Partial differential equation which describes the time evolution of the wavefunction of a quantum system. It is one of the first and most fundamental equations of quantum mechanics.

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Quantum Mechanics and Economics… What

I was reading this paper: http://papers.ssrn.com/sol3/papers.cfm?abstract_id=2002698&download=yes The author has the model presented here: ...
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2answers
65 views

What state does the particle in a box occupy?

My textbook derives the equations for the different energy states $E_n$ of the particle in a box. But my professor in class said this example was a good one because it spoke about the "superposition ...
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3answers
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Spin in Schrodingers Equations

With the usage of Dirac notation we've gotten around a large amount of of inconvenience that would be dealing with spin. But, I was wondering, do we merely do this because it is inconvenient to try ...
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23 views

Is there a physical interpretation of Neumann boundary conditions for the free Schrodinger equation on a domain?

Let $\Omega$ be a domain in $\mathbb{R}^n$. Consider the time-independent free Schrodinger equation $\Delta \psi = E\psi$. Solutions subject to Dirichlet boundary conditions can be physically ...
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24 views

Time dependent and Time Independent Schrödinger Equation [on hold]

What is the meaning of Schrödinger's Time dependent and Time Independent Equation?
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32 views

WKB boundary conditions [duplicate]

Technically, this is a math problem but I think it is better here than in the math stacks. Consider the differential equation \begin{equation} y'' = (x^4 - E)y \end{equation} The boundary ...
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2answers
59 views

Why do we not require higher derivatives to match at boundary when solving the Schrödinger equation in a given potential?

When solving the time independent Schrödinger equation for a given potential in 1D, the main part of the solving involves matching boundary conditions. Usually, we require the value and the first ...
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1answer
67 views

Why is probabilty conserved under time evolution of a system in quantum mechanics?

I've studied quantum mechanics to a certain degree, but one question that I've never been able to get a fully satisfactory answer to is why probability is conserved (by this I mean that it has either ...
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1answer
32 views

Use of termination in solving quantum harmonic oscillator, hydrogen atom etc

I can't seem to understand the use of termination to make the series solutions physically acceptable (when solving the linear harmonic oscillator etc.). So what if the series does not terminate, it's ...
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1answer
51 views

Why is the position space free particle wavefunction a function of momentum?

This is one of those little things that has always confused me. If someone said to you "in quantum mechanics, the eigenfunctions of a free particle are $\exp(ipx/\hbar)$" how would you know that ...
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1answer
37 views

Infinite Energies of a particle in a rectangular box

For a particle trapped inside a rectangular box of side lengths $l_x$ $l_y$ and $l_z$, the energies are ...
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0answers
50 views

Unitary evolution operator

Assume we have a system in a state $\psi$ that is a superposition of eigenvectors of some observable $A$. Now we make a measurement of the observable $A$; the state after the measurement $\phi$ is a ...
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2answers
66 views

Time dependent Hamiltonian and Gauge invariance

In general, in quantum mechanics we can prove probability current or the Schrodinger equation and other quantities are gauge invariant. However, the Hamiltonian isn't gauge invariant. Under a gauge ...
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86 views

Schrödinger Equation [closed]

A stronger Adam replies, "...No Eve Honey! We instead eat the snake!" We can only now do away with Voodoo Physics, if we go back to square one. If an object travels in a circle around a fixed point ...
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1answer
60 views

Probability of finding particle in infinite square well, displaced walls

Initially a quantum particle moves in a one-dimensional well ($x$-axis) from $-a$ to $ a$, $ V = \infty $ outside and $ V = 0 $ inside the well. So initially, the wave-function $$ \psi_0 = ...
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1answer
34 views

Importance of bound states

While solving a potential well problem we get scattering states and bound states (if exist). Number of the bound states we get depends on the potential profile. What I want to ask is, what is the ...
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0answers
24 views

How do I find the electron confinement energies in a spherical quantum dot?

So if I've got a spherical quantum dot, we'll say it has a 10nm diameter for simplicity. This dot is a semiconductor and it has an electron with an effective mass altered by a factor of 0.2. How do I ...
5
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1answer
71 views

Has anyone published the procedure to generalize ladder operators for any potential in Schrodinger's equation?

I know that the ladder operator for the quantum harmonic oscillator \begin{align} H\psi_m = \left(\dfrac{p^2}{2m}+\dfrac{1}{2}m\omega^2x^2\right)\psi_m=E_m\psi_m \end{align} is \begin{align} A = ...
6
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4answers
413 views

Why aren't orbitals symmetric?

