Partial differential equation which describes the time evolution of the wavefunction of a quantum system. It is one of the first and most fundamental equations of quantum mechanics.

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Potential step and exponential decay?

Let us say we have a wave going from a region ($x<0$) where the potential is $U_1$ to a region ($x>0$) where the potential is $U_2$. The wave function in the second region takes the form: ...
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55 views

Naive quantization of Schrödinger field

I just started learning QFT and I was wondering if one is able to quantize the Schrödinger field similar to the way one is able to quantize electromagnetic or elastic mechanical wave modes. E.g. ...
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21 views

Metastable $E=0$ s-wave bound state in a spherical potential well

I am currently dealing with scattering theory. I looked up the scattering on a spherical well potential. $$V(r) = \begin{cases} -V_0 & , r \leq R\\ 0 & ,r > R \end{cases} $$ where ...
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1answer
57 views

Why is the ground state energy of a 2DEG higher compared to the 3DEG?

I am reading something about a 2DEG (2-dimensional electrongas model) and can not understand it. My book says the ground state of the 2DEG is higher compared to a 3DEG because the confinement to 2D ...
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1answer
49 views

What does it mean for a quantum particle to have energy $E_n$? And what is its general normalised state?

In this particular case, I have found the energy to be quantised with energy levels $\frac{h^2n^2}{2m} >0 $ where $n$ is an integer. Suppose a particle has energy $E=\frac{4h^2}{2m}$, then this ...
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Quantum Physics - Step Potential? Don't understand it and how it relates to debroglie wavelength

Ok so I posted a question in the wrong format so it got closed, I hope this one is formatted better. I have a revision question that gives me the total energy of the electron, it then states that the ...
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1answer
48 views

Boundary conditions of the radial Schrodinger equation

Consider the radial differential equation $$\bigg( - \frac{d^2}{dr^2} + \frac{(\ell+\frac{d-3}{2})(\ell+\frac{d-1}{2})}{r^2} + V(r) + m^2 \bigg) \phi_\ell (r) = \lambda\ \phi_\ell (r),$$ which I've ...
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1answer
36 views

Normalizing a wave function in a mixed well

So I got this potential and want to solve for the even wavefunctions http://imgur.com/GKAy4nD Since it's symmetric around the origin I need only to look at the interval [0,b] and solve for the ...
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21 views

Ground State energy as a function of $N$ and $B$, $E_0(N,B)$

The one-particle Hamiltonian is given by: $$\hat{H}=\frac{1}{2m}\left(p+\frac{e}{c}A\right)^2$$ where $p=\hbar\vec{k}$ with $e > 0$ and vector potential $A=(0,x,0)B$, such $B=\triangledown ...
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16 views

Enforcing the exchange criteria for two particles in a box in different states

Suppose you have two identical particles (for simplicity we can think of spin 0 bosons for which are represented as a scalar wave-functions, but fermions have a similar problem) in a 1D box that ...
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1answer
45 views

Applying Schrodinger equation to find the energies of a free electron model in a metal [closed]

The one-particle Hamiltonian is given by $$\hat{H}=\frac{1}{2m}\left(p+\frac{e}{c}A\right)$$ with $e > 0$ and vector potential $A=(0,x,0)B$, such $B=\triangledown \times A=(0,0,B)$ Question: "I ...
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11 views

Periodic Boundary Conditions in 2D Box [duplicate]

In a 2D box with both dimensions of $L$, the electron can move freely within this large box. Use periodic boundary condition, and find the wavefunctions and corresponding energies in this 2D box. I'm ...
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1answer
37 views

How to determine if a potential admits bound states?

According to Griffith's Quantum Mechanics, "$E$ must exceed the minimum value of $V(x)$, for every normalizable solution to the time independent Schroedinger equation" As an example, there is no ...
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95 views

Quantum Mechanics and Economics… What [migrated]

I was reading this paper: http://papers.ssrn.com/sol3/papers.cfm?abstract_id=2002698&download=yes The author has the model presented here: ...
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2answers
89 views

What state does the particle in a box occupy?

My textbook derives the equations for the different energy states $E_n$ of the particle in a box. But my professor in class said this example was a good one because it spoke about the "superposition ...
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3answers
79 views

Spin in Schrodingers Equations

With the usage of Dirac notation we've gotten around a large amount of of inconvenience that would be dealing with spin. But, I was wondering, do we merely do this because it is inconvenient to try ...
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52 views

Is there a physical interpretation of Neumann boundary conditions for the free Schrodinger equation on a domain?

