1
vote
0answers
33 views

Quick question on sketching wavefunction in well

Usually for an infinite well, the sketch for n=3 level is this: Now I think if one side of the potential barrier is higher, the particle will be more likely to spend time on the left side than ...
1
vote
2answers
52 views

Stationary state of time-independent Schroedinger equation is always real valued function?

I am reflecting on the solution of the time-independent Schroedinger equation. My reasoning is that the stationary state of the time-independent Schroedinger equation must be a real valued function ...
2
votes
1answer
66 views

On use of Hamiltonians for Helium

The Hamiltonian of helium can be expressed as the sum of two hydrogen Hamiltonians and that of the Coulomb interaction of two electrons. $$\hat H = \hat H_1 + \hat H_2 + \hat H_{1,2}.$$ The wave ...
0
votes
1answer
84 views

Is it possible to find the hydrogen atom's radial wavefunctions?

Is there a way to actually find the equation of $R(r)$ without looking at a table with these equations already given? I'm given $n$, $\ell$, and $m$.
2
votes
1answer
74 views

Kronig-Penney model

I am studying the Kronig-Penney model as treated in the book by Kittel: Introduction to Solid State Physics. In this model one considers a period potential which is zero in the region $[0,a]$ ...
1
vote
1answer
65 views

Obtain the eigenfunction of Jz for the wave function of an electron in a hydrogen atom? [closed]

The wave function of an electron in a hydrogen atom is given by Is this wave function an eigenfunction of Jz , the z-component of the electron’s total angular momentum? If yes, find the ...
2
votes
1answer
94 views

Expectation value of Hamiltonian in different pictures of quantum mechanics

We start with the familiar Schrodinger equation: $$ i\hbar \frac{\partial \left|\psi_S\right\rangle}{\partial t} = \hat{H}_S \left|\psi_S\right\rangle $$ As we switch to a different picture than ...
6
votes
2answers
169 views

When can we assume that the wavefunction is separable

While working out the stationary states of a single particle in a 3d infinite potential box ($V=0$ inside a cuboid of known dimensions, $V=\infty$ everywhere else), I realized I had to assume the ...
2
votes
2answers
43 views

How will a particle with energy less than $V_{\rm min}$ behave?

Consider e.g. the finite square well: $V = -V_o$ between $x=-a$ and $x=a$, $V=0$ elsewhere Now for scattering states, $E$ must be $> 0$. For normalizable bound states, $E$ must be $< 0$ and ...
0
votes
1answer
62 views

Solving the 1D Schrodinger Equation for a Free Particle - Two Different Methods?

So starting from the time dependent schrodinger equation I perform separation of variables and obtain a time and spatial part. The spatial part is in effect the time independent schrodinger equation. ...
2
votes
1answer
49 views

Free particle Schrödinger Equation

Some sources give the free-particle solution to Schrödinger equation as $$\psi(x,t) =Ae^{i(kx-\omega t)} + Be^{-i(kx+\omega t)}$$ while some sources give it as $$\psi(x,t) =Ae^{i(kx-\omega t)}$$ ...
1
vote
1answer
46 views

Reflection of an evanescent matter wave within a finite barrier?

To my understanding if I have a finite barrier with potential $V(x)>E$, then to the left of the barrier, the wavefunction can be represented as two exponentials: $$\psi= e^{(ik_{left} x)} + ...
3
votes
1answer
178 views

Harmonic Oscillator potential, proof that Gaussians remain Gaussians?

I read in several papers that for a Harmonic Oscillator Hamiltonian in the time dependent Schrödinger equation a Gaussian wave packet remains Gaussian. Unfortunately I could not find any proof for ...
10
votes
2answers
213 views

The formal solution of the Schrodinger equation

Let's have Schrodinger equation (or some equation in Schrodinger form) $$ \tag 1 i \partial_{0} \Psi ~=~ \hat{H} \Psi . $$ One likes to write that it has formal solution $$ \tag 2 \Psi (t) ~=~ ...
0
votes
1answer
51 views

Regarding derivation of Probability Current

The question for the full derivation of Probability Conservation -> Probability Current was already asked here: Probability current. I apologize for not retyping it out, but it's already beautifully ...
0
votes
2answers
315 views

Schrödinger's Equation and the depth of a finite potential well

Before I ask my question, I have to stress: I have absolutely no idea what the math is going on. I've read my textbook, several Wikipedia articles, scoured the internet, and don't feel anymore ...
2
votes
2answers
102 views

Box normalisation and Particle in a box - Quantum Mechanics

I have been long itched by this issue of subtle difference between box-normalised free particle and infinite-dimensional potential well. Choosing a one dimensional case, the Hamiltonian in two cases ...
7
votes
2answers
439 views

