the practice of separating a signal by frequency (or sometimes energy or momentum) and analyzing the resulting spectrum.

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Activation energy of luminescence

Assuming that activation energy is constant for some range of temperature, it can be determined from the slope of the plot: $$\ln{I}=A-\frac {E_a}{k_bT}$$ where $I$ - intensity , $E_a$ - activation ...
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18 views

Using stellar spectroscopy to measure stellar parameters, why is it log g?

Stellar spectroscopy can in principle measure the stellar surface gravity, radii, effective temperature, and stellar rotation. Why is it that surface gravity g is ...
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15 views

How to get a better handle on Spectral Irradiance conversion?

I'm using a computer program to simulate a lightsource. I can feed my own spectral irradiance values into the program to simulate color rendering accuracy. The program takes values in electron volt ...
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1answer
21 views

Hydrogen Spectra using Hydrogen Gas Discharge Tube

I am doing an experiment for my lab work which include determination of value of Rydberg Constant using method of Interpolation. For this we first plot calibration curve for various wavalengths ...
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1answer
96 views
+50

Spin Orbit (lS) interaction energy

Well, I am currently using a pretty old book by H.E White "Atomic Spectra", and he defined spin orbit interaction energy as the product of the resultant frequency and the projection of spin angular ...
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1answer
51 views

Temperature dependence of spectra

I have a question that is short and sweet: Are spectra (both fluorescence and absorbance) of any molecule dependent on temperature? In particular, is the spectral lineshape function of any molecule ...
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28 views

UV absorption decrease with an increase in concentration

I am working on a project measuring the absorbance of a solution which contains surfactant and hard brine. The solution has a constant concentration of surfactant and varying concentration of hard ...
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1answer
19 views

Gamma Spectroscopy - Why no Intensity level for Neutron Capture?

I'm undertaking a bit of work looking at a Background Gamma Spectrum. On the spectrum, I have a clear, tall line at 834 KeV. I have a PDF file of a table of Gamma Spectra (ordered in energy) from ...
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33 views

How to begin using SDSS data?

SDSS has gone through so many updates, it's difficult to find out how to access the data today in 2015. How can I use SQL and Python to access SDSS data, e.g. the photometry and spectra of quasars, ...
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21 views

Help reading power spectrum graphs?

How would I go about figuring out how long a source was measured when given a graph of the power spectrum? From notes I'm following, they just state the total observation time as being roughly ...
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1answer
27 views

Detecting molecules in space?

http://www.forbes.com/sites/alexknapp/2012/02/24/nasa-detects-solid-buckyballs-in-space/ I refer to the above article, which mentions that buckyballs "far smaller than the width of a hair" were ...
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30 views

Converting spectra to rgb colour

I am having trouble obtaining RGB colour values from the spectra of an object. I have the specific flux $F_\nu$ as a function of $\nu$ for each pixel of the image I'd like to make, but am unsure of ...
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43 views

What causes this IR emission in UV 365nm LED?

I've just got access to spectrometer and measuring spectrum of everything. But when I took a look at 365nm UV led from chinese UV flashlight I got something really strange - it had some IR at exactly ...
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19 views

Can near-infrared spectroscopy distinguish between various metals?

Can near-infrared spectroscopy be used to distinguish metals from another? If not, why not?
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135 views

How is this possible that photons are absorbed?

From the lessons on QM, I got impression that there are some discrete orbitals that emit light when electron drops from one to another. Specific molecules emit light in very narrow bands, therefore. ...
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31 views

How was hydrogen gas (H) obtained by spectroscopists? Why is there more H than H2 in space?

Introductory quantum mechanics lessons talk about emission and absorption spectra for the hydrogen gas, and then give you an explanation as if this gas were pure $H$ atoms, and not the $H_2$ molecule ...
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32 views

Difference between Rayleigh scattering and fluorescence spectroscopy [closed]

How can we differentiate Rayleigh scattering from fluorescence spectrum?
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1answer
76 views

Is the Energy of an absorbed photon exactly the energy of the band gap?

