Partial differential equation which describes the time evolution of the wavefunction of a quantum system. It is one of the first and most fundamental equations of quantum mechanics.

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Do I need to consider the spin of electrons when they are in infinite potential well

This is the problem I have And this is one of my books tell me what should I do And my question is: Do I need to consider spin in this case?(that is, I don't think the book is right...) I found ...
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23 views

Deriving Wave Function for Scattering States with Delta-Function Potential

I am following the Griffiths Book on Quantum Mechanics, and am following the derivation for the wave function for Delta-Function Potentials. $$V(x) = -\alpha \delta(x)$$ In the scattering states, ...
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47 views

Is the potential energy term of the Schrodinger equation correct?

The nonhomogeneous heat equation is of the form: $$\frac{\partial }{\partial t} u(x,t) = \alpha^2 \frac{\partial^2}{\partial x^2} u(x,t) + f(x,t)$$ it appears as though we can always find some ...
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33 views

Is the conservation of probability in the Schroedinger's equation unique?

The Schroedinger's equation can be viewed as a diffusion equation with imaginary constants $a$ and $b$ satisfying, $$(1) \quad \Psi_t=a \cdot \Delta \Psi-b \cdot V(x,t) \cdot \Psi$$ However if $a$ ...
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65 views

Conservation of momentum in infinite square well

This is inspired by Griffiths QM section 2.2, on the infinite square well, which is about how far I've gotten (so, sorry if this is addressed later in the book). For any given starting wavefunction, ...
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51 views

Energy of hydrogen atom - Schrodinger equation [closed]

The wavefunction of the electron in the hydrogen atom is $ k* exp(-r/a)$ (k is the normalization constant), but it does not take n into account, whereas the solution of Schrödinger's equation ...
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78 views

Schroedinger Picture more general than Heisenberg Picture?

When thinking about the two pictures, what I found to be strange was: I can write the postulate of time-evolution in the Schroedinger picture by: \begin{align} i \hbar \frac{d}{dt} \lvert \Psi(t) ...
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87 views

Energy equation in Quantum Mechanics

We know that total energy of the system is classically continuous, but in quantum mecanics (QM) it is quantised. My question is: How can we use the conservation of energy equation to derive ...
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76 views

Numerically solving a simple Schrodinger equation with fast Fourier transforms

While trying to solve a stochastic Gross-Piaevskii equation I have found a problem that can be tracked down to something buggy occurring in the simplest Schrodinger equation possible: $$\partial_t ...
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59 views

Why are the allowed energies a continuum in the region $V_{\_} < E < V_{+}$?

I'm studying quantum mechanics and I don't quite understand why there's an energy continuum in the region $V_{\_} < E < V_{+}$ in the following example: It was explained that because of the ...
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93 views

Radial quantum number for infinite circular well

For completeness, I will sketch the solution of a particle in an infinite circular well first and then get to my question. I apologize in advance since the introduction is standard undergraduate ...
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55 views

Deriving the Bohr radius of a hydrogen atom using Schrödinger's equation

I'm trying to follow the book for the introduction to quantum mechanics by Griffiths. I'm following the part where he is solving Schrödinger's equation for the hydrogen atom. There, he found the Bohr ...
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53 views

Tricky particle in an infinite potential well question

For a particle in an infinite square-well potential in an energy eigenstate, the probability distribution relating to outcomes of position measurements vanishes outside the square well and takes a ...
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39 views

Rewrite schroedinger's equation in gravitational field? [closed]

I'd like to consider the $H=mgx+\frac{p^2}{2m}$, and by the Schroedinger's equation:$H\psi=i\hbar \frac{d\psi}{dt}$. By making the transformation $$\psi(t) = e^{-\frac{imgx}{\hbar}t}\phi(t)$$ so that ...
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57 views

Superpotential for Gaussian potential well? [closed]

so I am looking for the super potential of a Gaussian well, namely $V= -e^{-x^2/2}$, and the super potential has to satisfy the Riccati equation,$ − W′ ( x ) + W ( x ) = V ( x ) − a$. Somehow I ...
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99 views

Shifting momentum by a constant in the Schrodinger Equation

My book states that if we perturb a given Hamiltonian for the Schrödinger Equation $$ H = \frac{p^2}{2m} +V(x) $$ to $$ H' = \frac{p^2}{2m} + V(x) + \frac{\lambda p}{m} $$ then we can rewrite ...
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87 views

Prove time-dependent hamiltonian is hermitian from unitarity of time-evolution operator

