the practice of separating a signal by frequency (or sometimes energy or momentum) and analyzing the resulting spectrum.

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91 views

Is it possible to reconstruct the wavefunction of a molecule from a collection of spectra?

Spectra of a molecule can be calculated if the wavefunction is known. Is it possible to do the opposite?
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4answers
234 views

How do we demonstrate that all spectral colors exist in nature?

Spectral emission by elements occurs in discrete wavelengths. There are only about 118 elements. My question is whether there are pure colors either disfavored in nature or even disallowed? The sun ...
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489 views

Do cosmological and Doppler redshift produce different patterns?

For a given black body radiation curve, would the changes to the spectrum resulting from cosmological expansion and those from Doppler effects be distinguishable on the basis of the shapes of the ...
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1answer
92 views

Temperature dependence of spectra

I have a question that is short and sweet: Are spectra (both fluorescence and absorbance) of any molecule dependent on temperature? In particular, is the spectral lineshape function of any molecule ...
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2answers
34 views

Is it possible to calculate the relative abundances of elements in the sun based on its line spectrum using a common lab spectroscope?

There are many problems that I feel would hinder the process: atmospheric noise, light pollution etc. Let's assume that I bypass these problems and get an accurate emission line spectrum on the ...
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3answers
223 views

Why is the planck function continuous and not discrete?

If we imagine a object made up of Hydrogen gas that is optically thick to all radiation, and is in thermal equilibrium, then, microscopically, photons will be emitted and absorbed as ...
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1answer
231 views

THT (Tetrahydrothiophene) absorption spectrum

I am looking for the absorption spectrum of THT. What is the best way to find these types of exotic material's spectral characteristics?
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938 views

Unstable energy levels

Well, reading about "Raman Effect" I saw that when the electron absorb some energy, with frequency $ \omega_{abs} $, that is different from $ \omega_{n} - \omega_{n-1} \neq \omega_{abs1} $, it go to ...
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147 views

Spin Orbit (lS) interaction energy

Well, I am currently using a pretty old book by H.E White "Atomic Spectra", and he defined spin orbit interaction energy as the product of the resultant frequency and the projection of spin angular ...
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1answer
191 views

Gravitational Stark Effect

Could gravity induce line splittings in the optical spectrum of a molecule similar to the Stark or Zeeman Effects? Naively, a gravitational potential would be a simple addition to the Hamiltonian ...
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1answer
1k views

How can I subtract Spectra?

I am writing an application that should allow to view and manipulate spectra (Raman). I am only given one normal spectrum consisting of 1024 coordinate points. Plus I have a background spectrum that ...
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1k views

Photon absorption probability for a given molecule in gas phase

So I'm pretty sure I'm approaching this problem in the wrong way and I need some guidance (my first hint is that I think I'm thinking about a quantum mechanical problem too classically) Suppose there ...
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3answers
145 views

Can a multipass x-ray absorption cell be constructed?

I've been trying to understand the various concepts behind x-ray optics compared to standard visible/IR optics like mirrors and such. However, the x-ray mirrors I've been finding typically have ...
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1answer
157 views

pGRE question on natural line width

The lifetime for the $2p \rightarrow 1s$ transition in hydrogen is $1.6 \times 10^{-9}$ s. The natural line width for the radiation emitted during the transition is approximately... Their solution: ...
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330 views

What does the $y$-axis represent in the atomic spectra and what is its significance?

The picture is an emission spectrum of Helium. The spectrum has sharp lines (peaks) at certain wave lengths characterizing it as helium. Agreed that it characterizes Helium as atomic spectral line ...
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1answer
118 views

Apparent color of flame as superposition of spectral lines?

In some cases one can identify a substance by the color emitted as it burns in a flame. A green flame might indicate the presence of copper. So here is the question. If we know wavelength and ...
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1answer
64 views

Why can I see the 5D0 to 7F3 transition in the trivalent Eu?

