Partial differential equation which describes the time evolution of the wavefunction of a quantum system. It is one of the first and most fundamental equations of quantum mechanics.

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Inconsistency in the delta potential

I encountered an inconsistency in the one-dimensional delta potential. Suppose we have a one-dimensional infinitely deep square well from $-L$ to $+L$. We know the eigenstates are sine and cosine ...
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24 views

Dynamics of modifing a Hamiltonian

I am working on quantum mechanics right now, and I am wondering if there is a qualitative way to think about off diagonal term of a Hamiltonian matrix? I know that we can diagonalize a matrix, then ...
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40 views

Quantum decoherence and Schrodinger's equation

In non-relativistic quantum mechanics, the equation of evolution of the quantum state is given by Schrodinger's equation and measurement of a state of particle is itself a physical process. Thus, ...
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2k views

How can one derive Schrödinger equation?

The Schrödinger equation is the basis to understanding quantum mechanics, but how can one derive it? I asked my instructor but he told me that it came from the experience of Schrödinger and his ...
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201 views

1D Infinite Square Box Discrete Energy levels but Continous Momenta?

In the 1d particle in the box the energy of the particle should be completely determined by the momentum of the particle that you observe correct? So how can you have discrete energy levels and a ...
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65 views

Chaotic behaviour re-obtained in QM

In classical mechanics, when we talk about chaotic systems (e.g. double pendulum), we always associate (or justify) them with the non-linearity(and non-integrability) of the differential equations ...
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Finding out time $t$ when a particle is more likely to be on the right half than the left half of the box [closed]

Question: A particle with mass $m$ is trapped in a box of length $L$. At $t=0$, it has wavefunction as following: $$\psi(x,t=0)=\sqrt[]{\frac2{41\pi}}(3u_1(x)+4u_2(x))$$ where $u_1(x)$ and ...
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30 views

Introductory Quantum, trouble with this boundary condition and potential

Working on problem 2.40 from Griffiths but can't seem to understand the first boundary condition. We are given the potential $V(x) = \left\{\begin{matrix} \infty & x < 0\\ ...
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67 views

Schroedinger wave equation [closed]

Has there been any work on how the Schroedinger wave equation is affected in the stretched spacetime of a strong gravitational field in General relativity?. Rather than being a 'broad' question this ...
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1answer
69 views

Rewriting the Hydrogen Schrodinger Equation as a system of differential equations

I have only ever seen the Schrodinger equation for the hydrogen atom written out in a form like this: $$ -\frac{\hbar^2}{2\mu}\left[\frac{1}{r^2}\frac{\partial}{\partial r}\left(r^2\frac{\partial ...
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39 views

Scattering and bound States

So from my understanding, as long as $E>0$ you will have scattering states and these scattering states will always result in an imaginary $\psi$, but bound states can also have an imaginary ...
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117 views

The Delta-Function Potential

I'm reading through Griffiths Intro to QM 2nd Ed. and when it comes to bound/scattering states (2.5) they say: $E<0 \implies$ bound state $E>0 \implies$ scattering state Why doesn't this ...
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106 views

Particle in a Box: Energy Less than the Potential Energy

I am reading quantum mechanics from Shankar's Principles of Quantum Mechanics. On page 157 he defines the box potential $V(x)$ as $$ V(x) = \left\{ \begin{array}{rl} 0 &\mbox{ if $|x|< L/2$} ...
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1answer
103 views

Quantum harmonic oscillator solved by analytic method using Schrödinger equation and wave function

I'm having trouble understanding the recursion formula. Using $\xi \equiv \sqrt{m\omega/\hbar}x$ and $K = 2E/\hbar\omega$, the time-independent Schrödinger equation becomes $$\frac{d^2\psi}{d\xi ^2} ...
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51 views

Find Equation of Motion given Hamiltonian

So I am given a harmonic oscillator in an electric field. At $t=0$, we are given that the oscillator is in the ground state. The Hamiltonian is: $$H=\hbar \omega[a^{\dagger}a+\frac12+\kappa ...
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82 views

Why can we leave off half of the general solution?

