the practice of separating a signal by frequency (or sometimes energy or momentum) and analyzing the resulting spectrum.

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Resources and requirements for amateur spectroscopy

If I wanted to move beyond just looking through my eyepieces and taking photographs of astronomical objects, what can I do do move into astronomical spectroscopy? Are there any good resources for ...
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972 views

Phonons, rotons, and maxons

What are phonons, rotons, and maxons, and what does their dispersion curve have to do with superfluidity? I understand that they are quasiparticles, but I'm not entirely sure what that implies. Are ...
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145 views

Absorption lines in the context of identifying elements in far away celestial objects

I understand that absorption lines are used to identify elements but how are individual absorption spectrums identified in the light that is received by a telescope?
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3k views

Energy shift between hydrogen and deuterium

Stated: The atomic spectra of hydrogen and deuterium are similar however shifted in energies. So im trying to explain why it is that the emission lines are shifted and how they are shifted. Since ...
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239 views

Is it possible to determine timescales of electron dynamics from the natural linewidth of an electronic transition?

A lot of work has been done recently on electron dynamics using attosecond pump-probe techniques; for instance in this paper. In this particular paper, the authors photoionized the neutral ...
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45 views

How do space probes identify molecules?

How does a space probe identify molecules without actually obtaining the molecules? The common identification techniques I can think of are spectroscopy and magnetic resonance, but for both of them, ...
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105 views

Why does the refractive index not mirror the Lorentzian peak shape of the absorption index?

In the characterization of materials, there are many methods used: One of them is infrared spectroscopy. In a lab we saw the indices of refraction and absorption of a certain (semiconductor) solid ...
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2k views

Understanding the Selection Rules of a Spin-Forbidden, Magnetic Dipole Transition in Molecular Oxygen

I am studying the transition from the second excited electronic state of molecular oxygen, $b^1\Sigma_g^+$ , to the ground state, $X^3\Sigma_g^-$. I know that the ground state has total angular ...
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997 views

Why does the addition of paramagnetic ions decrease the spin lattice relaxation time of protons?

My question pertains to NMR (nuclear magnetic resonance). $T_1$, the spin lattice relaxation time of protons in water is about 2.5 seconds. If you add some $CuSO_4$ (copper sulfate) to the water the ...
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110 views

What causes this IR emission in UV 365nm LED?

I've just got access to spectrometer and measuring spectrum of everything. But when I took a look at 365nm UV led from chinese UV flashlight I got something really strange - it had some IR at exactly ...
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202 views

How hot is aurora?

Has anyone done research on how hot aurora is? I mean if it is plasma it should be hot and since it is emitting mostly green light due to nitrogen (~78%) in the air, could it then be considered that ...
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221 views

why do we get continuous intensity in spectra?

we know energy levels of a molecule is discrete. So we should get only sharp peaks for any spectra. But in most of the spectra I see a continuous intensity? why is so? In the following spectra the ...
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365 views

QM with complex eigenvalues

What class of theories/physical systems own finite/infinite complex eigenvalues? I do know that e.g., quasinormal modes of BH do have complex eigenvalues, but are they finite or infinite in number? ...
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49 views

Do XAFS excitations and subsequent relaxations lead to vibrationally hot molecules?

I'm in the process of trying to understand X-Ray Absorption Fine Structure (XAFS) spectroscopy, but I think this question is more fundamental than merely as it pertains to XAFS. I think I don't ...
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160 views

Interchange symmetry for states with identical particles

I was reading this web page about interchange symmetry for states with identical particles here: http://quantummechanics.ucsd.edu/ph130a/130_notes/node317.html The article states that the highest ...
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138 views

What does a hot, optically thin gas *look* like?

In another question I tried to answer what a sample of the Sun's photosphere or core would look like, if it could be brought into the lab. Here is a broader question - if I have a small inert ...
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3k views

Why do stars have absorption spectra?

Absorption spectra are a result of light of a certain wavelength exciting an atom from a lower energy level to a higher one and at the same time being absorbed. However, the atom should eventually go ...
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409 views

How do NASA's Curiosity determine the elemental composition of Mars using spectrometer?