In an hydrogen-like atoms the orbitals are solutions to the Schrodinger equation suitable for the problem. They describe the regions where an electron can be found. So, why don't they have spherical ...
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2answers
61 views

Particle in a one dimensional box conditions

Why does the wave function have to be $C^1(\mathbb{R})$ for a finite square well but not for an infinite square well? For an infinite square well with boundaries at $x=0$ and $x=L$, we have ...
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3answers
123 views

Why does the density matrix $\rho$ obey a wrong-signed Heisenberg equation of motion?

The density matrix is defined as $$ \rho_\psi ~:=~ \frac{\lvert\psi(t)\rangle \langle \psi(t)\vert}{ \langle \psi(t) |\psi(t)\rangle }$$ in the Schrödinger picture. $\rho_\psi$ is obviously a time ...
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1answer
46 views

Finding finite square well width and depth from transmission resonance

For an electron incident a one-dimensional finite square well the transmission probability is $\approx$1 for electron energies $E_1=0.6 \textbf{ eV}$, $E_2=1.9 \textbf{ eV}$ and $E_3=3.4 \textbf{ ...
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1answer
311 views

What is a 'turning point' in WKB and why does it fail at that point?

What is meant by a classical turning point in quantum mechanics and why does the WKB approximation fail at that point?
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2answers
62 views

Using Maxwell's demon alongside quantum mechanics to contradict 2nd law of thermodynamics

Suppose we have a steady state universe with a gas chamber resembling that of Maxwell's demon that is used to power this hypothetical heat engine as molecules transfer to their respectable sides based ...
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1answer
37 views

How to solve infinite square well with exponential solution (of oscillatory type)?

Given a potential well of $V = 0$ on the interval $(0,L)$ and $V = \infty$ outside the well, I am working to solve the Time Independent Schrodinger Equation $$\dfrac{d^2}{dx^2} \psi= ...
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1answer
72 views

Why does this resource say that the Schrodinger Equation can be derived? [duplicate]

http://arxiv.org/abs/physics/0610121 If this is true, why do resources say that it cannot be derived? If it isn't true, can someone explain where the above preprint is wrong? I believe that my ...
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1answer
57 views

QM: Why is there a minus sign on the Energy operator when using complex conjugate?

I understand how they get the first equation. But I have no idea why there is a minus sign on the second equation: This is from a derivation for the probability density current found here: ...
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1answer
345 views

How to find the time evolution for two-component spinor? [closed]

I would like to find the time evolution for the given Hamiltonian, the initial state of the system we choose two spinor wavefunction $\psi_{+}(t=0)$ and $\psi_{-}(t=0)$ as given below: The effective ...
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2answers
75 views

Why isn't the Time-Independent Schrödinger Equation an equation of motion?

I thought an equation of motion was something where you are given a Lagrangian and, using the Euler-Lagrange equation, you then find the equations of motion for that system. Same basic idea for the ...
2
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1answer
61 views

Help in solving Schrödinger equation for Hydrogen

I have almost finished getting the solution to the Schrödinger equation for the hydrogen atom (got the theta and phi component equations), but am stuck on the r component equation. Can anyone help me ...
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1answer
47 views

How do I take take the partial derivatives of the general solution to the TDSE for a free particle? [closed]

Consider the general solution to the time-dependent Schrödinger equation for a free particle \begin{align*} \Psi(x,t) &=\frac{1}{\sqrt{2\pi}}\int_{-\infty}^{+\infty} \phi(k) e^{i\left(\hbar ...
2
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1answer
35 views

Can someone clarify what should and should not be an operator in my verification of the 1D solution to the SE for a free particle?

I just worked out the 1D free particle solution to the Schrödinger equation. My wave function was \begin{equation} \psi(x,t) = Ae^{i(px-Et)/\hbar} \end{equation} So I plugged this into both sides ...
0
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1answer
37 views

How do I find the average kinetic energy and average potential energy of a hydrogen electron in the ground state?

