ln{p_r} - \ln{p_s}],$$ and assuming $p_r = e^{-\beta r}$, the equation looks like $$ ...
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0answers
31 views

How to calculate the partial entropy in a fully connected ising system

I'm trying to reproduce a calculation that should lead to the partial entropy in a fully connected ising model for the high-temperature range ($\beta < 2$) in the thermodynamic Limit ($N ...
1
vote
1answer
140 views

Can exergy and exergy destruction be understood through thermodynamical and/or statistical-mechanical principles?

My textbook Fundamentals of engineering thermodynamics, Moran and Shapiro states: The exergy is the maximum theoretical work obtainable for an overall system consisting of a system and the ...
7
votes
1answer
425 views

Why is (von Neumann) entropy maximized for an ensemble in thermal equilibrium?

Consider a quantum system in thermal equilibrium with a heat bath. In determining the density operator of the system, the usual procedure is to maximize the von Neumann entropy subject to the ...
1
vote
0answers
45 views

Any new texts directly on second law of thermodynamics? [duplicate]

Possible Duplicate: Recommendations for Statistical Mechanics book Is anyone aware of any recent text that summarises the research and arguments on second law of thermodynamics and also on ...
3
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2answers
403 views

Time to establish saturated vapour pressure above liquid

Thought experiment - a liquid is in a closed container in equilibrium with its vapour, and then suddenly all the vapour is pumped away. Switch off the pump so that instantaneosuly there is no vapour ...
3
votes
3answers
238 views

What are some creative illustrations of the nature of dissipative forces?

I'm teaching a conceptual introduction to physics for American 13-15 year old students this summer. One of the main ideas I want to hit on is the relationship between energy conservation, ...
20
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3answers
2k views

Prove that negative absolute temperatures are actually hotter than positive absolute temperatures

Could someone provide me with a mathematical proof of why, a system with an absolute negative Kelvin temperature (such that of a spin system) is hotter than any system with a positive temperature (in ...
7
votes
4answers
392 views

Applying the Maxwell–Boltzmann statistics to astrophysical objects

Quoting Wikipedia: In statistical mechanics, Maxwell–Boltzmann statistics describes the statistical distribution of material particles over various energy states in thermal equilibrium, when the ...
1
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1answer
514 views

Statistical physics of molecular dissociation of a diatomic gas

Say there are $N$ atoms of type $A$ in a box of volume $V$ and they are undergoing a reversible association-dissociation reaction $A + A = A_2$. Let an $A$ atom have mass $m$, and hence the molecule ...