Partial differential equation which describes the time evolution of the wavefunction of a quantum system. It is one of the first and most fundamental equations of quantum mechanics.

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Schroedinger Equation and Special Relativity

From what I understand, the Schroedinger equation describes how the wave function of a quantum system evolves in space over a given time (I am referring to a relativistic version of the Schroedinger ...
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Cubic perturbation to coupled quantum harmonic oscillators

I recently came across this two-dimensional problem of a particle in a potential of the form $$V = \displaystyle{\frac{1}{2}m \omega^2} \big(y^2 + x^2y \big) - \alpha y,$$ where $x$ and $y$ are known ...
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Double well potential [on hold]

A particle is in the following double-well potential with $E<0$: $$V(x)=0 \quad for \quad x<-a, x>a; -V_0 \quad for \quad -a<x<-b, b<x<a; 0 \quad for \quad -b<x<b$$ I am ...
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51 views

using a given wavefunction to find particle properties

Let's say we have a given wavefunction and we want to find a particle that will fulfill the properties for that wavefunction. How can we do that? Is it possible? I was thinking of using Schrodinger's ...
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62 views

Bound States in quantum mechanics [on hold]

A particle is found in the following potential: $$V(x)=\infty \quad \text{for} \quad x<0;$$ $$V(x) = -V_0 \quad \text{for} \quad 0<x<a;$$ $$V(x) = 0 \quad \text{for} \quad x>a.$$ Given ...
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How to motivate Schrödinger's Equation? [duplicate]

Schrödinger's equation is supposed to be a differential equation for the wave function of a particle. As I currently understand, De Broglie's hypothesis is a hypothesis that for particles there should ...
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18 views

Applications of the study of Hamiltonians with constant magnetic fields

I am interested in understanding possible applications for the study of quantum systems with constant magnetic fields. For definiteness, consider the Landau Hamiltonian $$H_{0} = ...
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25 views

Allowed energies for semi-harmonic oscillator

Question: If a particle is attached to a semi-harmonic oscillator (that is, for example, the spring is stretchable but not compressible) such that the potential $V(x)$ is infinity for $x\leq0$ and ...
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23 views

Units for Schrödinger equation? [closed]

What units are usually used for mass and position when dealing with the Schrödinger equation? If I have the position of electron i out of N electrons, what would the units be?
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Schrödinger: Coherent states

A coherent state is called $\Psi_{{\alpha}} \left( x,t=0 \right)$ and is defined by: $a_{{{\it \_}}}\Psi_{{\alpha}} \left( x \right) =\alpha\,\Psi_{{\alpha}} \left( x \right) $ where $a_{{{\it ...
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Wave-Particle Duality in the Confinement of an Electron in a Box [closed]

According to the wave particle duality, one can say that an electron is both a wave and a particle. If we confine it in a box, it can only form standing waves at particular wavelengths, which leads ...
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84 views

Complex comjugate of Schrodinger equation: paradox in matrix form?

We can take the complex conjugate of schrodinger equation, and obtain $$ -\frac{\hbar^2 }{2m}\frac{\partial^2\psi}{\partial x^2} + V(x)\psi = i \hbar \frac{\partial \psi}{\partial t} $$ $$ ...
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How are electrons restricted to individual orbitals?

Since orbitals are just regions of electron density, they allow electrons to occupy the same space. I feel like in some sense this contradicts the Pauli exclusion principle limiting two fermions, or ...
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13 views

Low-momentum behaviour of a short-range potential

I've read the follow sentence in a journal article (arXiv preprint) which constitutes part of my coursework. As discussed in the previous section, the low-momentum behavior of any short-range ...
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19 views

What's the elementary reason for the formation of a band gap?