I was wondering, if the Energy of a Photon which is absorbed by an Electron, hast to be exactly the Energy of the bound gap. So if i have two energy levels in an atom $E_2$ and $E_1$, does my ...
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25 views

Estimation of source irradiance given the spectral sensitivity of the instrument and spectrum of the source

I am trying to measure the irradiance of a UV source, but the available instrument has a different sensitivity. Suppose the black line corresponds to the spectral sensitivity of the instrument ...
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2answers
31 views

Is it possible to calculate the relative abundances of elements in the sun based on its line spectrum using a common lab spectroscope?

There are many problems that I feel would hinder the process: atmospheric noise, light pollution etc. Let's assume that I bypass these problems and get an accurate emission line spectrum on the ...
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35 views

What does 'easily reversed' mean in the NIST spectral database? [closed]

Cross posted to http://engineering.stackexchange.com/q/3303/ I'm trying to do some processing of optical emission spectra from sputtering plasmas, and am confused by what NIST means by 'easily ...
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27 views

Deconvoluting Raman spectras from different wavelengths

I am using a laser source that is wider than typical laser source for Raman spectroscopy. This mean that the full width at half maximum (FWHM) of the laser is about 5-10 nm, compared to the normal 1-3 ...
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52 views

Spectroscopy from a classical light wave or photon only?

In chemistry we mostly regard light/electromagnetic radiation as a beam of particles or photons. This is a very useful model to explain molecular excitations and ionisations from quantum interactions. ...
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97 views

Having trouble understanding spectral lines

In my notes I wrote that Rutherford's model of the atom could not explain spectral lines, because that is what my textbook says. I'm not really sure about the details of spectral lines though. I know ...
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11 views

Hyperfine structure interval rule only obeyed approximately?

The hyperfine interaction is given by $\Delta E = A \langle I \cdot J \rangle = \frac{A}{2}\left[ F(F+1) - I(I+1) - J(J+1) \right]$. The interval rule is given by: $$ \frac{\Delta E_{F,F-1}}{\Delta ...
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31 views

Asymmetric photoluminescence spectra

Why do photoluminescence spectra have asymmetric lineshapes as those here http://www.scielo.br/img/revistas/bjp/v37n4/a04fig01.gif or here: ...
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28 views

On energy levels and emission of photons

This is a very basic question but I cannot seem to find the answer anywhere. Say we have an atom in ground state. Its first energy level is 2 eV. An incoming photon of energy 2.5 eV hits an electron ...
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19 views

Does water absorb microwaves above of beneath its relaxation frequency

I am a bit confused about the concept of relaxation frequency. In my course text we derived a model with the help of Newton's law to describe the movement of polar molecules in an electromagnetic ...
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30 views

PM-IRRAS Equidistant Fringes in Spectrum

What is the cause, and best method to prevent / minimize, fringes in one's FTIR (PM-IRRAS) spectrum on samples deposited on a thin metal film? The fringes look as though they are spaced out by a ...
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26 views

Sonoluminescence spectrum

During cavitation created by sound in a liquid the collapse of the bubbles can lead to very high temperatures and pressures resulting in the emission of light - sonoluminescence. Can the spectrum of ...
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9 views

Velocity Selective Coherent Population Trapping and recoil limit on temperature

I have read that it is possible to go under recoil temperature limit using VSCPT (Velocity Selective Coherent Population Trapping) and that this method is based on atoms trapping in quantum state in ...
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1answer
50 views

photon absorption by atoms causes heat?

I have came up with a weird doubt: photon absorption by atoms causes heat? I mean, I was always told that if the photon's frequency is the magic one, the atoms absorbs the photon and goes to an ...
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17 views

Doppler and recoil limit on temperature

I havent't understood the causes of Doppler limit and recoil limit. I have found on the net different observations about them ("Doppler limit is due to the fact that the atom can't have a smaller ...
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49 views

Can anybody explain about phase shift and phase spectrum terms in case of multidimensional signal?