Let $\Omega$ be a domain in $\mathbb{R}^n$. Consider the time-independent free Schrodinger equation $\Delta \psi = E\psi$. Solutions subject to Dirichlet boundary conditions can be physically ...
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33 views

WKB boundary conditions [duplicate]

Technically, this is a math problem but I think it is better here than in the math stacks. Consider the differential equation \begin{equation} y'' = (x^4 - E)y \end{equation} The boundary ...
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2answers
65 views

Why do we not require higher derivatives to match at boundary when solving the Schrödinger equation in a given potential?

When solving the time independent Schrödinger equation for a given potential in 1D, the main part of the solving involves matching boundary conditions. Usually, we require the value and the first ...
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1answer
69 views

Why is probabilty conserved under time evolution of a system in quantum mechanics?

I've studied quantum mechanics to a certain degree, but one question that I've never been able to get a fully satisfactory answer to is why probability is conserved (by this I mean that it has either ...
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1answer
33 views

Use of termination in solving quantum harmonic oscillator, hydrogen atom etc

I can't seem to understand the use of termination to make the series solutions physically acceptable (when solving the linear harmonic oscillator etc.). So what if the series does not terminate, it's ...
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1answer
64 views

Why is the position space free particle wavefunction a function of momentum?

This is one of those little things that has always confused me. If someone said to you "in quantum mechanics, the eigenfunctions of a free particle are $\exp(ipx/\hbar)$" how would you know that ...
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1answer
40 views

Infinite Energies of a particle in a rectangular box

For a particle trapped inside a rectangular box of side lengths $l_x$ $l_y$ and $l_z$, the energies are ...
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52 views

Unitary evolution operator

Assume we have a system in a state $\psi$ that is a superposition of eigenvectors of some observable $A$. Now we make a measurement of the observable $A$; the state after the measurement $\phi$ is a ...
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2answers
82 views

Time dependent Hamiltonian and Gauge invariance

In general, in quantum mechanics we can prove probability current or the Schrodinger equation and other quantities are gauge invariant. However, the Hamiltonian isn't gauge invariant. Under a gauge ...
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1answer
82 views

Probability of finding particle in infinite square well, displaced walls

Initially a quantum particle moves in a one-dimensional well ($x$-axis) from $-a$ to $ a$, $ V = \infty $ outside and $ V = 0 $ inside the well. So initially, the wave-function $$ \psi_0 = ...
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1answer
38 views

Importance of bound states

While solving a potential well problem we get scattering states and bound states (if exist). Number of the bound states we get depends on the potential profile. What I want to ask is, what is the ...
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25 views

How do I find the electron confinement energies in a spherical quantum dot?

So if I've got a spherical quantum dot, we'll say it has a 10nm diameter for simplicity. This dot is a semiconductor and it has an electron with an effective mass altered by a factor of 0.2. How do I ...
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1answer
79 views

Has anyone published the procedure to generalize ladder operators for any potential in Schrodinger's equation?

I know that the ladder operator for the quantum harmonic oscillator \begin{align} H\psi_m = \left(\dfrac{p^2}{2m}+\dfrac{1}{2}m\omega^2x^2\right)\psi_m=E_m\psi_m \end{align} is \begin{align} A = ...
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4answers
425 views

Why aren't orbitals symmetric?

In an hydrogen-like atoms the orbitals are solutions to the Schrodinger equation suitable for the problem. They describe the regions where an electron can be found. So, why don't they have spherical ...
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2answers
65 views

Particle in a one dimensional box conditions

Why does the wave function have to be $C^1(\mathbb{R})$ for a finite square well but not for an infinite square well? For an infinite square well with boundaries at $x=0$ and $x=L$, we have ...
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3answers
144 views

Why does the density matrix $\rho$ obey a wrong-signed Heisenberg equation of motion?

The density matrix is defined as $$ \rho_\psi ~:=~ \frac{\lvert\psi(t)\rangle \langle \psi(t)\vert}{ \langle \psi(t) |\psi(t)\rangle }$$ in the Schrödinger picture. $\rho_\psi$ is obviously a time ...
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1answer
97 views

Finding finite square well width and depth from transmission resonance

For an electron incident a one-dimensional finite square well the transmission probability is $\approx$1 for electron energies $E_1=0.6 \textbf{ eV}$, $E_2=1.9 \textbf{ eV}$ and $E_3=3.4 \textbf{ ...
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1answer
332 views

What is a 'turning point' in WKB and why does it fail at that point?

