the practice of separating a signal by frequency (or sometimes energy or momentum) and analyzing the resulting spectrum.

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Spectroscopic notation for more than one excited electron

In spectroscopy, notation like $^3S_1$ or similar is often used to define atomic states. This is unambiguous when considering only a single electron excited from the outermost energy level. But how ...
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43 views

Total magnetic moment in an atom

I have a doubt regarding the calculation of total angular momentum of electron in an atom.Which is the right way to do it? Method 1: Total magnetic moment $$ \begin{align} \vec{\mu_J} &= ...
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22 views

What is the 'triangle selection rule' in spectroscopy?

This paper states that However, the multiphonon relaxation bridging the $^5\!D_1$ and $^5\!D_0$ levels is a well-known exception because it is formally forbidden by the triangle rule and occurs ...
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1answer
24 views

How does change of pressure affect molecular rovibrational bands position and width?

Lets say I have $CO_2$ gas chamber with pressure $P_0$. How do rotation-vibrational transition bands alter when I change pressure P? Do they shift or not and why?
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2answers
373 views

Homemade Spectrometer

Recently I have had ideas of how to build a spectroscope, but I'm not sure if it will work. As can be seen in the diagram, the experiment is simple: it consists of a laser that generates the light ...
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21 views

Doppler effect for the electrons emitted from ions moving at a particular velocity

If I have ions moving in X axis (along both directions; positive X axis and negative X axis) and if I irradiate laser along the positive X axis, electron will be ejected from the ions (if I am using a ...
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4answers
290 views

Machine to identify substances

I was looking at Wikipedia's article on mass spectrometers, and realized that the method described was to heat a sample into its gas phase and separate the ions by mass using a large magnet. While I ...
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1answer
33 views

Is the emission spectrum of a muonic atom different?

From my quick investigation, the spectrum is based on the Rydberg formula, and with a small change, would lead to $$ {1 \over \lambda_\mu} = {m_\mu \over m_e} \left( R \left( {1\over n_1^2} - ...
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1answer
47 views

Why is cesium used to measure time in atomic clocks?

Seconds are measured by the frequency emission of cesium. Why is a frequency from the emission spectrum of cesium used as the standard in defining a second? Why particularly cesium?
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44 views

Can this simple spectrometer be precise without collimation?

Consider the following spectrometer structure: Here the slit can be changed in size, and the lens and detector can be moved closer to or farther from the diffraction grating. I was trying to get ...
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1answer
27 views

Hydrogen Spectra [closed]

I am talking about hydrogen spectral lines such as Lyman, Balmer etc. In order to make those spectral lines series more than one electron are needed to jump from higher orbits to lower orbit. But ...
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23 views

Appearance of the recomposition of a given spectrum? [duplicate]

Given a visible spectrum, i.e. a function from the set of visible wavelengths into the set of intensities, I would like to see the color having this spectrum decomposition. Question: How can I do ...
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9 views

Dielectric resonance spectroscopy of thin and thick film

How does the technique vary for dielectric resonance spectroscopy for thin film of ~ 3 micrometer and a relatively thick film of 100 micrometer?
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78 views

Do all elements spectrum lines fall within the visible light range?

I was wondering if whether we were extremely lucky to have found spectral (absorption) lines of astronomical objects because they fell within the visible light range or if there something intrinsic ...
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7 views

What is the difference between Linear and Non-Linear Magneto-optical effects?

