the practice of separating a signal by frequency (or sometimes energy or momentum) and analyzing the resulting spectrum.

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14 views

Doppler-free saturation spectrscopy line

Throught he Doppler-free saturation spectroscopy technique I can see the absorption lines of $^{39}$ K: The hyperfine structure of the excited state (D2 line) of K is not resolved enough to see the ...
6
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3answers
84 views

Why absorption spectum is not identical to emission spectrum?

Hydrogen emission and absorption spectral lines are typically depicted as the same: (source) However, in more complex systems, the emission and absorption spectra are significantly different. For ...
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4answers
4k views

Why in professional spectroscopes diffraction gratings are used instead of prisms?

Why in professional spectroscopes diffraction gratings are used instead of prisms? I guess transparency is not an issue, as we need optics anyway.
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1answer
140 views

Thermionic emission, delayed emission and predissociation

In molecular photodissociation, the thermionic emission, delayed emission and predissociation are the same? Otherwise, what is the difference between them? My question is not about the solids, but I ...
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1answer
425 views

Why is the spectrum of old stellar populations characterized by broad lines?

I'm taking a course in astrophysics and my teacher said that old stellar populations have broad lines whereas young populations have narrow emission lines. My first thought was to consider then case ...
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0answers
30 views

Distribution of quantum beating among spectral frequencies

Let's imagine that we have 3-level system: ground state $\vert 0 \rangle$ and two excited states $\vert 1 \rangle$, $\vert 2 \rangle$ with similar energies $\hbar \omega _1$ and $\hbar \omega _2$ ...
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1answer
205 views

On characteristic X-ray spectra and relative intensity

I am looking at the following image (from http://www.schoolphysics.co.uk/age16-19/Atomic%20physics/X%20rays/text/X_ray_spectra/index.html): and I want to know, of the two curves, which one ...
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1answer
80 views

Why infrared absorption is a nonlinear technique?

I am looking for a good explanation and/or reference quotation explaining why infrared absorption technique is essentially nonlinear (eg. for carbon monoxide quantification). When using UV/visible/...
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1answer
527 views

Wigner Threshold law in Photodetachment and Photoionization

I am writing this question here because I have a problem in understanding the Wigner Threshold law in Photodetachment and Photoionization. The Wigner Threshold Law is given by: $\sigma$=$E^{L+1/2}$. ...
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2answers
2k views

Do excited electrons drop back to same quantum state?

I'm trying to wrap my head around spectroscopy, therefore, I am looking for as complete an answer as possible here, hence why I have broken the question into a different points. Here is what I know ...
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0answers
24 views

Determining bond length of HCN using rotational constant (Physical Chemistry 2)

Context: 2nd year undergraduate student taking Physical Chemistry II. Question: Determine the HC and CN bond lengths in HCN from the rotational constants: B($^{1}H$$^{12}C$$^{14}N$) = 44.316 GHz B($...
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1answer
27 views

Does the sign of imaginary part of complex permittivity have any physical meaning?

I have noticed some papers having written complex permittivity as $e' + je'' $ and others as $e' - je''$. The data in literature does not specify the sign. What should I use and does the sign of $e''$ ...
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1answer
40 views

Spectroscopic properties of hydrogen: H vs. H2

One of the basic experiments everybody learns about when it comes to physics is the spectroscopy of hydrogen gas. The typical set-up has a charge discharge lamp containing the hydrogen. The resulting ...
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1answer
277 views

Why is an exciton only observed when we excite to the conduction band and not to other electronic level inside the bandgap?

Excitons can be observed when we excite electrons to the conduction band. I don't know about excitons being observed when we excite the electrons to an electronic level that would eventually be in ...
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1answer
25 views

Absorption spectra of molecules library

Do you know where I can find a library with absorption spectra? I would like it if then I could input a wavelength and get back a specific value. More specifically I would like to see the absorption ...
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1answer
47 views

Why do High Pressure Gases produce a Continuous Spectrum?

I am aware that low pressure/density gases produce an emission spectrum as there are specific energy transitions that the electrons can make, emitting certain frequencies of EM waves. However high ...
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0answers
5 views

Can I approximate the emission line FWHM for an etalon through doppler broadening?

