the practice of separating a signal by frequency (or sometimes energy or momentum) and analyzing the resulting spectrum.

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23 views

What is the meaning of the magnitudes on the axes of this spectrum?

I'm taking a course on radiation physics and I've been given an spectrum by my professor (concretely it is a spectrum of $\left.^{22} Na \right.$). This is the first time that I come across this kind ...
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1answer
38 views

Stark broadening and Voigt fitting

I have LIBS spectral data acquired with a CT spectrometer of resolution 0.4nm. I fitted the Voigt profile into the spectral peak at $\lambda_0$. The lorentz $\Delta \lambda_L$ and the gaussian $\...
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1answer
31 views

Where can I find the Auger emission spectra of the most common chemical elements?

I am looking for an online resource where I can find the Auger emission spectra of (most common) chemical elements, i need them for AES (Auger Emission Spectroscopy). Thank you.
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3answers
597 views

How can light emit three kinds of spectra?

In case of black-body radiation, radiation gives continuous spectra. Molecular spectra is an example of band spectra. Similarly, there's also the atomic spectra. Why are the spectra of light not same ...
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1answer
223 views

Exact meaning of “pi/2 pulse”

In studying Mach-Zehnder and Ramsey interferometers, I came across the expression "$\pi/2$ pulse". What does it mean exactly? I am working with a Bloch vector representation $(u,v,w)$ of a 2 state ...
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44 views

Sum rule in X-ray Photoelectron Spectroscopy (XPS)

What is the sum rule in X-ray Photoelectron Spectroscopy (XPS)? how can I derive it? Can anybody explain the principle of sum rule in XPS or in spectroscopy in general? How can I apply it to a ...
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40 views

Multi-photon excitation probability for a two-level system

If a two-level system with a lifetime $\tau$ is excited with a pulse of duration $t_{pulse}$, what is the probability of exciting more than one photon? For simplicity we can take it to be a $\alpha \...
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37 views

Book on spectroscopy (line dependency on parameters)

I am trying to find a book (undergraduate level) on Spectroscopy. I am interested in how molecular absorption lines depend on parameters like temperature and pressure (for example with gases). Can ...
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28 views

What is the origin of the naming convention for the various branches in vibration-rotational spectroscopy?

In vibration-rotational spectroscopy, the different spectral lines are grouped into branches for different changes in the total angular momentum, i.e. $$ \begin{array}{rrrrrr} & \mathrm{O} & \...
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73 views

Difference between three mutually complementary methods: Raman, Infra-red spectroscopy and inelastic incoherent neutron spectroscopy?

When I read the wiki on Raman spectroscopy, I found a paragraph explaining what system is suitable for using Raman and what others do not. It provide two other method as shown in title: infrared ...
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30 views

Why higher FAT level implies more signal in XPS analysis?

In XPS analysis, the FAT (Fixed Analyzer Transmission) parameter controls the electrostatic field of an emispheric analyzer, called Pass Energy $E_P$. The FWHM of a peak of signal is given by $$\...
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17 views

Gamma spectroscopy - Extractable information from peak significance changes?

Apologies for the title - I couldn't think of a better way to summarize my question I have a table which contains information on 60 gamma spectra taken over a total period of 20 days, from the hall ...
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49 views

Quantum beats and Quantum mechanical side of photosynthesis

I have two questions. One concerning quantum beats alone, another - process of photosynthesis. I am very well aware that there is strong evidence suggesting that mechanism that leads light through, ...
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0answers
57 views

Can one measure experimentally the average distance between the two electrons in the excited state of helium in the singlet versus triplet states?

$\frac{1}{\lvert\ \vec(r_{1})-\vec(r_{2})\rvert}$ is a hermitian operator so I am supposing there could potentially be an observable with this which might be experimentally measured. We can measure ...
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54 views

Beta decay - Relative probability of electronic conversion for different disexcitations energies

I'm studying, experimentally, beta decay phenomena. Internal conversion of electrons happens when we have a sobreposition between a excited nucleus with it's electronic cloud. The colision between the ...
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1answer
56 views

Antisymmetry requirement for the total wavefunction

My understanding is that if we are dealing with a system of two electrons, the total wavefunction needs to be antisymmetric only when the two electrons have same value of n and l ( i.e. they are ...
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31 views

How can I determine if a peak in a spectrofluorometer's spectrum is erroneous?