Bohr's solution for an isolated hydrogen atom showed that there are only discrete allowed energy levels, $E_n = -{E_0\over n^2}$ and the solution of the Schreodinger equation provided a certain ...
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Naive interpretation of Galilean invariance of the TDSE

I was told today by someone smarter than myself that the time-dependent Schroedinger equation in one dimension was invariant under a Galilean transformation of $(x,t)$, namely under ...
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123 views

Quantum Spin Simulation

In Leonard Susskind's Quantum Mechanics: The Theoretical Minimum, he describes a computer program that could fool you into thinking there is a quantum spin in a magnetic field. This spin is inside a ...
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Physical interpretation of a certain Hamiltonian

Consider a $2 \times 2$ Hermitian (or symmetric) matrix-valued function $$g(x) = \{ g_{jk}(x)\}_{j,k=1,2}, \quad x \in \mathbb{R}^{2},$$ such that $0 < m_{-}I \leq g(x) \leq m_{+}I$, for some ...
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Estimate of the second shallowest bound state?

Suppose we have a 1D potential $V(x)$ of finite range, i.e., $$ V(x) ~=~0 $$ for $|x| > b $. The potential is assume to support at least two bound states, but might have more, say $n\geq 2$. ...
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How to know if a wave function is physically acceptable solution of a Schrödinger equation?

How does one decide whether a wave function is a physically acceptable solution of the Schrödinger equation? For example: $\tan x$ , $\sin x$, $1/x$, and so on.
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127 views

1D Finite potential well: solutions with $\sinh$ and $\cosh$?

So I am studying the (one dimensional) quantum mechanical finite potential well defined by: $$ V(x) = \cases{0, &|x|>a\cr -V_0, &|x|<a} $$ where $V_0>0$ is a real number. I know ...
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Collapse of the wave function and Heisenberg uncertainty

I have been studying quantum mechanics for a few weeks, in particular wave mechanics, as created by Schrodinger, and his equation. As a high school student, I haven't found an answer to this question ...
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113 views

Deriving a Useful Solution of the Schrödinger Equation [closed]

How does one derive the fact that $$\psi(t,x) = (\tfrac{2 \pi \hbar t}{m})^{-d/2}\int_{\mathbb{R}^d} e^{im\tfrac{(x-y)^2}{2\hbar t}}\psi_0(y)dy$$ is a solution of the time-dependent Schrödinger ...
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Why discrepancies in the Schrödinger equation? [duplicate]

Why is there seemingly two definitions of the Schrödinger equation? \begin{equation} i\hbar\frac{\partial}{\partial t}\Psi=\hat H\Psi. \end{equation} And \begin{equation} i\hbar ...
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Quasiclassical QM for central fields

Let's have quasiclassical QM for central field $V(r)$. The Schroedinger equation for radial part of wavefunction $R_{nl}$ after substitution $u_{nl} = rR_{nl}$ takes the form $$ u_{nl}{''} + ...
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What is the most agreed upon quantum mechanical equation of motion?

On multiple Wikipedia articles, it mentions several quantum mechanical equations of motion, namely those by Schrödinger and Heisenberg. Which one is the most accurate and agreed upon quantum ...
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110 views

A misunderstanding regarding infinite square well

Here is a picture of the energy states of infinite potential well. We can see That the first level have a half wavelength which fittes with a full wave of the second level. $$\frac{ \lambda _{1} ...
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135 views

Ground state of Spherical symmetric potential always have $\ell=0$?

I was given a problem where I have a spherically symmetric potential (the exact form is not relevant to this question, I think - but anyway is it 0 for $r\in[a,b]$ and $\infty$ everywhere else) and I ...
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60 views

Semiclassical quantization of bouncing ball

Consider an elastically bouncing ball of mass $m$ and energy $E$. This has a triangular potential $$ V(x)~=~\left\{\begin{array}{ll} mgx & \text{if } x>0, \\ \infty & \text{if } x<0, ...
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25 views

Quantization in a 2D quasicrystal?

let be the Schroedinger equation with a potential in a quascristal $$ -( \partial _{x}^{2}+ \partial _{y}^{2}) \Psi (x,y)+ V(x,y)=E_{n} \Psi (x,y) $$ if we were in a crystal we could impose the ...
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On the Equivalence of Schrodinger and Heisenberg Descriptions of Quantum Mechanics and Observability

I'm not a physicist, but rather a control (feedback) systems engineer eager to understand more than just a cursory explanation of quantum mechanics. The StackExchange has been an excellent forum for ...
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59 views

What really generates time evolution?