When we solve the Schrodinger equation for the time-evolution operator: \begin{equation} i\hbar\frac{\partial}{\partial t}U(t,t_{0})=HU(t,t_{0}), \end{equation} We have three cases to be treated ...
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36 views

Experimental Bases for Schrodinger Equation and Matrix Mechanics

I am curious about the motivation for developing the Schrodinger equation (SE), and its subsequent acceptance. Are the primary experimental findings that led to the development of the SE: 1) the ...
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41 views

Propagation of momentum space wave function in linear potential [closed]

Under linear potential which denoted as $$V(x)=-Fx$$ Momentum space eigenket at time $t=0$ and some time $t$ has a relationship of $$\phi(p,t) = \mathrm{exp}\left[\frac{(p-Ft)^3-p^3}{6m\hbar ...
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42 views

Infinite square well physical interpretation

In quantum mechanics, the description of the infinite square well is given with the potential energy defined as $$V(x) = \begin{cases} 0 & \text{if } 0 \leq x \leq a,\\ \infty & ...
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1answer
81 views

Finite two-dimensional potential square well [closed]

I'm trying to solve the Schrodinger equation $$ -\frac{\hbar^2}{2m}\nabla^2 \psi+V(x,y)\psi(x,y)=E\psi(x,y) \tag{1}$$ for the finite two dimensional potential square well, that is, where ...
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50 views

Transmission and reflection amplitudes for delta potential Schrodinger equation

I hope this question is not too straightforward for this Q&A site. I have been reading a set of notes in which the transmission and reflection amplitudes for the delta potential Schrodinger ...
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3answers
87 views

What is the purpose of taking coefficients as 1 in numerical solutions?

How can we recover the real solution after getting a solution by solving with parameters set to 1? For example, on my case to solve the Shrödinger equation via finite difference method, the author ...
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61 views

What is the time imaginary method? [closed]

I have to submit homework about the scheme which solves the time-independent Schrödinger equation and finds the ground state by the imaginary time method. I know the substitution ...
2
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1answer
328 views

How is it possible to pull out derivatives of a wavefunction?

In an early derivation, the following equation was stated: $$\frac\partial{\partial t}\lvert\psi\rvert^2 = \frac{i\hbar}{2m}\biggl(\psi^*\frac{\partial^2\psi}{\partial x^2} - ...
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81 views

How do we find the number of bounded states in this potential?

for the potential $$V(x)=-\frac{1}{1+\frac{x^2}{m^2}}$$ we can approximate the wave function and bounded state accurately for $x << m$ as simple harmonic oscillator, so what are we gonna do if ...
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68 views

Guess the wave function in a given potential

Are there any techniques in guessing the ground state wave function in any given potential? For example, for a given potential like $$ \frac{1}{1-x^2}$$ or $$ \frac{1}{1-x^3}~?$$ I know wave ...
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73 views

Measurement of energy apparently violating the position-momentum Uncertainty Principle in a potential that does not depend on distance?

I am taking a beginning course in QM and I have learnt that the measurement of energy collapses the wavefunction of a particle to one of its energy eigenstates. But some misconceptions regarding this ...
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26 views

Non normalisability implies uncertainty principle? [duplicate]

The wave function $\psi(x,t)$ for a free particle assuming that the position and momentum is well defined, can be solved from the schroedinger equation, ...
3
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2answers
151 views

General Solution to Linear Schrodinger equation

I am trying to find a solution to $$\displaystyle \left[-\frac{1}{2}\nabla^2 - \frac{2}{r} + C(r)\right]\phi(r) = E\phi(r)$$ where $C(r)$ is a known function of r. I am just looking for some help on ...
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79 views

Normalisation of free particle wavefunction

The wavefunction $\Psi(x,t)$ for a free particle is given by $$\Psi(x,t) = A e^{i(kx-\frac{\hbar k}{2m}t)}$$ This wavefunction is non-normalisable. Does this mean that free particles do not exist in ...
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Solution of Schrodinger equation for scattering

The following extract is taken from Appendix A of the following paper: http://arxiv.org/abs/0810.0713. Any solution of the Schrodinger equation with rotational invariance around the $z$ axis can ...
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108 views

Quantum Mechanics in your face

In this lecture Quantum Mechanics in your face by Sidney Coleman http://www.youtube.com/watch?v=EtyNMlXN-sw Does he state that there's only evolution according to Schrodinger's equation in QM and it ...
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75 views

