Quantum mechanics describes the microscopic properties of nature in a regime where classical mechanics no longer applies. It explains phenomena such as the wave-particle duality, quantization of energy and the uncertainty principle and is generally used in single body systems. Use the ...

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Expression of density operator

States in Quantum Mechanics can be thought of as density operators, i.e., positive semi-definite, normalized trace class operators on a Hilbert Space $\mathcal{H}$. In the case ...
2
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0answers
34 views

Are there resources for simulating and/or theoretically describing solitons?

Recently there are striking new ideas emerging on "lower level" dynamics with respect to quantum mechanics involving fluid mechanics principles, including hints of soliton-like aspects to particle ...
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33 views

Variational principle proof (summing over $n$)

From http://en.wikipedia.org/wiki/Variational_method_%28quantum_mechanics%29 $$= \sum_n \sum_m c_n^*c_mE_m \langle \psi_n|\psi_m \rangle$$ $$= \sum_n |c_n|^2E_n$$ I just want to better understand ...
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5answers
257 views

Why do we need a wave function?

Assuming our only aim is to solve double slit experiment (or other problems that can be mapped into that). Knowing that electron does some strange thing not expected of a particle, we need a function ...
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1answer
53 views

Are all properties entangled when one property is entangled?

When one or more particles are quantum entangled by say their spin property, do their other measurable properties (e.g., momentum, polarization, whatever?) become entangled as well?
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26 views

Wigner $d$-matrix for $j=1$

In Sakurai's Modern Quantum Mechanics p.198-199, he states that for the matrix $$J_y^{(j=1)} = \frac{J_+-J_-}{2i} = \frac{\hbar}{2} \begin{pmatrix} 0 & -\sqrt{2}i & 0 \\ \sqrt{2}i & 0 ...
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3answers
133 views

How does independence of two systems follows from the fact that they are both completely described?

A quote from Landau & Lifshitz (Quantum Mechanics - Non-relativistic Theory, §2): "Let us consider a system composed of two parts, and suppose that the state of this system is given in such a way ...
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2answers
302 views

Can expectation value be imaginary?

I was solving a problem and the result of the expectation value of an operator came out to be $-\frac{\hbar}{4}$ $i$. Is this result possible? It seems counter intuitive.
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2answers
81 views

How do probabilities emerge in the many-worlds interpretation?

My understanding is that at each quantized unit of time that a split occurs, every possible recombination of particles occurs in the 'objective' universe. If this is the case, what relevance to ...
3
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4answers
275 views

Does $\lvert\langle p\lvert\psi\rangle\rvert^2$ have any meaning at all?

I used to think $\lvert\langle p\lvert\psi\rangle\rvert^2$ had the meaning of some likelihood of the particle's momentum being $p$ (within some tolerance interval $\Delta p$). Now I'm just confused. ...
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0answers
16 views

Energy conservation if photon absorbed below resonance

Suppose I have some quantum system (like atom) with excitation energy $E_{exc}$ which is homogeneously broadened due to finite lifetime. I shine light with narrow spectrum centred around energy ...
4
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1answer
81 views

What exactly happens at the second-order phase transition of the 2D Toric code?

For a 2D Toric code specified by $$H = -J_s\sum_{s} \prod_{j\in s} \sigma^x_j - J_p\sum_{p} \prod_{j\in p} \sigma^z_p - h_x\sum_{l} \sigma^x_l - h_z\sum_{l} \sigma^z_l$$ where $s$ denotes stars, $p$ ...
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2answers
44 views

What kind of potentials can be used in Schrödinger's equation?

I have a couple of questions about what kind of potentials can be used in Schrödinger's equation: How about the potential from a magnetic field? Isn't Dirac's equation more appropriate in that case, ...
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0answers
19 views

Selection rules for iodine

I try to find some selections rules for the electrionic transitions. I know the Wigner Eckart theorem an the dipole approximation. With that it's easy to find some selections rules for hydrogen. But ...
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2answers
71 views

Calulate the eigenvalues and the possible states after measurement [on hold]

An observable is given by $$\sum\limits_{n= 1}^N a_n|a_n\rangle\langle a_n | $$ Here $\langle a_n |a_m\rangle = \delta_{nm}$. What are the possible measurement results corresponding to the operator ...
2
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0answers
33 views

Asymptotic Analysis of 1-D Schrödinger Equation [closed]

I'm looking to do a small personal project regarding the time independent Schrödinger equation in 1-D: $$y'' +V(x)y=Ey$$ $$y''=Q(x)y$$ where $ Q(x):=E-V(x) $. There is obviously nothing stopping ...
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2answers
65 views

Can someone clarify which (if any) of these three QM assumptions is wrong?

