the practice of separating a signal by frequency (or sometimes energy or momentum) and analyzing the resulting spectrum.

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122 views

Interchange symmetry for states with identical particles

I was reading this web page about interchange symmetry for states with identical particles here: http://quantummechanics.ucsd.edu/ph130a/130_notes/node317.html The article states that the highest ...
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157 views

Is there a difference between “two photon absorption” and “double quantum transitions”?

Wikipedia has articles on two photon absorption. And a lot of NMR literature refers to double quantum transitions. But is there a difference? As far as I can tell, a double quantum transition is has ...
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29 views

Fermi's understanding of the Doppler effect

I am now reading the classic paper by Dicke, The Effect of Collisions upon the Doppler Width of Spectral Lines At the very beginning of the paper, Dicke said ''Quantum mechanically, the Doppler ...
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44 views

Quantum description of Raman effect

In the classical description of Raman effect the object of study is the electric polarizability of the system. Since I'm interested in learning the quantum description of the Raman effect and in ...
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56 views

SHS Interferometer and diffraction limit

I'm currently researching Spatial Heterodyned Spectrometers (SHS) and I'm a bit at a loss understanding the influence of the diffraction limit. I'll be measuring a diffuse visible light source with ...
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53 views

Spectroscopy from a classical light wave or photon only?

In chemistry we mostly regard light/electromagnetic radiation as a beam of particles or photons. This is a very useful model to explain molecular excitations and ionisations from quantum interactions. ...
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26 views

Sonoluminescence spectrum

During cavitation created by sound in a liquid the collapse of the bubbles can lead to very high temperatures and pressures resulting in the emission of light - sonoluminescence. Can the spectrum of ...
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63 views

How to deal with coma and oblique spherical aberration in a Czerny Turner configuration?

I am modelling my own spectrometer using Zemax when all of a sudden I've been told that: even if you manage to optimize the angles or positions of the grating and the mirrors, you won't get ...
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40 views

How to distinguish Shake-Up Satellites from Plasmons?

I am studying XPS spectra (X-ray Photoelectron Spectroscopy) at the moment. In XPS, different processes can influence the final state energy of detected electrons. One of these processes is the ...
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44 views

Spectroscopy Question

So if we were to view the visible spectrum of a white dwarf star. Would the planetary nebula essentially block what would be an absorption spectrum? If so, would we all just see emission lines. I'm ...
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110 views

Line-shape asymmetry in undergraduate Hydrogen-Deuterium experiment

I'm working as an LA (undergraduate TA) for an undergraduate physics laboratory experiment where students test the Bohr model and use reduced mass to determine the approximate mass of the neutron. In ...
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51 views

How large would the electric field need to be to split the mj -/+1 626.6 nm line of neon?

I am an undergraduate considering an extension on a quantum beats experiment with neon. The premise is to excite neon atoms coherently from a metastable 'ground' state into a superposition of excited ...
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34 views

Activation energy of luminescence

Assuming that activation energy is constant for some range of temperature, it can be determined from the slope of the plot: $$\ln{I}=A-\frac {E_a}{k_bT}$$ where $I$ - intensity , $E_a$ - activation ...
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20 views

Using stellar spectroscopy to measure stellar parameters, why is it log g?

Stellar spectroscopy can in principle measure the stellar surface gravity, radii, effective temperature, and stellar rotation. Why is it that surface gravity g is ...
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28 views

UV absorption decrease with an increase in concentration

I am working on a project measuring the absorbance of a solution which contains surfactant and hard brine. The solution has a constant concentration of surfactant and varying concentration of hard ...
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30 views

PM-IRRAS Equidistant Fringes in Spectrum

What is the cause, and best method to prevent / minimize, fringes in one's FTIR (PM-IRRAS) spectrum on samples deposited on a thin metal film? The fringes look as though they are spaced out by a ...
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49 views

Can anybody explain about phase shift and phase spectrum terms in case of multidimensional signal?