Let me give you the specific scenario since I'm really not sure which factors are relevant or not: Our lab made our own upconversion nanoparticles (UCNP) following a popular paper on the subject. ...
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1answer
35 views

Heterodyne detection

According to Phase-stabilized two-dimensional electronic spectroscopy the local oscillator, LO, used for heterodyned signal detection always arrives first at time $t_4$, which is -700fs. In 2D-...
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2answers
129 views

Why is the blue line in the Balmer series sometimes not visible?

So I've conducted an experiment to find the four visible hydrogen emission spectrum lines in the Balmer series in a laboratory. I don't have any background in quantum physics. When I looked through ...
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1answer
42 views

How deep within the sample can the DOS(density of states) be detected by STM(scanning tunnel microscope)?

Using STM equipment, we can get the LDOS(local density of states) on the surface of a sample. I want to know whether the LDOS within the sample(not surface) can be detected by STM. what is the ...
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4answers
3k views

Why can't I see the blue color scattered by the lower atmosphere of the earth?

I understand that the blue colour of the sky is because of the scattering of blue light by molecules in earth's atmosphere. The scattering appears to be happening from molecules that are far above in ...
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3answers
121 views

FWHM increase with energy (gamma spectra)

Below I have two plots from a gamma spectrum which I've been analyzing. The first plot is between a low energy range, the second between a significantly higher energy range. It is clear that the FWHMs ...
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1answer
10 views

Sound range and depth it travells whe it hits sound

I know most people hear from 20hz to 20000hz and about the absorption spectrum of water absorption spectrum of water link but how deep does sound travel when it hits the skin and which range of ...
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55 views

In what cases would using a non-resonant spectroscopy be preferable to using the resonant type?

Here it is mentioned that non-resonant Raman spectroscopy is desirable for avoiding fluorescence and for studying water due to water's low polarizability. How is non-resonant Raman desirable in the ...
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1answer
56 views

Dispersion in ultrafast lasers

In mode-locked Ti:sapphire lasers, positive dispersion is caused mainly by the crystal. A prism pair placed in the laser resonator can compensate for some of the dispersion by introducing negative ...
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2answers
37 views

Gamma spectroscopy - Fitted Singlet

I'm using some gamma acquisition and analysis software. When I ask the software to do some sort of Nuclide Identification, almost every single peak in the generated output is marked with "F". ...
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1answer
50 views

How do space probes identify molecules?

How does a space probe identify molecules without actually obtaining the molecules? The common identification techniques I can think of are spectroscopy and magnetic resonance, but for both of them, ...
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36 views

determination of electron dispersion curves

I am somewhat new to quantum physics and I am studying electron dispersion band structures of SiC like the one here I want to know what spectroscopic techniques/methods or if they are spectroscopic ...
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1answer
17 views

Is it possible to do IR spectrometry with emitter and photoresistor on the same side?

When doing spectrophotometry, there is generally a light source that emits the light that then passes trough whatever you want to measure, and then on the other side, a photoresistor that can sense ...
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7answers
981 views

Why is absorption spectrum a line spectrum?

The minimum energy required to excite a hydrogen electron is 10.2 eV. When photons of energy spread over a continuous range of wavelengths fall on a sample of hydrogen, why are only those photons ...
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1answer
43 views

How does this type of pump-probe spectroscopy work?

In optical Kerr effect spectroscopy, a pump beam causes a temporary birefringence in a sample, while a probe beam measures the return of the sample to equilibrium. Here’s a schematic: The pump and ...
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1answer
4k views

What is the correct relationship between light intensity and wavelength?

