1
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1answer
32 views

Effective masses for different direction

Assume we have an indirect semiconductor where the effective mass becomes anisotropic in different directions. Usually, one talks about a mass in parallel and perpendicular direction referring to ...
2
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0answers
18 views

How to check the ohmic contact to the film?

I have a thin semiconductor film deposited on an isolating substrate. I would like to check different metals to find out do they form the ohmic contact or Schottky barrier. What is the best way to do ...
1
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0answers
18 views

How can we determine the inbuilt barrierpotential and electric feld for a given band diagram?

Suppose I have got two p type silicon materials of different concentrations (the difference in thier concentrations is small but considerable enough that their fermi levels differ by noticeable ...
1
vote
1answer
67 views

Sold-State Band Structure - connection between Fermi Energy, Fermi Level and Work Fuction

I've been struggling with the concepts of these three terms - Fermi Energy, Fermi Level and work fuction. Now, I was given these definitions (in the context of semi-conductors): Fermi Level is the ...
0
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1answer
22 views

Calculating band gap from band structure

If while calculating a band gap, the band just below the Fermi level touches the Fermi level, can we say the material is semiconducting?
4
votes
3answers
56 views

How does temperature affect photovoltaics (PV) efficiency?

I know that photovoltaic panels are more efficient at lower temperatures: As the temperature increases, the output voltage decreases. I am looking for an explanation of the mechanism behind this ...
0
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2answers
72 views

List of experimental band gap

does anyone know where one can find a list, database, book of experimental bandgap values of semiconductors? Is there such a collection? Or do I need to scour papers one at a time to get the values?
1
vote
1answer
179 views

Band gaps: are they at the centre or at the edge of the Brillouin zone?

Reading about electronic band structures, I came across the following: Band gaps open at the edges of the Brillouin zone (BZ), since that is where the Bragg scattering occurs. I am slightly ...
2
votes
0answers
114 views

Derivation of existence of energy band gap in semiconductor (solid State)

I am looking for both a mathematical and a physical reason for energy band gap in metals. For Physical reason, I was told that at each reciprocal lattice, you could have Bragg scattering, that would ...
2
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1answer
116 views

Effective mass of a particle

I was reading about concept of effective mass on Wikipedia and came across the line that effective mass of a particle can be negative and even zero. How is this possible?
1
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0answers
438 views

What is the reason behind band gap narrowing in semiconductors

I want to know why some semiconductors band gap decreases after doping with elements. Burstein-Moss band-filling effect can be useful to explain band gap widing in a semiconductor materials but i was ...
1
vote
0answers
63 views

Nature of electron states in a semiconductor

Usually one is led to think of an electron moving from the valence band to the conduction band as an electron leaving the atom it is bound to in the lattice, and becoming free to move, while leaving ...
0
votes
1answer
100 views

Semiconductors: why the mass action law is not valid for very low temperatures?

I thought that it was valid for very low temperatures since for it to be valid I think that it is necessary to be in the non-degeneracy condition, which requires $E_G >> k_B T$ (with $E_G$ being ...
2
votes
1answer
782 views

Valence band and conduction band, trying to get a clear picture!

I am trying to get a clear picture of the valence band, conduction band, and the band gap. Now I've been researching it for a little while now and understand most of what's going on. I'm still a ...
1
vote
0answers
113 views

Energy band diagram of a metal-silicon-metal device, bias voltage applied

I have an intrinsic silicon layer sandwiched in between two aluminum contacts. I'm trying to figure out the band diagram of the entire device when a positive bias (much larger than the work function ...
0
votes
1answer
703 views

How does temperature affect a semiconductor band gap?

From this link, I've read that An increased interatomic spacing decreases the potential seen by the electrons in the material, which in turn reduces the size of the energy bandgap. Can this ...
4
votes
2answers
677 views

Need help understanding Semiconductor physics

I am trying to read Kittel for a project, and he mentions the properties on silicon and germanium so briefly, that I don't understand it at all. He talks about p states, and I don't really know what ...
4
votes
1answer
160 views

Is it possible to excite a semiconductor @ k=0?

Let us assume a direct semiconductor with parabolic band structure around the $\Gamma$ point (which is not bad for most semiconductors) in momentum ($k$) space. Now we excite it with light: I ...
4
votes
2answers
226 views

Why are there direct bandgaps?

This Question has been bugging me for sometime. Some semiconductors have direct bandgaps and indirect bandgaps. So what causes a direct bandgap to occur? The physics behind ,why there are direct ...
1
vote
1answer
160 views

How bandgap engineering works?

Currently i am reading about bandgap engineering in zinc oxide. I read that using external dopents likes magnesium or cadmium we can increase or decrease bandgap of zinc oxide,thus giving unique ...
8
votes
1answer
1k views

Why do electrons in graphene behave as Dirac fermions near the Dirac points?

I've been learning about graphene, and I recently calculated the band structure for it using a nearest-neighbor tight-binding model for the $\pi$ electrons: $$\varepsilon(\vec k)=\pm t\sqrt{3+2 \cos ...
1
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1answer
217 views

DFT for bandstructure

Density Functional Theory (DFT) is not appropriate in predicting the band gap of the materials. However, which functional gives close value to the experimentally observed band gap of semiconductors? ...
2
votes
0answers
109 views

Why does silicon have an indirect gap?

Is there an intuitive explanation as to why silicon has an indirect gap? I have heard that this can explained using pseudopotentials.
0
votes
1answer
2k views

PN Junction Depletion Region

So it took me a little bit to understand this, but I want to make sure I have a few things right. First of all, when a Crystal Structure with One side N-Doped, One Side P-Doped are in the same ...
0
votes
1answer
62 views

Regarding “Holes” in bands, and Photons

So from learning Band theory, and PN Junction and such, I've learned that photons are created when "holes" are filled in a band, and this is what can create light (Isn't this how LEDs work?) Anyways, ...
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2answers
2k views

Band Gap/Energy Bands in Semiconductors?

I think i've finally nailed down the Semiconductor Physics (Well the general part, whats and why's etc, as per my previous question) Anyways there is one small part that confuses me, and thats BAND ...
1
vote
1answer
225 views

Semiconductors and localization of the electrons

When looking at the band diagram of a semi-conductor, direct conclusion of the invariance under discrete translations, for a filled state with an electron, one does know precisely it's momentum, so my ...
2
votes
1answer
186 views

Does anyone know the difference and relation between $k\cdot p$ method and tight binding (TB) method?

Among the methods of calculating energy bands for crystals, first-principles method is the most accurate. Besides first principles, two commonly used modeling methods are the $k\cdot p$ method and ...
3
votes
1answer
193 views

Confused about charge seperation in solar cells

I'm a bit confused about how solar cells work. My understanding is that there is a p-n junction. A photon is absorbed which creates an electron-hole pair, and the idea is to separate the electron ...
2
votes
1answer
1k views

What does the Fermi Energy really signify in a Semiconductor?

In understanding the behavior of semiconductors, I'm coming across a description of the Fermi Energy here and at Wikipedia's page (Fermi Energy, Fermi Level). If I understand correctly, the Fermi ...
8
votes
2answers
725 views

Modern and complete references for the $k\cdot p$ method?

I've recently started studying the $k\cdot p$ method for describing electronic bandstructures near the centre of the Brillouin zone and I've been finding it hard to find any pedagogical references on ...