Partial differential equation which describes the time evolution of the wavefunction of a quantum system. It is one of the first and most fundamental equations of quantum mechanics.

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Correct approach for calculating excited states of circular quantum dot under effective mass approximation

From Asnani, Mahajan et al, Pramana Journal Of Physics 73 #3 (2009) p574-580 "Effective mass theory of a two-dimensional quantum dot in the presence of magnetic field", which can be seen here: ...
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136 views

Particle Outside the Box

What prohibits, mathematically, that a particle cannot be found outside the box ? Here, I am referring to particle in a box problem (infinite potential on both ends & zero potential along the ...
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1answer
120 views

Is there only radial motion in the Hydrogen ground state?

The ground state of the Hydrogen atom is spherically symmetric. In other words, the wave function Psi depends only on the distance r of the electron from the nucleus. As a consequence all ...
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102 views

What is the difference between the Bohr model of the atom and Schrödinger's model?

What is the difference between the Bohr model of the atom and The solution of the Schrödinger equation for the hydrogen atom? Are there any difference between definition of the electric potential ...
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2answers
85 views

System without ground state is not real in nature?

We know that Coulomb force is real phenomena in nature and with Coulomb potential $V(x) \thicksim -\frac{1}{|x|}$ lowest energy is bounded in hydrogen atom. But it's mathematically clear that if ...
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1answer
50 views

Degeneracy in One Dimension

I'm reading this wikipedia article and I'm trying to understand the proof under "Degeneracy in One Dimension". Here's what it says: Considering a one-dimensional quantum system in a potential ...
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130 views

Infinitely many degeneracy of Landau level: Countable or Uncountable?

Description of Landau levels can be found in many standard textbooks of quantum mechanics and here. Two ubiquitous solutions apply either the symmetric gauge $\vec{A}=(-\frac{1}{2}By,\frac{1}{2}Bx,0)$ ...
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3answers
269 views

What does the Schrodinger Equation really mean?

I understand that the Schrodinger equation is actually a principle that cannot be proven. But can someone give a plausible foundation for it and give it some physical meaning/interpretation. I guess ...
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350 views

What exactly does the Hamiltonian operator tell us?

I'm confused about how energy and time are linked. On the one hand, the Hamiltonian seems to describe the time evolution of the system because in the time dependent Schrodinger equation, $$ \hat H ...
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42 views

Eigenfunctions for $1s$ hydrogen Schrodinger equation

I am a computer scientist and started my Phd in material science. The second course os my Phd is material simulation by computer. One the task is show the verification of the eigenfunction $1s$ from ...
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57 views

Dependence of sign on operators in wave equation?

In the time-dependent Schrödinger equation, our teacher told us about energy and momentum operators. He just defined them, the equation was of the form $A\exp(i(kx-\omega t))$, if we take the ...
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315 views

Am I missing a trick to solving this differential equation?

I was playing around with a 3-D potential $V$ such that $V_{(r)} = 0$ for $r<a$, and $V_{(r)} = V_0$ otherwise. By using the Schrödinger Equation, I showed that: ...
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66 views

Definite energy states for a single non-relativistic particle with a time dependent potential

Do definite energy states exist for a single particle when its potential itself changes with time? I tried solving it and the equations seem to show that they do not exist. But then i am confused as ...
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34 views

Uncertain if invoking uncertainty principle for wave function is handwaving [duplicate]

Why doesn't the electron collapse onto the proton in a hydrogen atom? One explanation seems to be given by the Heisenberg uncertainty principle, which follows from the purely physical assertion that ...
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70 views

Lack of scale in Schrödinger equation for square-inverse potential

I see that if we set our potential in schrodinger equation to be a inverse-square dependence we don't have a typical unit of length as we have for hydrogen atom. $$-{\hbar^2\over 2m}\nabla^2\psi + ...
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79 views

Energy of an Electron in a One Dimensional Periodic Potential

First, we consider the time independent Schrodinger equation of the form: $$\bigg(-\frac{\hbar^2}{2m}\frac{d^2}{dx^2}+u(x) \bigg)\phi_A(x)=E_A\phi_A(x)$$ Where $u(x)$ is a potential created by a ...
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107 views

Doubt in a certain equation of a research paper [closed]

In the given paper, I am stuck at equation (7). The equation that I am trying to solve for particle outside the well is : (1/g)*(g'') + (1/(r*g))*g' - (k_o)^2 = 0 where g = Radial wave function. r = ...
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36 views

Expected value $<\hat{x}>$ of: $\Phi(x,t)=Ne^{-a[(Mx^2/\hbar)+it]}$ is infinite, why?