Principle difference between Linear and Non-Linear Magneto-optical effects and how they affect the property of light passing through a Vapor medium.
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52 views

Autocorrelation function for deterministic nonlinear dynamical systems

I am quite puzzled with the problem that spectral analysis has been either applied to noisy dynamical systems or to chaotic ones. I was wondering why nobody makes analysis of non-linear dynamical ...
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1answer
60 views

Continuous spectra of photons

I guess this is a basic quantum mechanics problem, but I'm not entirely sure of my answer. Suppose we have an electron in a hydrogen atom having the state \begin{equation} ...
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1answer
50 views

What happens to light at sharp points? [closed]

At the tip of the sharp point shown, what will happen to light incident on it. This curiosity was invoked by a friend and also my childhood of watching shiny pointed swords in cartoons. Original ...
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30 views

What are the current size limitations of NIR spectroscopes? [closed]

So few days ago I came across this new tool for smart phones http://www.consumerphysics.com/myscio/. It says it uses NIR spectroscopy, which I don't know lot about. My question is: Is it possible for ...
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34 views

Quantum description of Raman effect

In the classical description of Raman effect the object of study is the electric polarizability of the system. Since I'm interested in learning the quantum description of the Raman effect and in ...
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1answer
74 views

Spectral series' formula of a given atom (other than hydrogen-like)?

The hydrogen spectral series is given by the Rydberg formula: The energy differences between levels in the Bohr model, and hence the wavelengths of emitted/absorbed photons, is given by the ...
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1answer
75 views

Wigner Threshold law in Photodetachment and Photoionization

I am writing this question here because I have a problem in understanding the Wigner Threshold law in Photodetachment and Photoionization. The Wigner Threshold Law is given by: $\sigma$=$E^{L+1/2}$. ...
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3answers
86 views

What does the $y$-axis represent in the atomic spectra and what is its significance?

The picture is an emission spectrum of Helium. The spectrum has sharp lines (peaks) at certain wave lengths characterizing it as helium. Agreed that it characterizes Helium as atomic spectral line ...
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54 views

Why does inelastic X-ray scattering probe the longitudinal dielectric function as opposed to the transverse dielectric function?

Light is a transverse wave. Therefore, light in the optical range (i.e. visible light) couples to transverse collective excitations of a material when measuring the optical conductivity for instance. ...
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1answer
38 views

Why infrared absorption is a nonlinear technique?

I am looking for a good explanation and/or reference quotation explaining why infrared absorption technique is essentially nonlinear (eg. for carbon monoxide quantification). When using ...
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3answers
86 views

Can stimulated emitted photons be absorbed?

Typically a stimulated photon will be one of a pair with its stimulating photon. If the leading photon is absorbed by a particle in the ground state, will it then be re-emited by the stimulated ...
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1answer
36 views

What will be the effect of placing a light source very close to a photodiode?

What will be the effect of placing a photodiode really close to a laser source and what should be the appropriate distance between a light source and photodiode to get maximum output current?
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41 views

For a planet which has a temperature gradient, hot in the center and cooler on the surface, why do we get absorption lines?

For a planet which has a temperature gradient, hot in the center and cooler on the surface, why do we see absorption lines? Similarly, why do we see emission lines if the planet is hot on the ...
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95 views

How hot is aurora?

Has anyone done research on how hot aurora is? I mean if it is plasma it should be hot and since it is emitting mostly green light due to nitrogen (~78%) in the air, could it then be considered that ...
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1answer
45 views

Absorption lines in the context of identifying elements in far away celestial objects

I understand that absorption lines are used to identify elements but how are individual absorption spectrums identified in the light that is received by a telescope?
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1answer
79 views

Calibrating the relative intensity of a spectrometer with a blackbody source?

I am trying to compare the relative brightness of H-Beta and H-Alpha lines using a CCD spectrometer. In order to correct for the different grating efficiency at the two different wavelengths. I took ...
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53 views

Absorption coefficient from HITEMP or HITRAN [closed]

How to calculate the absorption coefficient (for radiation) from HITEMP or HITRAN databases? Or where can I find some tables or plots for the absorption coefficient?
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1answer
32 views

Nuclear explosion wavelength data

I am looking for data source (or chart) of spectral data that is being emitted on detonation of nuclear or thermonuclear explosion. Reason I am looking is to see if this data has specific signature ...
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10 views

Spatial Resolution in Magnetocardiography

In the science paper called Development of an optical cardio-magnetometer by George Bison, it is mentioned that spatial resolution of 10-20mm is required for mapping MCG signal(page 52). What does the ...
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1answer
58 views

What causes the triplet state in Helium?

