the practice of separating a signal by frequency (or sometimes energy or momentum) and analyzing the resulting spectrum.

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Why does the spectrum for deuterium show a weak line at H-alpha?

I was wondering why the spectrum for deuterium shows a weak line at H-alpha, the first line in the hydrogen spectrum.
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25 views

Possible to download SAANI/other freeware for gamma peak analysis? [closed]

I would like to know whether its possible to download the open soure software called "SAANI" which is described here http://library.sinap.ac.cn/db/hedianwencui201102/%E5%85%A8%E6%96%87/41100117.pdf ...
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1answer
39 views

What's the difference between NMR and EPR?

Both NMR and EPR describe the response of magnetic spin to external field. When collecting data, how do you know you're looking at nucleus spin flip or electron spin flip? In other words, since every ...
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16 views

Resolving power of a diffraction grating?

I was working thru a derivation of the resolving power of a diffraction grating at the $n$th order. Here is that derivation: Let us say we have a diffraction grating width $W$ and are looking at ...
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1answer
32 views

Photometric surveys vs. Spectroscopic surveys

I consistently read about certain astronomical surveys which are either described as "photometric surveys" or "redshift surveys". I'm still unclear as to how these two methods differ. Photometry ...
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1answer
27 views

Why is there no fluorescence background in CARS?

In CARS (coherent anti-Stokes Raman scattering), the detected signal is blue-shifted with respect to the excitation - how does this mean that there is no fluorescence or that the fluorescence can be ...
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1answer
28 views

Resonant vs. Non-resonant Raman

What does it mean to say that the conventional Raman effect is non-resonant? And, how/why does resonant Raman give a stronger signal than the non-resonant type?
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2answers
390 views

Sun spectroscopy - Home experiment

We let the sun light run through a 5x3x3cm triangular glass prism and we examined the formed 'rainbow' in search of Fraunhofer lines. However, even though we looked close enough (even with a ...
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3answers
63 views

What is meant by a “sodium line”?

What speed should a galaxy move with respect to us so that the sodium line at $589.0\ \mathrm{nm}$ is observed at $589.6\ \mathrm{nm}$? In the above question what's meant by a sodium line? The ...
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1answer
21 views

Spectroscopy - Absorption lines

Let's say we run a light source (a strong torch) with full spectrum light through a big, transparent, glass box filled with neon. Will we be able to see any Fraunhofer lines on the spectral analysis ...
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32 views

Bandwidth-Pulse Duration Relationship

Assuming Gaussian pulse, the relationship between pulse duration and bandwidth is given by: $$\Delta \nu \cdot \tau \geq 0.441$$ If the rms bandwidth and rms pulse duration are used, then the ...
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1answer
22 views

Which g factor in an EPR spectra is the right one?

I was reading this introduction to EPR and it seems to imply both that there is a unique g-factor of a given compound, but also that we can calculate multiple g-factors for a compound. For example, ...
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3answers
75 views

Is it possible to reconstruct the wavefunction of a molecule from a collection of spectra?

Spectra of a molecule can be calculated if the wavefunction is known. Is it possible to do the opposite?
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36 views

What's the difference between microscopy and spectroscopy?

Both methods collect particles or electromagnetic waves, and in both methods it's possible to reconstruct a 2D image, which may represent morphology (AFM, LEED for example), electronic structure (STM, ...
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2answers
40 views

Where can I find spectral data for materials?

The chemical library of ChemSpider has a dedicated section for spectra, but I haven't found any materials that have such data. Is there a (public) database of spectral data?
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1answer
48 views

Is there a correct yet more compact way to write these equations?

I've got the following equation which denotes the total absorbance $A$ as determined by the sum of the absorbances of individual molecules: \begin{equation} A(\nu,c_{1},...,c_{n}) = \sum_{mol=1}^{n} ...
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24 views

What's the difference between “spectromicroscopy” and “microspectroscopy”?