Infinite and Finite Square Wells

For the infinite square well in the first region, outside the well: $$\frac{-\hbar^2}{2m}\frac{d^2 \psi}{dx^2} + V(x) \psi (x) = E \psi (x),$$ where you set $V = 0$. Rearranging gives $$\frac{d^2 ...
1
vote
0answers
85 views

Particle in a higher-dimensional box with an attractive delta potential

Suppose you have a particle in the box $[0,L]^d$, with an attractive Dirac delta potential $-\delta_{\vec w}(x)$ at $\vec w$. How do you solve the Schroedinger equation for this system? In the case ...
2
votes
2answers
105 views

Infinite well particle subject to additional time dep. potential

I am asked to find the wavefunction of the particle in a well subject to an additional potential $$V(x,t)=\frac{\pi x \hbar}{L}\delta(t).$$ I have already solved that ...
5
votes
2answers
243 views

Non-separable solution for the Schrödinger equation

Schrödinger solutions are usually if not always of the type: $\psi=\operatorname{T}(t)*\operatorname{X}(x)$ (we use the separation of variables method to arrive at the time independent Schroedinger ...
2
votes
2answers
256 views

Solving quantum radial equation for infinite potential spherical annulus for $l=0$

There is a mass $m$ in a potential such that $$ V(r) = \left\{ \begin{array}{lr} 0, & a \leq r \leq b\\ \infty, & \text{everywhere else} \end{array} \right. $$ ...
4
votes
1answer
167 views

Virial theorem and variational method: an exercise (re-edited)

I have a hydrogen atom, knowing that its Hamiltonian has been modified turning the standard potential $$ V_{0}(r) = -\frac{Z}{r} $$ into $$ V(r) = -\frac{g}{r^{\frac{3}{2}}} $$ with $g$ a positive ...
0
votes
1answer
135 views

Infinite potential square well solutions

My question is about understanding the different solutions of the potential square well. Imagine a square well defined this way: $$ V(x) = \begin{cases} ∞&\,{\rm if} x<0 \\ 0&\,{\rm ...
7
votes
4answers
330 views

Can we safely assume $\Psi(x,t) = \psi(x)e^{-i\omega t}$ always in QM?

In the particle in a box, harmonic oscillator and in Hydrogen Atom, we can safely assume $$\Psi(x,t) = \psi(x)e^{-i\omega t}.$$ So why not make it a postulate to consider the wave function to be ...
5
votes
5answers
1k views

Example of the time-independent Schrödinger equation having a complex solution?

We know $\Psi(x,t)$ is complex, but can $\Psi(x)$ be complex? I have seen particle in a box, well and harmonic oscillator. All have real solutions for time-independent Schrödinger equation. Hence, I ...
4
votes
3answers
396 views

Comparison of 1D and 3D wave functions

When discussing the Schroedinger equation in spherical coordinates, it is standard practice in QM handbooks to point out that the radial part of the 3-dimensional wave equation bears a strong analogy ...
1
vote
2answers
240 views

General wavefunction and Schrödinger Equation

I'm starting with quantum mechanics and the book I follow (Griffiths) first introduces the wavefunction as the probability density of the position of a 0-spin single particle. Later on I've realized ...
0
votes
1answer
430 views

Wave packets and the derivation of Schrodinger's equation

I studied in my class, that a plane progressive wave cannot be used to represent the wave nature of a particle as it is not square integrable. Also, the phase velocity can get above the value of $c$, ...
0
votes
2answers
331 views

A few parity questions for simple harmonic oscillator

I think I understand that the solution to the Schrodinger equation for the SHO is based on the Hermite polynomials (and the Guassian function). The solution set of all even Hermite polynomials are a ...
3
votes
2answers
282 views

Formulation and probability of a wave-function [closed]

I have got this problem where I have been given the following wave function: $$\Psi = 0\quad\text{if}~|x| > a\quad\text{and}\quad A(a^2-x^2)\quad \text{if} \quad |x|< a$$ Now the first question ...
4
votes
2answers
408 views

Understanding the Wave Function and Excited States

A wave function is an infinite dimensional vector space, how can it "live" in $\mathbb{R}^3$? Given the equation that is built like: $$\Psi (x,t) = \sum ^{\infty} _{n=1} c_n \psi _n (x) e^{-i E_n t / ...
3
votes
5answers
715 views

Infinite Wells and Delta Functions

In considering a delta potential barrier in an infinite well, I can just enforce continuity at the potential barrier-it doesn't have to go to zero. Why then does it need to go to zero at the walls of ...
-1
votes
1answer
317 views

Why is the wave function complex? [duplicate]

Why should an equation (TDSE) in which first time derivative is related to second space derivative have a solution that contains $i$?The wave function is supposed to be complex, but I am unable to ...
0
votes
1answer
192 views

In Schrödinger equation, can we get $\Psi$ if we know $\varphi(n)$?

