the practice of separating a signal by frequency (or sometimes energy or momentum) and analyzing the resulting spectrum.

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2answers
44 views

How organic impurities in the air affects laser?

We have a Nd YAG laser pumped Optical Parameter Oscillator in our lab. A technician came to our lab (my professor called him for its maintenance) and while he was working on it, he told me that ...
2
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1answer
71 views

Relative weights in rotational bands of symmetric diatomic molecules

In an old paper, Ehrenfest 1931, the introduction starts off as follows: The band spectra of symmetric diatomic molecules show certain striking differences from those of asymmetric molecules. For ...
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1answer
69 views

Why is an exciton only observed when we excite to the conduction band and not to other electronic level inside the bandgap?

Excitons can be observed when we excite electrons to the conduction band. I don't know about excitons being observed when we excite the electrons to an electronic level that would eventually be in ...
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1answer
164 views

Why does the addition of paramagnetic ions decrease the spin lattice relaxation time of protons?

My question pertains to NMR (nuclear magnetic resonance). $T_1$, the spin lattice relaxation time of protons in water is about 2.5 seconds. If you add some $CuSO_4$ (copper sulfate) to the water the ...
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1answer
200 views

What is the secondary electron cutoff in ultraviolet photoelectron spectroscopy?

While the fasted emitted electrons comes from the fermi level of the material in UPS measurement, where does the slowest, which is called secondary electron cut-off orginate from? I really can't ...
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1answer
17 views

Where I could find values for rare earth metalls levels diagramm (Dieke diagram)?

The Dieke diagrams like this: could be easily found in internet. But it is impossible to determine from where they get values initially, everyone is making cross-links. I'm especially interested ...
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1answer
26 views

Is the temperature different and or salinity different can lead to different colour of the water bodies?

I had skimming on an article about Thermocline and Halocline. How can two seas not mix? However, I am still curious on: Why the effect of Thermocline and Halocline are distinguishable based on ...
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1answer
79 views

Thermionic emission, delayed emission and predissociation

In molecular photodissociation, the thermionic emission, delayed emission and predissociation are the same? otherwise, what is the difference between them? My question is not about the solids, but I ...
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1answer
187 views

What is electron momentum density in solids and molecules?

Can someone kindly help me to know how can i get electron momentum density for one orbital like home? what is the theory of electron momentum density? how can I derive electron momentum density from ...
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0answers
87 views

Is there a difference between “two photon absorption” and “double quantum transitions”?

Wikipedia has articles on two photon absorption. And a lot of NMR literature refers to double quantum transitions. But is there a difference? As far as I can tell, a double quantum transition is has ...
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0answers
45 views

SHS Interferometer and diffraction limit

I'm currently researching Spatial Heterodyned Spectrometers (SHS) and I'm a bit at a loss understanding the influence of the diffraction limit. I'll be measuring a diffuse visible light source with ...
2
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0answers
30 views

Unknown peaks on RBS spectrum

I was given a sample, that it is supposed to be a medium thickness Rhodium on top of an infinite silicon waffer. The experimental RBS spectrum along with the simulation looks like that Apparently, ...
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0answers
93 views

Line-shape asymmetry in undergraduate Hydrogen-Deuterium experiment

I'm working as an LA (undergraduate TA) for an undergraduate physics laboratory experiment where students test the Bohr model and use reduced mass to determine the approximate mass of the neutron. In ...
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0answers
41 views

How large would the electric field need to be to split the mj -/+1 626.6 nm line of neon?

I am an undergraduate considering an extension on a quantum beats experiment with neon. The premise is to excite neon atoms coherently from a metastable 'ground' state into a superposition of excited ...
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0answers
96 views

Intensive radiative heat transfer in very hot gas ( >5000K, gas core nuclear reactor related )

The question: At temperatures above ~5000K are not stable any solid or liquid materials or even more complex molecules (such as fullerenes and Polycyclic aromatic hydrocarbons) which emit/absorb ...
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0answers
96 views

