the practice of separating a signal by frequency (or sometimes energy or momentum) and analyzing the resulting spectrum.

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52 views

Fermi's understanding of the Doppler effect

I am now reading the classic paper by Dicke, The Effect of Collisions upon the Doppler Width of Spectral Lines At the very beginning of the paper, Dicke said ''Quantum mechanically, the Doppler ...
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1answer
68 views

Switching a PMT from PC-mode to DC-mode: What happens?

I was wondering a bit how it is possible to switch a photo multiplier tube from the photon counting mode to the DC (I assume direct current)-mode. If I simply add a high voltage (as usual), I get the ...
3
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0answers
55 views

How to distinguish Shake-Up Satellites from Plasmons?

I am studying XPS spectra (X-ray Photoelectron Spectroscopy) at the moment. In XPS, different processes can influence the final state energy of detected electrons. One of these processes is the ...
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0answers
101 views

Help Interpreting Ultraviolet Photoelectron Spectroscopy (UPS) data

I was given a batch of UPS data without any background other than the materials examined and I don't have any experiencing interpreting it. I wanted to reach out to some experts (hopefully, someone ...
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2answers
81 views

Photon yield of NaI

We have to calculate the photon yield of the scintillator NaI. We have measured his pulse height spectrum but we have no idea how to solve this problem. Can someone explain it? The source that we used ...
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1answer
204 views

pGRE question on natural line width

The lifetime for the $2p \rightarrow 1s$ transition in hydrogen is $1.6 \times 10^{-9}$ s. The natural line width for the radiation emitted during the transition is approximately... Their solution: ...
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1answer
455 views

How are problems in astronomical spectroscopy solved?

Astronomers based on the ground telescopes, watch the stars and make predictions about them based on the spectrum of light. But when the light from those stars reach the telescopes through the ...
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0answers
19 views

Explain materials with 4 fold symmetry having same reflectance when shone with LCP and RCP

This is my first post here. I am currently reading "Optical planar chiral metamaterial designs for strong circular dichroism and polarization rotation" by Do-Hoon Kwon, Pingjuan L. Werner, and ...
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2answers
89 views

How are different wavelength components collected by the same detector in a spectrometer?

Let's think, we have a detector array (128x1 and each CMOS detector responds 400 to 1000 nm TSL1401CL that way, each detector has 4.6875 nm interval). Then, basically in a spectrometer a prism reflect ...
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1answer
141 views

What does a hot, optically thin gas *look* like?

In another question I tried to answer what a sample of the Sun's photosphere or core would look like, if it could be brought into the lab. Here is a broader question - if I have a small inert ...
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4answers
5k views

Spectrometer vs. Spectrophotometer

I have been researching about the difference of a spectrometer and a spectrophotometer. They both sound the same. What is the difference?
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1answer
453 views

What is harmonic and fundamental bands in IR spectroscopy?

What is harmonic and fundamental bands in IR spectroscopy? I'm trying to find exact definitions. I guess that fundamental is $1\leftarrow 0$ transition (the most intense and energetic) and harmonic ...
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2answers
188 views

Why doesn't the color of an object change when signal of different frequency impinge upon it?

Correct me if I'm wrong but I've always thought that the color that an object has is due to the oscillation of the atoms that makes up the material of that object. When white light is shine upon an ...
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0answers
152 views

Reason behind formation of doublets in diffraction spectrum

like if you see is Sodium (and also in Mercury), there are two discrete lines of Yellow color.. What's the reason behind formation of doublets?
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0answers
156 views

Why is the color of fire is yellow or blue sometimes? [duplicate]

If you light up any thing it burns in yellow and as well when you light up a gas stove it burns in blue color. What brings this color change?
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1answer
21 views

What methods are there to obtain flourescence?

Blackbody radiation is fairly easy to obtain. However, Atomic Emission spectrum based on fluorescence requires more work and provides more information. Traditional methods use a flame or plasma to ...
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0answers
56 views

Spectroscopy Question

So if we were to view the visible spectrum of a white dwarf star. Would the planetary nebula essentially block what would be an absorption spectrum? If so, would we all just see emission lines. I'm ...
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5answers
320 views

What's the difference between frequency domain and time domain spectra?

