Solid-state physics studies how macroscopic properties of solids (mechanical, electrical, optical, etc.) result from their microscopic structure. It usually deals with the scale where quantum properties of the particles are substantial.

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Liquid benzene magnetic susceptibility

In a solid state physics problem, I'm asked to make a rough estimate of the contribution to the diamagnetic susceptibility of the outer electron of each carbon atom. The wavefunction of these ...
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5k views

How can crystal structures be determined using X-ray diffraction?

You have the intensity peaks and the diffraction angles. Let's say you suspect the material is cubic, how do I find if it's simple cubic or BCC or FCC? I've googled and all my textbooks just state ...
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627 views

What is different between resolvent and green function

I bumped into a book, where Resolvent $R^{\pm}(E)$ is defined as $e^{\mp iHt/\hbar}=\pm\frac{i}{2\pi}\int_{-\infty}^{\infty}dER^{\pm}(E)e^{\mp iEt/\hbar}$ and $R^{\pm}(E)=\frac{1}{\pm ...
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221 views

What is the difference between contact-limited and space-charge-limited charge transport?

I am reading a paper ("Tunable Electrical Conductivity of Individual Graphene Oxide Sheets Reduced at 'Low' Temperatures," Jung, et al. Nano Lett. 2008, 8, 4283-4287) about electrical conductivity in ...
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84 views

What's the difference between hopping and tunneling?

My professor made a distinction between electron hopping (the closest wikipedia had an article on) and tunneling, saying that one (he didn't say which, but I assume hopping) was temperature dependent ...
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84 views

What is the performance of a silicon crystal that makes it an essential component to computing

I'm on a thread of interest in the precise physics that allow the creation of the computing process. It began as a question posted in search of an understandable explanation of what physical form ...
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4answers
178 views

I don't get band structure of solids

If the energy levels of bound electrons are discrete, why do band structures in solids arise?
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54 views

Schottky Barrier - Why energy band levels at interface are assumed to remain the same that bulk

I have been chewing up some time ago the Schottky-Mott theory of Schottky Barrier height (which ignores the surface states). All the deduction seems to ground on fundamental thermodynamical principles ...
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107 views

How to calculate energy in two-band Hubbard model

It might be a very easy question for you, but I am confused and I need helps. In the simplest Hubbard model at one-dimensional lattice, I ignore the $U$ term and only remain the hopping term. ...
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38 views

Compressibility of solids (quadratic approximation)

(according to Steven H. Simon's "The Oxford Solid State Basics") A well-known approach to describe a one-dimensional chain of atoms is to approximate the potential of each of the atoms quadratically: ...
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338 views

Fermi level and conductivity

Can someone in a simple way explain me what the Fermi level is and what does it have to do with conductivity. My teacher said that Cu conducts electric current better than Al because of something in ...
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185 views

A conceptual question about Green's function's treatment of interaction

Here we have electron gas and some other stuff. We expand the Hamiltonian to the 1st order of one single harmonic oscillator's displacement $\vec{u}$. Its equilibrium position is at the origin. Then ...
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136 views

Phonon-phonon interaction

I have been told that phonon-phonon Interaction is an anharmonic effect so only arises if terms of third and higher order in the displacement of the ions the Hamiltonian for the nuclii is taken into ...
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97 views

Why is more intrinsic carriers bad for high temperature semiconductors?

I'm taking a solid state course, and is currently on the subject of dielectrics. In one of the sections, concerning "Impurities in Dielectrics" the books says: "Impurities can also be used to make ...
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322 views

Bloch wave function orthonormality?

there is this text book that is giving me a hard time for a while now: It shows that Bloch wave functions can be written as $$\Psi_{n\vec{k}}\left(\vec{r}\right) = \frac{1}{\sqrt{V}}e^{i\vec k \vec ...
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461 views

Question about the quantization of lattice vibration (phonons)

In my syllabus about solid state physics they state that lattice vibration is quantized, analogous to the harmonic oscillator: $$E = (n+\frac{1}{2})\hbar\omega$$ So the lattice vibration has ...
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429 views