The problem says: A particle of mass $M$ is described by the wave function: $$\Phi(x,t)=Ne^{-a[(Mx^2/\hbar)+it]}$$ where a is a positive constant. Asked to determine such things as the ...
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64 views

Complex Conjugate of Wave Function's Derivative

I am reading Griffiths QM textbook and I got confused by the following identity: How to prove from $$\frac{\partial \Psi}{\partial t} = \frac{i\hbar}{2m} \frac{\partial^2 \Psi}{\partial x^2} - ...
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105 views

Determining the Wave Function From Initial Conditions

This is Problem 2.6 (b) in Griffiths, Intro to QM: A particle in an infinite square well has its initial wave function an even mixture of the first two stationary states: $\Psi(x,0) = ...
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187 views

The Dirac-Delta function as an initial state for the quantum free particle

I want to ask if it is reasonable that I use the Dirac-Delta function as an intial state ($\Psi (x,0) $) for the free particle wavefunction and interpret it such that I say that the particle is ...
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257 views

Can a relativistic quantum particle be completely confined into a finite hole?

If we write the Klein-Gordon equation in this form \begin{equation*} c^2 \hbar^2 \nabla^2 \Psi = \hbar^2 \ddot{\Psi} + 2i\hbar (U - mc^2) \dot{\Psi} + U (2mc^2 - U) \Psi \end{equation*} we have a ...
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129 views

Is it true that the Schrödinger equation only applies to spin-1/2 particles?

I recently came across a claim that the Schrödinger equation only describes spin-1/2 particles. Is this true? I realize that the question may be ill-posed as some would consider the general ...
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300 views

Relationship between Schrodinger equation and string/membrane

In Sakurai's Modern Quantum Mechanics (2nd ed) p.99, he says We know from the theory of partial differential equations that (time-independent Schrodinger equation) subject to boundary ...
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466 views

Electron shells in atoms: What causes them to exist as they do?

I have seen similar posts, but I haven't seen what seems to be a clear and direct answer. Why do only a certain number of electrons occupy each shell? Why are the shells arranged in certain distances ...
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44 views

(Level: Undergrad) Continuity Conditions on the Wavefunction and Initial Values

I know that a physically meaningful $\Psi$ needs to be continuous. However, recently I came across a problem in which they were considering a wavefunction for the infinite square well potential and ...
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74 views

First-order and second-order wave equations, versus the uncertainty principle

In classical physics, we have second-order equations like Newton's laws, so we need to specify both position (zeroth order) and velocity (first order) of a particle as initial conditions, in order to ...
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40 views

Writing Schrodinger equation with central potential in Atomic unit

I'm struggling to write Schrodinger equation with a central potential in Atomic unit. $$ ...
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69 views

Justification of discrete spectrum for V(x) unbounded at $\pm \infty$ in Pauling and Wilson

In Pauling and Wilson, Introduction to Quantum Mechanics, they offer the following intuitive reason for the discrete spectrum of a potential which is unbounded at $\pm \infty$: This is ...
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69 views

Proving that the electronic Schrödinger equation has no closed analytic solutions for >1 electron

It is stated in many books that analytic closed solutions to the time-independent electronic Schrödinger equation, $$\hat{H}\Psi = E\Psi, $$ exist for the one-electron problem (e.g. hydrogen atom, ...
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86 views

Is there some quantum potential producing exponential eigenvalues?

Usual central potentials produce quantum spectra with energy levels going as $n$, $n^2$, $n^3$ and so on, being $n$ the quantum number of the orbit. In the other extreme we have "dirac-delta" ...
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257 views

Does Heisenberg equation of motion imply the Schrodinger equation for evolution operator?

Let us choose to postulate (e.g. considering the analogy of the Hamiltonian being a generator of time evolution in classical mechanics) $$ i\hbar \frac{d\hat{U}}{dt}=\hat{H}\hat{U}\tag{1} $$ where ...
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Computational package to find the ground state of a particle in 3D domain

I am developing a numerical algorithm to find the ground state of a Hermitian matrix. Obvious applications are quantum many-body systems and particles in various potentials. I am a little stuck with ...
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113 views

Solving the Schrödinger equation where the initial wave function is an energy eigenfunction

I was watching Allan Adams' lecture on energy eigenfunctions, and there's one part (around 43 minutes into the lecture) that confuses me. Suppose we have the initial wave function $\Psi (x,0)$ such ...
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55 views

What is the energy operator and from where do we get it?