I know about phase of a 1D signal, but when I move into higher dimensions like 2D or 3D etc, it becomes headache to grasp the concept. What do the terms "phase shift" and "phase spectrum" mean in ...
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27 views

Why graphene's substrate is important

I just have some feelings that somehow it is important what specific subtrate is used to grow graphene monolayer on. Some substrates are better, another ones are not so good. But I cannot completely ...
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61 views

Angle-resolved photoemission spectral (ARPES) function from band Hamiltonian

I am trying to derive spectral function for a band Hamiltonian. I am using http://arxiv.org/abs/cond-mat/0306084 as a prototype reference. I do not understand how the coherence factors $u_k$ and $v_k$ ...
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50 views

Rotational Spectrum of a Diatomic Molecule

The rotational energy levels of a diatomic molecule are given by $$E_l=\frac{\hbar^2}{2I}l(l+1)$$ where $l$ is an integer. If the molecule is a dipole it can emit or absorb electromagnetic radiation ...
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15 views

Explain materials with 4 fold symmetry having same reflectance when shone with LCP and RCP

This is my first post here. I am currently reading "Optical planar chiral metamaterial designs for strong circular dichroism and polarization rotation" by Do-Hoon Kwon, Pingjuan L. Werner, and ...
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28 views

Vibrational quantum notation

Reading articles on spectroscopy I often see this notation: 30001 <- 01101, 00011 <- 00001 in context of molecular ...
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17 views

Dielectric resonance spectroscopy of thin and thick film

How does the technique vary for dielectric resonance spectroscopy for thin film of ~ 3 micrometer and a relatively thick film of 100 micrometer?
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74 views

Why does inelastic X-ray scattering probe the longitudinal dielectric function as opposed to the transverse dielectric function?

Light is a transverse wave. Therefore, light in the optical range (i.e. visible light) couples to transverse collective excitations of a material when measuring the optical conductivity for instance. ...
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17 views

Spatial Resolution in Magnetocardiography

In the science paper called Development of an optical cardio-magnetometer by George Bison, it is mentioned that spatial resolution of 10-20mm is required for mapping MCG signal(page 52). What does the ...
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176 views

Intensive radiative heat transfer in very hot gas ( >5000K, gas core nuclear reactor related )

The question: At temperatures above ~5000K are not stable any solid or liquid materials or even more complex molecules (such as fullerenes and Polycyclic aromatic hydrocarbons) which emit/absorb ...
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170 views

Total angular momentum in multielectron atoms

I have some confusion about orbitals in multielectron atoms. Let's say we consider an atom (Lithium, for example, $1s^2\, 2p^1$) and that the state of the last electron is [n=2, l=1, ml=0, s=1/2, ...
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67 views

How to absorb a characteristic line in a spectrum

I have an x-ray tube. When I see the spectrum, I notice the characteristic lines of the anode. What do I have to do if I want to absorb a characteristic line? I have thought that I can add a filter. ...
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105 views

Correlation function in relaxation in NMR

I am new in this community, I am from a chemistry background. I want to know a detailed solution of a density matrix for a singlet state using the concept of spin lattice relaxation in NMR. I will ...
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128 views

Linewidth pressure broadening due to organic molecules

In relation to atmospheric spectroscopy and some other gaseous spectroscopy applications where organic molecules are present in the vapor, does anyone know of any papers or resources on pressure ...
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19 views

Can near-infrared spectroscopy distinguish between various metals?

Can near-infrared spectroscopy be used to distinguish metals from another? If not, why not?
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25 views

Estimation of source irradiance given the spectral sensitivity of the instrument and spectrum of the source

I am trying to measure the irradiance of a UV source, but the available instrument has a different sensitivity. Suppose the black line corresponds to the spectral sensitivity of the instrument ...
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27 views

Deconvoluting Raman spectras from different wavelengths

I am using a laser source that is wider than typical laser source for Raman spectroscopy. This mean that the full width at half maximum (FWHM) of the laser is about 5-10 nm, compared to the normal 1-3 ...
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11 views

Hyperfine structure interval rule only obeyed approximately?

