the practice of separating a signal by frequency (or sometimes energy or momentum) and analyzing the resulting spectrum.

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99 views

Why is an exciton only observed when we excite to the conduction band and not to other electronic level inside the bandgap?

Excitons can be observed when we excite electrons to the conduction band. I don't know about excitons being observed when we excite the electrons to an electronic level that would eventually be in ...
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172 views

How would a physicist measure temperature of molten metals in 1850-1920s?

How would a physicist measure temperature of molten metals in 1850-1920s? What equipment would be used?
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63 views

Precision of spectroscopy for astronomy

How precise can the measurements be when looking at spectral lines in astrophysics? For example, suppose I have a telescope in orbit, and I am looking at $H_\alpha$ lines coming from a star at 613 ...
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3answers
97 views

How to smooth the spectrum of a light source?

Could somebody please tell me if there's a reasonably cheap substance or device can I use to smooth the spectrum of a light source? For example, if the spectrum has spikes as in the blue graph below, ...
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2answers
114 views

why do we get continuous intensity in spectra?

we know energy levels of a molecule is discrete. So we should get only sharp peaks for any spectra. But in most of the spectra I see a continuous intensity? why is so? In the following spectra the ...
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44 views

Resonance Raman spectroscopy vs fluorescence

In Resonance Raman Spectroscopy we often want to avoid the fluorescence. But what is the problem with fluorescence . What we want is a shift between exciting line and emitted radiation and both can ...
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129 views

The effect of dark lines in the Sun's spectrum on reflected paint/ color

Its well known that the Sun's spectrum is not continuous, and that there are dark bands within the suns spectrum. Is it possible to produce a color of paint that is bright in, say, indoor lighting and ...
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73 views

Where to find detailed measured emission spectra of all chemical elements?

I'd like to have something like this, but for single atoms and with more extended range of wavelengths. All I could find e.g. for hydrogen was lots of talks about Rydberg formula etc. and plots of ...
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88 views

Gravitational Stark Effect

Could gravity induce line splittings in the optical spectrum of a molecule similar to the Stark or Zeeman Effects? Naively, a gravitational potential would be a simple addition to the Hamiltonian ...
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171 views

Why is spectrum obtained by sunlight, said to be continuous?

My sir spoke about atomic spectra today. Sir said that, unlike the spectrum obtained by analyzing the sunlight, the spectra of atoms are not continuous. I got a doubt here, i,e even the sunlight ...
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351 views

Diffraction Grating Spectrometry Question [closed]

Yes, this is a homework question, but I've already failed to solve it enough times that the online system hosting it isn't going to give me any marks, so I figure it's a good time to stop hitting the ...
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1answer
44 views

Unknown peaks on RBS spectrum

I was given a sample, that it is supposed to be a medium thickness Rhodium on top of an infinite silicon waffer. The experimental RBS spectrum along with the simulation looks like that Apparently, ...
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63 views

4 element super conductor without oxygen and iron

I am trying to find a list with super conductors. In particular I am searching for a superconductor, that consists of 4 elements none of which is Oxygen. The reason I rejected Oxygen, is because(from ...
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102 views

Diffraction Grating in spectrophotometer

In terms of spectrophotometer, we need to make the light monochromatic before passing it to sample. For that, we use diffraction grating. From the research, I found out that the grating reflects light ...
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1answer
252 views

Why does the addition of paramagnetic ions decrease the spin lattice relaxation time of protons?

My question pertains to NMR (nuclear magnetic resonance). $T_1$, the spin lattice relaxation time of protons in water is about 2.5 seconds. If you add some $CuSO_4$ (copper sulfate) to the water the ...
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106 views

Is there a difference between “two photon absorption” and “double quantum transitions”?

Wikipedia has articles on two photon absorption. And a lot of NMR literature refers to double quantum transitions. But is there a difference? As far as I can tell, a double quantum transition is has ...
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39 views

$a^3B_2$, $b^3A_2$ and $A^1A_2$ states in electron spectroscopy

I am new to electron spectroscopy. I have a basic question regarding the molecular transition. I have learned about the states $\Sigma_g^+$ $\Pi_g$.. etc electronic states. But I could never find in ...
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1answer
135 views

What determines the form of the intensity curves in Laser-Induced Fluorescence (LIF) measurements?

