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4
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1answer
33 views

Laser speckle reduction for integration time of microseconds

How to reduce laser speckle noise for an imaging system that demands integration times of microseconds? I am aware of these two commercial solutions: Optotune laser speckle reducer. It has a ...
2
votes
1answer
56 views

Trace of raman tensors

A raman tensor $\gamma_m$ is defined as the derivative of the polarizability tensor $\alpha$ with respect to a raman mode $Q_m$, so $$ \gamma_m =\frac{\partial\alpha}{\partial Q_m} $$ $\gamma_m$ will ...
1
vote
1answer
37 views

Why are numbers not consistent? (Identifying phonon's frequency)

I am trying to connect several facts between each other to acquire a consistent picture. Fact 1. Monolayers of tungsten disulphide $WS_2$ have hexagonal crystal lattice, and the first Brillouin zone ...
0
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0answers
18 views

How one can count how many phonon modes is there in the crystal?

I'm reading the review on phonon and Raman scattering in 2D transition metal dichalcogenides (2D TMDCs). At the beginning of Section 2.1 it is said that, since there are two X-M-X units in the crystal'...
3
votes
1answer
28 views

Why is a notch filter required for Raman Spectroscopy?

It is my understanding that Raman Spectroscopy uses a notch filter (or sometimes an edge filter) to remove the light from the laser, so only the relevant Raman bands are present. However, if this is ...
0
votes
1answer
36 views

Why does Raman activity depend on polarizability?

Raman spectroscopy essentially records photoluminescence: (source) and a molecule is considered to be Raman active when there is a change of polarizability $\alpha$ (where $\mathbf{P}=\alpha \mathbf{...
1
vote
1answer
33 views

Why hydrofluoric acid (HF) has two Raman bands?

Hydrofluoric acid (HF) is a diatomic molecule with only one vibrational coordinate. Therefore I would expect only one Raman band, however there are two. Why? (source)
0
votes
0answers
16 views

How do I determine the stacking order of Bilayer Graphene from a Raman scan?

I have high-purity samples of exfoliated bilayer graphene on SiO2. I get raman scans with four clearly differentiated Lorentzians in the 2D peak. Similar to http://users.aalto.fi/~mtomi/jssfig2.png (...
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0answers
14 views

Whether raman spectroscopy is dependent on crystallographic orientation

If I have three bars of Si, and each has the (100) (110) and (111) surface pointing up at the laser respectively, will I get a different raman spectra for each of them? In my opinion, I shouldn't ...
0
votes
0answers
14 views

Reason for the difference between Photoluminescence and RAMAN widths

I am measuring the Photoluminescence and RAMAN spectra of a few samples but am unable to understand one thing, why are the width of the photoluminescence bulges so broad while the width of the RAMAN ...
2
votes
0answers
28 views

What is the origin of the naming convention for the various branches in vibration-rotational spectroscopy?

In vibration-rotational spectroscopy, the different spectral lines are grouped into branches for different changes in the total angular momentum, i.e. $$ \begin{array}{rrrrrr} & \mathrm{O} & \...
16
votes
4answers
3k views

Why can't I see the blue color scattered by the lower atmosphere of the earth?

I understand that the blue colour of the sky is because of the scattering of blue light by molecules in earth's atmosphere. The scattering appears to be happening from molecules that are far above in ...
0
votes
1answer
43 views

Calculate complete function from imaginary part in raman response

When I want to calculate the raman response function $R$ from the molecular responses $g_a$ and $g_b$, I have to use the functions $$g_n(\Omega) = 2\gamma f_r\text{Im}\left[\tilde{R}_n\left(\Omega\...
0
votes
0answers
38 views

Deconvoluting Raman spectras from different wavelengths

I am using a laser source that is wider than typical laser source for Raman spectroscopy. This mean that the full width at half maximum (FWHM) of the laser is about 5-10 nm, compared to the normal 1-3 ...
3
votes
1answer
187 views

How to deal with coma and oblique spherical aberration in a Czerny Turner configuration?