I am trying to learn more about quantum mechanics. I am reading a book by Griffiths that I like. I'm trying to summarize what I've learned. So below I provided three assumptions. I'd like to know if ...
2
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1answer
80 views

Is the Hilbert space spanned by both bound and continuous hydrogen atom eigenfunctions?

As e.g. Griffiths says (p. 103, Introduction to Quantum Mechanics, 2nd ed.), if a spectrum of a linear operator is continuous, the eigenfunctions are not normalizable, therefore it has no ...
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1answer
41 views

Variational Principle to find Energy Eigenfunctions

In Quantum Mechanics one can estimate an upper bound for the ground state energy with the following functional: $$\mathcal{F}[\psi(x)] \equiv \int_{-\infty}^\infty \psi^*(x)\hat{H}\psi(x) \,\, dx ...
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0answers
17 views

normal degeneracy and the “span” of an irreducible representation

In Tinkham's "Group Theory and Quantum Mechanics", Tinkham defines normal degeneracy so that the span of the action of the Hamiltonian's symmetry group on any energy eigenstate yields all possible ...
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1answer
56 views

Bell's original inequality in "Speakable and Unspeakable in Quantum Mechanics

I'm having difficulty in understanding the setting for the derivation of Bell's inequality. The passage which sets the context below is from the beginning of the second essay in "Speakable and ...
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1answer
38 views

Cayley's expansion

Is Cayley's expansion $$\exp(-iH\delta t) \psi(x,t)=\frac{1-\frac{i\delta t}{2}H}{1+\frac{i\delta t}{2}H}\psi(x,t)$$ valid for any operator $H$? What conditions should $H$ fulfill?
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1answer
70 views

Contructive Proof of 2nd Quantization form of Operators

Is there a constructive proof for these forms of operators in second quantization $$R= \sum \limits_a \sum \limits_b \langle a | R_1 | b \rangle C_a^\dagger C_b $$ using the general form $R = \sum ...
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0answers
59 views

About long range entanglement [closed]

“topologically non-trivial” ground states have long-range entanglement. Is this possible to process the quantum information with help of the studies in topological non-trivial ground states for ...
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3answers
100 views

QM rotation operator

I have seen the proof that for fermions a rotation of $2 \pi$ does not return a spin angular momentum eigenstate to its original form, but instead multiplies the wavefunction by $-1$. Here is an ...
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2answers
125 views

Fock Space and fermionic annihilation & creation operators

I have been trying very hard to understand, I am reading Ballentine's book on this topic, but I need help: I realized that I don't understand how many particle states work with the creation & ...
4
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1answer
137 views

How do I show that a given Hamiltonian does not affect the overall number of particles in a given state?

I'm struggling with the following problem: Consider a system of an arbitrary number of indistinguishable bosonic particles. The system has two sites and $a_i^{\dagger}$ and $a_i$ are the ...
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1answer
43 views

Relation between number of photons and energy?

Please can anyone explain it. If number of photons are increased will it increase the providing energy. Suppose, we are sending a limited number of photons each carrying energy. We have a energy ...
5
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1answer
80 views

Complete derivation of generator of rotations

I have been look all across the internet and every book I could find trying to get a full derivation of the generator of rotations and more specifically angular momentum as a generator of rotations. I ...
5
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2answers
81 views

When does Pauli's exclusion principle kick in?

Imagine that I prepare a fermion in the $\left|\uparrow \right\rangle$ state and a second one far away in the $\left|\downarrow \right\rangle$ state and set them in a path for collision. According to ...
4
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6answers
517 views

Explanation for the EPR-like paradox

I am trying to understand the process of Quantum Entanglement for use in Quantum computers. The problem I have is this: Suppose some nuclear process emits an electron-positron pair. Now after ...
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0answers
22 views

How to understand the Bose glass phase has infinite superfluid susceptibility?

The Bose glass phase is characterized by a gapless excitation spectrum, exponential decay of superfluid correlations, finite compressibility and infinite superfluid susceptibility. The disordered ...
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2answers
88 views

What Planck units are limits?

