1
vote
2answers
85 views

System without ground state is not real in nature?

We know that Coulomb force is real phenomena in nature and with Coulomb potential $V(x) \thicksim -\frac{1}{|x|}$ lowest energy is bounded in hydrogen atom. But it's mathematically clear that if ...
3
votes
3answers
189 views

The Dirac-Delta function as an initial state for the quantum free particle

I want to ask if it is reasonable that I use the Dirac-Delta function as an intial state ($\Psi (x,0) $) for the free particle wavefunction and interpret it such that I say that the particle is ...
0
votes
1answer
45 views

(Level: Undergrad) Continuity Conditions on the Wavefunction and Initial Values

I know that a physically meaningful $\Psi$ needs to be continuous. However, recently I came across a problem in which they were considering a wavefunction for the infinite square well potential and ...
3
votes
1answer
69 views

Justification of discrete spectrum for V(x) unbounded at $\pm \infty$ in Pauling and Wilson

In Pauling and Wilson, Introduction to Quantum Mechanics, they offer the following intuitive reason for the discrete spectrum of a potential which is unbounded at $\pm \infty$: This is ...
4
votes
1answer
86 views

Is there some quantum potential producing exponential eigenvalues?

Usual central potentials produce quantum spectra with energy levels going as $n$, $n^2$, $n^3$ and so on, being $n$ the quantum number of the orbit. In the other extreme we have "dirac-delta" ...
7
votes
4answers
257 views

Does Heisenberg equation of motion imply the Schrodinger equation for evolution operator?

Let us choose to postulate (e.g. considering the analogy of the Hamiltonian being a generator of time evolution in classical mechanics) $$ i\hbar \frac{d\hat{U}}{dt}=\hat{H}\hat{U}\tag{1} $$ where ...
8
votes
1answer
179 views

Time derivative of the state vector as expressed in abstract Hilbert space vs. as a wavefunction

The Schrodinger equation in Hilbert space is expressed as : $$\frac{\partial}{\partial t} \psi(t) = \frac{-i}{\hbar}H\psi(t). $$ Here $\frac{\partial}{\partial t} \psi(t) \equiv \psi'(t) \equiv\lim ...
6
votes
2answers
191 views

When can we assume that the wavefunction is separable

While working out the stationary states of a single particle in a 3d infinite potential box ($V=0$ inside a cuboid of known dimensions, $V=\infty$ everywhere else), I realized I had to assume the ...
2
votes
0answers
95 views

Solving the Schrodinger equation with appropriate symmetry

In the paper Markov Fields by Edward Nelson the introduction section claims that analytically continuing a Markov process with appropriate symmetry properties yields the solution of the Schrodinger ...
11
votes
1answer
189 views

Lie group of Schrodinger Wave equation

In Ballentine's book on quantum mechanics (in 3rd chapter), he introduces the symmetry transformation of Galilean group associated with Schrodinger equation. Now the Galilean group as such has 10 ...
2
votes
0answers
139 views

Understanding the algebra associated with an implicit potential

In the paper here(page 7-8) the authors make a claim that the Natanzon potential (an implicit potential) follows an $SO(2,2)$ algebra. This potential defined as : $$ U(z(r)) = ...
2
votes
2answers
171 views

Harmonic Oscillator - Energy quantisation

The one-dimensional quantum HO can be solved in Schrodinger representation by getting Hermite Differential Equation $$ \frac{d^2y}{dx^2} - 2x \frac{dy}{dx} + \lambda y = 0 $$ with solutions $$ y(x) = ...
3
votes
1answer
100 views

Determining the group associated with a given potential?

I'm trying to understand how symmetry groups are related to potentials of the Schrodinger equation. In particular, I wish to know if it is possible to find the symmetry group of this potential $$V(x) ...
3
votes
1answer
91 views

Differential Realizations of certain algebras

I'm a first year graduate student in Mathematical Physics, and I am trying to generalise a certain method involving the so-called "Differential realizations" of certain algebras. The problem I'm ...
1
vote
2answers
199 views

Can we have a physical interpretation for a time independent Schrodinger equation of this form?

I am interested in a time independent Schrodinger equation of this form. $$F*\psi - \frac{\hbar^2}{2m} \frac{\partial^2{\psi}}{\partial{x^2}} = E\psi$$ Here the product $V\psi$ is replaced by the ...
4
votes
3answers
437 views

Comparison of 1D and 3D wave functions

When discussing the Schroedinger equation in spherical coordinates, it is standard practice in QM handbooks to point out that the radial part of the 3-dimensional wave equation bears a strong analogy ...
1
vote
2answers
146 views

Separation of variables in various PDEs, physical meaning

The method of separation of variables produces an undetermined separation constant and a family of solutions indexed by the values of this constant. For instance, in the case of an infinitely long ...
15
votes
1answer
582 views

Discreteness of set of energy eigenvalues

Given some potential $V$, we have the eigenvalue problem $$ -\frac{\hbar^2}{2m}\Delta \psi + V\psi = E\psi $$ with the boundary condition $$ \lim_{|x|\rightarrow \infty} \psi(x) = 0 $$ If we ...
3
votes
3answers
711 views

Can we have discontinuous wavefunctions in the Infinite Square well?

The energy eigenstates of the infinite square well problem look like the Fourier basis of L2 on the interval of the well. So then we should be able to for example make square waves that are an ...
1
vote
1answer
632 views

The Hermiticity of the Laplacian (and other operators)

Is the Laplacian operator, $\nabla^{2}$, a Hermitian operator? Alternatively: is the matrix representation of the Laplacian Hermitian? i.e. $$\langle \nabla^{2} x | y \rangle = \langle x | ...
9
votes
2answers
746 views

Why does iteratively solving the Hartree-Fock equations result in convergence?

[ Cross-posted to the Computational Science Stack Exchange: http://scicomp.stackexchange.com/questions/1297/why-does-iteratively-solving-the-hartree-fock-equations-result-in-convergence ] In the ...
1
vote
1answer
326 views

A quantum particle in a box (with a catch)

I am reading Shankar's Quantum Mechanics and I am looking at the case where there is one particle inside a box, where the potential is zero inside the wall and abruptly goes to infinity outside the ...
1
vote
1answer
329 views

Is it a total or an explicite time derivative in the Schrödinger equation?

I am always dubious when I need write Schrödinger equation: do I write $\partial / \partial t$ or $d/dt$ ? I suppose it depends on the space in which it is considered. How?
24
votes
4answers
1k views

In quantum mechanics, given certain energy spectrum can one generate the corresponding potential?

A typical problem in quantum mechanics is to calculate the spectrum that corresponds to a given potential. Is there a one to one correspondence between the potential and its spectrum? If the ...