According to the selection rules of the intra-configurational f-f transitions, if the J of the initial or final state is zero, a transition with $\Delta J = 3$ is forbidden by electrical dipole, ...
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1answer
176 views

How do micro-channel plates detect neutral molecules?

Micro-channel plate (MCP) detectors are used to detect photons, electrons or charged particles. But how can MCPs be used to detect neutral particles? In ion traps, the neutral molecules (after being ...
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1answer
69 views

Electronic, vibrational and rotational autoionization

Can anyone please explain me the concept of electronic, vibrational and rotational autoionization. What I understood is, autoionization usually occurs when the ion core is rotationally or ...
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2answers
833 views

Absorption Spectral Broadening

I'm working on a research project involving absorption spectra of particulates in solution. I was curious if someone could clarify or direct me to a resource that explains broadening mechanisms ...
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2answers
3k views

How do electron configuration microstates map to term symbols?

I am trying to understand energy levels of electron configurations. I visited the NIST web site and discovered that the notation used here are called term symbols. After reading corresponding ...
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1answer
37 views

Antisymmetry requirement for the total wavefunction

My understanding is that if we are dealing with a system of two electrons, the total wavefunction needs to be antisymmetric only when the two electrons have same value of n and l ( i.e. they are ...
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1answer
48 views

Dispersion in ultrafast lasers

In mode-locked Ti:sapphire lasers, positive dispersion is caused mainly by the crystal. A prism pair placed in the laser resonator can compensate for some of the dispersion by introducing negative ...
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1answer
60 views

Difference between Rayleigh scattering and fluorescence spectroscopy [closed]

How can we differentiate Rayleigh scattering from fluorescence spectrum?
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1answer
330 views

What's the difference between NMR and EPR?

Both NMR and EPR describe the response of magnetic spin to external field. When collecting data, how do you know you're looking at nucleus spin flip or electron spin flip? In other words, since every ...
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1answer
178 views

Which g factor in an EPR spectra is the right one?

I was reading this introduction to EPR and it seems to imply both that there is a unique g-factor of a given compound, but also that we can calculate multiple g-factors for a compound. For example, ...
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1answer
71 views

How is “Band Intensity” related to absorption coefficient

I am interested in the linear absorption of 762nm light near a transition of molecular oxygen. I need to find some experimental numbers that will tell us how far the 762nm light will propagate before ...
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2answers
142 views

Driving a solution of optical isomer molecules with the resonant frequency

What happens when we drive a solution of optical isomer molecules (enantiomers) with a microwave radiation in resonance with the tunneling frequency of the molecules (the frequency of the transition ...
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1answer
351 views

Confusion concerning the use of wavenumber in exercise about Fabry-Perot etalon

In the exercise we are given that the spectrum of a light source consists of two spectral lines, which both have wavelengths around $500 \text{ nm}$ and the separation between them - given in ...
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54 views

Estimating temperature with Boltzmann relation with split emission lines

I'm trying to estimate the temperature of a plasma through the use of hydrogen lines, $H_{\alpha}$ and $H_{\beta}$ using the Boltzmann relation: $$ \frac{ n_{2} }{ n_{1} } = \frac{ g_{2} }{ g_{1} ...
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23 views

What is the origin of the naming convention for the various branches in vibration-rotational spectroscopy?

In vibration-rotational spectroscopy, the different spectral lines are grouped into branches for different changes in the total angular momentum, i.e. $$ \begin{array}{rrrrrr} & \mathrm{O} & ...
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1answer
31 views

How deep within the sample can the DOS(density of states) be detected by STM(scanning tunnel microscope)?

Using STM equipment, we can get the LDOS(local density of states) on the surface of a sample. I want to know whether the LDOS within the sample(not surface) can be detected by STM. what is the ...
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49 views

In what cases would using a non-resonant spectroscopy be preferable to using the resonant type?

Here it is mentioned that non-resonant Raman spectroscopy is desirable for avoiding fluorescence and for studying water due to water's low polarizability. How is non-resonant Raman desirable in the ...
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56 views

Spectroscopy from a classical light wave or photon only?

