Partial differential equation which describes the time evolution of the wavefunction of a quantum system. It is one of the first and most fundamental equations of quantum mechanics.

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Why is the position space free particle wavefunction a function of momentum?

This is one of those little things that has always confused me. If someone said to you "in quantum mechanics, the eigenfunctions of a free particle are $\exp(ipx/\hbar)$" how would you know that ...
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1answer
33 views

Infinite Energies of a particle in a rectangular box

For a particle trapped inside a rectangular box of side lengths $l_x$ $l_y$ and $l_z$, the energies are ...
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47 views

Unitary evolution operator

Assume we have a system in a state $\psi$ that is a superposition of eigenvectors of some observable $A$. Now we make a measurement of the observable $A$; the state after the measurement $\phi$ is a ...
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2answers
55 views

Time dependent Hamiltonian and Gauge invariance

In general, in quantum mechanics we can prove probability current or the Schrodinger equation and other quantities are gauge invariant. However, the Hamiltonian isn't gauge invariant. Under a gauge ...
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69 views

Schrödinger Equation [on hold]

Thank you for putting my question on hold. If you will allow me a few days, beyond this weekend, to adequately rephrase the question. I need the time to find a local physicst/math professor to aid ...
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1answer
55 views

Probability of finding particle in infinite square well, displaced walls

Initially a quantum particle moves in a one-dimensional well ($x$-axis) from $-a$ to $ a$, $ V = \infty $ outside and $ V = 0 $ inside the well. So initially, the wave-function $$ \psi_0 = ...
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34 views

Importance of bound states

While solving a potential well problem we get scattering states and bound states (if exist). Number of the bound states we get depends on the potential profile. What I want to ask is, what is the ...
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23 views

How do I find the electron confinement energies in a spherical quantum dot?

So if I've got a spherical quantum dot, we'll say it has a 10nm diameter for simplicity. This dot is a semiconductor and it has an electron with an effective mass altered by a factor of 0.2. How do I ...
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1answer
70 views

Has anyone published the procedure to generalize ladder operators for any potential in Schrodinger's equation?

I know that the ladder operator for the quantum harmonic oscillator \begin{align} H\psi_m = \left(\dfrac{p^2}{2m}+\dfrac{1}{2}m\omega^2x^2\right)\psi_m=E_m\psi_m \end{align} is \begin{align} A = ...
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28 views

s,p,d,f Orbital visualization or simulation? [closed]

So my question is pretty straight forward and in two parts Q.1 I want to simulate the orbitals and visualize them in 3D using real Schrodinger wave function. Since the equation has partial ...
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4answers
409 views

Why aren't orbitals symmetric?

In an hydrogen-like atoms the orbitals are solutions to the Schrodinger equation suitable for the problem. They describe the regions where an electron can be found. So, why don't they have spherical ...
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2answers
59 views

Particle in a one dimensional box conditions

Why does the wave function have to be $C^1(\mathbb{R})$ for a finite square well but not for an infinite square well? For an infinite square well with boundaries at $x=0$ and $x=L$, we have ...
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121 views

Why does the density matrix $\rho$ obey a wrong-signed Heisenberg equation of motion?

The density matrix is defined as $$ \rho_\psi ~:=~ \frac{\lvert\psi(t)\rangle \langle \psi(t)\vert}{ \langle \psi(t) |\psi(t)\rangle }$$ in the Schrödinger picture. $\rho_\psi$ is obviously a time ...
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1answer
44 views

Finding finite square well width and depth from transmission resonance

For an electron incident a one-dimensional finite square well the transmission probability is $\approx$1 for electron energies $E_1=0.6 \textbf{ eV}$, $E_2=1.9 \textbf{ eV}$ and $E_3=3.4 \textbf{ ...
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1answer
303 views

What is a 'turning point' in WKB and why does it fail at that point?

What is meant by a classical turning point in quantum mechanics and why does the WKB approximation fail at that point?
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60 views

Using Maxwell's demon alongside quantum mechanics to contradict 2nd law of thermodynamics

Suppose we have a steady state universe with a gas chamber resembling that of Maxwell's demon that is used to power this hypothetical heat engine as molecules transfer to their respectable sides based ...
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36 views

How to solve infinite square well with exponential solution (of oscillatory type)?