In these pdf notes, it says at the bottom of the first page and beginning of the second: [...] whose solution is: $$\Psi(\theta) = c_1 e^{i\omega\theta} + c_2 e^{-i\omega\theta}$$ Since we are ...
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54 views

Correct approach for calculating excited states of circular quantum dot under effective mass approximation

From Asnani, Mahajan et al, Pramana Journal Of Physics 73 #3 (2009) p574-580 "Effective mass theory of a two-dimensional quantum dot in the presence of magnetic field", which can be seen here: ...
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162 views

Particle Outside the Box

What prohibits, mathematically, that a particle cannot be found outside the box ? Here, I am referring to particle in a box problem (infinite potential on both ends & zero potential along the ...
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148 views

Is there only radial motion in the Hydrogen ground state?

The ground state of the Hydrogen atom is spherically symmetric. In other words, the wave function Psi depends only on the distance r of the electron from the nucleus. As a consequence all ...
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395 views

What is the difference between the Bohr model of the atom and Schrödinger's model?

What is the difference between the Bohr model of the atom and The solution of the Schrödinger equation for the hydrogen atom? Are there any difference between definition of the electric potential ...
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89 views

System without ground state is not real in nature?

We know that Coulomb force is real phenomena in nature and with Coulomb potential $V(x) \thicksim -\frac{1}{|x|}$ lowest energy is bounded in hydrogen atom. But it's mathematically clear that if ...
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1answer
58 views

Degeneracy in One Dimension

I'm reading this wikipedia article and I'm trying to understand the proof under "Degeneracy in One Dimension". Here's what it says: Considering a one-dimensional quantum system in a potential ...
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142 views

Infinitely many degeneracy of Landau level: Countable or Uncountable?

Description of Landau levels can be found in many standard textbooks of quantum mechanics and here. Two ubiquitous solutions apply either the symmetric gauge $\vec{A}=(-\frac{1}{2}By,\frac{1}{2}Bx,0)$ ...
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380 views

What does the Schrodinger Equation really mean?

I understand that the Schrodinger equation is actually a principle that cannot be proven. But can someone give a plausible foundation for it and give it some physical meaning/interpretation. I guess ...
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371 views

What exactly does the Hamiltonian operator tell us?

I'm confused about how energy and time are linked. On the one hand, the Hamiltonian seems to describe the time evolution of the system because in the time dependent Schrodinger equation, $$ \hat H ...
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46 views

Eigenfunctions for $1s$ hydrogen Schrodinger equation

I am a computer scientist and started my Phd in material science. The second course os my Phd is material simulation by computer. One the task is show the verification of the eigenfunction $1s$ from ...
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323 views

Am I missing a trick to solving this differential equation?

I was playing around with a 3-D potential $V$ such that $V_{(r)} = 0$ for $r<a$, and $V_{(r)} = V_0$ otherwise. By using the Schrödinger Equation, I showed that: ...
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72 views

Definite energy states for a single non-relativistic particle with a time dependent potential

Do definite energy states exist for a single particle when its potential itself changes with time? I tried solving it and the equations seem to show that they do not exist. But then i am confused as ...
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34 views

Uncertain if invoking uncertainty principle for wave function is handwaving [duplicate]

Why doesn't the electron collapse onto the proton in a hydrogen atom? One explanation seems to be given by the Heisenberg uncertainty principle, which follows from the purely physical assertion that ...
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74 views

Lack of scale in Schrödinger equation for square-inverse potential

I see that if we set our potential in schrodinger equation to be a inverse-square dependence we don't have a typical unit of length as we have for hydrogen atom. $$-{\hbar^2\over 2m}\nabla^2\psi + ...
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83 views

Energy of an Electron in a One Dimensional Periodic Potential

First, we consider the time independent Schrodinger equation of the form: $$\bigg(-\frac{\hbar^2}{2m}\frac{d^2}{dx^2}+u(x) \bigg)\phi_A(x)=E_A\phi_A(x)$$ Where $u(x)$ is a potential created by a ...
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1answer
111 views

Doubt in a certain equation of a research paper [closed]

In the given paper, I am stuck at equation (7). The equation that I am trying to solve for particle outside the well is : (1/g)*(g'') + (1/(r*g))*g' - (k_o)^2 = 0 where g = Radial wave function. r = ...
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41 views

Expected value $<\hat{x}>$ of: $\Phi(x,t)=Ne^{-a[(Mx^2/\hbar)+it]}$ is infinite, why?