A fundamental principle of quantum mechanics, as far as I can tell, states that the Hamiltonian generates time evolution. A common result about generators are the following: let $\mathrm T$ be the ...
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276 views

Do the probability density and the probability current density have a unit

I could not find what is the probability density and the probability current density of one-dimensional Schrödinger equation units?
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50 views

Choice of the z-axis in the Schrödinger equation for the hydrogen atom

I am reading about the solution of the Schrödinger equation for the hydrogen atom and have a question about the choice of the z-axis. Most websites say that the z-axis is arbitrarily chosen. If so, ...
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3answers
143 views

Schrödinger equation derivation and Diffusion equation

I am aware of the debate on whether Schrödinger equation was derived or motivated. However, I have not seen this one that I describe below. Wonder if it could be relevant. If not historically but for ...
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Bosonic Schrödinger field [closed]

When second quantizating the Schrödinger field $$\psi(r,t) = \sum_i \phi_i(r)b_i(t),\quad\mbox{and}\quad \psi^{\dagger}(r,t) = \sum_i \phi_{i}(r)^* b_i^{\dagger}(t),$$ we have the commutation ...
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Why the statement “there exist at least one bound state for negative potential” doesn't hold for 3D case?

Previously I thought this is a universal theorem, for one can prove it in the one dimensional case using variational principal. However, today I'm doing a homework considering a potential like ...
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WKB approximation for multiple turning points

I'm working on a numerical program which approximates the eigenvalues of a Schrödinger equation by making use of the WKB approximation formulas. For example, if the Schrödinger equation is $$ y''(x) = ...
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Quantum Mechanics in Electric Field

I am working on a problem which looks like this. Consider a charged particle with charge $q$ trapped in a box of length $L$ with finite constant potential $ V_0 $ on both ends. A constant (static) ...
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Quantum mechanics: Finite square well problem

What will happen if the potential is less than 0, for instance $V(x)=-10eV$. Is this means there will be no bound states? Since solution to the time independent Schrodinger equation (those discrete ...
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1answer
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Interaction pictures of Quantum Mechanics

I want to understand the Schrödinger, Heisenberg and interaction picture and have a few questions about them: So in general you have a time-dependent Hamiltonian $H$, as for example the potential may ...
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1answer
80 views

Inconsistency in the delta potential

I encountered an inconsistency in the one-dimensional delta potential. Suppose we have a one-dimensional infinitely deep square well from $-L$ to $+L$. We know the eigenstates are sine and cosine ...
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Dynamics of modifing a Hamiltonian

I am working on quantum mechanics right now, and I am wondering if there is a qualitative way to think about off diagonal term of a Hamiltonian matrix? I know that we can diagonalize a matrix, then ...
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Quantum decoherence and Schrodinger's equation

In non-relativistic quantum mechanics, the equation of evolution of the quantum state is given by Schrodinger's equation and measurement of a state of particle is itself a physical process. Thus, ...
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How can one derive Schrödinger equation?

The Schrödinger equation is the basis to understanding quantum mechanics, but how can one derive it? I asked my instructor but he told me that it came from the experience of Schrödinger and his ...
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2answers
257 views

1D Infinite Square Box Discrete Energy levels but Continous Momenta?

In the 1d particle in the box the energy of the particle should be completely determined by the momentum of the particle that you observe correct? So how can you have discrete energy levels and a ...
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Introductory Quantum, trouble with this boundary condition and potential

Working on problem 2.40 from Griffiths but can't seem to understand the first boundary condition. We are given the potential $V(x) = \left\{\begin{matrix} \infty & x < 0\\ ...
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Rewriting the Hydrogen Schrodinger Equation as a system of differential equations

I have only ever seen the Schrodinger equation for the hydrogen atom written out in a form like this: $$ -\frac{\hbar^2}{2\mu}\left[\frac{1}{r^2}\frac{\partial}{\partial r}\left(r^2\frac{\partial ...
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1answer
53 views

Scattering and bound States

So from my understanding, as long as $E>0$ you will have scattering states and these scattering states will always result in an imaginary $\psi$, but bound states can also have an imaginary ...
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The Delta-Function Potential

I'm reading through Griffiths Intro to QM 2nd Ed. and when it comes to bound/scattering states (2.5) they say: $E<0 \implies$ bound state $E>0 \implies$ scattering state Why doesn't this ...