If I have a mechanical oscillator and want to observe the dynamical behavior of the oscillator, is there any additional information to observe it in time domain and frequency domain? Normally, we ...
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1answer
70 views

What is “Lifetime Intensity” in photoluminescence?

I'm reading an article "Surface plasmon enhanced Förster resonance energy transfer between the CdTe quantum dots". Link The reasearchers are writing about increase in "lifetime intensity" and even ...
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0answers
35 views

Vibrational quantum notation

Reading articles on spectroscopy I often see this notation: 30001 <- 01101, 00011 <- 00001 in context of molecular ...
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1answer
229 views

Total magnetic moment in an atom

I have a doubt regarding the calculation of total angular momentum of electron in an atom. Which is the right way to do it? Method 1: Total magnetic moment $$ \begin{align} \vec{\mu_J} &= \vec{...
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1answer
222 views

What is the 'triangle selection rule' in spectroscopy?

This paper states that However, the multiphonon relaxation bridging the $^5\!D_1$ and $^5\!D_0$ levels is a well-known exception because it is formally forbidden by the triangle rule and occurs ...
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1answer
42 views

How does change of pressure affect molecular rovibrational bands position and width?

Lets say I have $CO_2$ gas chamber with pressure $P_0$. How do rotation-vibrational transition bands alter when I change pressure P? Do they shift or not and why?
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2answers
935 views

Homemade Spectrometer

Recently I have had ideas of how to build a spectroscope, but I'm not sure if it will work. As can be seen in the diagram, the experiment is simple: it consists of a laser that generates the light ...
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4answers
478 views

Machine to identify substances

I was looking at Wikipedia's article on mass spectrometers, and realized that the method described was to heat a sample into its gas phase and separate the ions by mass using a large magnet. While I ...
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1answer
94 views

Is the emission spectrum of a muonic atom different?

From my quick investigation, the spectrum is based on the Rydberg formula, and with a small change, would lead to $$ {1 \over \lambda_\mu} = {m_\mu \over m_e} \left( R \left( {1\over n_1^2} - {1\...
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1answer
743 views

Why is cesium used to measure time in atomic clocks?

Seconds are measured by the frequency emission of cesium. Why is a frequency from the emission spectrum of cesium used as the standard in defining a second? Why particularly cesium?
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1answer
802 views

Can this simple spectrometer be precise without collimation?

Consider the following spectrometer structure: Here the slit can be changed in size, and the lens and detector can be moved closer to or farther from the diffraction grating. I was trying to get ...
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1answer
51 views

Hydrogen Spectra [closed]

I am talking about hydrogen spectral lines such as Lyman, Balmer etc. In order to make those spectral lines series more than one electron are needed to jump from higher orbits to lower orbit. But ...
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24 views

Dielectric resonance spectroscopy of thin and thick film

How does the technique vary for dielectric resonance spectroscopy for thin film of ~ 3 micrometer and a relatively thick film of 100 micrometer?
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2answers
437 views

Do all elements spectrum lines fall within the visible light range?

I was wondering if whether we were extremely lucky to have found spectral (absorption) lines of astronomical objects because they fell within the visible light range or if there something intrinsic ...
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1answer
209 views

Autocorrelation function for deterministic nonlinear dynamical systems

I am quite puzzled with the problem that spectral analysis has been either applied to noisy dynamical systems or to chaotic ones. I was wondering why nobody makes analysis of non-linear dynamical ...
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1answer
75 views

Continuous spectra of photons

I guess this is a basic quantum mechanics problem, but I'm not entirely sure of my answer. Suppose we have an electron in a hydrogen atom having the state \begin{equation} \frac{1}{\sqrt{x^2+(1-x)^2}}...
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1answer
74 views

What happens to light at sharp points? [closed]

At the tip of the sharp point shown, what will happen to light incident on it. This curiosity was invoked by a friend and also my childhood of watching shiny pointed swords in cartoons. Original ...
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0answers
65 views

Quantum description of Raman effect

In the classical description of Raman effect the object of study is the electric polarizability of the system. Since I'm interested in learning the quantum description of the Raman effect and in ...
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1answer
104 views

Spectral series' formula of a given atom (other than hydrogen-like)?