From this article on hindustantimes.com - Curiosity sends data about Martian surface: The resultant flash of glowing plasma is viewed by the system’s 4.3-inch aperture telescope, which sends the ...
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181 views

Absorption line detected with a significance of $2.2\sigma$

What do we mean by the following statement? The SV $\lambda$ 786.46 line is detected with a equivalent width of $W = 22.7\pm10.2$ corresponding to a significance of $2.2\sigma$ How does one ...
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3k views

Why do we take the first derivative of EPR/ESR spectra?

Apologies if this question is a bit too chemistry-flavoured. In electron paramagnetic resonance spectroscopy, there's a practically ubiquitous convention of plotting the first derivative of the ...
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1answer
358 views

Suns emission spectrum

I learnt that in astrophysical spectroscopy, the emission spectrum of distant stars is used to determine what they're made of. So why is it that our own Sun is emitting the whole spectrum ? (or is ...
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29 views

Different width of spectral lines for different groups of stars

As seen in an HR-diagram, a certain stellar classification can correspond to more than one group/sequence of stars (G5 could for instance be either a giant, main sequence star or a white dwarf and so ...
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25 views

Why is a notch filter required for Raman Spectroscopy?

It is my understanding that Raman Spectroscopy uses a notch filter (or sometimes an edge filter) to remove the light from the laser, so only the relevant Raman bands are present. However, if this is ...
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90 views

Is the emission spectrum of a muonic atom different?

From my quick investigation, the spectrum is based on the Rydberg formula, and with a small change, would lead to $$ {1 \over \lambda_\mu} = {m_\mu \over m_e} \left( R \left( {1\over n_1^2} - ...
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491 views

Calibrating the relative intensity of a spectrometer with a blackbody source?

I am trying to compare the relative brightness of H-Beta and H-Alpha lines using a CCD spectrometer. In order to correct for the different grating efficiency at the two different wavelengths. I took ...
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1answer
214 views

absorption and emission lines in Cassiopeia A hydrogen spectrum

we recently took a tour to a radio telescope and recorded some spectra, one of them being Cassiopeia A. Looking at the difference in on-source and off-source spectra, we find sharp absorption and ...
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228 views

What determines the form of the intensity curves in Laser-Induced Fluorescence (LIF) measurements?

What determines the form of the intensity spectra of different particle species in Laser-Induced Fluorescence (LIF) measurements? See e.g. I figure that bigger particles have more ways to get ...
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171 views

Absorption cross section for direct dissociation and predissociation - Photoelectric absorption

Why the absorption cross section in direct dissociation process is wide and structureless while the absorption cross section in the predissociation process is structured and containing lines which are ...
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160 views

How to deal with coma and oblique spherical aberration in a Czerny Turner configuration?

I am modelling my own spectrometer using Zemax when all of a sudden I've been told that: even if you manage to optimize the angles or positions of the grating and the mirrors, you won't get ...
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1k views

What are the purposes of slits inside a spectrometer (Czerny-Turner)?

I am building a Raman spectrometer with a Czerny Turner configuration (with RamanPi). Why does the light source (A) appear to be converging into the entrance slit (B)? When a sample is excited by ...
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695 views

Why is cesium used to measure time in atomic clocks?

Seconds are measured by the frequency emission of cesium. Why is a frequency from the emission spectrum of cesium used as the standard in defining a second? Why particularly cesium?
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775 views

Can this simple spectrometer be precise without collimation?