Probability of Different States - Canonical Ensemble - Partition Function

Consider a canonical ensemble of $N$ ideal gas atoms, which could have spin up or spin down. Why is it that the probability of finding the particle in a spin up state generally only involves the ...
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868 views

Determining if a semiconductor is n-type, p-type or intrinsic

The probability that an energy state in the conduction band is occupied by an electron is 0.001. Would this semiconductor then be n-type, p-type, or intrinsic? Notation that I use: $E_F$ represents ...
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200 views

Connecting Fermi levels and band diagrams to potential diagrams?

I'm trying to make sense of how you can find the potential diagram given the band diagrams of a few adjacent materials. As a simple example, in semiconducting heterostructures, if you have sandwich ...
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55 views

Why can I see the 5D0 to 7F3 transition in the trivalent Eu?

According to the selection rules of the intra-configurational f-f transitions, if the J of the initial or final state is zero, a transition with $\Delta J = 3$ is forbidden by electrical dipole, ...
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What is the difference between lattice vectors and basis vectors?

Google has not been very useful in this regard. It seems no one has clearly defined terms and Kittel has too little on this.
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384 views

Ashcroft Mermin Solid State Physics Eq. 2.60ff

I'm trying to follow the steps in Eq. 2.60 of said book. What I cant seem to figure out is how to change the integration variables from 'k' to 'E', as they state. The equation is $$\int ...
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Mobility in semiconductors

Good afternoon everybody. I am reading on a book about semiconductor mobility. I have fully understood the definition, but I also noticed that often one talks about high or low mobility. My question ...
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691 views

How robust is Kramers degeneracy in real material?

Kramers theorem rely on odd total number of electrons. In reality, total number of electrons is about 10^23. Can those electrons be so smart to count the total number precisely and decide to form ...
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196 views

Does anyone know the difference and relation between $k\cdot p$ method and tight binding (TB) method?

Among the methods of calculating energy bands for crystals, first-principles method is the most accurate. Besides first principles, two commonly used modeling methods are the $k\cdot p$ method and ...
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500 views

Energy band diagram of a system of Silicon Quantum dots

Suppose that we have a system of Silicon nanoparticles embedded in ZnO dielectric matrix. i'm thinking about how to construct the energy band structure of this system , suppose that we already have ...
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854 views

How is contact resistivity defined for a Schottky contact, or the Schottky barrier height for an ohmic contact?

Based on the transfer length method (TLM), one can accurately calculate the contact resistivity for an ohmic contact, by evaluating the absolute resistance measured through the test structure and ...
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25 views

The Debye temperature for diamond

To simplify the calculation, let's assume that the average speed of sound in the diamond is simply $v_s=\sqrt{E/\rho}\simeq1.414\times10^4 \ \text{m/s}$, and the Debye frequency $$\omega_D=v_s\left( ...
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34 views

Help needed to understand the dispersion curve of a 1D lattice with diatomic basis

I am trying to understand the dispersion curve (as shown below) of a 1D lattice with diatomic basis. Here are my questions: Can both optical and acoustic branch of phonon simultaneously exist in ...
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57 views

Electron density in metals at non zero temperature

When computing the electron density in metals, the usual crude result is computed for zero temperature. That is, we integrate \begin{equation} n=\frac{8\sqrt{2}\pi m^{3/2}}{h^{3}} ...
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38 views

Is there Johnson noise in superconductor?

For conductor, the Johnson Noise is $v_n = \sqrt { 4 k_B T R \Delta f }$. It is clear that the noise depends on $R$. I'm curious whether this noise will appear in supercondutor? That is for ...
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51 views

What exactly are crystal planes and how do they reflect x-rays?

