the practice of separating a signal by frequency (or sometimes energy or momentum) and analyzing the resulting spectrum.

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99 views

Thermionic emission, delayed emission and predissociation

In molecular photodissociation, the thermionic emission, delayed emission and predissociation are the same? Otherwise, what is the difference between them? My question is not about the solids, but I ...
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1answer
9 views

What is harmonic and fundamental bands in IR spectroscopy?

What is harmonic and fundamental bands in IR spectroscopy? I'm trying to find exact definitions. I guess that fundamental is $1\leftarrow 0$ transition (the most intense and energetic) and harmonic ...
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1answer
74 views

Autocorrelation function for deterministic nonlinear dynamical systems

I am quite puzzled with the problem that spectral analysis has been either applied to noisy dynamical systems or to chaotic ones. I was wondering why nobody makes analysis of non-linear dynamical ...
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2answers
25 views

Why doesn't the color of an object change when signal of different frequency impinge upon it?

Correct me if I'm wrong but I've always thought that the color that an object has is due to the oscillation of the atoms that makes up the material of that object. When white light is shine upon an ...
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3k views

How do we know the temperature on the planets?

I was watching a show and they were saying that the temperature of Pluto (I know it is not a planet) is about -300 degrees. I know that depends where in the orbit Pluto is, but how do we determine ...
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1answer
97 views

Wigner Threshold law in Photodetachment and Photoionization

I am writing this question here because I have a problem in understanding the Wigner Threshold law in Photodetachment and Photoionization. The Wigner Threshold Law is given by: $\sigma$=$E^{L+1/2}$. ...
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1answer
453 views

What is the secondary electron cutoff in ultraviolet photoelectron spectroscopy?

While the fasted emitted electrons comes from the fermi level of the material in UPS measurement, where does the slowest, which is called secondary electron cut-off orginate from? I really can't ...
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15 views

Reason behind formation of doublets in diffraction spectrum

like if you see is Sodium (and also in Mercury), there are two discrete lines of Yellow color.. What's the reason behind formation of doublets?
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29 views

Why is the color of fire is yellow or blue sometimes? [duplicate]

If you light up any thing it burns in yellow and as well when you light up a gas stove it burns in blue color. What brings this color change?
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17 views

What methods are there to obtain flourescence?

Blackbody radiation is fairly easy to obtain. However, Atomic Emission spectrum based on fluorescence requires more work and provides more information. Traditional methods use a flame or plasma to ...
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3answers
65 views

What's the difference between frequency domain and time domain spectra?

If I have a mechanical oscillator and want to observe the dynamical behavior of the oscillator, is there any additional information to observe it in time domain and frequency domain? Normally, we ...
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0answers
17 views

Spectroscopy Question

So if we were to view the visible spectrum of a white dwarf star. Would the planetary nebula essentially block what would be an absorption spectrum? If so, would we all just see emission lines. I'm ...
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1answer
18 views

What is “Lifetime Intensity” in photoluminescence?

I'm reading an article "Surface plasmon enhanced Förster resonance energy transfer between the CdTe quantum dots". Link The reasearchers are writing about increase in "lifetime intensity" and even ...
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1answer
49 views

Total magnetic moment in an atom

I have a doubt regarding the calculation of total angular momentum of electron in an atom.Which is the right way to do it? Method 1: Total magnetic moment $$ \begin{align} \vec{\mu_J} &= ...
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1answer
89 views

Resolution in a Fourier transform spectroscopy setup

I am a bachelor physics student and as an assignment we had to perform measurements on an FT spectroscopy setup. Context. Our setup consisted of a Michelson interferometer through which the light ...
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1answer
140 views

Why is an exciton only observed when we excite to the conduction band and not to other electronic level inside the bandgap?

