Partial differential equation which describes the time evolution of the wavefunction of a quantum system. It is one of the first and most fundamental equations of quantum mechanics.

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Estimate of the second shallowest bound state?

Suppose we have a 1D potential $V(x)$ of finite range, i.e., $$ V(x) ~=~0 $$ for $|x| > b $. The potential might support several bound states. The shallowest one can be infinitesimally small. ...
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182 views

How to know if a wave function is physically acceptable solution of a Schrödinger equation?

How does one decide whether a wave function is a physically acceptable solution of the Schrödinger equation? For example: $\tan x$ , $\sin x$, $1/x$, and so on.
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1answer
114 views

1D Finite potential well: solutions with $\sinh$ and $\cosh$?

So I am studying the (one dimensional) quantum mechanical finite potential well defined by: $$ V(x) = \cases{0, &|x|>a\cr -V_0, &|x|<a} $$ where $V_0>0$ is a real number. I know ...
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2answers
61 views

Collapse of the wave function and Heisenberg uncertainty

I have been studying quantum mechanics for a few weeks, in particular wave mechanics, as created by Schrodinger, and his equation. As a high school student, I haven't found an answer to this question ...
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1answer
111 views

Deriving a Useful Solution of the Schrödinger Equation [on hold]

How does one derive the fact that $$\psi(t,x) = (\tfrac{2 \pi \hbar t}{m})^{-d/2}\int_{\mathbb{R}^d} e^{im\tfrac{(x-y)^2}{2\hbar t}}\psi_0(y)dy$$ is a solution of the time-dependent Schrödinger ...
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237 views

Why discrepancies in the Schrödinger equation? [duplicate]

Why is there seemingly two definitions of the Schrödinger equation? \begin{equation} i\hbar\frac{\partial}{\partial t}\Psi=\hat H\Psi. \end{equation} And \begin{equation} i\hbar ...
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1answer
49 views

Quasiclassical QM for central fields

Let's have quasiclassical QM for central field $V(r)$. The Schroedinger equation for radial part of wavefunction $R_{nl}$ after substitution $u_{nl} = rR_{nl}$ takes the form $$ u_{nl}{''} + ...
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78 views

What is the most agreed upon quantum mechanical equation of motion?

On multiple Wikipedia articles, it mentions several quantum mechanical equations of motion, namely those by Schrödinger and Heisenberg. Which one is the most accurate and agreed upon quantum ...
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104 views

A misunderstanding regarding infinite square well

Here is a picture of the energy states of infinite potential well. We can see That the first level have a half wavelength which fittes with a full wave of the second level. $$\frac{ \lambda _{1} ...
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2answers
103 views

Ground state of Spherical symmetric potential always have $\ell=0$?

I was given a problem where I have a spherically symmetric potential (the exact form is not relevant to this question, I think - but anyway is it 0 for $r\in[a,b]$ and $\infty$ everywhere else) and I ...
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35 views

Derivation of Schrodingers equation [duplicate]

I need some help as i don't have any textbook available at the moment and only tech I have got is a old cell phone so could anyone show me the derivation of the Schrodingers equation?
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2answers
55 views

Semiclassical quantization of bouncing ball

Consider an elastically bouncing ball of mass $m$ and energy $E$. This has a triangular potential $$ V(x)~=~\left\{\begin{array}{ll} mgx & \text{if } x>0, \\ \infty & \text{if } x<0, ...
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25 views

Quantization in a 2D quasicrystal?

let be the Schroedinger equation with a potential in a quascristal $$ -( \partial _{x}^{2}+ \partial _{y}^{2}) \Psi (x,y)+ V(x,y)=E_{n} \Psi (x,y) $$ if we were in a crystal we could impose the ...
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38 views

On the Equivalence of Schrodinger and Heisenberg Descriptions of Quantum Mechanics and Observability

I'm not a physicist, but rather a control (feedback) systems engineer eager to understand more than just a cursory explanation of quantum mechanics. The StackExchange has been an excellent forum for ...
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1answer
56 views

What really generates time evolution?