In my modern physics class, we are wrapping up the 3D Schrödinger equation, and I am more than a little lost. A few chapters ago, we learned about operators, and I have an equation for both these ...
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4answers
174 views

Derivation of Schrödinger equation - free particle

I learn quantum physics from Alonso-Finn's book (Amazon link), there's one step of Schrödinger equation for a free particle that I couldn't understand. $$ \frac{\mathrm{d^{2}\Psi } }{\mathrm{d} ...
4
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2answers
351 views

Numerical solution to Schrödinger equation - eigenvalues

This is my first question on here. I'm trying to numerically solve the Schrödinger equation for the Woods-Saxon Potential and find the energy eigenvalues and eigenfunctions but I am confused about how ...
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1answer
126 views

Eigenvalues of the radial Schrödinger equation on a finite integration interval

There are numerous ways to estimate the eigenvalues of a radial Schrödinger equation, see http://arxiv.org/abs/math-ph/0703040 as an example. Anyhow, the formulas only cover the Schrödinger equations ...
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1answer
62 views

Energy levels in close-proximity of each other in time-independent degenerate perturbation theory

I've applied second order time-independent degenerate perturbation theory corrections to the energy with the method presented in Modern Quantum Mechanics by J.J. Sakurai. I shortly summaries this ...
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2answers
36 views

Interaction Hamiltonian in the interaction picutre

The Schrodinger and Heisenberg pictures make sense to me. But the interaction picture which is a hybrid of the two does not. Author of this text first splits the Hamiltonian up as ...
2
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3answers
167 views

Quantum Mechanincs - Dirac notation and solving time dependant schrodinger [closed]

The $\hat{S}_{x},\hat{S}_{y},\hat{S}_{z}$ obviously correlate to $x,y,z$ components of the operators. Consider the Hamiltonian: $$\hat{H}=C*(\vec{B} \cdot \vec{S})$$ where $C$ is a ...
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1answer
40 views

Centrifugal Term

I'm studying quantum mechanics with Griffiths (2 nd edition) and I have one question related to the Schrodinger equation in spherical coordinates. In the radial equation: ...
2
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1answer
61 views

WKB Quantization Condition - negative?

In deriving the quantization condition for a bound state in a potential with "no verticle walls" we start with the WKB connection formulas to find the wavefunction in the interior of the well ...
0
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1answer
41 views

How much time between measurements do you have in order to make the same measurement on a particle?

As I understand it, you can make a measurement on a particle and if you quickly carry out a second measurement you will get the same outcome as the prior measurement. If this is the case, how much ...
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2answers
95 views

How do we know $\psi$ depends on $n,l,m$

Regarding the separation of $\psi$ to an angular and radial part, why does each part have a specific dependence of the quantum numbers? How can Schrodinger equation describe a system just from its ...
6
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2answers
143 views

Triangular barrier in infinite potential well

Suppose I am looking to solve the wavefunction for the following 1D potential: $$U(x) = \begin{cases}V_0\frac{a-|x|}{a}&\quad\text{for}\quad|x|<a ...
2
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0answers
59 views

WKB formula and Langer correction [duplicate]

The general WKB approximation formula states that $$ \int_a^b\sqrt{E_k-V(x)} = (k+1)\pi \text{ with } x \in [a,b] $$ for a regular Schrödinger equation (without the $\hbar$ and such). However, in the ...
0
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0answers
54 views

Solving Schrodinger Equation with Anisotropic Effective Mass

How can I discretize a time-independent Schrodinger equation using the mass tensor and considering the valley degeneracy for the specific material at hand? I intend to investigate the confinement ...
2
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0answers
33 views

How to solve a difficult equation describing large vacuum fluctuations?

Suppose that a Quantum System can be described by the wavefunction $\psi(\vec{x},t)$, but due to the occurence of chaotic noise within the Quantum System, only the "filtered" wavefunction ...
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1answer
91 views

Can I state that $\Psi (x_1, \dots , x_n,t)= \sum_{i=1}^n a_i \psi (x_i,t) $ via superposition?

Given that the hamiltonian $\hat H$ of a system is a linear operator and $\dot \psi (x_i,t)$ does not depend on spatial coordinates $x_1, ..., x_n$ with bases $\hat e_1, ... , \hat e_n$ can I state ...
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1answer
44 views

Probability density function of a particle for computation [closed]

I'm writing a program, part of which relies on a particle being able to change location similar to a how a real particle would behave (pardon my physics). For example, on a grid of 100x100, a ...
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2answers
90 views

Is the formula for Schrodinger's equation on Wikipedia incorrect?

http://en.wikipedia.org/wiki/Schr%C3%B6dinger_equation#Time-dependent_equation On Wikipedia, the SWE contains a term called reduced mass. After consulting several peers, no one knows what this has to ...