the practice of separating a signal by frequency (or sometimes energy or momentum) and analyzing the resulting spectrum.

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210 views

Why is an exciton only observed when we excite to the conduction band and not to other electronic level inside the bandgap?

Excitons can be observed when we excite electrons to the conduction band. I don't know about excitons being observed when we excite the electrons to an electronic level that would eventually be in ...
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0answers
12 views

Using stellar spectroscopy to measure stellar parameters, why is it log g?

Stellar spectroscopy can in principle measure the stellar surface gravity, radii, effective temperature, and stellar rotation. Why is it that surface gravity g is ...
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1answer
15 views

How to get a better handle on Spectral Irradiance conversion?

I'm using a computer program to simulate a lightsource. I can feed my own spectral irradiance values into the program to simulate color rendering accuracy. The program takes values in electron volt ...
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1answer
20 views

Hydrogen Spectra using Hydrogen Gas Discharge Tube

I am doing an experiment for my lab work which include determination of value of Rydberg Constant using method of Interpolation. For this we first plot calibration curve for various wavalengths ...
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1answer
63 views
+50

Spin Orbit (lS) interaction energy

Well, I am currently using a pretty old book by H.E White "Atomic Spectra", and he defined spin orbit interaction energy as the product of the resultant frequency and the projection of spin angular ...
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1answer
19 views

Gamma Spectroscopy - Why no Intensity level for Neutron Capture?

I'm undertaking a bit of work looking at a Background Gamma Spectrum. On the spectrum, I have a clear, tall line at 834 KeV. I have a PDF file of a table of Gamma Spectra (ordered in energy) from ...
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1answer
147 views

Total magnetic moment in an atom

I have a doubt regarding the calculation of total angular momentum of electron in an atom. Which is the right way to do it? Method 1: Total magnetic moment $$ \begin{align} \vec{\mu_J} &= ...
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1answer
118 views

Thermionic emission, delayed emission and predissociation

In molecular photodissociation, the thermionic emission, delayed emission and predissociation are the same? Otherwise, what is the difference between them? My question is not about the solids, but I ...
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0answers
27 views

UV absorption decrease with an increase in concentration

I am working on a project measuring the absorbance of a solution which contains surfactant and hard brine. The solution has a constant concentration of surfactant and varying concentration of hard ...
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1answer
51 views

Temperature dependence of spectra

I have a question that is short and sweet: Are spectra (both fluorescence and absorbance) of any molecule dependent on temperature? In particular, is the spectral lineshape function of any molecule ...
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1answer
781 views

What is the secondary electron cutoff in ultraviolet photoelectron spectroscopy?

While the fasted emitted electrons comes from the fermi level of the material in UPS measurement, where does the slowest, which is called secondary electron cut-off orginate from? I really can't ...
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1answer
30 views

How to begin using SDSS data?

SDSS has gone through so many updates, it's difficult to find out how to access the data today in 2015. How can I use SQL and Python to access SDSS data, e.g. the photometry and spectra of quasars, ...
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1answer
134 views

Resolution in a Fourier transform spectroscopy setup

I am a bachelor physics student and as an assignment we had to perform measurements on an FT spectroscopy setup. Context. Our setup consisted of a Michelson interferometer through which the light ...
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1answer
101 views

Which g factor in an EPR spectra is the right one?

I was reading this introduction to EPR and it seems to imply both that there is a unique g-factor of a given compound, but also that we can calculate multiple g-factors for a compound. For example, ...
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1answer
21 views

Help reading power spectrum graphs?

How would I go about figuring out how long a source was measured when given a graph of the power spectrum? From notes I'm following, they just state the total observation time as being roughly ...
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1answer
191 views

What's the difference between microscopy and spectroscopy?

