Partial differential equation which describes the time evolution of the wavefunction of a quantum system. It is one of the first and most fundamental equations of quantum mechanics.

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60 views

Expectation value of Hamiltonian in different pictures of quantum mechanics

We start with the familiar Schrodinger equation: $$ i\hbar \frac{\partial \left|\psi_S\right\rangle}{\partial t} = \hat{H}_S \left|\psi_S\right\rangle $$ As we switch to a different picture than ...
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2answers
99 views

When can we assume that the wavefunction is separable

While working out the stationary states of a single particle in a 3d infinite potential box ($V=0$ inside a cuboid of known dimensions, $V=\infty$ everywhere else), I realized I had to assume the ...
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0answers
23 views

Quantum physics particle in a box [on hold]

A problem I've been given states: Without calculation, write down and explain the energy expectation value $\langle H\rangle$ and the uncertainty $σ_H$ for the $ψ_n$ energy eigenstate of the ...
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2answers
29 views

Schroedinger equation. Mass. Charge

The mass of a particle appears in Schroedinger equation but it does not appear its charge, although both terms have their effect on movement.Why?
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1answer
36 views

Schroedinger equation. Why Potential energy instead of Force?

What is the reason Schroedinger equation is quoted in terms of potential energy instead of force?
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32 views

Quantization of linear momentum in 'particle in a box' problem [on hold]

I am new in Quantum Mechanics. I am 2nd year UG (Physics Major). I had few conceptions to clear.. I was going through particle in a box problem ...So while deriving that we used the time independent ...
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1answer
32 views

Finding the odd parity bound state wave function for a particle in one dimension

Let a particle of mass $m$ and energy $E$ be moving on the $x$-axis in a potential $V(x)$ given by $$V(x)=\left\{\begin{matrix} -V_{0}, & -a<x<a\\ 0, & otherwise \end{matrix}\right.$$ ...
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0answers
40 views

Particle in a 2D box degeneracy [closed]

I'm doing revision for my quantum test next week and my university, irritatingly, doesn't provide mark schemes to past questions. I feel like I've done most of this one right, but the end has thrown ...
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1answer
38 views

Change of variable in harmonic oscillator time independent Schrodinger equation

I was revising the harmonic oscillator for my intro to quantum course and realised I'd sort of accepted a change of variable result without actually being able to get to it. It says: The stationary ...
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0answers
77 views

Solving the Schrodinger equation with appropriate symmetry

In the paper Markov Fields by Edward Nelson the introduction section claims that analytically continuing a Markov process with appropriate symmetry properties yields the solution of the Schrodinger ...
2
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2answers
36 views

How will a particle with energy less than $V_{\rm min}$ behave?

Consider e.g. the finite square well: $V = -V_o$ between $x=-a$ and $x=a$, $V=0$ elsewhere Now for scattering states, $E$ must be $> 0$. For normalizable bound states, $E$ must be $< 0$ and ...
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5answers
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How does the hydrogen atom know which frequencies it can emit photons at?

At university, I was shown the Schrodinger Equation, and how to solve it, including in the $1/r$ potential, modelling the hydrogen atom. And it was then asserted that the differences between the ...
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1answer
40 views

Solving the 1D Schrodinger Equation for a Free Particle - Two Different Methods?

So starting from the time dependent schrodinger equation I perform separation of variables and obtain a time and spatial part. The spatial part is in effect the time independent schrodinger equation. ...
2
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2answers
109 views

Computer simulation of Schrödinger equation [duplicate]

I am looking for a computer program which simulates the Schrödinger equation (say for a single particle) in two dimensions and for potentials and initial states specified by the user. Typical ...
2
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1answer
44 views

Free particle Schrödinger Equation

Some sources give the free-particle solution to Schrödinger equation as $$\psi(x,t) =Ae^{i(kx-\omega t)} + Be^{-i(kx+\omega t)}$$ while some sources give it as $$\psi(x,t) =Ae^{i(kx-\omega t)}$$ ...
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60 views

Free-particle solution to Schrödinger Equation

The free particle solution in stationary state (with definite energy) to the Schrödinger equation is $$\psi(x,t) =Ae^{i(kx-\omega t)} + Be^{-i(kx+\omega t)}$$ Since the energy is definite, and ...
2
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1answer
45 views

Solving the 1-d time-independent Schroedinger's equation with an infinite boundary

In my introductory modern physics class we have examined time-independent solutions to the Schrödinger equation in 1 dimension. We looked at a few cases without finite boundary, e.g., free particles ...
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1answer
36 views

Reflection of an evanescent matter wave within a finite barrier?