Given a potential well of $V = 0$ on the interval $(0,L)$ and $V = \infty$ outside the well, I am working to solve the Time Independent Schrodinger Equation $$\dfrac{d^2}{dx^2} \psi= ...
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72 views

Why does this resource say that the Schrodinger Equation can be derived? [duplicate]

http://arxiv.org/abs/physics/0610121 If this is true, why do resources say that it cannot be derived? If it isn't true, can someone explain where the above preprint is wrong? I believe that my ...
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57 views

QM: Why is there a minus sign on the Energy operator when using complex conjugate?

I understand how they get the first equation. But I have no idea why there is a minus sign on the second equation: This is from a derivation for the probability density current found here: ...
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1answer
336 views

How to find the time evolution for two-component spinor? [closed]

I would like to find the time evolution for the given Hamiltonian, the initial state of the system we choose two spinor wavefunction $\psi_{+}(t=0)$ and $\psi_{-}(t=0)$ as given below: The effective ...
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2answers
73 views

Why isn't the Time-Independent Schrödinger Equation an equation of motion?

I thought an equation of motion was something where you are given a Lagrangian and, using the Euler-Lagrange equation, you then find the equations of motion for that system. Same basic idea for the ...
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1answer
61 views

Help in solving Schrödinger equation for Hydrogen

I have almost finished getting the solution to the Schrödinger equation for the hydrogen atom (got the theta and phi component equations), but am stuck on the r component equation. Can anyone help me ...
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1answer
47 views

How do I take take the partial derivatives of the general solution to the TDSE for a free particle? [closed]

Consider the general solution to the time-dependent Schrödinger equation for a free particle \begin{align*} \Psi(x,t) &=\frac{1}{\sqrt{2\pi}}\int_{-\infty}^{+\infty} \phi(k) e^{i\left(\hbar ...
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1answer
35 views

Can someone clarify what should and should not be an operator in my verification of the 1D solution to the SE for a free particle?

I just worked out the 1D free particle solution to the Schrödinger equation. My wave function was \begin{equation} \psi(x,t) = Ae^{i(px-Et)/\hbar} \end{equation} So I plugged this into both sides ...
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How do I find the average kinetic energy and average potential energy of a hydrogen electron in the ground state?

In my modern physics class, we are wrapping up the 3D Schrödinger equation, and I am more than a little lost. A few chapters ago, we learned about operators, and I have an equation for both these ...
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4answers
173 views

Derivation of Schrödinger equation - free particle

I learn quantum physics from Alonso-Finn's book (Amazon link), there's one step of Schrödinger equation for a free particle that I couldn't understand. $$ \frac{\mathrm{d^{2}\Psi } }{\mathrm{d} ...
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2answers
334 views

Numerical solution to Schrödinger equation - eigenvalues

This is my first question on here. I'm trying to numerically solve the Schrödinger equation for the Woods-Saxon Potential and find the energy eigenvalues and eigenfunctions but I am confused about how ...
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1answer
125 views

Eigenvalues of the radial Schrödinger equation on a finite integration interval

There are numerous ways to estimate the eigenvalues of a radial Schrödinger equation, see http://arxiv.org/abs/math-ph/0703040 as an example. Anyhow, the formulas only cover the Schrödinger equations ...
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1answer
58 views

Energy levels in close-proximity of each other in time-independent degenerate perturbation theory

I've applied second order time-independent degenerate perturbation theory corrections to the energy with the method presented in Modern Quantum Mechanics by J.J. Sakurai. I shortly summaries this ...
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2answers
36 views

Interaction Hamiltonian in the interaction picutre

The Schrodinger and Heisenberg pictures make sense to me. But the interaction picture which is a hybrid of the two does not. Author of this text first splits the Hamiltonian up as ...
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3answers
164 views

Quantum Mechanincs - Dirac notation and solving time dependant schrodinger [closed]

The $\hat{S}_{x},\hat{S}_{y},\hat{S}_{z}$ obviously correlate to $x,y,z$ components of the operators. Consider the Hamiltonian: $$\hat{H}=C*(\vec{B} \cdot \vec{S})$$ where $C$ is a ...
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1answer
40 views

Centrifugal Term

I'm studying quantum mechanics with Griffiths (2 nd edition) and I have one question related to the Schrodinger equation in spherical coordinates. In the radial equation: ...
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WKB Quantization Condition - negative?

In deriving the quantization condition for a bound state in a potential with "no verticle walls" we start with the WKB connection formulas to find the wavefunction in the interior of the well ...
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41 views

How much time between measurements do you have in order to make the same measurement on a particle?

