the practice of separating a signal by frequency (or sometimes energy or momentum) and analyzing the resulting spectrum.

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2answers
160 views

Relationship of the abundance of an isotope and the vapor pressure

Say I have a sample of some alkali metal - Rubidium for example. A sample of Rubidium consists of approximately 27% $^{87}$Rb and 73% $^{85}$Rb. Does the vapor pressure of each isotope individual ...
1
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0answers
125 views

Linewidth pressure broadening due to organic molecules

In relation to atmospheric spectroscopy and some other gaseous spectroscopy applications where organic molecules are present in the vapor, does anyone know of any papers or resources on pressure ...
0
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2answers
914 views

Do excited electrons drop back to same quantum state?

I'm trying to wrap my head around spectroscopy, therefore, I am looking for as complete an answer as possible here, hence why I have broken the question into a different points. Here is what I know ...
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1answer
236 views

Spectroscopic notation $s$, $p$, $d$, $f$, $\ldots$

$s$ is sharp, $p$ for principal, $d$ for diffuse, $f$ for fundamental. Where do all those term come from? I do not see any link with the corresponding shapes.
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1answer
79 views

Precision measurements on sodium doublet wavelength?

I'm currently searching for a good and reliable source where precision measurements on the wavelength of the so called sodium doublet ($D_1$ and $D_2$ lines) at approximately 589.0 nm and 589.6 nm are ...
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1answer
27 views

Hydrogen Spectra [closed]

I am talking about hydrogen spectral lines such as Lyman, Balmer etc. In order to make those spectral lines series more than one electron are needed to jump from higher orbits to lower orbit. But ...
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2answers
41 views

For a planet which has a temperature gradient, hot in the center and cooler on the surface, why do we get absorption lines?

For a planet which has a temperature gradient, hot in the center and cooler on the surface, why do we see absorption lines? Similarly, why do we see emission lines if the planet is hot on the ...
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1answer
66 views

4 element super conductor without oxygen and iron

I am trying to find a list with super conductors. In particular I am searching for a superconductor, that consists of 4 elements none of which is Oxygen. The reason I rejected Oxygen, is because(from ...
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1answer
120 views

Diffraction Grating in spectrophotometer

In terms of spectrophotometer, we need to make the light monochromatic before passing it to sample. For that, we use diffraction grating. From the research, I found out that the grating reflects light ...
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1answer
200 views

Thermionic emission and delayed emission

I want to understand the concepts behind the thermionic emission. In thermionic emission, the energy randomization occurs and the energy may be split to electronic or roto-vibrational states. If this ...
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1answer
32 views

Nuclear explosion wavelength data

I am looking for data source (or chart) of spectral data that is being emitted on detonation of nuclear or thermonuclear explosion. Reason I am looking is to see if this data has specific signature ...
0
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1answer
104 views

Non Adiabatic Coupling Term in Born Oppenheimer Approximation

I am attaching a section from a text book (Conical Intersections Electronic Structure, dynamics and spectroscopy: David R Yarkony & Horst Koppel). Here I am not understanding the so called 'Non ...
0
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1answer
43 views

Where I could find values for rare earth metalls levels diagramm (Dieke diagram)?

The Dieke diagrams like this: could be easily found in internet. But it is impossible to determine from where they get values initially, everyone is making cross-links. I'm especially interested ...
0
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1answer
166 views

What is decay associated spectra?

What is decay associated spectra? Suppose we measure the fluorescence intensity over different wavelengths and over time, we get: $$I(\lambda,t) = \sum_i^n \alpha_i(\lambda) ...
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2answers
670 views

How to calculate the total angular momentum (J) values

How can I calculate the values of $J$ (total angular momentum) for a particular term, for instance, ${}^3P$?
0
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1answer
41 views

Is the temperature different and or salinity different can lead to different colour of the water bodies?

I had skimming on an article about Thermocline and Halocline. How can two seas not mix? However, I am still curious on: Why the effect of Thermocline and Halocline are distinguishable based on ...
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1answer
244 views

UV-VIS spectrometer on Solids

I ran an experiment using translucent single crystal solids. I modified the solids along the way using different chemical/temperature environments. After every stage, I ran the samples through a ...
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1answer
216 views

What is the reference spectrum?

What is the reference spectrum? I need to know how to calculate the reference spectrum of a wavelength 500nm.
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1answer
361 views

Given temperature, composition, column density, and radial velocity, can I find the bulk flow of a gas cloud?

We've got a hot star in the middle of a gas cloud. We point a spectrometer at the star, calculating the following attributes of our line of sight at the star through the cloud: Total number of ...
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0answers
3 views

Spectroscopic notation for more than one excited electron

In spectroscopy, notation like $^3S_1$ or similar is often used to define atomic states. This is unambiguous when considering only a single electron excited from the outermost energy level. But how ...
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0answers
21 views

Doppler effect for the electrons emitted from ions moving at a particular velocity

If I have ions moving in X axis (along both directions; positive X axis and negative X axis) and if I irradiate laser along the positive X axis, electron will be ejected from the ions (if I am using a ...
0
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0answers
23 views

Appearance of the recomposition of a given spectrum? [duplicate]

Given a visible spectrum, i.e. a function from the set of visible wavelengths into the set of intensities, I would like to see the color having this spectrum decomposition. Question: How can I do ...
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0answers
7 views

What is the difference between Linear and Non-Linear Magneto-optical effects?