I am trying to learn Quantum mechanics from MIT OCW Videos about quantum mechanics. I have reached the 5th lecture. Please help me in understanding this: In the middle (At 32:08), the professor wrote ...
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91 views

Poles for a particle scattered in a delta potential

I am working on problem a professor gave me to get an idea for the research he does, and have hit a point where I'm having a difficult time seeing where I need to go from where I'm at. I would also ...
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99 views

Divergent solution in time-dependent Schrödinger equation

if I transform the time-dependent Schrödinger equation without a potential I get: $$ - \hbar \omega \psi(\omega,x) = \frac{- \hbar^2}{2m} \frac{\partial^2 \psi(\omega,x)}{\partial x^2}$$ The ...
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174 views

Initial condition for Fourier transformed Schrödinger equation

I asked in this thread Time-dependet Schrödinger equation how to solve the Time-dependent Schrödinger equation. One of JamalS' recommendations was the Fourier transform, which is why I want to quote ...
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273 views

Time-dependent Schrödinger equation with $V=V(x,t)$

I was wondering about the following: If you have the time-dependent Schrödinger equation such that $$i \hbar \frac{\partial\psi(x,t)}{\partial t} = - \frac{\hbar^2}{2m} ...
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89 views

How is the time independent potential term a solution of Schrodinger equation

Consider a time-independent potential: $V(x)$. Then, it is usually stated that $$ \Psi(x,t)=\rho(x)\exp{\left(-\frac{i}{\hbar}Et\right)} $$ is the general form of a solution of the Schrodinger ...
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69 views

Calculating Quantum number from initial conditions

I have solved the particle in a box problem to get energy eigenstates and wave vectors: $$E_{n}=\frac{\hbar^{2} k^2}{2m} ,\hspace{1cm} k_{n}=\frac{\pi n}{L}$$ And now I am trying to figure out how ...
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25 views

Particle in a box under harmonic driving

Is the particle in a box under harmonic driving electric field solvable analytically? Here is the Schrodinger equation: $$ i\frac{\partial \psi(x,t)}{\partial t}=\left[-\frac{1}{2} ...
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121 views

Quick question on perturbation theory

Suppose we have a particle in an infinite potential well, with $V(x) = 0,\space 0< x < a $ and infinity everywhere else. Now suppose we have a perturbation on the LHS of the well: $V_1(x) = v, ...
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1answer
73 views

Stabilization of von Neumann equation

Given the solution of the Von Neumann equation $\rho(t) = e^{-i H t/\hbar} \rho(0) e^{i H t/\hbar}$ How can we justify if it will be stabilized as $t\rightarrow\infty$ in general? For example, ...
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1answer
45 views

Time evolution of states - Is total energy constant or not?

Suppose the state of the particle is given as follows: $$ |\psi_{(t)}\rangle = \frac{1}{\sqrt2} \left( e^{-\frac{i\omega t}{2}} |0\rangle + e^{-\frac{3i\omega t}{2}} |1\rangle \right) $$ Where the ...
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Quick question on sketching wavefunction in well

Usually for an infinite well, the sketch for n=3 level is this: Now I think if one side of the potential barrier is higher, the particle will be more likely to spend time on the left side than ...
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154 views

Why are hydrogen energy levels degenerate in $\ell$ and $m$?

Is there a good physical picture of why the energy levels in a hydrogen atom are independent of the angular momentum quantum number $\ell$ and $m$?
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1answer
57 views

Nuclear shell model - finite square well

I am trying to make a simplified approximation and solve Schrodinger equation in the finite square well to model the nucleus of Ca (shell nuclear model). The potential is $ V(r) = -V_0$ for ...
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2answers
68 views

Stationary state of time-independent Schroedinger equation is always real valued function?

I am reflecting on the solution of the time-independent Schroedinger equation. My reasoning is that the stationary state of the time-independent Schroedinger equation must be a real valued function ...
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68 views

Time-dependent perturbation - details in derivation

I get confused about two things when deriving the time-dependent perturbative approach. We have the Hamiltonian $$H = H_0 + \lambda H^{(1)}$$ and we have solved (from Schroedinger) $$\dot{C_f(t)} ...