I am not familiar with the notation used on wikipedia (http://en.wikipedia.org/wiki/Triplet_state). Is there a more physcial way to explain the cause of the triplet state (maybe without referencing ...
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1answer
29 views

Why is solar eclipse so important for sunlight spectrum analysis?

People wait for decades to catch the chance of a solar eclipse to observe the sun. Why cannot they do it every noon?
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Why photoelectron imaging is a 'complete' measurement?

In many articles and books, it says that photoelectron imaging gives a 'complete' information. What is mean by 'complete' measurement or a 'complete' information? Through photoelectron imaging ...
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1answer
65 views

Absorption line detected with a significance of $2.2\sigma$

What do we mean by the following statement? The SV $\lambda$ 786.46 line is detected with a equivalent width of $W = 22.7\pm10.2$ corresponding to a significance of $2.2\sigma$ How does one ...
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14 views

Interpretation of decay associated difference spetrum

We measured transient absorption spectra and we got $\Delta A(\lambda,t)=A(\lambda,t)-A(\lambda,0)$. If we use DAS (decay associated spectra) for interpretation, we assume that our data have this ...
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Interchange symmetry for states with identical particles

I was reading this web page about interchange symmetry for states with identical particles here: http://quantummechanics.ucsd.edu/ph130a/130_notes/node317.html The article states that the highest ...
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14 views

Dipole and multipole bound state anions: Do these bound electrons behave exactly like conventional electrons in the molecular orbitals?

Recently, I read about dipole and multipole bound anions. Dipole bound anions are those, if I understood correctly, when an electron is attached electrostatically on a neutral molecule which is polar. ...
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1answer
78 views

Resolution in a Fourier transform spectroscopy setup

I am a bachelor physics student and as an assignment we had to perform measurements on an FT spectroscopy setup. Context. Our setup consisted of a Michelson interferometer through which the light ...
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36 views

how does different colour wavelength intefere? [duplicate]

Say a red colour with 400nm mixes with blue colour with 700nm, but out of phase by a little. What would be the resultant colour? I would know how to represent the resulting wave mathematically, but ...
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2answers
150 views

Self-study: resources for understanding Gamma spectroscopy

I work in applied mathematics and have no background in atomic physics. I need to have a good understanding of the principle and application of Gamma spectroscopy. I am ok to spend the needed time but ...
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51 views

On characteristic X-ray spectra and relative intensity

I am looking at the following image (from http://www.schoolphysics.co.uk/age16-19/Atomic%20physics/X%20rays/text/X_ray_spectra/index.html): and I want to know, of the two curves, which one ...
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1answer
104 views

Non Adiabatic Coupling Term in Born Oppenheimer Approximation

I am attaching a section from a text book (Conical Intersections Electronic Structure, dynamics and spectroscopy: David R Yarkony & Horst Koppel). Here I am not understanding the so called 'Non ...
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1answer
38 views

Why some electrons in ESR aligned their spin towards external magnetic and some against

Why some electrons in ESR aligned their spin towards magnetic field and some against?
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1answer
29 views

Spectroscopy and the current state of our ability to determine the composition of extra-solar planets

I was interested in learning more about the status of our scientific understanding and technological instruments regarding extra solar spectroscopy. I am motivated by this almost 3 year old ...
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3answers
148 views

Raman vs. Brillouin Scattering

In my class notes, I have the two types of inelastic scattering described as follows. (Note that the "difference in energy" here is the difference between the incident frequency of the light and the ...
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1answer
39 views

How is “Band Intensity” related to absorption coefficient

I am interested in the linear absorption of 762nm light near a transition of molecular oxygen. I need to find some experimental numbers that will tell us how far the 762nm light will propagate before ...