I'm asked to find the finesse for an etalon needed to make the Zeeman effect of the red Cd line measurable. I found the Zeeman separation of the lines to be about $7 GHz$ for the apparatus given. I ...
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2answers
24 views

Gamma spectroscopy - Nuclide identification

I have a question about what the usual practice is for nuclide identification in gamma spectroscopy. For example, if I see a line at 477 keV, I would write that the origin of this line is $^7Be$. As ...
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2answers
68 views

Can we determine the surface temperature of stars other than the sun by using the black body radiation theory?

It is well known that the surface temperature of the sun can be determined by fitting the solar spectrum to the black body radiation spectrum. Is this scheme feasible for other stars? Possibly the ...
2
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2answers
146 views

What will be the effect of placing a light source very close to a photodiode?

What will be the effect of placing a photodiode really close to a laser source and what should be the appropriate distance between a light source and photodiode to get maximum output current?
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2answers
33 views

Different width of spectral lines for different groups of stars

As seen in an HR-diagram, a certain stellar classification can correspond to more than one group/sequence of stars (G5 could for instance be either a giant, main sequence star or a white dwarf and so ...
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1answer
35 views

Heterodyne detection

According to Phase-stabilized two-dimensional electronic spectroscopy the local oscillator, LO, used for heterodyned signal detection always arrives first at time $t_4$, which is -700fs. In 2D-...
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1answer
18 views

Could IR and Raman be measured simultaneously?

IR and Raman are measured using two different machines. Looking at the nature of excitation and at the way data is collected, it seems that these two measurements could be done simultaneously (or with ...
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0answers
66 views

Why does fluorescence emission detector pick up second order wavelengths with first order scan, even though they have different angles?

my question in more detail and with an example: Let's say I have a 980nm laser and I use that laser to excite my fluorescent solution in cuvette. My scan range is from 300 to 800nm. If, for example I ...
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2answers
968 views

What is decay associated spectra?

What is decay associated spectra? Suppose we measure the fluorescence intensity over different wavelengths and over time, we get: $$I(\lambda,t) = \sum_i^n \alpha_i(\lambda) \exp(\frac{-t}{\tau_i}).$...
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0answers
39 views

Plasmon quenching vs plasmon decay. What is the difference?

I'm reading an article "Quenching, Plasmonic, and Radiative Decays in Nanogap Emitting Devices" (pubs.acs.org/journal/apchd5). I don't understand the following: Counterintuitively, we evidence ...
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1answer
25 views

Why Doppler shift is applicable to spectral lines alone?

In astronomical spectroscopy, Doppler shift is an important parameter. But why is it applicable to spectral lines alone, and not to the continuous spectrum in the background? Shouldn't the motion of ...
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0answers
10 views

Change in Q factor on tuning external magnetic field in Electron spin resonance experiment

Does the Q factor of the cavity resonator show a dip at the resonant value of the external magnetic field while performing an ESR experiment?If so, what is the physical reason behind it?
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9 views

Lorentzian nature of reflected microwave power in Electron Spin Resonance

Reflected microwave power has Lorentzian shape when plotted against frequency in ESR. How to mathematically prove this?
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4answers
13k views

What is the difference between Raman scattering and fluorescence?

What is the difference between Raman scattering and fluorescence? Both phenomena involve the emission of photons shifted in frequency relative to the incident light, because of some energetic ...
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0answers
31 views

Which Hydrogen Emission Lines Appear First?

When a blackbody is heated, it radiates photons. At low temperatures, there isn't much radiation at high-energy end of the spectrum but as the temperature raises, high-energy radiation becomes ...
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0answers
16 views

What photomultiplier failure causes a zero signal?

I have a photomultiplier detector that suddenly stopped working. Usually I would have expected damage to occur over time by overexcitation, leaving a distorted signal. Now I'm unsure whether the PMT ...
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1answer
37 views

Stark broadening and Voigt fitting

I have LIBS spectral data acquired with a CT spectrometer of resolution 0.4nm. I fitted the Voigt profile into the spectral peak at $\lambda_0$. The lorentz $\Delta \lambda_L$ and the gaussian $\...
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1answer
27 views

Should I see evidence of neutron induced gammas on a background spectrum?