Difference for boundary condition, particle in a box

When solving the simple problem of a free particle in a box of volume $V = L^3$, we can impose either periodic boundary conditions $\psi(0) = \psi(L)$ and $\psi '(0)= \psi'(L)$ either strict boundary ...
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86 views

Bound states of Dirac Delta function in infinite well

If there is a potential of $-\alpha\delta(x)$ for $-a<x<a$ and $\infty$ elsewhere, and the energy of the system is less than 0, then I'm trying to find the wave function. From the Schrodinger ...
2
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150 views

Wave function collapse and Schrodinger's equation without measurement

Will wave function collapse without measurement? Since all matters are described by wave functions, then in principle, I should be able to describe wave function collapse by Schrodinger's equation. ...
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70 views

Is the collapsed wavefunction a solution of Time-dependent Schrodinger equation?

For measurement of any observable associated with the particle, should the wavefunction after collapse be a solution of the time-dependent Schrodinger equation? A general solution of the time ...
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81 views

Similarity between Schrodinger and Euler-Bernoulli equations - any possible physical meaning?

I noticed a long time ago the similarity between Schrodinger equation and Euler-Bernoulli beam equation. Namely, Euler-Bernoulli equation is equivalent to the system of Schrodinger equation for a free ...
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95 views

Schrodinger equation violates mathematics?

By the Hamiltonian formalism of quantum mechanics, given a quantum system in a state $\Psi$ in a Hilbert space $\mathcal H$, the state will instantaneously evolve in time according to ...
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161 views

Why does the wavefunction have to be continuous in the presence of a Dirac delta potential?

Considering the time-independent Schrödinger equation, I can see for a finite potential, why the wavefunction has to be continuous, I can also see why the first derivative of the wavefunction is ...
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114 views

Why is $n=0$ allowed for a particle on a ring?

Is there a simple intuitive explanation for why a particle on a ring has no zero point energy? That is, if we write the energy as: $$ E_n = \frac{n^2\hbar^2}{2mr^2} $$ then the integer $n$ is ...
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97 views

Time dependent and time independent Schrödinger equations

I'm trying to understand the relation between the time dependent and time dependent Schrödinger equations. In particular, we know that the TDSE is $$H\Psi=i\hbar \frac{\partial \Psi}{\partial t}$$ ...
2
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1answer
122 views

Minimum uncertainity

I'm confused in finding the condition for minimum uncertainty, The author in the book I refer goes on saying that $|g\rangle=c|f\rangle$ is the condition for minimum uncertainity for some constant ...
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35 views

Is the there a unique correspondence between the potential and bound state wave functions? [duplicate]

I'm asking specifically for the schrodinger equation. Is there a unique correspondence between the energy eigenfunctions $\phi_i(x)$ and the potential term $U(x) = V(x)\phi(x)$? Furthermore, is this ...
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Transforming the Schrodinger equation from momentum-space to position-space [closed]

I am working on a problem right now that states the following: A particle of mass $m$ is subjected to a force $\mathbf{F}(\mathbf{r}) = - \nabla V(\mathbf{r})$ such that the wave function ...
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169 views

How can quantum wavefunctions be smooth/continuous when particles are created/destroyed/changed?

My (admittedly limited) understanding of the Schrodinger equation tells me that the vector differential operators are only meaningful over a differentiable phase space. For example, if the dimensions ...
2
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1answer
100 views

Is a non-degenerate wavefunction real or complex?

In this video it is stated that: It can easily be verified that the wavefunction of a non-degenerate quantum mechanical system will be real. However the presenter does not explain why this ...
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97 views

Question on momentum space Schrodinger equation

In the lecture, my professor wrote: With potential $V(x)=-Fx$, where $F$ is a constant, in momentum space the Schrodinger equation takes the form $$ \left[\frac{p^2}{2m}-i\hbar ...
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Measure-theoretic maths behind Born's probabilistic interpretation of Schrodinger's equation

I was reading a bit about Quantum Mechanics, Schrodinger's equation and its probabilistic interpretation (found this very insightful intro here https://plus.maths.org/content/schrodinger-1), my ...
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1answer
68 views

Demonstration that the $\langle f(x)\rangle$ of an odd function $f(x)=-f(-x)$ of position $x$ in a symmetric potential well $V(x)=V(-x)$ is null

Consider a potential infinite well, which borders are $x=-a$ and $x=a$. I pretend to demonstrate that the expected value of a odd function $f(x)$, i.e., $\langle f(x)\rangle$, is null. We have the ...