A fundamental principle of quantum mechanics, as far as I can tell, states that the Hamiltonian generates time evolution. A common result about generators are the following: let $\mathrm T$ be the ...
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253 views

Do the probability density and the probability current density have a unit

I could not find what is the probability density and the probability current density of one-dimensional Schrödinger equation units?
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1answer
47 views

Choice of the z-axis in the Schrödinger equation for the hydrogen atom

I am reading about the solution of the Schrödinger equation for the hydrogen atom and have a question about the choice of the z-axis. Most websites say that the z-axis is arbitrarily chosen. If so, ...
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3answers
110 views

Schrödinger equation derivation and Diffusion equation

I am aware of the debate on whether Schrödinger equation was derived or motivated. However, I have not seen this one that I describe below. Wonder if it could be relevant. If not historically but for ...
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1answer
64 views

Bosonic Schrödinger field [closed]

When second quantizating the Schrödinger field $$\psi(r,t) = \sum_i \phi_i(r)b_i(t),\quad\mbox{and}\quad \psi^{\dagger}(r,t) = \sum_i \phi_{i}(r)^* b_i^{\dagger}(t),$$ we have the commutation ...
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256 views

Why the statement “there exist at least one bound state for negative potential” doesn't hold for 3D case?

Previously I thought this is a universal theorem, for one can prove it in the one dimensional case using variational principal. However, today I'm doing a homework considering a potential like ...
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1answer
269 views

WKB approximation for multiple turning points

I'm working on a numerical program which approximates the eigenvalues of a Schrödinger equation by making use of the WKB approximation formulas. For example, if the Schrödinger equation is $$ y''(x) = ...
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1answer
105 views

Quantum Mechanics in Electric Field

I am working on a problem which looks like this. Consider a charged particle with charge $q$ trapped in a box of length $L$ with finite constant potential $ V_0 $ on both ends. A constant (static) ...
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71 views

Quantum mechanics: Finite square well problem

What will happen if the potential is less than 0, for instance $V(x)=-10eV$. Is this means there will be no bound states? Since solution to the time independent Schrodinger equation (those discrete ...
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1answer
75 views

Interaction pictures of Quantum Mechanics

I want to understand the Schrödinger, Heisenberg and interaction picture and have a few questions about them: So in general you have a time-dependent Hamiltonian $H$, as for example the potential may ...
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1answer
78 views

Inconsistency in the delta potential

I encountered an inconsistency in the one-dimensional delta potential. Suppose we have a one-dimensional infinitely deep square well from $-L$ to $+L$. We know the eigenstates are sine and cosine ...
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25 views

Dynamics of modifing a Hamiltonian

I am working on quantum mechanics right now, and I am wondering if there is a qualitative way to think about off diagonal term of a Hamiltonian matrix? I know that we can diagonalize a matrix, then ...
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Quantum decoherence and Schrodinger's equation

In non-relativistic quantum mechanics, the equation of evolution of the quantum state is given by Schrodinger's equation and measurement of a state of particle is itself a physical process. Thus, ...
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How can one derive Schrödinger equation?

The Schrödinger equation is the basis to understanding quantum mechanics, but how can one derive it? I asked my instructor but he told me that it came from the experience of Schrödinger and his ...
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2answers
246 views

1D Infinite Square Box Discrete Energy levels but Continous Momenta?

In the 1d particle in the box the energy of the particle should be completely determined by the momentum of the particle that you observe correct? So how can you have discrete energy levels and a ...
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1answer
37 views

Introductory Quantum, trouble with this boundary condition and potential

Working on problem 2.40 from Griffiths but can't seem to understand the first boundary condition. We are given the potential $V(x) = \left\{\begin{matrix} \infty & x < 0\\ ...
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1answer
80 views

Rewriting the Hydrogen Schrodinger Equation as a system of differential equations

I have only ever seen the Schrodinger equation for the hydrogen atom written out in a form like this: $$ -\frac{\hbar^2}{2\mu}\left[\frac{1}{r^2}\frac{\partial}{\partial r}\left(r^2\frac{\partial ...
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1answer
50 views

Scattering and bound States

So from my understanding, as long as $E>0$ you will have scattering states and these scattering states will always result in an imaginary $\psi$, but bound states can also have an imaginary ...
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The Delta-Function Potential

I'm reading through Griffiths Intro to QM 2nd Ed. and when it comes to bound/scattering states (2.5) they say: $E<0 \implies$ bound state $E>0 \implies$ scattering state Why doesn't this ...
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140 views