Total angular momentum in multielectron atoms

I have some confusion about orbitals in multielectron atoms. Let's say we consider an atom (Lithium, for example, $1s^2\, 2p^1$) and that the state of the last electron is [n=2, l=1, ml=0, s=1/2, ...
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0answers
59 views

How to absorb a characteristic line in a spectrum

I have an x-ray tube. When I see the spectrum, I notice the characteristic lines of the anode. What do I have to do if I want to absorb a characteristic line? I have thought that I can add a filter. ...
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0answers
78 views

Correlation function in relaxation in NMR

I am new in this community, I am from a chemistry background. I want to know a detailed solution of a density matrix for a singlet state using the concept of spin lattice relaxation in NMR. I will ...
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0answers
122 views

Linewidth pressure broadening due to organic molecules

In relation to atmospheric spectroscopy and some other gaseous spectroscopy applications where organic molecules are present in the vapor, does anyone know of any papers or resources on pressure ...
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0answers
23 views

Saddle point and transition state of a molecule

During a transition of a molecule from one state to another, it pass through a transition state. This transition state, mathematically speaking, is a saddle point. That means, the second derivative ...
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0answers
16 views

What is the perceived color of a D-illuminant?

I am implementing a software that simulates the color of the sky. To do this, I use a model that takes as input the sun position and returns the Yxy components of a D-illuminant for each point of the ...
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0answers
20 views

Textbook on Diffusion and Diffusion NMR Spectroscopy

I am looking for textbooks ( Mathematical / Theoretical Physics ) that cover diffusion in general. Although it is not necessary that your recommendation covers it, I am also particularly interested ...
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0answers
24 views

Difficult to visualize Franck-Condon overlap

The franc condon principle says about the vertical transitions, means the coordinates of the nuclei remains unchanged during an electronic transition. But, what is the physical meaning or how to ...
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0answers
19 views

Doppler broadening: time scale to frequency scale

Consider a cell containing Rubidium and enlight it with a laser. Connect the system with an oscilloscope and give a triangular wave as input (so you can know when the Rubidium is resonant). This is ...
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0answers
48 views

Spectroscopy: clarification about doppler shift

I've just begun to study spectroscopy, and I need a clarification about the Doppler Effect. Considering this graph: could you explain me how I can see the doppler shift related to the deeper peak ...
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0answers
56 views

What is the physical meaning of multiplicity of an electronic state in a molecule?

When we specify the electronic states, we specify its multiplicity as well. If S is the spin quantum number, then 2S+1 is the corresponding multiplicity. Two states having same L value but with ...
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0answers
57 views

How to measure distances to stars by means of spectroscopic parallaxes?

How to measure distances to stars by means of spectroscopic parallaxes on practice? What is the accuracy of measuring distances using this method compared with distances based on HIPPARCOS ...
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0answers
27 views

Elemental sensitivity factors for Auger electrons

Is there any open database of elemental sensitivity factors for Auger electrons? I'm trying to figure out graphite oxidation degree from AES spectra, so relative sensitivity of O to C is required. ...
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0answers
75 views

Looking for raw interferogram data / raw FID data from FT-IR / FT-NIR / FT-NMR

I'm trying to get my hands on some raw interferogram data / raw FID data from an FT-IR / FT-NIR / FT-NMR so I can run some tests using FFT with it (it needs to be real data). Here's a picture below of ...
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0answers
36 views

$a^3B_2$, $b^3A_2$ and $A^1A_2$ states in electron spectroscopy

I am new to electron spectroscopy. I have a basic question regarding the molecular transition. I have learned about the states $\Sigma_g^+$ $\Pi_g$.. etc electronic states. But I could never find in ...
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0answers
110 views

Something Weird About My Kurie Plot - Beta Spectroscopy

So I'm doing a Beta Spectroscopy of Sodium and apart from the Energy Spectrum, I'm intending to use the Kurie Plot to incorporate the Coulomb Correction Factor $F(Z,p)$. But when I try plotting the ...
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0answers
70 views

Photometric versus radiometric and spectral quantities

Are spectral quantities the same as photometric quantities? How do you pass from a radiometric quantity $R$ to the correspondent spectral quantity $R_λ$ I've been ask to pass from Irradiance to ...