Both definitions that I found are rather vague. (Related question: What's the difference between microscopy and spectroscopy?)
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9 views

Moisture measurement through PVC using spectroscopy

Is it possible to measure moisture content in a blister through a PVC layer? The distance that the laser will have to travel will be around 3-3.5 mm. The thickness of PVC layer is 100 micron. I was ...
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26 views

Fermi's understanding of the Doppler effect

I am now reading the classic paper by Dicke, The Effect of Collisions upon the Doppler Width of Spectral Lines At the very beginning of the paper, Dicke said ''Quantum mechanically, the Doppler ...
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1answer
26 views

Switching a PMT from PC-mode to DC-mode: What happens?

I was wondering a bit how it is possible to switch a photo multiplier tube from the photon counting mode to the DC (I assume direct current)-mode. If I simply add a high voltage (as usual), I get the ...
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0answers
24 views

How to distinguish Shake-Up Satellites from Plasmons?

I am studying XPS spectra (X-ray Photoelectron Spectroscopy) at the moment. In XPS, different processes can influence the final state energy of detected electrons. One of these processes is the ...
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22 views

Help Interpreting Ultraviolet Photoelectron Spectroscopy (UPS) data

I was given a batch of UPS data without any background other than the materials examined and I don't have any experiencing interpreting it. I wanted to reach out to some experts (hopefully, someone ...
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2answers
50 views

Photon yield of NaI

We have to calculate the photon yield of the scintillator NaI. We have measured his pulse height spectrum but we have no idea how to solve this problem. Can someone explain it? The source that we used ...
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1answer
41 views

pGRE question on natural line width

The lifetime for the $2p \rightarrow 1s$ transition in hydrogen is $1.6 \times 10^{-9}$ s. The natural line width for the radiation emitted during the transition is approximately... Their solution: ...
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17 views

Is there any application for an advanced spectrometer in geometrical optics experiments?

We have an advanced spectrometer in our geometrical optics lab! I'm seeking for any experiment in geometrical optics to include it!
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1answer
314 views

How are problems in astronomical spectroscopy solved?

Astronomers based on the ground telescopes, watch the stars and make predictions about them based on the spectrum of light. But when the light from those stars reach the telescopes through the ...
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10 views

Explain materials with 4 fold symmetry having same reflectance when shone with LCP and RCP

This is my first post here. I am currently reading "Optical planar chiral metamaterial designs for strong circular dichroism and polarization rotation" by Do-Hoon Kwon, Pingjuan L. Werner, and ...
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2answers
35 views

How are different wavelength components collected by the same detector in a spectrometer?

Let's think, we have a detector array (128x1 and each CMOS detector responds 400 to 1000 nm TSL1401CL that way, each detector has 4.6875 nm interval). Then, basically in a spectrometer a prism reflect ...
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20 views

Hydrogen spectrum intensity using a monochromator

Using a monochromator (350->800 nm) and a hydrogen gas lamp, I find this spectrum : We can see 3->2, 4->2, 5->2 transitions from Balmer series, but not 6->2 (which we should expect at 410 nm). As ...
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1answer
87 views

What does a hot, optically thin gas *look* like?

In another question I tried to answer what a sample of the Sun's photosphere or core would look like, if it could be brought into the lab. Here is a broader question - if I have a small inert ...
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3answers
41 views

Spectrometer vs. Spectrophotometer

I have been researching about the difference of a spectrometer and a spectrophotometer. They both sound the same. What is the difference?
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1answer
45 views

What is harmonic and fundamental bands in IR spectroscopy?

What is harmonic and fundamental bands in IR spectroscopy? I'm trying to find exact definitions. I guess that fundamental is $1\leftarrow 0$ transition (the most intense and energetic) and harmonic ...
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2answers
41 views

Why doesn't the color of an object change when signal of different frequency impinge upon it?