Particle in a Box: Energy Less than the Potential Energy

I am reading quantum mechanics from Shankar's Principles of Quantum Mechanics. On page 157 he defines the box potential $V(x)$ as $$ V(x) = \left\{ \begin{array}{rl} 0 &\mbox{ if $|x|< L/2$} ...
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1answer
151 views

Quantum harmonic oscillator solved by analytic method using Schrödinger equation and wave function

I'm having trouble understanding the recursion formula. Using $\xi \equiv \sqrt{m\omega/\hbar}x$ and $K = 2E/\hbar\omega$, the time-independent Schrödinger equation becomes $$\frac{d^2\psi}{d\xi ^2} ...
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Find Equation of Motion given Hamiltonian

So I am given a harmonic oscillator in an electric field. At $t=0$, we are given that the oscillator is in the ground state. The Hamiltonian is: $$H=\hbar \omega[a^{\dagger}a+\frac12+\kappa ...
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1answer
83 views

Why can we leave off half of the general solution?

In these pdf notes, it says at the bottom of the first page and beginning of the second: [...] whose solution is: $$\Psi(\theta) = c_1 e^{i\omega\theta} + c_2 e^{-i\omega\theta}$$ Since we are ...
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1answer
61 views

Correct approach for calculating excited states of circular quantum dot under effective mass approximation

From Asnani, Mahajan et al, Pramana Journal Of Physics 73 #3 (2009) p574-580 "Effective mass theory of a two-dimensional quantum dot in the presence of magnetic field", which can be seen here: ...
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1answer
165 views

Particle Outside the Box

What prohibits, mathematically, that a particle cannot be found outside the box ? Here, I am referring to particle in a box problem (infinite potential on both ends & zero potential along the ...
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Is there only radial motion in the Hydrogen ground state?

The ground state of the Hydrogen atom is spherically symmetric. In other words, the wave function Psi depends only on the distance r of the electron from the nucleus. As a consequence all ...
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1answer
3k views

What is the difference between the Bohr model of the atom and Schrödinger's model?

What is the difference between the Bohr model of the atom and The solution of the Schrödinger equation for the hydrogen atom? Are there any difference between definition of the electric potential ...
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2answers
91 views

System without ground state is not real in nature?

We know that Coulomb force is real phenomena in nature and with Coulomb potential $V(x) \thicksim -\frac{1}{|x|}$ lowest energy is bounded in hydrogen atom. But it's mathematically clear that if ...
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1answer
77 views

Degeneracy in One Dimension

I'm reading this wikipedia article and I'm trying to understand the proof under "Degeneracy in One Dimension". Here's what it says: Considering a one-dimensional quantum system in a potential ...
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163 views

Infinitely many degeneracy of Landau level: Countable or Uncountable?

Description of Landau levels can be found in many standard textbooks of quantum mechanics and here. Two ubiquitous solutions apply either the symmetric gauge $\vec{A}=(-\frac{1}{2}By,\frac{1}{2}Bx,0)$ ...
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3answers
428 views

What does the Schrodinger Equation really mean?

I understand that the Schrodinger equation is actually a principle that cannot be proven. But can someone give a plausible foundation for it and give it some physical meaning/interpretation. I guess ...
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1answer
389 views

What exactly does the Hamiltonian operator tell us?

I'm confused about how energy and time are linked. On the one hand, the Hamiltonian seems to describe the time evolution of the system because in the time dependent Schrodinger equation, $$ \hat H ...
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1answer
55 views

Eigenfunctions for $1s$ hydrogen Schrodinger equation

I am a computer scientist and started my Phd in material science. The second course os my Phd is material simulation by computer. One the task is show the verification of the eigenfunction $1s$ from ...
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1answer
339 views

Am I missing a trick to solving this differential equation?

I was playing around with a 3-D potential $V$ such that $V_{(r)} = 0$ for $r<a$, and $V_{(r)} = V_0$ otherwise. By using the Schrödinger Equation, I showed that: ...
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2answers
78 views

Definite energy states for a single non-relativistic particle with a time dependent potential

Do definite energy states exist for a single particle when its potential itself changes with time? I tried solving it and the equations seem to show that they do not exist. But then i am confused as ...
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34 views

Uncertain if invoking uncertainty principle for wave function is handwaving [duplicate]

Why doesn't the electron collapse onto the proton in a hydrogen atom? One explanation seems to be given by the Heisenberg uncertainty principle, which follows from the purely physical assertion that ...