Let $A$ be a mechanical quantity and we know its eigenfunction $\varphi(n)$. Can we get its wave function $\Psi$, if we measure $A$ for many (maybe infinite) times at the same time?
1
vote
1answer
291 views

Tunnelling through a Dirac potential barrier

I am reading a QM book by Griffiths, which says it is possible for wave particle to tunnel through a barrier formulated by a Dirac function. This function is known to peak at infinity and also ...
2
votes
2answers
147 views

Does Schrödinger equation have dual-property with Heat equation?

I have experimental data that Schödinger equation maintains high frequencies, while heat equation low. Does Schrödinger equation have some duality property with heat equation?
1
vote
1answer
1k views

How to find the wavefunction that solves an infinite square well with a delta function well in the middle?

Solutions for the wavefunction in an infinite square well with a delta function barrier in the middle are easily found online (see here for an example). I am wondering what the wavefunction is for an ...
1
vote
1answer
214 views

Quantum harmonic Oscillator analytic method

I'm using a book from Griffiths, I got really stuck about how he arrived at the approximate solution, is it just by trying( trial solution method?), I really appreciate any help on this. ...
2
votes
1answer
241 views

Given wave function at $t=0$, what is the process of deriving time dependent wave equation? [closed]

Suppose $$\Psi (x, t=0)=Ae^{i\alpha _1}\psi _1(x)+Be^{i\alpha _2}\psi_2(x)+Ce^{i\alpha _3}\psi_3(x).$$ If $\psi _n$ are the energy eigenfunctions how would I derive $\Psi (x,t)$? I am having trouble ...
2
votes
3answers
140 views

Non-normalizable QM bound state in 4 spatial dimensions?

Edit 26/Sept/13: Fixed Typo in potential I'm solving the following (seemingly simple) quantum-mechanical problem in four spatial dimensions. In natural units ($\hbar^2/2m=1$), the Schrödinger ...
3
votes
3answers
527 views

When Eigenfunctions/Wavefunctions are real?

When the Hamiltonian is Hermitian(i,e. beyond the effective mass approximation), generally under which conditions the eigenfunctions/wavefunctions are real? What happens in 1D case like the finite ...
1
vote
1answer
700 views

How to prove dp/dt = -dV/dx? Quantum mechanics [closed]

I got this problem from a book called Introduction to quantum mechanics, griffin 2nd edition. and I did not get why the solution says first term integrates to zero, integration by parts twice?! ...
2
votes
1answer
320 views

A Simple Explanation for the Schrödinger Equation and Model of Atom? [closed]

I tried reading the Wikipedia article to no avail - I simply cannot understand the Schrödinger Equation (what does each of the variables mean, especially the wave function), and the Schrödinger Model ...
2
votes
2answers
645 views

Wavefunction as a combination of two stationary states - how to find those states?

Lets say we have a particle in a infinite square well which has a wavefunction like this ($A$ is some constant and $d$ is the width of the well): \begin{align} A\left[ \sin \left(\frac{2 \pi ...
1
vote
2answers
1k views

The Energy Eigenvalue of a Wavefunction

I've been reading an introduction to quantum mechanics online, and while constructing the Schrodinger equation for a free particle, the equation $i\hbar \frac{d \Psi}{dt}=\hbar\omega\Psi$ is obtained. ...
9
votes
1answer
1k views

Variational Derivation of Schrodinger Equation

In reading Weinstock's Calculus of Variations, on pages 261 - 262 he explains how Schrodinger apparently first derived the Schrodinger equation from variational principles. Unfortunately I don't ...
1
vote
1answer
503 views

Solution of 1-D Schrodinger equation for the potential $V(x) = -\frac{1}{|x|}$

May be this question might have already been asked but i couldn't find it, so let me know if its already there. Consider a potential, $V(x) = -\frac{1}{|x|}$ and if we apply this to a one dimensional ...
2
votes
1answer
634 views

Solving a time independent Schrödinger equation with a given potential

I'm trying to rework this old homework problem, and I am having problems arriving at the same solution on the answer sheet: Let $$V(x)=\begin{cases}\infty &\text{ if } x < 0\\ ...
-1
votes
1answer
247 views

Problem from Sakurai about a delta-function potential [closed]

Can you help me with this problem from Sakurai: A particle of mass m in one dimension is bound to a fixed center by an attractive delta-function potential: $$V(x) ~= ~-a\delta(x) , \qquad ...