So we looked at the emission line spectra of noble gases in the lab today (hydrogen, neon, helium). And I noticed that the brightest spectral line in the helium spectrum is the yellow one and the ...
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1answer
105 views

Uncertainty in the average of a series of photon counting measurements

I'm a bit stuck on a problem relating to statistics in photon counting. I'm measuring a spectra with a spectrometer and can set a measurement time and number of times to repeat the measurement in ...
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1answer
67 views

FWHM of different spectra and separation in fine structure

I'm doing some research on spectroscopy and there are some phenomena I can't explain (only a second year physics student). I took some spectra of neon in the 659.89529 nm and then of hydrogen at 656....
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23 views

Diffusion of magnetization (NMR)

In the context of MRI I'm trying to understand the mechanisms of magnetization diffusion. Consider a sample that is magnetized by an external magnetic field. We have displacement of magnetic moment ...
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3answers
132 views

How to measure thickness of an ultra-thin metal layer?

I have a sample of a metal (aluminum/oxide) layer with a gradual thickness ranging from monolayer to 100nm. This layer is deposited on a transparent substrate, like glass. How can I measure this ...
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3answers
798 views

What does it mean to “bin” in a spectroscopy context

In the following online article http://www.star.le.ac.uk/~sav2/stats/a.html I see the word "bin" used, in relation to x-ray spectroscopy, both as a verb and as a noun (people both "bin" things and ...
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2answers
33 views

How to measure the spectra of the stars

I recently made a mini spectrometer using a CD. I have used that to measure the spectrum of the Sun, moon and various artificial light sources. My question is how can I use it or modify it to measure ...
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0answers
18 views

Modelling populations of GE isotopes

I asked a question similar to this here: What combination of stable GE isotopes make up the germanium in a Ge(Li) spectrometer And got some very good answers. This question is instead based on the ...
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2answers
21 views

What combination of stable GE isotopes make up the germanium in a Ge(Li) spectrometer

I work with a Ge(Li) gamma spectrometer. I'm trying to work out the different populations of stable Germanium isotopes in it. I'm trying to model the unrealistic scenario where none of these isotopes ...
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1answer
154 views

define narrow band and broadband in Infrared light source

I have an infrared transmitter where the specification sheet says Broadband Emission from 400 to 2200 nm Does this mean it will transmit all mixed wavelength of infrared light between 400 to ...
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1answer
85 views

I don't understand the spectrum of elements e.g. hydrogen spectrum [closed]

Quote from my textbook The hydrogen spectrum has spectral lines which correspond to transitions of the electron between energy levels. This statement implies that hydrogen has multiple electron ...
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0answers
17 views

Distribution law in Spectroscopy

In NMR, when we study about the transition of nuclei, we use Boltzmann's law for the calculation of population and polarization. Similarly, when we study electronic,IR spectra, we again use Boltzmann'...
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0answers
25 views

mutual exclusive principle in raman and ir spectroscopy

Why the mutual exclusive principle is valid for centro symmetric molecules in raman and ir spectroscopy? What does it really mean?
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2answers
127 views

Gamma spectroscopy - Do annihilation photons produce a backscatter peak?

Below is a diagram of part of a structure which I find in a gamma spectrum taken from a hall in which a neutron source is undergoing spallation. The structure which I'm interested in can be seen ...
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60 views

Coincidence summing in gamma spectrum

Question on coincidence summing here. I've been reading about the coincidence summing effect when a radionuclide has two energy levels that decay to another state in rapid succession. There is also ...
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0answers
53 views

Zeeman effect number of lines split into?

The Zeeman effect comes in two times, normal and anomalous. I have some confusion over the number of levels each original level splits into. For the normal Zeeman effect we have: $$\Delta E=m_l \...
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0answers
211 views

Instrumental function vs. instrumental line profile?

I am reading into spectroscopy and the terms instrumental function and instrumental line profile come up regularly. I have reason to believe that they are not equivalent but cannot find any clear ...
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0answers
85 views

Activation energy of luminescence

Assuming that activation energy is constant for some range of temperature, it can be determined from the slope of the plot: $$\ln{I}=A-\frac {E_a}{k_bT}$$ where $I$ - intensity , $E_a$ - activation ...
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64 views

Using stellar spectroscopy to measure stellar parameters, why is it log g?

Stellar spectroscopy can in principle measure the stellar surface gravity, radii, effective temperature, and stellar rotation. Why is it that surface gravity g is ...