What exactly are crystal planes and how do they reflect x-rays? Are crystal planes real physical planes or just an abstract concept? What are these planes made of? If they are an abstraction, what ...
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69 views

Relationship between Polarizability and Conductivity

I've seen in the literature the relation: $\sigma (q,\omega) = \frac{i e^2 \omega}{q^2}\chi(q,\omega)$ where $\sigma$ is the conductivity and $\chi$ the polarizability. However my attempt to derive ...
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60 views

What are hot electrons?

What are they? How are they created? And what do they have to do with plasmons? I searched the web, but I would like more reliable and straightforward sources.
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120 views

Kronig-Penney model

I am studying the Kronig-Penney model as treated in the book by Kittel: Introduction to Solid State Physics. In this model one considers a period potential which is zero in the region $[0,a]$ ...
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51 views

How does band gap vary with the cell volume?

How does band gap vary with the cell volume? is there a relation? If the volume is compressed, the interaction between atoms would be more, therefore the perturbation is higher hence the splitting ...
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76 views

What is $\epsilon_\infty$ in this equation and why can it be neglected in the IR?

I'm reading this paper (warning, PDF) and they mention that the complex permittivity $\epsilon$ and complex conductivity $\sigma$ are related through the equation $$\epsilon - \epsilon_\infty = (4\pi ...
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269 views

Energy dispersion in graphene

Given that graphene has linear energy dispersion near the Fermi level and the dispersion is given by $E=\hbar \nu_F|\vec{K}|$, I would like to determine the density of states. I think it is equal to ...
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75 views

Frequency dependence of permittivity — why not monotonic?

I naively thought that most materials were transparent to radiation of frequencies above their plasma frequency, and opaque to radiation below it. The most intuitive (and analyzed lightly in ...
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253 views

Absorption of a gas into a solid

When a gas interacts with a (crystalline) solid, some scenarios may happen: scattering: gas atoms will not stick or penetrate (do not interact with the solid) Adsorption: gas atoms stick to the ...
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638 views

How to interpret band structures

I'm currently taking a Solid State Physics class, and is currently reading about the quantum mechanical description of solids. I then came across the following figure: It's supposed to be the band ...
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788 views

Partition Function for Two Level System

I have a system with $N_s$ sites and $N$ particles, such that $N_s >> N >> 1$. If a site has no particle, then there is zero energy associated with that site. The $N$ particles occupy the ...
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77 views

Why do excitonic absorptions have small bandwidth?

Below is an image of the optical density (proportional to the absorption coefficient) of KBr crystal at low temperature. Indicated at 6.6 ev and 7.7 eV are the absorption by excitons. As you can see, ...
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400 views

Derivation of Matrix Components of Hamiltonian in Tight Binding Method

Im currently struggling with the description of the tight binding method in the original paper by Slater and Koster from 1954 (where a free version of the paper can be found under this link). In ...
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194 views

A few questions about the Fermi Level/Energy

My first question is, how is the Fermi Energy for a material actually determined? I know this derivation, but it seems to say that the Fermi Energy is just based on the electron density (and maybe ...
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2answers
248 views

Difference between charge density wave and charge distribution

We can always see modulated charge density, the Friedel Oscillation, around an probe charge due to other electrons' response. Can this be called charge density wave (I believe not)? If not, what is ...
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393 views

valence bands in graphene

In Graphene, each carbon use 3 electrons to form sp2 bonding with neighboring, and in a unit cell, there are 2 carbon atoms, so at least these 6 electrons contribute to 6 valence bands. Then my ...
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108 views

Is this 2D structure triclinic?

The only rotation axis obvious to me is rotation by 360 degrees, the identity. Vertical mirror planes I've been dicing and cutting it through several planes and I still see none. Yet, the structure ...
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215 views

What are the rainbow and ladder approximations in a solid state physics context?

All references I find talk about quarks and gluons, where I have only very limited knowledge about. From it's name (rainbow) I guess it applies to fermions coupled to bosons and we're interested in ...
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333 views

I can't figure out crystal planes with negative intercepts

As seen above, I don't follow how you figure out those planes. It seems they're not using the origin labeled. I'm not really sure I understand spatially what's going on in the left figure so let's ...