the practice of separating a signal by frequency (or sometimes energy or momentum) and analyzing the resulting spectrum.

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253 views

How the spectrum of the hydrogen atom is checked/detected experimentally?

When solving the hydrogen atom, as a 2 body problem, we have the motion of the center of mass and the motion relative to the center of mass. The well known energy spectrum, $E_n$, that goes like ...
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2answers
44 views

How organic impurities in the air affects laser?

We have a Nd YAG laser pumped Optical Parameter Oscillator in our lab. A technician came to our lab (my professor called him for its maintenance) and while he was working on it, he told me that ...
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1answer
24 views

Equivalent temperature: laser and cell containing Rb

What's the meaning of "equivalent temperature" related to a cell containing rubidium and crossed by laser?
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1answer
69 views

Why is an exciton only observed when we excite to the conduction band and not to other electronic level inside the bandgap?

Excitons can be observed when we excite electrons to the conduction band. I don't know about excitons being observed when we excite the electrons to an electronic level that would eventually be in ...
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1answer
164 views

Why does the addition of paramagnetic ions decrease the spin lattice relaxation time of protons?

My question pertains to NMR (nuclear magnetic resonance). $T_1$, the spin lattice relaxation time of protons in water is about 2.5 seconds. If you add some $CuSO_4$ (copper sulfate) to the water the ...
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0answers
96 views

Intensive radiative heat transfer in very hot gas ( >5000K, gas core nuclear reactor related )

The question: At temperatures above ~5000K are not stable any solid or liquid materials or even more complex molecules (such as fullerenes and Polycyclic aromatic hydrocarbons) which emit/absorb ...
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0answers
96 views

Total angular momentum in multielectron atoms

I have some confusion about orbitals in multielectron atoms. Let's say we consider an atom (Lithium, for example, $1s^2\, 2p^1$) and that the state of the last electron is [n=2, l=1, ml=0, s=1/2, ...
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1answer
200 views

What is the secondary electron cutoff in ultraviolet photoelectron spectroscopy?

While the fasted emitted electrons comes from the fermi level of the material in UPS measurement, where does the slowest, which is called secondary electron cut-off orginate from? I really can't ...
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59 views

How to absorb a characteristic line in a spectrum

I have an x-ray tube. When I see the spectrum, I notice the characteristic lines of the anode. What do I have to do if I want to absorb a characteristic line? I have thought that I can add a filter. ...
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0answers
78 views

Correlation function in relaxation in NMR

I am new in this community, I am from a chemistry background. I want to know a detailed solution of a density matrix for a singlet state using the concept of spin lattice relaxation in NMR. I will ...
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2answers
134 views

Relationship of the abundance of an isotope and the vapor pressure

Say I have a sample of some alkali metal - Rubidium for example. A sample of Rubidium consists of approximately 27% $^{87}$Rb and 73% $^{85}$Rb. Does the vapor pressure of each isotope individual ...
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122 views

Linewidth pressure broadening due to organic molecules

In relation to atmospheric spectroscopy and some other gaseous spectroscopy applications where organic molecules are present in the vapor, does anyone know of any papers or resources on pressure ...
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514 views

Do excited electrons drop back to same quantum state?

I'm trying to wrap my head around spectroscopy, therefore, I am looking for as complete an answer as possible here, hence why I have broken the question into a different points. Here is what I know ...
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1answer
205 views

Spectroscopic notation $s$, $p$, $d$, $f$, $\ldots$

$s$ is sharp, $p$ for principal, $d$ for diffuse, $f$ for fundamental. Where do all those term come from? I do not see any link with the corresponding shapes.
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1answer
19 views

Precision measurements on sodium doublet wavelength?

I'm currently searching for a good and reliable source where precision measurements on the wavelength of the so called sodium doublet ($D_1$ and $D_2$ lines) at approximately 589.0 nm and 589.6 nm are ...
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1answer
42 views

Can scientists tell the energy levels of the atom?

In the hydrogen spectral series how did the scientists know the number of the energy level which the electron is moving from or to?
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1answer
58 views

4 element super conductor without oxygen and iron

I am trying to find a list with super conductors. In particular I am searching for a superconductor, that consists of 4 elements none of which is Oxygen. The reason I rejected Oxygen, is because(from ...
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1answer
86 views

Diffraction Grating in spectrophotometer

In terms of spectrophotometer, we need to make the light monochromatic before passing it to sample. For that, we use diffraction grating. From the research, I found out that the grating reflects light ...
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1answer
168 views

Thermionic emission and delayed emission

I want to understand the concepts behind the thermionic emission. In thermionic emission, the energy randomization occurs and the energy may be split to electronic or roto-vibrational states. If this ...
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1answer
38 views

What is decay associated spectra?

What is decay associated spectra? Suppose we measure the fluorescence intensity over different wavelengths and over time, we get: $$I(\lambda,t) = \sum_i^n \alpha_i(\lambda) ...
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2answers
152 views

How to calculate the total angular momentum (J) values

How can I calculate the values of $J$ (total angular momentum) for a particular term, for instance, ${}^3P$?
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1answer
202 views

UV-VIS spectrometer on Solids

I ran an experiment using translucent single crystal solids. I modified the solids along the way using different chemical/temperature environments. After every stage, I ran the samples through a ...
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1answer
159 views

What is the reference spectrum?