Excitons can be observed when we excite electrons to the conduction band. I don't know about excitons being observed when we excite the electrons to an electronic level that would eventually be in ...
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128 views

Total angular momentum in multielectron atoms

I have some confusion about orbitals in multielectron atoms. Let's say we consider an atom (Lithium, for example, $1s^2\, 2p^1$) and that the state of the last electron is [n=2, l=1, ml=0, s=1/2, ...
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1answer
264 views

Can one compute the vibrational spectrum of a bond by the Fourier transform of the dipole moment vector autocorrelation function $C_{\mu\mu}(t)$?

Is it true that one can calculate the vibrational spectrum of a bond by the Fourier transform of the dipole moment vector autocorrelation function $C_{\mu \mu}(t)$? For example, suppose that I have ...
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1answer
45 views

What will be the effect of placing a light source very close to a photodiode?

What will be the effect of placing a photodiode really close to a laser source and what should be the appropriate distance between a light source and photodiode to get maximum output current?
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14 views

Vibrational quantum notation

Reading articles on spectroscopy I often see this notation: 30001 <- 01101, 00011 <- 00001 in context of molecular ...
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1answer
56 views

Unknown peaks on RBS spectrum

I was given a sample, that it is supposed to be a medium thickness Rhodium on top of an infinite silicon waffer. The experimental RBS spectrum along with the simulation looks like that Apparently, ...
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0answers
7 views

Spectroscopic notation for more than one excited electron

In spectroscopy, notation like $^3S_1$ or similar is often used to define atomic states. This is unambiguous when considering only a single electron excited from the outermost energy level. But how ...
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1answer
27 views

What is the 'triangle selection rule' in spectroscopy?

This paper states that However, the multiphonon relaxation bridging the $^5\!D_1$ and $^5\!D_0$ levels is a well-known exception because it is formally forbidden by the triangle rule and occurs ...
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1answer
27 views

How does change of pressure affect molecular rovibrational bands position and width?

Lets say I have $CO_2$ gas chamber with pressure $P_0$. How do rotation-vibrational transition bands alter when I change pressure P? Do they shift or not and why?
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426 views

Homemade Spectrometer

Recently I have had ideas of how to build a spectroscope, but I'm not sure if it will work. As can be seen in the diagram, the experiment is simple: it consists of a laser that generates the light ...
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4answers
308 views

Machine to identify substances

I was looking at Wikipedia's article on mass spectrometers, and realized that the method described was to heat a sample into its gas phase and separate the ions by mass using a large magnet. While I ...
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28 views

Doppler effect for the electrons emitted from ions moving at a particular velocity

If I have ions moving in X axis (along both directions; positive X axis and negative X axis) and if I irradiate laser along the positive X axis, electron will be ejected from the ions (if I am using a ...
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1answer
36 views

Is the emission spectrum of a muonic atom different?

From my quick investigation, the spectrum is based on the Rydberg formula, and with a small change, would lead to $$ {1 \over \lambda_\mu} = {m_\mu \over m_e} \left( R \left( {1\over n_1^2} - ...
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1answer
57 views

Why is cesium used to measure time in atomic clocks?

Seconds are measured by the frequency emission of cesium. Why is a frequency from the emission spectrum of cesium used as the standard in defining a second? Why particularly cesium?
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1answer
48 views

Can this simple spectrometer be precise without collimation?

Consider the following spectrometer structure: Here the slit can be changed in size, and the lens and detector can be moved closer to or farther from the diffraction grating. I was trying to get ...
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1answer
28 views

Hydrogen Spectra [closed]

I am talking about hydrogen spectral lines such as Lyman, Balmer etc. In order to make those spectral lines series more than one electron are needed to jump from higher orbits to lower orbit. But ...
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0answers
23 views

Appearance of the recomposition of a given spectrum? [duplicate]

Given a visible spectrum, i.e. a function from the set of visible wavelengths into the set of intensities, I would like to see the color having this spectrum decomposition. Question: How can I do ...
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10 views

Dielectric resonance spectroscopy of thin and thick film

How does the technique vary for dielectric resonance spectroscopy for thin film of ~ 3 micrometer and a relatively thick film of 100 micrometer?
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2answers
104 views

Do all elements spectrum lines fall within the visible light range?