In chemistry we mostly regard light/electromagnetic radiation as a beam of particles or photons. This is a very useful model to explain molecular excitations and ionisations from quantum interactions. ...
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34 views

Sonoluminescence spectrum

During cavitation created by sound in a liquid the collapse of the bubbles can lead to very high temperatures and pressures resulting in the emission of light - sonoluminescence. Can the spectrum of ...
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121 views

How to deal with coma and oblique spherical aberration in a Czerny Turner configuration?

I am modelling my own spectrometer using Zemax when all of a sudden I've been told that: even if you manage to optimize the angles or positions of the grating and the mirrors, you won't get ...
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49 views

How to distinguish Shake-Up Satellites from Plasmons?

I am studying XPS spectra (X-ray Photoelectron Spectroscopy) at the moment. In XPS, different processes can influence the final state energy of detected electrons. One of these processes is the ...
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56 views

Spectroscopy Question

So if we were to view the visible spectrum of a white dwarf star. Would the planetary nebula essentially block what would be an absorption spectrum? If so, would we all just see emission lines. I'm ...
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33 views

Vibrational quantum notation

Reading articles on spectroscopy I often see this notation: 30001 <- 01101, 00011 <- 00001 in context of molecular ...
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1answer
200 views

Total magnetic moment in an atom

I have a doubt regarding the calculation of total angular momentum of electron in an atom. Which is the right way to do it? Method 1: Total magnetic moment $$ \begin{align} \vec{\mu_J} &= ...
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1answer
411 views

Wigner Threshold law in Photodetachment and Photoionization

I am writing this question here because I have a problem in understanding the Wigner Threshold law in Photodetachment and Photoionization. The Wigner Threshold Law is given by: $\sigma$=$E^{L+1/2}$. ...
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2answers
123 views

What will be the effect of placing a light source very close to a photodiode?

What will be the effect of placing a photodiode really close to a laser source and what should be the appropriate distance between a light source and photodiode to get maximum output current?
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116 views

Line-shape asymmetry in undergraduate Hydrogen-Deuterium experiment

I'm working as an LA (undergraduate TA) for an undergraduate physics laboratory experiment where students test the Bohr model and use reduced mass to determine the approximate mass of the neutron. In ...
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53 views

How large would the electric field need to be to split the mj -/+1 626.6 nm line of neon?

I am an undergraduate considering an extension on a quantum beats experiment with neon. The premise is to excite neon atoms coherently from a metastable 'ground' state into a superposition of excited ...
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2answers
2k views

Do excited electrons drop back to same quantum state?

I'm trying to wrap my head around spectroscopy, therefore, I am looking for as complete an answer as possible here, hence why I have broken the question into a different points. Here is what I know ...
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1answer
1k views

What is the correct relationship between light intensity and wavelength?

So we looked at the emission line spectra of noble gases in the lab today (hydrogen, neon, helium). And I noticed that the brightest spectral line in the helium spectrum is the yellow one and the ...
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1answer
40 views

How to begin using SDSS data?

SDSS has gone through so many updates, it's difficult to find out how to access the data today in 2015. How can I use SQL and Python to access SDSS data, e.g. the photometry and spectra of quasars, ...
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1answer
123 views

Is the Energy of an absorbed photon exactly the energy of the band gap?

I was wondering, if the Energy of a Photon which is absorbed by an Electron, hast to be exactly the Energy of the bound gap. So if i have two energy levels in an atom $E_2$ and $E_1$, does my ...
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3answers
261 views

What is meant by a “sodium line”?

What speed should a galaxy move with respect to us so that the sodium line at $589.0\ \mathrm{nm}$ is observed at $589.6\ \mathrm{nm}$? In the above question what's meant by a sodium line? The ...
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2answers
361 views

Do all elements spectrum lines fall within the visible light range?

I was wondering if whether we were extremely lucky to have found spectral (absorption) lines of astronomical objects because they fell within the visible light range or if there something intrinsic ...