Both methods collect particles or electromagnetic waves, and in both methods it's possible to reconstruct a 2D image, which may represent morphology (AFM, LEED for example), electronic structure (STM, ...
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1answer
292 views

Wigner Threshold law in Photodetachment and Photoionization

I am writing this question here because I have a problem in understanding the Wigner Threshold law in Photodetachment and Photoionization. The Wigner Threshold Law is given by: $\sigma$=$E^{L+1/2}$. ...
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0answers
75 views

What's the difference between “spectromicroscopy” and “microspectroscopy”? [duplicate]

Both definitions that I found are rather vague. (Related question: What's the difference between microscopy and spectroscopy?)
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1answer
26 views

Detecting molecules in space?

http://www.forbes.com/sites/alexknapp/2012/02/24/nasa-detects-solid-buckyballs-in-space/ I refer to the above article, which mentions that buckyballs "far smaller than the width of a hair" were ...
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3answers
134 views

How is this possible that photons are absorbed?

From the lessons on QM, I got impression that there are some discrete orbitals that emit light when electron drops from one to another. Specific molecules emit light in very narrow bands, therefore. ...
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1answer
30 views

Converting spectra to rgb colour

I am having trouble obtaining RGB colour values from the spectra of an object. I have the specific flux $F_\nu$ as a function of $\nu$ for each pixel of the image I'd like to make, but am unsure of ...
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1answer
42 views

What causes this IR emission in UV 365nm LED?

I've just got access to spectrometer and measuring spectrum of everything. But when I took a look at 365nm UV led from chinese UV flashlight I got something really strange - it had some IR at exactly ...
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19 views

Can near-infrared spectroscopy distinguish between various metals?

Can near-infrared spectroscopy be used to distinguish metals from another? If not, why not?
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1answer
31 views

How was hydrogen gas (H) obtained by spectroscopists? Why is there more H than H2 in space?

Introductory quantum mechanics lessons talk about emission and absorption spectra for the hydrogen gas, and then give you an explanation as if this gas were pure $H$ atoms, and not the $H_2$ molecule ...
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1answer
31 views
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75 views

Is the Energy of an absorbed photon exactly the energy of the band gap?

I was wondering, if the Energy of a Photon which is absorbed by an Electron, hast to be exactly the Energy of the bound gap. So if i have two energy levels in an atom $E_2$ and $E_1$, does my ...
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1answer
40 views

What is the reason that EXAFS are done with monochromatic x-ray light?

Why is the light incident on the samples in EXAFS experiments monochromatic? What would happen if a broad bandwidth hits a grating and then all the diffraction spectrum goes through the sample and is ...
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0answers
25 views

Estimation of source irradiance given the spectral sensitivity of the instrument and spectrum of the source

I am trying to measure the irradiance of a UV source, but the available instrument has a different sensitivity. Suppose the black line corresponds to the spectral sensitivity of the instrument ...
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35 views

What does 'easily reversed' mean in the NIST spectral database? [closed]

Cross posted to http://engineering.stackexchange.com/q/3303/ I'm trying to do some processing of optical emission spectra from sputtering plasmas, and am confused by what NIST means by 'easily ...
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2answers
31 views

Is it possible to calculate the relative abundances of elements in the sun based on its line spectrum using a common lab spectroscope?

There are many problems that I feel would hinder the process: atmospheric noise, light pollution etc. Let's assume that I bypass these problems and get an accurate emission line spectrum on the ...
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25 views

Deconvoluting Raman spectras from different wavelengths

I am using a laser source that is wider than typical laser source for Raman spectroscopy. This mean that the full width at half maximum (FWHM) of the laser is about 5-10 nm, compared to the normal 1-3 ...
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0answers
51 views

Spectroscopy from a classical light wave or photon only?

In chemistry we mostly regard light/electromagnetic radiation as a beam of particles or photons. This is a very useful model to explain molecular excitations and ionisations from quantum interactions. ...
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3answers
95 views

Having trouble understanding spectral lines

In my notes I wrote that Rutherford's model of the atom could not explain spectral lines, because that is what my textbook says. I'm not really sure about the details of spectral lines though. I know ...
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0answers
11 views

Hyperfine structure interval rule only obeyed approximately?