To my understanding if I have a finite barrier with potential $V(x)>E$, then to the left of the barrier, the wavefunction can be represented as two exponentials: $$\psi= e^{(ik_{left} x)} + ...
11
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1answer
144 views

Lie group of Schrodinger Wave equation

In Ballentine's book on quantum mechanics (in 3rd chapter), he introduces the symmetry transformation of Galilean group associated with Schrodinger equation. Now the Galilean group as such has 10 ...
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1answer
150 views

Harmonic Oscillator potential, proof that Gaussians remain Gaussians?

I read in several papers that for a Harmonic Oscillator Hamiltonian in the time dependent Schrödinger equation a Gaussian wave packet remains Gaussian. Unfortunately I could not find any proof for ...
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2answers
179 views

The formal solution of the Schrodinger equation

Let's have Schrodinger equation (or some equation in Schrodinger form) $$ \tag 1 i \partial_{0} \Psi ~=~ \hat{H} \Psi . $$ One likes to write that it has formal solution $$ \tag 2 \Psi (t) ~=~ ...
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2answers
52 views

Schrödinger's Equation and its complex conjugate

I would like to know why there is a minus sign on the right-hand side of the Schrödinger's complex conjugate equation, whereas in the Schrödinger's equation there isn't. I know it is a simple ...
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1answer
41 views

Regarding derivation of Probability Current

The question for the full derivation of Probability Conservation -> Probability Current was already asked here: Probability current. I apologize for not retyping it out, but it's already beautifully ...
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4answers
320 views

How to derive Schrödinger equation?

How is the Schrödinger equation $$\frac {\partial }{\partial t}\psi=-\frac {i }{\hbar }H{\psi }$$ being derived?
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52 views

Interesting Harmonic Oscillator Solution

On page 89 of Griffith's QM book, an exact solution to the time-dependent SE equation for the harmonic oscillator is mentioned: $$ ...
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1answer
52 views

Relating Schrödinger's Wave Equation and Heisenberg Uncertainty Principle

A homework question that I don't conceptually understand: A quantum particle of mass M is trapped inside an infinite, one-dimensional square well of width $L$. If we were to solve Schrodinger's wave ...
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235 views

Schrödinger's Equation and the depth of a finite potential well

Before I ask my question, I have to stress: I have absolutely no idea what the math is going on. I've read my textbook, several Wikipedia articles, scoured the internet, and don't feel anymore ...
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2answers
80 views

Box normalisation and Particle in a box - Quantum Mechanics

I have been long itched by this issue of subtle difference between box-normalised free particle and infinite-dimensional potential well. Choosing a one dimensional case, the Hamiltonian in two cases ...
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2answers
365 views

Infinite and Finite Square Wells

For the infinite square well in the first region, outside the well: $$\frac{-\hbar^2}{2m}\frac{d^2 \psi}{dx^2} + V(x) \psi (x) = E \psi (x),$$ where you set $V = 0$. Rearranging gives $$\frac{d^2 ...
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2answers
127 views

Eigenvalue problem for differential equations in QM

I have a very simple question with regard to numerical methods in physics. I want to solve the eigenvalue problem for a particle moving in an arbitrary potential. Let's take 1D to be concrete. I.e. I ...
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1answer
53 views

Is there a closed form expression for Landau-level eigenstates?

Is there a closed form expression for the Landau-level eigenstates (preferably in the symmetric gauge)? This is the 2-dimensional quantum mechanical problem of a charged particle moving in a ...
3
votes
1answer
70 views

weak solution of Schroedinger equation .. are they useful?