Principle difference between Linear and Non-Linear Magneto-optical effects and how they affect the property of light passing through a Vapor medium.
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0answers
15 views

Why photoelectron imaging is a 'complete' measurement?

In many articles and books, it says that photoelectron imaging gives a 'complete' information. What is mean by 'complete' measurement or a 'complete' information? Through photoelectron imaging ...
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0answers
14 views

Interpretation of decay associated difference spetrum

We measured transient absorption spectra and we got $\Delta A(\lambda,t)=A(\lambda,t)-A(\lambda,0)$. If we use DAS (decay associated spectra) for interpretation, we assume that our data have this ...
0
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0answers
14 views

Dipole and multipole bound state anions: Do these bound electrons behave exactly like conventional electrons in the molecular orbitals?

Recently, I read about dipole and multipole bound anions. Dipole bound anions are those, if I understood correctly, when an electron is attached electrostatically on a neutral molecule which is polar. ...
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0answers
36 views

how does different colour wavelength intefere? [duplicate]

Say a red colour with 400nm mixes with blue colour with 700nm, but out of phase by a little. What would be the resultant colour? I would know how to represent the resulting wave mathematically, but ...
0
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0answers
51 views

On characteristic X-ray spectra and relative intensity

I am looking at the following image (from http://www.schoolphysics.co.uk/age16-19/Atomic%20physics/X%20rays/text/X_ray_spectra/index.html): and I want to know, of the two curves, which one ...
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0answers
66 views

Saddle point and transition state of a molecule

During a transition of a molecule from one state to another, it pass through a transition state. This transition state, mathematically speaking, is a saddle point. That means, the second derivative ...
0
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0answers
27 views

What is the perceived color of a D-illuminant?

I am implementing a software that simulates the color of the sky. To do this, I use a model that takes as input the sun position and returns the Yxy components of a D-illuminant for each point of the ...
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0answers
31 views

Textbook on Diffusion and Diffusion NMR Spectroscopy

I am looking for textbooks ( Mathematical / Theoretical Physics ) that cover diffusion in general. Although it is not necessary that your recommendation covers it, I am also particularly interested ...
0
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0answers
36 views

Difficult to visualize Franck-Condon overlap

The franc condon principle says about the vertical transitions, means the coordinates of the nuclei remains unchanged during an electronic transition. But, what is the physical meaning or how to ...
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0answers
33 views

Doppler broadening: time scale to frequency scale

Consider a cell containing Rubidium and enlight it with a laser. Connect the system with an oscilloscope and give a triangular wave as input (so you can know when the Rubidium is resonant). This is ...
0
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0answers
59 views

Spectroscopy: clarification about doppler shift

I've just begun to study spectroscopy, and I need a clarification about the Doppler Effect. Considering this graph: could you explain me how I can see the doppler shift related to the deeper peak ...
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0answers
69 views

How to measure distances to stars by means of spectroscopic parallaxes?

How to measure distances to stars by means of spectroscopic parallaxes on practice? What is the accuracy of measuring distances using this method compared with distances based on HIPPARCOS ...
0
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0answers
70 views

Elemental sensitivity factors for Auger electrons

Is there any open database of elemental sensitivity factors for Auger electrons? I'm trying to figure out graphite oxidation degree from AES spectra, so relative sensitivity of O to C is required. ...
0
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0answers
107 views

Looking for raw interferogram data / raw FID data from FT-IR / FT-NIR / FT-NMR

I'm trying to get my hands on some raw interferogram data / raw FID data from an FT-IR / FT-NIR / FT-NMR so I can run some tests using FFT with it (it needs to be real data). Here's a picture below of ...
0
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1answer
92 views

Does every wavenumber of IR result in a different kind of vibration?

Does every wavenumber of IR result in a different kind of vibration? If that is true, what if a molecule absorb 2 different wavenumbers (which cause different rocking and symmetrical stretching for ...
0
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2answers
377 views

Diffraction Grating Spectrometry Question [closed]

Yes, this is a homework question, but I've already failed to solve it enough times that the online system hosting it isn't going to give me any marks, so I figure it's a good time to stop hitting the ...
-1
votes
1answer
227 views

What is electron momentum density in solids and molecules?

Can someone kindly help me to know how can i get electron momentum density for one orbital like home? what is the theory of electron momentum density? how can I derive electron momentum density from ...
-4
votes
1answer
620 views

Spectral radiance unit conversion [closed]

I have spectral radiance data in SRUs (spectral radiance units), as a function of wavelength: $$a = \mu W cm^{-2} sr^{-1} nm^{-1} $$ However, I am working with software which requires my data in the ...