The hyperfine interaction is given by $\Delta E = A \langle I \cdot J \rangle = \frac{A}{2}\left[ F(F+1) - I(I+1) - J(J+1) \right]$. The interval rule is given by: $$ \frac{\Delta E_{F,F-1}}{\Delta ...
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1answer
31 views

Asymmetric photoluminescence spectra

Why do photoluminescence spectra have asymmetric lineshapes as those here http://www.scielo.br/img/revistas/bjp/v37n4/a04fig01.gif or here: ...
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2answers
28 views

On energy levels and emission of photons

This is a very basic question but I cannot seem to find the answer anywhere. Say we have an atom in ground state. Its first energy level is 2 eV. An incoming photon of energy 2.5 eV hits an electron ...
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19 views

Does water absorb microwaves above of beneath its relaxation frequency

I am a bit confused about the concept of relaxation frequency. In my course text we derived a model with the help of Newton's law to describe the movement of polar molecules in an electromagnetic ...
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0answers
30 views

PM-IRRAS Equidistant Fringes in Spectrum

What is the cause, and best method to prevent / minimize, fringes in one's FTIR (PM-IRRAS) spectrum on samples deposited on a thin metal film? The fringes look as though they are spaced out by a ...
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0answers
24 views

Sonoluminescence spectrum

During cavitation created by sound in a liquid the collapse of the bubbles can lead to very high temperatures and pressures resulting in the emission of light - sonoluminescence. Can the spectrum of ...
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0answers
9 views

Velocity Selective Coherent Population Trapping and recoil limit on temperature

I have read that it is possible to go under recoil temperature limit using VSCPT (Velocity Selective Coherent Population Trapping) and that this method is based on atoms trapping in quantum state in ...
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1answer
50 views

photon absorption by atoms causes heat?

I have came up with a weird doubt: photon absorption by atoms causes heat? I mean, I was always told that if the photon's frequency is the magic one, the atoms absorbs the photon and goes to an ...
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0answers
17 views

Doppler and recoil limit on temperature

I havent't understood the causes of Doppler limit and recoil limit. I have found on the net different observations about them ("Doppler limit is due to the fact that the atom can't have a smaller ...
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0answers
47 views

Can anybody explain about phase shift and phase spectrum terms in case of multidimensional signal?

I know about phase of a 1D signal, but when I move into higher dimensions like 2D or 3D etc, it becomes headache to grasp the concept. What do the terms "phase shift" and "phase spectrum" mean in ...
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0answers
26 views

Why graphene's substrate is important

I just have some feelings that somehow it is important what specific subtrate is used to grow graphene monolayer on. Some substrates are better, another ones are not so good. But I cannot completely ...
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1answer
36 views

Optical spectrometer

I am new on optical spectrometer, my particular interest is the spectrometer in which the deflection is produced by diffraction in a diffraction grating. But I can not find a good schematic and the ...
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2answers
60 views

How to measure temperature of a laser cooled sample at picoKelvin temperatures?

I'm reading about laser cooling.. my question is: how can the temperature of the sample be measured? (using laser cooling we can reach $10^{-12}K...)$
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0answers
59 views

How to deal with coma and oblique spherical aberration in a Czerny Turner configuration?

I am modelling my own spectrometer using Zemax when all of a sudden I've been told that: even if you manage to optimize the angles or positions of the grating and the mirrors, you won't get ...
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1answer
149 views

What are the purposes of slits inside a spectrometer (Czerny-Turner)?

I am building a Raman spectrometer with a Czerny Turner configuration (with RamanPi). Why does the light source (A) appear to be converging into the entrance slit (B)? When a sample is excited by ...
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1answer
30 views

How to convert the molar attenuation coefficient, ie. molar absorptivity, to heat capacity?

In spectroscopy techniques, such as infrared spectroscopy, light of a certain wavelength is absorbed. I see parallels to the concept of heat capacity, i.e. the heat necessary to change the temperature ...
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1answer
98 views

How to measure distances to stars by means of spectroscopic parallaxes?

How to measure distances to stars by means of spectroscopic parallaxes on practice? What is the accuracy of measuring distances using this method compared with distances based on HIPPARCOS ...