2
votes
2answers
85 views

The nature of “hard wall” boundary condition for Schrodinger's equation

For a quantum particle in an one-dimensional infinite well of width $L$, the potential has the formal expression: $$ V(x) = \begin{cases} \infty, & x < 0 \\ 0, & 0 \le x \le L \\ \infty, ...
0
votes
1answer
71 views

Finding the odd parity bound state wave function for a particle in one dimension

Let a particle of mass $m$ and energy $E$ be moving on the $x$-axis in a potential $V(x)$ given by $$V(x)=\left\{\begin{matrix} -V_{0}, & -a<x<a\\ 0, & otherwise \end{matrix}\right.$$ ...
2
votes
1answer
55 views

Solving the 1-d time-independent Schroedinger's equation with an infinite boundary

In my introductory modern physics class we have examined time-independent solutions to the Schrödinger equation in 1 dimension. We looked at a few cases without finite boundary, e.g., free particles ...
4
votes
3answers
396 views

Comparison of 1D and 3D wave functions

When discussing the Schroedinger equation in spherical coordinates, it is standard practice in QM handbooks to point out that the radial part of the 3-dimensional wave equation bears a strong analogy ...
3
votes
5answers
715 views

Infinite Wells and Delta Functions

In considering a delta potential barrier in an infinite well, I can just enforce continuity at the potential barrier-it doesn't have to go to zero. Why then does it need to go to zero at the walls of ...
2
votes
1answer
423 views

How to solve bound states of 2D finite rectangular square well?

I want to solve bound states (in fact only base state is needed) of time-independent Schrodinger equation with a 2D finite rectangular square well \begin{equation}V(x,y)=\cases{0,&$ |x|\le a ...
0
votes
1answer
1k views

Periodic boundary condition on a Wave Function of a Particle in a Box

Until now solving the Schrodinger Equation for a particle in a box was relatively easy because the boundaries conditions imposed zero value on the wave function at the boundaries. But now I must find ...
1
vote
2answers
1k views

Barrier in an infinite double well

I am stuck on a QM homework problem. The setup is this: (To be clear, the potential in the left and rightmost regions is $0$ while the potential in the center region is $V_0$, and the wavefunction ...
2
votes
2answers
485 views

Can we impose a boundary condition on the derivative of the wavefunction through the physical assumptions?

Consider the Schrödinger equation for a particle in one dimension, where we have at least one boundary in the system (say the boundary is at $x=0$ and we are solving for $x>0$). Sometimes we want ...