The hydrogen spectral series is given by the Rydberg formula: The energy differences between levels in the Bohr model, and hence the wavelengths of emitted/absorbed photons, is given by the ...
3
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1answer
526 views

Wigner Threshold law in Photodetachment and Photoionization

I am writing this question here because I have a problem in understanding the Wigner Threshold law in Photodetachment and Photoionization. The Wigner Threshold Law is given by: $\sigma$=$E^{L+1/2}$. ...
2
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3answers
453 views

What does the $y$-axis represent in the atomic spectra and what is its significance?

The picture is an emission spectrum of Helium. The spectrum has sharp lines (peaks) at certain wave lengths characterizing it as helium. Agreed that it characterizes Helium as atomic spectral line ...
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0answers
88 views

Why does inelastic X-ray scattering probe the longitudinal dielectric function as opposed to the transverse dielectric function?

Light is a transverse wave. Therefore, light in the optical range (i.e. visible light) couples to transverse collective excitations of a material when measuring the optical conductivity for instance. ...
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1answer
80 views

Why infrared absorption is a nonlinear technique?

I am looking for a good explanation and/or reference quotation explaining why infrared absorption technique is essentially nonlinear (eg. for carbon monoxide quantification). When using UV/visible/...
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3answers
162 views

Can stimulated emitted photons be absorbed?

Typically a stimulated photon will be one of a pair with its stimulating photon. If the leading photon is absorbed by a particle in the ground state, will it then be re-emited by the stimulated ...
2
votes
2answers
146 views

What will be the effect of placing a light source very close to a photodiode?

What will be the effect of placing a photodiode really close to a laser source and what should be the appropriate distance between a light source and photodiode to get maximum output current?
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2answers
58 views

For a planet which has a temperature gradient, hot in the center and cooler on the surface, why do we get absorption lines?

For a planet which has a temperature gradient, hot in the center and cooler on the surface, why do we see absorption lines? Similarly, why do we see emission lines if the planet is hot on the ...
4
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2answers
213 views

How hot is aurora?

Has anyone done research on how hot aurora is? I mean if it is plasma it should be hot and since it is emitting mostly green light due to nitrogen (~78%) in the air, could it then be considered that ...
4
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1answer
152 views

Absorption lines in the context of identifying elements in far away celestial objects

I understand that absorption lines are used to identify elements but how are individual absorption spectrums identified in the light that is received by a telescope?
3
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1answer
516 views

Calibrating the relative intensity of a spectrometer with a blackbody source?

I am trying to compare the relative brightness of H-Beta and H-Alpha lines using a CCD spectrometer. In order to correct for the different grating efficiency at the two different wavelengths. I took ...
3
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0answers
250 views

Absorption coefficient from HITEMP or HITRAN [closed]

How to calculate the absorption coefficient (for radiation) from HITEMP or HITRAN databases? Or where can I find some tables or plots for the absorption coefficient?
0
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1answer
138 views

Nuclear explosion wavelength data

I am looking for data source (or chart) of spectral data that is being emitted on detonation of nuclear or thermonuclear explosion. Reason I am looking is to see if this data has specific signature ...
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27 views

Spatial Resolution in Magnetocardiography

In the science paper called Development of an optical cardio-magnetometer by George Bison, it is mentioned that spatial resolution of 10-20mm is required for mapping MCG signal(page 52). What does the ...
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1answer
675 views

What causes the triplet state in Helium?

I am not familiar with the notation used on wikipedia (http://en.wikipedia.org/wiki/Triplet_state). Is there a more physcial way to explain the cause of the triplet state (maybe without referencing ...