What determines the form of the intensity spectra of different particle species in Laser-Induced Fluorescence (LIF) measurements? See e.g. I figure that bigger particles have more ways to get ...
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2answers
2k views

Full Width Half Maximum (FWHM) of a transmission spectrum

I have a transmission spectrum of a material which has been fit to a Lorentzian. According to Wikipedia here and here, FWHM is the spectral width which is wavelength interval over which the ...
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1answer
205 views

Are CCDs approaching the sensitivity of photomultiplier tubes?

I still see photomultiplier tubes (PMT) used for even benchtop spectroscopy experiments. How much more sensitive are they to CCDs? I found a post which claims about 1.5 x more sensitivity for ...
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1answer
51 views

Why can I see the 5D0 to 7F3 transition in the trivalent Eu?

According to the selection rules of the intra-configurational f-f transitions, if the J of the initial or final state is zero, a transition with $\Delta J = 3$ is forbidden by electrical dipole, ...
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2answers
780 views

What is the difference between the Balmer series of hydrogen and deuterium?

In my quantum mechanics textbook, it claims that the Balmer series between hydrogen and deuterium is different. However, I was under the impression that the Balmer series $$H_\alpha, H_\beta, ...
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2answers
667 views

Galaxy Spectra: Emission and Absorption Lines

Spectra from galaxies include both absorption and emission lines. I do understand how both types of spectral lines are produced but I am not quite sure where each type is coming from when we observe a ...
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1answer
83 views

Relative weights in rotational bands of symmetric diatomic molecules

In an old paper, Ehrenfest 1931, the introduction starts off as follows: The band spectra of symmetric diatomic molecules show certain striking differences from those of asymmetric molecules. For ...
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123 views

Something Weird About My Kurie Plot - Beta Spectroscopy

So I'm doing a Beta Spectroscopy of Sodium and apart from the Energy Spectrum, I'm intending to use the Kurie Plot to incorporate the Coulomb Correction Factor $F(Z,p)$. But when I try plotting the ...
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1answer
581 views

What is mean by 'good quantum number' in spectroscopy?

In electronic spectroscopy of molecules, why some quantum numbers are considered to be 'good quantum numbers'? For example, $n$ and $l$ are said to be not good quantum numbers while $j$ is considered ...
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62 views

Difference between photo electron spectrum and photoelectron angular distribution

I am trying to learn the Photoelectron velocity map imaging. While I was going through the article "Chem. Soc. Rev., 2009,38,2169-2177", it is said that the "photoelectron spectrum reflects the energy ...
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230 views

Polarisation of Light and Atomic Excitation

How does an atomic transition between ground and excited states depend upon the direction of polarisation of incident light?
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79 views

Molecular spectroscopy for atomic spectroscopers

My experience is with atomic spectroscopy of alkali atoms, I've recently been asked by a friend to help with some advice on analyzing molecular spectrophotometry data in the context of molecular ...
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106 views

Intensive radiative heat transfer in very hot gas ( >5000K, gas core nuclear reactor related )

The question: At temperatures above ~5000K are not stable any solid or liquid materials or even more complex molecules (such as fullerenes and Polycyclic aromatic hydrocarbons) which emit/absorb ...
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144 views

Absorption & emission spectra

The process of obtaining an absorption spectra involves passing a complete spectrum of light from the material under consideration. The material absorbs the specific wavelength and allows the rest to ...
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1answer
53 views

Intereference rings by light transmission?

Recently I recorded UV-Vis spectra of liquids with a two-beam spectrometer (Perkin Elmer 900). Lack of proper racks for cells of 0.5 cm optical path length let me use a stack consisting of a 0.2 cm ...
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1answer
53 views

Limits of laser spectroscopy for determining size of a molecule or particle

Say you have a number of particles respectively molecules suspended in air. The diameter of the particles $d_{particle}$ are of the order 1 to 100nm. Can you actually, i.e. in practice, measure the ...
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100 views

Total angular momentum in multielectron atoms

I have some confusion about orbitals in multielectron atoms. Let's say we consider an atom (Lithium, for example, $1s^2\, 2p^1$) and that the state of the last electron is [n=2, l=1, ml=0, s=1/2, ...
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311 views

What is the secondary electron cutoff in ultraviolet photoelectron spectroscopy?