Some Planck units, like time, length, or temperature, describe a physical maximum or minimum, at least approximately: you can't get hotter than the Planck temperature, measure anything smaller than ...
-2
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2answers
80 views

If a theory gets two predictions right, how likely it is that the rest of the predictions are true too? [closed]

The question lucidly defines what I am trying to inquire, so there is no need to elucidate it any further. Another question would be, General/Special Relativity has gotten some predictions right as ...
0
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1answer
57 views

Calculate the approximate number of conduction electrons

So i have the following problem: A cube of gold 0.1 meters on an edge, calculate the approximate number of conduction electrons whose energies lie in the range from 4.0 ev to 4.025 ev. But I'm not ...
0
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2answers
75 views

What is the necessity of wave packet in studying matter wave?

I am new to this realm of physics. I have literally understood the matter wave, wave function; read the trapped electron in an infinite potential-well. But what I didn't understand is the concept of ...
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0answers
67 views

How is the average particle density defined in condensed matter physics?

I am reading a script where average density is defined as: $n(\vec x) = \langle \hat \rho(\vec x) \rangle = \langle {\hat \Psi^\dagger(\vec x)} \hat \Psi(\vec x) \rangle$ which i absolutely don't ...
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1answer
43 views

Electron-Hole Spin Exchange Interaction

I am stuck with this seemingly "simple" Hamiltonian. I am dealing with an exchange term of a Hamiltonian for two different spin species: $$H_\text{exchange} = - \lambda J \cdot S = ...
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0answers
16 views

Stationary Perturbation Theory

We write first order correction in the wavefunction as a linear sum of eigenstates of unperturbed hamiltonian. Why is this possible?
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19 views

Why is the potential minimum of a molecule shifted towards greater nucleii separation for excited electron states?

I know it has to do with symmetry of the wave function, but I am having trouble piecing it all together. For a positive H ion we have a symmetric wave function $\psi_{+}$, which base functions ...
0
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0answers
39 views

Nodes of the ground state of a system of Schrödinger equations

In 1D, a single wave function that satisfies Schrödinger's equation representing the ground state for some $V(x)$ has no nodes. Suppose now that you have a system of $N\neq 1$ coupled Schrödinger ...
1
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5answers
154 views

Normalizing the solution to free particle Schrödinger equation

I have the one dimensional free particle Schrödinger equation $$i\hbar \frac{\partial}{\partial t} \Psi (x,t) = -\frac{\hbar^2}{2m} \frac{\partial^2}{\partial x^2} \Psi (x,t), \tag{1}$$ with ...
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0answers
28 views

grand-canonical ensemble

I was wondering if the following reasoning is correct for example for electrons in the classical or qm grand-canonical ensemble? Is it always valid in the grandcanonical ensemble to calculate the ...
1
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2answers
54 views

Half-integer spin and infinitesimal rotations

On p. 692 of 'Quantum Mechanics' by Cohen-Tannoudji, he states that: Every finite rotation can be decomposed into an infinite number of infinitesimal rotations, since the angle of rotation can ...
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0answers
41 views

Is special theory of relativity compatible with quantum mechanics? [duplicate]

Is special theory of relativity compatible with quantum mechanics? If yes, which is a good starting book which deals with this ? "Bird is bird. Knife is knife. Death is death." So special theory of ...
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1answer
41 views

Energy uncertainty in a general state

Suppose we have a hamiltonian H and two of it's eigen states. $H\psi_1 = E_1\psi_1$ and $H\psi_2 = E_2\psi_2$. Now what's the uncertainty of energy in the state $\psi_1 + \psi_2$. $$ \Delta E = ...
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1answer
46 views

Find the energy eigen value given wave function

I'm given the ground state wave function $\psi(x)=A\operatorname{sech}(bx)$. Potential is not given but told that it goes to 0 at $\infty$. How to find the eigen value of energy in this state? My ...
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2answers
47 views

What is the correct way to treat operators that has “time” in QM? [duplicate]

I don't know if this question has already been resolved but considering that $i\hbar\partial_t$ is the energy operator, and $\partial^2_t$ is the waves operator (or helmholtz), I can't accept that $t$ ...
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2answers
103 views

What is the expectation value of the position times momentum operator?

Should I write the expectation of the position times momentum operator as: $$\langle xp\rangle = \langle \psi|x (-i\hbar \partial_x) |\psi \rangle$$ or $$\langle xp\rangle = \langle \psi| (-i\hbar ...
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0answers
31 views

How to apply Wick's theorem in 2nd quantization for Spin Density Operators?

I am trying to work out a correlation function consisting of two spin density operators. Once I rewrite everything in 2nd quantized form, I am unsure of how to apply wicks theorem because the paul ...