What is meant by a classical turning point in quantum mechanics and why does the WKB approximation fail at that point?
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63 views

Using Maxwell's demon alongside quantum mechanics to contradict 2nd law of thermodynamics

Suppose we have a steady state universe with a gas chamber resembling that of Maxwell's demon that is used to power this hypothetical heat engine as molecules transfer to their respectable sides based ...
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1answer
42 views

How to solve infinite square well with exponential solution (of oscillatory type)?

Given a potential well of $V = 0$ on the interval $(0,L)$ and $V = \infty$ outside the well, I am working to solve the Time Independent Schrodinger Equation $$\dfrac{d^2}{dx^2} \psi= ...
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1answer
74 views

Why does this resource say that the Schrodinger Equation can be derived? [duplicate]

http://arxiv.org/abs/physics/0610121 If this is true, why do resources say that it cannot be derived? If it isn't true, can someone explain where the above preprint is wrong? I believe that my ...
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1answer
63 views

QM: Why is there a minus sign on the Energy operator when using complex conjugate?

I understand how they get the first equation. But I have no idea why there is a minus sign on the second equation: This is from a derivation for the probability density current found here: ...
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1answer
351 views

How to find the time evolution for two-component spinor? [closed]

I would like to find the time evolution for the given Hamiltonian, the initial state of the system we choose two spinor wavefunction $\psi_{+}(t=0)$ and $\psi_{-}(t=0)$ as given below: The effective ...
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2answers
82 views

Why isn't the Time-Independent Schrödinger Equation an equation of motion?

I thought an equation of motion was something where you are given a Lagrangian and, using the Euler-Lagrange equation, you then find the equations of motion for that system. Same basic idea for the ...
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1answer
67 views

Help in solving Schrödinger equation for Hydrogen

I have almost finished getting the solution to the Schrödinger equation for the hydrogen atom (got the theta and phi component equations), but am stuck on the r component equation. Can anyone help me ...
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1answer
49 views

How do I take take the partial derivatives of the general solution to the TDSE for a free particle? [closed]

Consider the general solution to the time-dependent Schrödinger equation for a free particle \begin{align*} \Psi(x,t) &=\frac{1}{\sqrt{2\pi}}\int_{-\infty}^{+\infty} \phi(k) e^{i\left(\hbar ...
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1answer
36 views

Can someone clarify what should and should not be an operator in my verification of the 1D solution to the SE for a free particle?

I just worked out the 1D free particle solution to the Schrödinger equation. My wave function was \begin{equation} \psi(x,t) = Ae^{i(px-Et)/\hbar} \end{equation} So I plugged this into both sides ...
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1answer
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How do I find the average kinetic energy and average potential energy of a hydrogen electron in the ground state?

In my modern physics class, we are wrapping up the 3D Schrödinger equation, and I am more than a little lost. A few chapters ago, we learned about operators, and I have an equation for both these ...
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4answers
186 views

Derivation of Schrödinger equation - free particle

I learn quantum physics from Alonso-Finn's book (Amazon link), there's one step of Schrödinger equation for a free particle that I couldn't understand. $$ \frac{\mathrm{d^{2}\Psi } }{\mathrm{d} ...
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475 views

Numerical solution to Schrödinger equation - eigenvalues

This is my first question on here. I'm trying to numerically solve the Schrödinger equation for the Woods-Saxon Potential and find the energy eigenvalues and eigenfunctions but I am confused about how ...
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1answer
134 views

Eigenvalues of the radial Schrödinger equation on a finite integration interval

There are numerous ways to estimate the eigenvalues of a radial Schrödinger equation, see http://arxiv.org/abs/math-ph/0703040 as an example. Anyhow, the formulas only cover the Schrödinger equations ...
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1answer
70 views

Energy levels in close-proximity of each other in time-independent degenerate perturbation theory

I've applied second order time-independent degenerate perturbation theory corrections to the energy with the method presented in Modern Quantum Mechanics by J.J. Sakurai. I shortly summaries this ...
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Interaction Hamiltonian in the interaction picutre

The Schrodinger and Heisenberg pictures make sense to me. But the interaction picture which is a hybrid of the two does not. Author of this text first splits the Hamiltonian up as ...
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3answers
183 views

Quantum Mechanincs - Dirac notation and solving time dependant schrodinger [closed]

The $\hat{S}_{x},\hat{S}_{y},\hat{S}_{z}$ obviously correlate to $x,y,z$ components of the operators. Consider the Hamiltonian: $$\hat{H}=C*(\vec{B} \cdot \vec{S})$$ where $C$ is a ...