The problem says: A particle of mass $M$ is described by the wave function: $$\Phi(x,t)=Ne^{-a[(Mx^2/\hbar)+it]}$$ where a is a positive constant. Asked to determine such things as the ...
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98 views

Complex Conjugate of Wave Function's Derivative

I am reading Griffiths QM textbook and I got confused by the following identity: How to prove from $$\frac{\partial \Psi}{\partial t} = \frac{i\hbar}{2m} \frac{\partial^2 \Psi}{\partial x^2} - ...
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140 views

Determining the Wave Function From Initial Conditions

This is Problem 2.6 (b) in Griffiths, Intro to QM: A particle in an infinite square well has its initial wave function an even mixture of the first two stationary states: $\Psi(x,0) = ...
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The Dirac-Delta function as an initial state for the quantum free particle

I want to ask if it is reasonable that I use the Dirac-Delta function as an intial state ($\Psi (x,0) $) for the free particle wavefunction and interpret it such that I say that the particle is ...
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269 views

Can a relativistic quantum particle be completely confined into a finite hole?

If we write the Klein-Gordon equation in this form \begin{equation*} c^2 \hbar^2 \nabla^2 \Psi = \hbar^2 \ddot{\Psi} + 2i\hbar (U - mc^2) \dot{\Psi} + U (2mc^2 - U) \Psi \end{equation*} we have a ...
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Is it true that the Schrödinger equation only applies to spin-1/2 particles?

I recently came across a claim that the Schrödinger equation only describes spin-1/2 particles. Is this true? I realize that the question may be ill-posed as some would consider the general ...
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1answer
312 views

Relationship between Schrodinger equation and string/membrane

In Sakurai's Modern Quantum Mechanics (2nd ed) p.99, he says We know from the theory of partial differential equations that (time-independent Schrodinger equation) subject to boundary ...
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507 views

Electron shells in atoms: What causes them to exist as they do?

I have seen similar posts, but I haven't seen what seems to be a clear and direct answer. Why do only a certain number of electrons occupy each shell? Why are the shells arranged in certain distances ...
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51 views

(Level: Undergrad) Continuity Conditions on the Wavefunction and Initial Values

I know that a physically meaningful $\Psi$ needs to be continuous. However, recently I came across a problem in which they were considering a wavefunction for the infinite square well potential and ...
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85 views

First-order and second-order wave equations, versus the uncertainty principle

In classical physics, we have second-order equations like Newton's laws, so we need to specify both position (zeroth order) and velocity (first order) of a particle as initial conditions, in order to ...
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45 views

Writing Schrodinger equation with central potential in Atomic unit

I'm struggling to write Schrodinger equation with a central potential in Atomic unit. $$ ...
3
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1answer
72 views

Justification of discrete spectrum for V(x) unbounded at $\pm \infty$ in Pauling and Wilson

In Pauling and Wilson, Introduction to Quantum Mechanics, they offer the following intuitive reason for the discrete spectrum of a potential which is unbounded at $\pm \infty$: This is ...
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1answer
79 views

Proving that the electronic Schrödinger equation has no closed analytic solutions for >1 electron

It is stated in many books that analytic closed solutions to the time-independent electronic Schrödinger equation, $$\hat{H}\Psi = E\Psi, $$ exist for the one-electron problem (e.g. hydrogen atom, ...
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Is there some quantum potential producing exponential eigenvalues?

Usual central potentials produce quantum spectra with energy levels going as $n$, $n^2$, $n^3$ and so on, being $n$ the quantum number of the orbit. In the other extreme we have "dirac-delta" ...
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Does Heisenberg equation of motion imply the Schrodinger equation for evolution operator?

Let us choose to postulate (e.g. considering the analogy of the Hamiltonian being a generator of time evolution in classical mechanics) $$ i\hbar \frac{d\hat{U}}{dt}=\hat{H}\hat{U}\tag{1} $$ where ...
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Computational package to find the ground state of a particle in 3D domain

I am developing a numerical algorithm to find the ground state of a Hermitian matrix. Obvious applications are quantum many-body systems and particles in various potentials. I am a little stuck with ...
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134 views

Solving the Schrödinger equation where the initial wave function is an energy eigenfunction

I was watching Allan Adams' lecture on energy eigenfunctions, and there's one part (around 43 minutes into the lecture) that confuses me. Suppose we have the initial wave function $\Psi (x,0)$ such ...
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What is the energy operator and from where do we get it?

I am trying to learn Quantum mechanics from MIT OCW Videos about quantum mechanics. I have reached the 5th lecture. Please help me in understanding this: In the middle (At 32:08), the professor wrote ...