The hyperfine interaction is given by $\Delta E = A \langle I \cdot J \rangle = \frac{A}{2}\left[ F(F+1) - I(I+1) - J(J+1) \right]$. The interval rule is given by: $$ \frac{\Delta E_{F,F-1}}{\Delta ...
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19 views

Does water absorb microwaves above of beneath its relaxation frequency

I am a bit confused about the concept of relaxation frequency. In my course text we derived a model with the help of Newton's law to describe the movement of polar molecules in an electromagnetic ...
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9 views

Velocity Selective Coherent Population Trapping and recoil limit on temperature

I have read that it is possible to go under recoil temperature limit using VSCPT (Velocity Selective Coherent Population Trapping) and that this method is based on atoms trapping in quantum state in ...
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17 views

Doppler and recoil limit on temperature

I havent't understood the causes of Doppler limit and recoil limit. I have found on the net different observations about them ("Doppler limit is due to the fact that the atom can't have a smaller ...
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26 views

Reflectance spectrum and Real Refractive Index Relation

I have taken in the laboratory mesurment of the Reflectance spectrum of a material and via mathematica calculated the phase for Kramers-Kronig Relations,and finnaly i calculated from it the real part ...
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19 views

Does the EXAFS oscillations occur when ultrashort x-ray pulse is used? Electron with a 50eV kinetic energy will travel in 0.1fs 4.2 Angstroms

In X-ray extended absorption spectroscopy (EXAF) an electron is excited by an x-ray photon into the continuum, the outgoing electron wave interferes with the scattered electron wave from the ...
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33 views

Why does the spectrum for deuterium show a weak line at H-alpha?

I was wondering why the spectrum for deuterium shows a weak line at H-alpha, the first line in the hydrogen spectrum.
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53 views

Bandwidth-Pulse Duration Relationship

Assuming Gaussian pulse, the relationship between pulse duration and bandwidth is given by: $$\Delta \nu \cdot \tau \geq 0.441$$ If the rms bandwidth and rms pulse duration are used, then the ...
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10 views

Moisture measurement through PVC using spectroscopy

Is it possible to measure moisture content in a blister through a PVC layer? The distance that the laser will have to travel will be around 3-3.5 mm. The thickness of PVC layer is 100 micron. I was ...
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37 views

Help Interpreting Ultraviolet Photoelectron Spectroscopy (UPS) data

I was given a batch of UPS data without any background other than the materials examined and I don't have any experiencing interpreting it. I wanted to reach out to some experts (hopefully, someone ...
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21 views

Is there any application for an advanced spectrometer in geometrical optics experiments?

We have an advanced spectrometer in our geometrical optics lab! I'm seeking for any experiment in geometrical optics to include it!
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41 views

Hydrogen spectrum intensity using a monochromator

Using a monochromator (350->800 nm) and a hydrogen gas lamp, I find this spectrum : We can see 3->2, 4->2, 5->2 transitions from Balmer series, but not 6->2 (which we should expect at 410 nm). As ...
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66 views

Reason behind formation of doublets in diffraction spectrum

like if you see is Sodium (and also in Mercury), there are two discrete lines of Yellow color.. What's the reason behind formation of doublets?
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38 views

Spectroscopic notation for more than one excited electron

In spectroscopy, notation like $^3S_1$ or similar is often used to define atomic states. This is unambiguous when considering only a single electron excited from the outermost energy level. But how ...
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54 views

Doppler effect for the electrons emitted from ions moving at a particular velocity

If I have ions moving in X axis (along both directions; positive X axis and negative X axis) and if I irradiate laser along the positive X axis, electron will be ejected from the ions (if I am using a ...
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40 views

What is the difference between Linear and Non-Linear Magneto-optical effects?

Principle difference between Linear and Non-Linear Magneto-optical effects and how they affect the property of light passing through a Vapor medium.
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31 views

Interpretation of decay associated difference spetrum

We measured transient absorption spectra and we got $\Delta A(\lambda,t)=A(\lambda,t)-A(\lambda,0)$. If we use DAS (decay associated spectra) for interpretation, we assume that our data have this ...