What is the reference spectrum? I need to know how to calculate the reference spectrum of a wavelength 500nm.
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1answer
490 views

Calculating Kramers-Kronig using Mathematica

First of all, I know there is a Mathematica group in beta, but I don't think the problem of the following is directly a Mathematica issue. I am trying to calculate the change of the refractive index ...
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1answer
349 views

Given temperature, composition, column density, and radial velocity, can I find the bulk flow of a gas cloud?

We've got a hot star in the middle of a gas cloud. We point a spectrometer at the star, calculating the following attributes of our line of sight at the star through the cloud: Total number of ...
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0answers
22 views

Saddle point and transition state of a molecule

During a transition of a molecule from one state to another, it pass through a transition state. This transition state, mathematically speaking, is a saddle point. That means, the second derivative ...
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0answers
16 views

What is the perceived color of a D-illuminant?

I am implementing a software that simulates the color of the sky. To do this, I use a model that takes as input the sun position and returns the Yxy components of a D-illuminant for each point of the ...
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20 views

Textbook on Diffusion and Diffusion NMR Spectroscopy

I am looking for textbooks ( Mathematical / Theoretical Physics ) that cover diffusion in general. Although it is not necessary that your recommendation covers it, I am also particularly interested ...
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1answer
17 views

Where I could find values for rare earth metalls levels diagramm (Dieke diagram)?

The Dieke diagrams like this: could be easily found in internet. But it is impossible to determine from where they get values initially, everyone is making cross-links. I'm especially interested ...
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0answers
24 views

Difficult to visualize Franck-Condon overlap

The franc condon principle says about the vertical transitions, means the coordinates of the nuclei remains unchanged during an electronic transition. But, what is the physical meaning or how to ...
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0answers
19 views

Doppler broadening: time scale to frequency scale

Consider a cell containing Rubidium and enlight it with a laser. Connect the system with an oscilloscope and give a triangular wave as input (so you can know when the Rubidium is resonant). This is ...
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0answers
48 views

Spectroscopy: clarification about doppler shift

I've just begun to study spectroscopy, and I need a clarification about the Doppler Effect. Considering this graph: could you explain me how I can see the doppler shift related to the deeper peak ...
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1answer
26 views

Is the temperature different and or salinity different can lead to different colour of the water bodies?

I had skimming on an article about Thermocline and Halocline. How can two seas not mix? However, I am still curious on: Why the effect of Thermocline and Halocline are distinguishable based on ...
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0answers
55 views

What is the physical meaning of multiplicity of an electronic state in a molecule?

When we specify the electronic states, we specify its multiplicity as well. If S is the spin quantum number, then 2S+1 is the corresponding multiplicity. Two states having same L value but with ...
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0answers
56 views

How to measure distances to stars by means of spectroscopic parallaxes?

How to measure distances to stars by means of spectroscopic parallaxes on practice? What is the accuracy of measuring distances using this method compared with distances based on HIPPARCOS ...
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0answers
27 views

Elemental sensitivity factors for Auger electrons

Is there any open database of elemental sensitivity factors for Auger electrons? I'm trying to figure out graphite oxidation degree from AES spectra, so relative sensitivity of O to C is required. ...
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0answers
74 views

Looking for raw interferogram data / raw FID data from FT-IR / FT-NIR / FT-NMR

I'm trying to get my hands on some raw interferogram data / raw FID data from an FT-IR / FT-NIR / FT-NMR so I can run some tests using FFT with it (it needs to be real data). Here's a picture below of ...
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0answers
36 views

$a^3B_2$, $b^3A_2$ and $A^1A_2$ states in electron spectroscopy

I am new to electron spectroscopy. I have a basic question regarding the molecular transition. I have learned about the states $\Sigma_g^+$ $\Pi_g$.. etc electronic states. But I could never find in ...
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0answers
110 views

Something Weird About My Kurie Plot - Beta Spectroscopy

So I'm doing a Beta Spectroscopy of Sodium and apart from the Energy Spectrum, I'm intending to use the Kurie Plot to incorporate the Coulomb Correction Factor $F(Z,p)$. But when I try plotting the ...
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0answers
70 views

Photometric versus radiometric and spectral quantities

Are spectral quantities the same as photometric quantities? How do you pass from a radiometric quantity $R$ to the correspondent spectral quantity $R_λ$ I've been ask to pass from Irradiance to ...
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1answer
79 views

Thermionic emission, delayed emission and predissociation

In molecular photodissociation, the thermionic emission, delayed emission and predissociation are the same? otherwise, what is the difference between them? My question is not about the solids, but I ...
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1answer
82 views

Does every wavenumber of IR result in a different kind of vibration?

Does every wavenumber of IR result in a different kind of vibration? If that is true, what if a molecule absorb 2 different wavenumbers (which cause different rocking and symmetrical stretching for ...
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2answers
267 views

Diffraction Grating Spectrometry Question [closed]

Yes, this is a homework question, but I've already failed to solve it enough times that the online system hosting it isn't going to give me any marks, so I figure it's a good time to stop hitting the ...
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1answer
187 views

What is electron momentum density in solids and molecules?

Can someone kindly help me to know how can i get electron momentum density for one orbital like home? what is the theory of electron momentum density? how can I derive electron momentum density from ...
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1answer
371 views

Spectral radiance unit conversion [closed]

I have spectral radiance data in SRUs (spectral radiance units), as a function of wavelength: $$a = \mu W cm^{-2} sr^{-1} nm^{-1} $$ However, I am working with software which requires my data in the ...