I know about phase of a 1D signal, but when I move into higher dimensions like 2D or 3D etc, it becomes headache to grasp the concept. What do the terms "phase shift" and "phase spectrum" mean in ...
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27 views

Why graphene's substrate is important

I just have some feelings that somehow it is important what specific subtrate is used to grow graphene monolayer on. Some substrates are better, another ones are not so good. But I cannot completely ...
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37 views

Optical spectrometer

I am new on optical spectrometer, my particular interest is the spectrometer in which the deflection is produced by diffraction in a diffraction grating. But I can not find a good schematic and the ...
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61 views

How to measure temperature of a laser cooled sample at picoKelvin temperatures?

I'm reading about laser cooling.. my question is: how can the temperature of the sample be measured? (using laser cooling we can reach $10^{-12}K...)$
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62 views

How to deal with coma and oblique spherical aberration in a Czerny Turner configuration?

I am modelling my own spectrometer using Zemax when all of a sudden I've been told that: even if you manage to optimize the angles or positions of the grating and the mirrors, you won't get ...
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1answer
152 views

What are the purposes of slits inside a spectrometer (Czerny-Turner)?

I am building a Raman spectrometer with a Czerny Turner configuration (with RamanPi). Why does the light source (A) appear to be converging into the entrance slit (B)? When a sample is excited by ...
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1answer
31 views

How to convert the molar attenuation coefficient, ie. molar absorptivity, to heat capacity?

In spectroscopy techniques, such as infrared spectroscopy, light of a certain wavelength is absorbed. I see parallels to the concept of heat capacity, i.e. the heat necessary to change the temperature ...
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25 views

Reflectance spectrum and Real Refractive Index Relation

I have taken in the laboratory mesurment of the Reflectance spectrum of a material and via mathematica calculated the phase for Kramers-Kronig Relations,and finnaly i calculated from it the real part ...
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1answer
16 views

What happens to the velocity map image if the plane of polarization is not on the plane of the detector?

In an electron Velocity Map Imaging (in Velocity Map Imaging in general) it is required that the plane of polarization to be parallel to the plane of the detector (in other words, plane or ...
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1answer
40 views

What is the reason that EXAFS are done with monochromatic x-ray light?

Why is the light incident on the samples in EXAFS experiments monochromatic? What would happen if a broad bandwidth hits a grating and then all the diffraction spectrum goes through the sample and is ...
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19 views

Does the EXAFS oscillations occur when ultrashort x-ray pulse is used? Electron with a 50eV kinetic energy will travel in 0.1fs 4.2 Angstroms

In X-ray extended absorption spectroscopy (EXAF) an electron is excited by an x-ray photon into the continuum, the outgoing electron wave interferes with the scattered electron wave from the ...
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61 views

Angle-resolved photoemission spectral (ARPES) function from band Hamiltonian

I am trying to derive spectral function for a band Hamiltonian. I am using http://arxiv.org/abs/cond-mat/0306084 as a prototype reference. I do not understand how the coherence factors $u_k$ and $v_k$ ...
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1answer
62 views

Why does the refractive index not mirror the Lorentzian peak shape of the absorption index?

In the characterization of materials, there are many methods used: One of them is infrared spectroscopy. In a lab we saw the indices of refraction and absorption of a certain (semiconductor) solid ...
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50 views

Rotational Spectrum of a Diatomic Molecule

The rotational energy levels of a diatomic molecule are given by $$E_l=\frac{\hbar^2}{2I}l(l+1)$$ where $l$ is an integer. If the molecule is a dipole it can emit or absorb electromagnetic radiation ...
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271 views

Does my green laser pointer emit three distinct frequencies, or is my measurement flawed?

I was playing around with a cheap diffraction grating and my set of laser pointers, and I noticed that while the red and the blue pointers produce a single point in the spectrum, my green laser ...
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Why do lines in atomic spectra have thickness? (Bohr's Model)

Consider the atomic spectrum (absorption) of hydrogen. The Bohr's model postulates that there are only certain fixed orbits allowed in the atom. An atom will only be excited to a higher orbit, if ...
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Why does the spectrum for deuterium show a weak line at H-alpha?

I was wondering why the spectrum for deuterium shows a weak line at H-alpha, the first line in the hydrogen spectrum.