As I understand it, you can make a measurement on a particle and if you quickly carry out a second measurement you will get the same outcome as the prior measurement. If this is the case, how much ...
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2answers
93 views

How do we know $\psi$ depends on $n,l,m$

Regarding the separation of $\psi$ to an angular and radial part, why does each part have a specific dependence of the quantum numbers? How can Schrodinger equation describe a system just from its ...
6
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2answers
132 views

Triangular barrier in infinite potential well

Suppose I am looking to solve the wavefunction for the following 1D potential: $$U(x) = \begin{cases}V_0\frac{a-|x|}{a}&\quad\text{for}\quad|x|<a ...
2
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0answers
59 views

WKB formula and Langer correction [duplicate]

The general WKB approximation formula states that $$ \int_a^b\sqrt{E_k-V(x)} = (k+1)\pi \text{ with } x \in [a,b] $$ for a regular Schrödinger equation (without the $\hbar$ and such). However, in the ...
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51 views

Solving Schrodinger Equation with Anisotropic Effective Mass

How can I discretize a time-independent Schrodinger equation using the mass tensor and considering the valley degeneracy for the specific material at hand? I intend to investigate the confinement ...
2
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0answers
33 views

How to solve a difficult equation describing large vacuum fluctuations?

Suppose that a Quantum System can be described by the wavefunction $\psi(\vec{x},t)$, but due to the occurence of chaotic noise within the Quantum System, only the "filtered" wavefunction ...
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1answer
91 views

Can I state that $\Psi (x_1, \dots , x_n,t)= \sum_{i=1}^n a_i \psi (x_i,t) $ via superposition?

Given that the hamiltonian $\hat H$ of a system is a linear operator and $\dot \psi (x_i,t)$ does not depend on spatial coordinates $x_1, ..., x_n$ with bases $\hat e_1, ... , \hat e_n$ can I state ...
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1answer
40 views

Probability density function of a particle for computation [closed]

I'm writing a program, part of which relies on a particle being able to change location similar to a how a real particle would behave (pardon my physics). For example, on a grid of 100x100, a ...
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2answers
90 views

Is the formula for Schrodinger's equation on Wikipedia incorrect?

http://en.wikipedia.org/wiki/Schr%C3%B6dinger_equation#Time-dependent_equation On Wikipedia, the SWE contains a term called reduced mass. After consulting several peers, no one knows what this has to ...
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2answers
51 views

What is the purpose of knowing the value of ground state energy of a potential well?

Using the formula $$E ~=~ \frac{\pi^2\hbar^2}{2 m a^2}$$ where $a$ is the length of an infinite potential well. It is apparent that as $a$ get smaller i.e. from a metal to the size of an atom, the ...
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2answers
86 views

Solution to Schrödinger equation

I'm trying to solve the Schrödinger equation for a given potential. With some assumptions I end up with: $$\frac{\hbar^2}{2M}\frac{d^2u(r)}{dr^2} = - \left(E - V(r)\right)u(r)$$ Since it's a square ...
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What kind of potentials can be used in Schrödinger's equation?

I have a couple of questions about what kind of potentials can be used in Schrödinger's equation: How about the potential from a magnetic field? Isn't Dirac's equation more appropriate in that case, ...
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0answers
40 views

Asymptotic Analysis of 1-D Schrödinger Equation [closed]

I'm looking to do a small personal project regarding the time independent Schrödinger equation in 1-D: $$y'' +V(x)y=Ey$$ $$y''=Q(x)y$$ where $ Q(x):=E-V(x) $. There is obviously nothing stopping ...
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2answers
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Can someone clarify which (if any) of these three QM assumptions is wrong?

I am trying to learn more about quantum mechanics. I am reading a book by Griffiths that I like. I'm trying to summarize what I've learned. So below I provided three assumptions. I'd like to know if ...
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50 views

Nodes of the ground state of a system of Schrödinger equations

In 1D, a single wave function that satisfies Schrödinger's equation representing the ground state for some $V(x)$ has no nodes. Suppose now that you have a system of $N\neq 1$ coupled Schrödinger ...
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5answers
257 views

Normalizing the solution to free particle Schrödinger equation

I have the one dimensional free particle Schrödinger equation $$i\hbar \frac{\partial}{\partial t} \Psi (x,t) = -\frac{\hbar^2}{2m} \frac{\partial^2}{\partial x^2} \Psi (x,t), \tag{1}$$ with ...
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Solving the quantum well gives you eigen energies gives $E_n$, are these energies in conduction band or valence band?

I wonder if the energies $E_n$ that is derived from solving the SWE for the quantum well can be considered as energies in the conduction band or the valence band. In other words is $E_1$ is lowest ...