While the fasted emitted electrons comes from the fermi level of the material in UPS measurement, where does the slowest, which is called secondary electron cut-off orginate from? I really can't ...
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1answer
269 views

How can we describe the electrons of multi-electron atoms (i.e. not Hydrogen) when equations/analytic solutions only exist for Hydrogen?

I've been digging into emission spectra of different elements and found that such things as the Rydberg equation, Bohr's model, and quantum mechanics can only fully describe the single electron in the ...
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47 views

SHS Interferometer and diffraction limit

I'm currently researching Spatial Heterodyned Spectrometers (SHS) and I'm a bit at a loss understanding the influence of the diffraction limit. I'll be measuring a diffuse visible light source with ...
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0answers
99 views

Line-shape asymmetry in undergraduate Hydrogen-Deuterium experiment

I'm working as an LA (undergraduate TA) for an undergraduate physics laboratory experiment where students test the Bohr model and use reduced mass to determine the approximate mass of the neutron. In ...
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59 views

How to absorb a characteristic line in a spectrum

I have an x-ray tube. When I see the spectrum, I notice the characteristic lines of the anode. What do I have to do if I want to absorb a characteristic line? I have thought that I can add a filter. ...
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2answers
697 views

Do excited electrons drop back to same quantum state?

I'm trying to wrap my head around spectroscopy, therefore, I am looking for as complete an answer as possible here, hence why I have broken the question into a different points. Here is what I know ...
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1answer
858 views

Bleaching groundstate

I'm reading an article about two-dimensional infrared spectroscopy and I don't understand the following sentence. Bleach or stimulated emission contributions yield negative signals. What are ...
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1answer
157 views

Rutherford Scattering Spectra

I am using SimNRA to simulate the classical Rutherford Scattering. Playing around with it, I came across some spectra that I cannot explain... First of all, if someone plots the spectrum of ...
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1answer
223 views

UV-VIS spectrometer on Solids

I ran an experiment using translucent single crystal solids. I modified the solids along the way using different chemical/temperature environments. After every stage, I ran the samples through a ...
2
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1answer
121 views

How do micro-channel plates detect neutral molecules?

Micro-channel plate (MCP) detectors are used to detect photons, electrons or charged particles. But how can MCPs be used to detect neutral particles? In ion traps, the neutral molecules (after being ...
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1answer
151 views

Rotational velocity of face-on spiral galaxies using spectroscopy

I am doing my first steps in spectroscopy (IFS actually) and how we can learn more about galaxies by using it. I came up with a simple question which, unfortunately, I can not answer: How can we ...
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1answer
54 views

Electronic, vibrational and rotational autoionization

Can anyone please explain me the concept of electronic, vibrational and rotational autoionization. What I understood is, autoionization usually occurs when the ion core is rotationally or ...
4
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1answer
204 views

QM with complex eigenvalues

What class of theories/physical systems own finite/infinite complex eigenvalues? I do know that e.g., quasinormal modes of BH do have complex eigenvalues, but are they finite or infinite in number? ...
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1answer
94 views

Mysterious spectra?

In my blog post Why riemannium? , I introduced the following idea. The infinite potential well in quantum mechanics, the harmonic oscillator and the Kepler (hygrogen-like) problem have energy spectra, ...
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1answer
288 views

Very large absorption lines in stellar spectrum

I was puzzled by the wide absorption lines in a stellar spectrum I found. The following is what I expect absorption lines to look like - thin, crisp lines: However, I found this stellar spectrum, ...
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84 views

Thermionic emission, delayed emission and predissociation

In molecular photodissociation, the thermionic emission, delayed emission and predissociation are the same? Otherwise, what is the difference between them? My question is not about the solids, but I ...