If I am looking at a background gamma spectrum taken from a neutron spallation source whilst the beam was off (IE in a shutdown period), should I expect to see emissions coming from neutron induced ...
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3answers
56 views

What physical properties can't be predicted based on index of refraction? [closed]

If I tell you the real and imaginary parts of the index of refraction for all frequencies, name a property that can't be predicted based on that information. If you're assuming this is a gas, specify ...
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0answers
50 views

Calculating Natural Broadening of Emission Lines

I'm trying to demonstrate the small effect of Natural Broadening as compared to other types of broadening (Doppler, Stark, van der Waals, etc.) and my calculations don't match the accepted values. My ...
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0answers
20 views

How to calculate term symbols and quantum numbers in spectroscopic physics?

I am studying for an exam in Quantum and Atomic Physics, and I having trouble working out what all of the possible term symbols are for a given electron configuration. So for instance, if I have the ...
3
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1answer
28 views

Why is a notch filter required for Raman Spectroscopy?

It is my understanding that Raman Spectroscopy uses a notch filter (or sometimes an edge filter) to remove the light from the laser, so only the relevant Raman bands are present. However, if this is ...
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1answer
41 views

Why don't stars re-emit the photons they absorb, thus restoring a continuous emission spectrum?

If you shine white light through a gas, electrons can absorb sufficiently energetic photons to reach higher excited states. This produces gaps in the spectrum and it's how Helium was discovered. So ...
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0answers
27 views

Role of Cavity Resonators in continuous wavelength-electron paramagnetic resonance(CW-EPR)

Why is it necessary to place the sample in a cavity resonator for obtaining EPR spectrum in CW-EPR? What role does a cavity resonator play in a CW-EPR spectrometer?
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0answers
18 views

Absorption cross-section in atoms

How could someone calculate the absorption cross-section for an atomic species, not only on a specific atomic resonance, but derive a result, for the dependence of the absorption cross-section from ...
2
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1answer
229 views

Total magnetic moment in an atom

I have a doubt regarding the calculation of total angular momentum of electron in an atom. Which is the right way to do it? Method 1: Total magnetic moment $$ \begin{align} \vec{\mu_J} &= \vec{...
3
votes
1answer
177 views

How to deal with coma and oblique spherical aberration in a Czerny Turner configuration?

I am modelling my own spectrometer using Zemax when all of a sudden I've been told that: even if you manage to optimize the angles or positions of the grating and the mirrors, you won't get good ...
0
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2answers
49 views

Characteristic frequency

Can you please give me shortest possible (bare basic definition) of the characteristic frequency of a spectrum? All that google gives me are books and articles where I don't understand a word.
2
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1answer
63 views

Why is intensity related to number of photons?

I have been reading up on Doppler broadening and have found a number of sources (for example here and here) which seem to be taking the number of photons in the range $[\nu,\nu+d\nu]$ to be the same ...
2
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2answers
69 views

How can only one valence electron in sodium cause doublet in spectrum?

The valence electron in sodium atom gets excited and moves to higher orbital say $3P$ and it then comes to the lower energy state $3S$ thus there should be only one line in spectrum (regarding this ...
3
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0answers
41 views

How come hydrogen produce spectrum in visible light

I am confused, how can hydrogen produce emission lines in the visible light region? the only excitation that can happen to hydrogen is from energy level 1 to any other energy level, all of that ...
3
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1answer
53 views

Fermi's understanding of the Doppler effect

I am now reading the classic paper by Dicke, The Effect of Collisions upon the Doppler Width of Spectral Lines At the very beginning of the paper, Dicke said ''Quantum mechanically, the Doppler ...
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1answer
22 views

Formation of Line Spectra in light of Bohr's Theory [closed]

I am reading about the electronic structure. It is written that when hydrogen's electron comes back to ground state from excited state, it releases energy in a specific amount according to Bohr. But ...
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199 views

Instrumental function vs. instrumental line profile?

I am reading into spectroscopy and the terms instrumental function and instrumental line profile come up regularly. I have reason to believe that they are not equivalent but cannot find any clear ...