I am modelling my own spectrometer using Zemax when all of a sudden I've been told that: even if you manage to optimize the angles or positions of the grating and the mirrors, you won't get good ...
3
votes
1answer
1k views

What are the purposes of slits inside a spectrometer (Czerny-Turner)?

I am building a Raman spectrometer with a Czerny Turner configuration (with RamanPi). Why does the light source (A) appear to be converging into the entrance slit (B)? When a sample is excited by a ...
0
votes
1answer
264 views

What is the relationship between Raman peaks and phonon vibration modes?

I've seen Raman spectra, such as here, where peaks at certain wavenumbers were identified with phonon vibration modes (TO, LO, TA, LA). What is the relationship behind this, and how could I make such ...
0
votes
1answer
461 views

What is harmonic and fundamental bands in IR spectroscopy?

What is harmonic and fundamental bands in IR spectroscopy? I'm trying to find exact definitions. I guess that fundamental is $1\leftarrow 0$ transition (the most intense and energetic) and harmonic ...
0
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0answers
34 views

Raman amplification

Recently I read a bit about Raman amplification. Unfortunately, I did not understand everything. As far as I understood the resulting wavelength only depends on the pumping wavelength. Now I heard on ...
2
votes
1answer
1k views

What is a virtual state?

In quantum mechanics / Raman spectroscopy, what is a virtual state? What is the difference between a virtual state and a superposition of states? Can you simply think of the virtual state as a ...
3
votes
0answers
65 views

Quantum description of Raman effect

In the classical description of Raman effect the object of study is the electric polarizability of the system. Since I'm interested in learning the quantum description of the Raman effect and in ...
1
vote
1answer
29 views

Do the characteristic vibrational modes of a material define how much will a material heat up upon radiation excitation?

Do, and if yes how, does the intensity and energy of the Raman modes of a material make it to heat more by radiation excitation. I see phonons and vibrations of the lattice as heat, but maybe I'm ...
1
vote
1answer
96 views

Usage of the terms Raman, Stokes and anti-Stokes scattering

I am confused over the correct usage of the terminology for "Raman scattering", "Stokes scattering", "anti-Stokes scattering", or even "Stokes-Raman scattering" and "anti-Stokes-Raman scattering". Is ...
2
votes
1answer
34 views

CARS microscopy

I have probably very naive question. In case of CARS microscopy http://en.wikipedia.org/wiki/Coherent_anti-Stokes_Raman_spectroscopy we have $ω_{pr}+ω_{p}-ω_{S}$, how can we have minus $ω_S$? In ...
3
votes
4answers
729 views

What's the difference between Raman scattering and second harmonic generation in crystal?

As far as I know, the Raman scattering is from the stokes and anti-stokes scattering that the laser light interact with molecular vibrations. So we know that ""laser light interact with molecular ...
2
votes
1answer
196 views

Phonon scattering process in raman spectroscopy

I am trying to understand diagrams that involve showing phonon scattering processes that contribute to raman spectroscopy peaks. For example, I drew the one at the bottom of this post. This is ...
0
votes
0answers
240 views

Looking for raw interferogram data / raw FID data from FT-IR / FT-NIR / FT-NMR

I'm trying to get my hands on some raw interferogram data / raw FID data from an FT-IR / FT-NIR / FT-NMR so I can run some tests using FFT with it (it needs to be real data). Here's a picture below of ...
1
vote
1answer
113 views

What happens to the $2\pi$ factor when calculating Raman-shifts in units of wavenumbers?

So from the classical theory, you find a formula for a dipole in a planar electromagnetic wave, where there will be two cosine terms with a frequency (actually angular velocity in $[rad/s]$, as the ...
2
votes
0answers
95 views

Are metal modes mixed with molecular modes during surface enhanced Raman effect?

This question is dedicated to Martin Fleischmann (1927-2012). When a molecule is adsorbed on a metal surface, the Raman scattering amplitude from the molecule is enhanced. According to Wikipedia, the ...