We know that Schroedinger equation can be deduced from a variational principle (non relativistic Schroedinger equation). Assuming this I have 2 questions: a) Using variational methods, could we ...
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0answers
53 views

Casimir operator for the $sl(2)$ group [duplicate]

The generators of the $sl(2)$ group can be expressed as: $$J^+ =z\frac{d}{dz}-2jz, \quad J^0=z\frac{d}{dz}-j, \quad J^-=\frac{d}{dz}$$ How would find the Casimir operator for such a group?
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Finding the energy eigenvalues of Hydrogen using WKB approach

I need help to find the energy eigen values of Hydrogen atom using WKB approach. So far I know, the radial equation is given by $$\frac{1}{r^2} \frac{\partial }{\partial r} \left( r^2 \frac{\partial ...
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0answers
73 views

Particle in a higher-dimensional box with an attractive delta potential

Suppose you have a particle in the box $[0,L]^d$, with an attractive Dirac delta potential $-\delta_{\vec w}(x)$ at $\vec w$. How do you solve the Schroedinger equation for this system? In the case ...
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59 views

Philosophical take on Schrodinger's cat paradox

I'm a mathematics undergrad currently doing a module on quantum mechanics. I am interested to delve into the more philosophical aspect of the paradox. Could anyone please give me some introductory ...
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0answers
59 views

Understanding the algebra associated with an implicit potential

In the paper here(page 7-8) the authors make a claim that the Natanzon potential (an implicit potential) follows an $SO(2,2)$ algebra. This potential defined as : $$ U(z(r)) = ...
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2answers
133 views

Harmonic Oscillator - Energy quantisation

The one-dimensional quantum HO can be solved in Schrodinger representation by getting Hermite Differential Equation $$ \frac{d^2y}{dx^2} - 2x \frac{dy}{dx} + \lambda y = 0 $$ with solutions $$ y(x) = ...
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1answer
78 views

Applying the Schroedinger equation

I hope this isn't a dumb question, but... If we have two fixed sine waves, both of which have a frequency range of +1 to -1, with a ratio between the waves of wave(1):3 to wave(2): 1, what does the ...
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1answer
98 views

Determining the group associated with a given potential?

I'm trying to understand how symmetry groups are related to potentials of the Schrodinger equation. In particular, I wish to know if it is possible to find the symmetry group of this potential $$V(x) ...
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2answers
90 views

Infinite well particle subject to additional time dep. potential

I am asked to find the wavefunction of the particle in a well subject to an additional potential $$V(x,t)=\frac{\pi x \hbar}{L}\delta(t).$$ I have already solved that ...
2
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1answer
154 views

How do electrons and photons interact?

Two electrons, or an electron and a proton, interact with each other because of the Coulomb potential, which can also be seen in the Schrödinger equation (which is the equation that describes the ...
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198 views

Non-separable solution for the Schrödinger equation

Schrödinger solutions are usually if not always of the type: $\psi=\operatorname{T}(t)*\operatorname{X}(x)$ (we use the separation of variables method to arrive at the time independent Schroedinger ...
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1answer
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Fixed Angular Momentum

Say I'm given the following Schrodinger equation $$\frac{d^2u}{dx^2}+ \left[E - V(x)+ \frac{a}{x^2}\right]u(x) =0$$ Where $a \in \mathbb{R}$. What are the physical interpretations of this equation? ...
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1answer
83 views

Differential Realizations of certain algebras

I'm a first year graduate student in Mathematical Physics, and I am trying to generalise a certain method involving the so-called "Differential realizations" of certain algebras. The problem I'm ...
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3answers
168 views

Is any time-dependent hydrogen atom Schrödinger equation solvable analytically?

It's well-known that hydrogen atom described by time-independent Schrödinger equation (neglecting any relativistic effects) is completely solvable analytically. But are any initial value problems for ...
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1answer
172 views

Proof of the time-independent Schrödinger equation

I have a question regarding the proof of the time-independent Schrödinger equation. So if we have a time-Independent Hamiltonian, we can solve the Schrödinger equation by adopting separation of ...
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1answer
100 views

TISE for a triangular potential

I want to solve the TISE of a particle of charge $q$ and mass $m$ in a one dimensional triangular potential, with an infinitely high potential wall at $x = 0$, i.e. ...
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2answers
190 views

Solving quantum radial equation for infinite potential spherical annulus for $l=0$

There is a mass $m$ in a potential such that $$ V(r) = \left\{ \begin{array}{lr} 0, & a \leq r \leq b\\ \infty, & \text{everywhere else} \end{array} \right. $$ ...
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1answer
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Change of operator in the Hamiltonian [closed]

We are told that the particle has mass m and charge e and is moving in 2 dimensions. The position operator $\mathbf{X}=(X_{1},X_{2})$ and momentum operator $\mathbf{P}=(P_{1},P_{2})$ We are given ...