Consider the following spectrometer structure: Here the slit can be changed in size, and the lens and detector can be moved closer to or farther from the diffraction grating. I was trying to get ...
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3k views

Bleaching groundstate

I'm reading an article about two-dimensional infrared spectroscopy and I don't understand the following sentence. Bleach or stimulated emission contributions yield negative signals. What are ...
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619 views

Enhance a home build spectrometer

I would like to build a home made spectrometer like it's describing here: http://coolcosmos.ipac.caltech.edu/cosmic_games/spectra/makeGrating.htm How can I improve this spectrometer? A prism from an ...
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5k views

Glycerol: refractive index & absorption spectra in 0.2-0.4um range

Could anyone suggest where can I find absorption spectra & refractive index of Glycerol? I am specifically interested in UV range, 200-400nm, everything I was able to find out was for standard ...
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835 views

Light emission spectrum units

Do someone knows the units of the spectra provided here ? It seems obvious enough that it's said nowhere, but even Wikipedia and other sites are quite blurry on this point. So, is it power ($W$), ...
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2answers
102 views

Why is the blue line in the Balmer series sometimes not visible?

So I've conducted an experiment to find the four visible hydrogen emission spectrum lines in the Balmer series in a laboratory. I don't have any background in quantum physics. When I looked through ...
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1answer
4k views

Resolving power of a diffraction grating?

I was working thru a derivation of the resolving power of a diffraction grating at the $n$th order. Here is that derivation: Let us say we have a diffraction grating width $W$ and are looking at ...
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1answer
124 views

Relative weights in rotational bands of symmetric diatomic molecules

In an old paper, Ehrenfest 1931, the introduction starts off as follows: The band spectra of symmetric diatomic molecules show certain striking differences from those of asymmetric molecules. For ...
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1k views

What is the secondary electron cutoff in ultraviolet photoelectron spectroscopy?

While the fasted emitted electrons comes from the fermi level of the material in UPS measurement, where does the slowest, which is called secondary electron cut-off orginate from? I really can't ...
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305 views

Rotational velocity of face-on spiral galaxies using spectroscopy

I am doing my first steps in spectroscopy (IFS actually) and how we can learn more about galaxies by using it. I came up with a simple question which, unfortunately, I can not answer: How can we ...
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387 views

Can one compute the vibrational spectrum of a bond by the Fourier transform of the dipole moment vector autocorrelation function $C_{\mu\mu}(t)$?

Is it true that one can calculate the vibrational spectrum of a bond by the Fourier transform of the dipole moment vector autocorrelation function $C_{\mu \mu}(t)$? For example, suppose that I have ...
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1answer
115 views

Does the spectrum of Sol's emission change as it ages?

A follow-up to my earlier question How would one navigate interstellar space? that just occurred to me; albeit on a different tack. Sol is probably in a state of continuous flux. The change of state ...
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1answer
243 views

How small of a depletion signal can the best modern mass spectrometers detect?

So I know the answer to this question varies widely across mass spec techniques, masses, and, of course, budgets, but my question is about the best case scenario for all of these variables (although ...
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41 views

How come hydrogen produce spectrum in visible light

I am confused, how can hydrogen produce emission lines in the visible light region? the only excitation that can happen to hydrogen is from energy level 1 to any other energy level, all of that ...
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35 views

Book on spectroscopy (line dependency on parameters)

I am trying to find a book (undergraduate level) on Spectroscopy. I am interested in how molecular absorption lines depend on parameters like temperature and pressure (for example with gases). Can ...
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1answer
52 views

Fermi's understanding of the Doppler effect

I am now reading the classic paper by Dicke, The Effect of Collisions upon the Doppler Width of Spectral Lines At the very beginning of the paper, Dicke said ''Quantum mechanically, the Doppler ...
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52 views

How to distinguish Shake-Up Satellites from Plasmons?

I am studying XPS spectra (X-ray Photoelectron Spectroscopy) at the moment. In XPS, different processes can influence the final state energy of detected electrons. One of these processes is the ...
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64 views

Quantum description of Raman effect

In the classical description of Raman effect the object of study is the electric polarizability of the system. Since I'm interested in learning the quantum description of the Raman effect and in ...
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1answer
501 views

Wigner Threshold law in Photodetachment and Photoionization

I am writing this question here because I have a problem in understanding the Wigner Threshold law in Photodetachment and Photoionization. The Wigner Threshold Law is given by: $\sigma$=$E^{L+1/2}$. ...