Correct me if I'm wrong but I've always thought that the color that an object has is due to the oscillation of the atoms that makes up the material of that object. When white light is shine upon an ...
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35 views

Reason behind formation of doublets in diffraction spectrum

like if you see is Sodium (and also in Mercury), there are two discrete lines of Yellow color.. What's the reason behind formation of doublets?
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90 views

Why is the color of fire is yellow or blue sometimes? [duplicate]

If you light up any thing it burns in yellow and as well when you light up a gas stove it burns in blue color. What brings this color change?
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19 views

What methods are there to obtain flourescence?

Blackbody radiation is fairly easy to obtain. However, Atomic Emission spectrum based on fluorescence requires more work and provides more information. Traditional methods use a flame or plasma to ...
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30 views

Spectroscopy Question

So if we were to view the visible spectrum of a white dwarf star. Would the planetary nebula essentially block what would be an absorption spectrum? If so, would we all just see emission lines. I'm ...
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5answers
125 views

What's the difference between frequency domain and time domain spectra?

If I have a mechanical oscillator and want to observe the dynamical behavior of the oscillator, is there any additional information to observe it in time domain and frequency domain? Normally, we ...
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1answer
26 views

What is “Lifetime Intensity” in photoluminescence?

I'm reading an article "Surface plasmon enhanced Förster resonance energy transfer between the CdTe quantum dots". Link The reasearchers are writing about increase in "lifetime intensity" and even ...
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21 views

Vibrational quantum notation

Reading articles on spectroscopy I often see this notation: 30001 <- 01101, 00011 <- 00001 in context of molecular ...
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18 views

Spectroscopic notation for more than one excited electron

In spectroscopy, notation like $^3S_1$ or similar is often used to define atomic states. This is unambiguous when considering only a single electron excited from the outermost energy level. But how ...
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1answer
93 views

Total magnetic moment in an atom

I have a doubt regarding the calculation of total angular momentum of electron in an atom. Which is the right way to do it? Method 1: Total magnetic moment $$ \begin{align} \vec{\mu_J} &= ...
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1answer
76 views

What is the 'triangle selection rule' in spectroscopy?

This paper states that However, the multiphonon relaxation bridging the $^5\!D_1$ and $^5\!D_0$ levels is a well-known exception because it is formally forbidden by the triangle rule and occurs ...
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1answer
30 views

How does change of pressure affect molecular rovibrational bands position and width?

Lets say I have $CO_2$ gas chamber with pressure $P_0$. How do rotation-vibrational transition bands alter when I change pressure P? Do they shift or not and why?
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2answers
568 views

Homemade Spectrometer

Recently I have had ideas of how to build a spectroscope, but I'm not sure if it will work. As can be seen in the diagram, the experiment is simple: it consists of a laser that generates the light ...
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38 views

Doppler effect for the electrons emitted from ions moving at a particular velocity

If I have ions moving in X axis (along both directions; positive X axis and negative X axis) and if I irradiate laser along the positive X axis, electron will be ejected from the ions (if I am using a ...
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4answers
333 views

Machine to identify substances

I was looking at Wikipedia's article on mass spectrometers, and realized that the method described was to heat a sample into its gas phase and separate the ions by mass using a large magnet. While I ...
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1answer
50 views

Is the emission spectrum of a muonic atom different?

From my quick investigation, the spectrum is based on the Rydberg formula, and with a small change, would lead to $$ {1 \over \lambda_\mu} = {m_\mu \over m_e} \left( R \left( {1\over n_1^2} - ...
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1answer
154 views

Why is cesium used to measure time in atomic clocks?

Seconds are measured by the frequency emission of cesium. Why is a frequency from the emission spectrum of cesium used as the standard in defining a second? Why particularly cesium?
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1answer
172 views

Can this simple spectrometer be precise without collimation?

Consider the following spectrometer structure: Here the slit can be changed in size, and the lens and detector can be moved closer to or farther from the diffraction grating. I was trying to get ...