I was wondering if whether we were extremely lucky to have found spectral (absorption) lines of astronomical objects because they fell within the visible light range or if there something intrinsic ...
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12 views

What is the difference between Linear and Non-Linear Magneto-optical effects?

Principle difference between Linear and Non-Linear Magneto-optical effects and how they affect the property of light passing through a Vapor medium.
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1answer
62 views

What causes the triplet state in Helium?

I am not familiar with the notation used on wikipedia (http://en.wikipedia.org/wiki/Triplet_state). Is there a more physcial way to explain the cause of the triplet state (maybe without referencing ...
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1answer
62 views

Continuous spectra of photons

I guess this is a basic quantum mechanics problem, but I'm not entirely sure of my answer. Suppose we have an electron in a hydrogen atom having the state \begin{equation} ...
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1answer
38 views

Why infrared absorption is a nonlinear technique?

I am looking for a good explanation and/or reference quotation explaining why infrared absorption technique is essentially nonlinear (eg. for carbon monoxide quantification). When using ...
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1answer
52 views

What happens to light at sharp points? [closed]

At the tip of the sharp point shown, what will happen to light incident on it. This curiosity was invoked by a friend and also my childhood of watching shiny pointed swords in cartoons. Original ...
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0answers
33 views

What are the current size limitations of NIR spectroscopes? [closed]

So few days ago I came across this new tool for smart phones http://www.consumerphysics.com/myscio/. It says it uses NIR spectroscopy, which I don't know lot about. My question is: Is it possible for ...
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0answers
35 views

Quantum description of Raman effect

In the classical description of Raman effect the object of study is the electric polarizability of the system. Since I'm interested in learning the quantum description of the Raman effect and in ...
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2answers
65 views

How organic impurities in the air affects laser?

We have a Nd YAG laser pumped Optical Parameter Oscillator in our lab. A technician came to our lab (my professor called him for its maintenance) and while he was working on it, he told me that ...
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2answers
499 views

Experimental observation of matter/antimatter in the universe

Ordinary matter and antimatter have the same physical properties when it comes to, for example, spectroscopy. Hydrogen and antihydrogen atoms produce the same spectroscopy when excited, and adsorb the ...
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2answers
171 views

Rotational velocity of face-on spiral galaxies using spectroscopy

I am doing my first steps in spectroscopy (IFS actually) and how we can learn more about galaxies by using it. I came up with a simple question which, unfortunately, I can not answer: How can we ...
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1answer
77 views

Spectral series' formula of a given atom (other than hydrogen-like)?

The hydrogen spectral series is given by the Rydberg formula: The energy differences between levels in the Bohr model, and hence the wavelengths of emitted/absorbed photons, is given by the ...
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3answers
97 views

What does the $y$-axis represent in the atomic spectra and what is its significance?

The picture is an emission spectrum of Helium. The spectrum has sharp lines (peaks) at certain wave lengths characterizing it as helium. Agreed that it characterizes Helium as atomic spectral line ...
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3answers
191 views

Raman vs. Brillouin Scattering

In my class notes, I have the two types of inelastic scattering described as follows. (Note that the "difference in energy" here is the difference between the incident frequency of the light and the ...
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55 views

Why does inelastic X-ray scattering probe the longitudinal dielectric function as opposed to the transverse dielectric function?

Light is a transverse wave. Therefore, light in the optical range (i.e. visible light) couples to transverse collective excitations of a material when measuring the optical conductivity for instance. ...
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3answers
88 views

Can stimulated emitted photons be absorbed?

Typically a stimulated photon will be one of a pair with its stimulating photon. If the leading photon is absorbed by a particle in the ground state, will it then be re-emited by the stimulated ...
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1answer
47 views

Where I could find values for rare earth metalls levels diagramm (Dieke diagram)?

The Dieke diagrams like this: could be easily found in internet. But it is impossible to determine from where they get values initially, everyone is making cross-links. I'm especially interested ...